Hyeon-Ju Kim

By Albert S. Kim and Heyon‐Ju Kim

In this chapter, we briefly review the thermodynamic ensembles and associated energy functions using the seven thermodynamic variables. The energy E, the entropy S, and the system volume V are used to derive the temperature T and pressure P. The chemical potential μ is derived as the change of the system energy with respect to the number of matters N in the isobaric‐isothermal environment. A dilute solution is defined as a homogeneous mixture of solvent and inert solutes, where the total number and volume of solutes are much smaller than those of the solvent. Gibbs free energy of the dilute solution is used to rigorously derive the osmotic pressure by equilibrating chemical potentials of solutes and solvent. Nonequilibrium of the filtration systems is reviewed by introducing the irreversible thermodynamic model with Onsager’s reciprocal theorem. Direct applications of the irreversible thermodynamic model are currently limited due to the absence of the exact nonequilibrium statistical mechanics. We hope this chapter, containing a review of statistical mechanics, related to membrane separations and osmosis phenomena, helps researchers and especially graduate students, who seek an in‐depth understanding of membrane separation from the theoretical statistical physics as applied to chemical and environmental engineering.

Part of the book: Desalination

By Hosaeng Lee, Seungtaek Lim, Jungin Yoon and Hyeonju Kim

The ocean thermal energy conversion (OTEC) plant is designed to improve the efficiency of the existing plants. Various researches are being conducted to increase the plant’s efficiency and output with the use of an enhancer, and studies for performance improvement are also in progress from the Kalina and Uehara cycles to ejector pump OTEC (EP-OTEC). Their performance can be improved by increasing the evaporation pressure using an unused heat source and reducing the heat consumption using a reheating system and a regenerator. In the case of EP-OTEC, an ejector is installed near the turbine-exit to reduce the pressure and therefore increase the power output. In simulations and experiments conducted in this study, EP-OTEC showed 38% efficiency improvement from the basic cycle, which is due to the power output volume increase. The optimum ratio was derived by adjusting the pressure ratio. The demonstration plant to be developed in the future is expected to be applied to the high-efficiency OTEC demonstration plant with improved performance, and new technologies will be continuously developed considering economics and commercial viability.

Part of the book: Ocean Thermal Energy Conversion (OTEC)

By Michael G. Petterson and Hyeon Ju Kim

The deployment of a land-based Ocean Thermal Energy Conversion (OTEC) plant in South Tarawa, Kiribati, Pacific Islands Region, in 2020/2021, represents a major technical achievement, alongside an international development opportunity. Pacific Small Island Developing States (PSIDS) are archipelago nations with small land areas and large oceanic exclusive economic zones. Geographical isolation and large transport distances make economic development a challenge. A lack of affordable and reliable energy in many PSIDS is a development inhibitor. PSIDS are situated within the areas of highest ocean thermal potential in the world. Temperature differences between surface and 1 km depth waters, are in excess of 24°C. Regional geology and tectonics allow access to deeper, colder, waters within few kilometres of many shorelines, and close to market. Seawater Utilization technologies can catalyse varied industrial development (e.g., fresh water/aquaculture/agriculture/mineral salts). The KRISO (Korean Research Institute of Ships and Ocean Engineering)-Government of Kiribati OTEC partnership is already 7 years old (2013–2020) and has involved extensive negotiations, awareness raising programmes, and inclusive collaboration. The project will test OTEC technologies and explore a range development opportunities for Kiribati. The programme could become a role model for the application of the concept of ‘Interconnected Geoscience’.

Part of the book: Ocean Thermal Energy Conversion (OTEC)