Behavioral change: skill vs. areas of interest.
\\n\\n
IntechOpen was founded by scientists, for scientists, in order to make book publishing accessible around the globe. Over the last two decades, this has driven Open Access (OA) book publishing whilst levelling the playing field for global academics. Through our innovative publishing model and the support of the research community, we have now published over 5,700 Open Access books and are visited online by over three million academics every month. These researchers are increasingly working in broad technology-based subjects, driving multidisciplinary academic endeavours into human health, environment, and technology.
\\n\\nBy listening to our community, and in order to serve these rapidly growing areas which lie at the core of IntechOpen's expertise, we are launching a portfolio of Open Science journals:
\\n\\nAll three journals will publish under an Open Access model and embrace Open Science policies to help support the changing needs of academics in these fast-moving research areas. There will be direct links to preprint servers and data repositories, allowing full reproducibility and rapid dissemination of published papers to help accelerate the pace of research. Each journal has renowned Editors in Chief who will work alongside a global Editorial Board, delivering robust single-blind peer review. Supported by our internal editorial teams, this will ensure our authors will receive a quick, user-friendly, and personalised publishing experience.
\\n\\n"By launching our journals portfolio we are introducing new, dedicated homes for interdisciplinary technology-focused researchers to publish their work, whilst embracing Open Science and creating a unique global home for academics to disseminate their work. We are taking a leap toward Open Science continuing and expanding our fundamental commitment to openly sharing scientific research across the world, making it available for the benefit of all." Dr. Sara Uhac, IntechOpen CEO
\\n\\n"Our aim is to promote and create better science for a better world by increasing access to information and the latest scientific developments to all scientists, innovators, entrepreneurs and students and give them the opportunity to learn, observe and contribute to knowledge creation. Open Science promotes a swifter path from research to innovation to produce new products and services." Alex Lazinica, IntechOpen founder
\\n\\nIn conclusion, Natalia Reinic Babic, Head of Journal Publishing and Open Science at IntechOpen adds:
\\n\\n“On behalf of the journal team I’d like to thank all our Editors in Chief, Editorial Boards, internal supporting teams, and our scientific community for their continuous support in making this portfolio a reality - we couldn’t have done it without you! With your support in place, we are confident these journals will become as impactful and successful as our book publishing program and bring us closer to a more open (science) future.”
\\n\\nWe invite you to visit the journals homepage and learn more about the journal’s Editorial Boards, scope and vision as all three journals are now open for submissions.
\\n\\nFeel free to share this news on social media and help us mark this memorable moment!
\\n\\n\\n"}]',published:!0,mainMedia:{caption:"",originalUrl:"/media/original/237"}},components:[{type:"htmlEditorComponent",content:'
After years of being acknowledged as the world's leading publisher of Open Access books, today, we are proud to announce we’ve successfully launched a portfolio of Open Science journals covering rapidly expanding areas of interdisciplinary research.
\n\n\n\nIntechOpen was founded by scientists, for scientists, in order to make book publishing accessible around the globe. Over the last two decades, this has driven Open Access (OA) book publishing whilst levelling the playing field for global academics. Through our innovative publishing model and the support of the research community, we have now published over 5,700 Open Access books and are visited online by over three million academics every month. These researchers are increasingly working in broad technology-based subjects, driving multidisciplinary academic endeavours into human health, environment, and technology.
\n\nBy listening to our community, and in order to serve these rapidly growing areas which lie at the core of IntechOpen's expertise, we are launching a portfolio of Open Science journals:
\n\nAll three journals will publish under an Open Access model and embrace Open Science policies to help support the changing needs of academics in these fast-moving research areas. There will be direct links to preprint servers and data repositories, allowing full reproducibility and rapid dissemination of published papers to help accelerate the pace of research. Each journal has renowned Editors in Chief who will work alongside a global Editorial Board, delivering robust single-blind peer review. Supported by our internal editorial teams, this will ensure our authors will receive a quick, user-friendly, and personalised publishing experience.
\n\n"By launching our journals portfolio we are introducing new, dedicated homes for interdisciplinary technology-focused researchers to publish their work, whilst embracing Open Science and creating a unique global home for academics to disseminate their work. We are taking a leap toward Open Science continuing and expanding our fundamental commitment to openly sharing scientific research across the world, making it available for the benefit of all." Dr. Sara Uhac, IntechOpen CEO
\n\n"Our aim is to promote and create better science for a better world by increasing access to information and the latest scientific developments to all scientists, innovators, entrepreneurs and students and give them the opportunity to learn, observe and contribute to knowledge creation. Open Science promotes a swifter path from research to innovation to produce new products and services." Alex Lazinica, IntechOpen founder
\n\nIn conclusion, Natalia Reinic Babic, Head of Journal Publishing and Open Science at IntechOpen adds:
\n\n“On behalf of the journal team I’d like to thank all our Editors in Chief, Editorial Boards, internal supporting teams, and our scientific community for their continuous support in making this portfolio a reality - we couldn’t have done it without you! With your support in place, we are confident these journals will become as impactful and successful as our book publishing program and bring us closer to a more open (science) future.”
\n\nWe invite you to visit the journals homepage and learn more about the journal’s Editorial Boards, scope and vision as all three journals are now open for submissions.
\n\nFeel free to share this news on social media and help us mark this memorable moment!
\n\n\n'}],latestNews:[{slug:"webinar-introduction-to-open-science-wednesday-18-may-1-pm-cest-20220518",title:"Webinar: Introduction to Open Science | Wednesday 18 May, 1 PM CEST"},{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"},{slug:"introducing-intechopen-book-series-a-new-publishing-format-for-oa-books-20210915",title:"Introducing IntechOpen Book Series - A New Publishing Format for OA Books"}]},book:{item:{type:"book",id:"75",leadTitle:null,fullTitle:"Advances in Analog Circuits",title:"Advances in Analog Circuits",subtitle:null,reviewType:"peer-reviewed",abstract:"This book highlights key design issues and challenges to guarantee the development of successful applications of analog circuits. Researchers around the world share acquired experience and insights to develop advances in analog circuit design, modeling and simulation. The key contributions of the sixteen chapters focus on recent advances in analog circuits to accomplish academic or industrial target specifications.",isbn:null,printIsbn:"978-953-307-323-1",pdfIsbn:"978-953-51-5982-7",doi:"10.5772/607",price:139,priceEur:155,priceUsd:179,slug:"advances-in-analog-circuits",numberOfPages:382,isOpenForSubmission:!1,isInWos:null,isInBkci:!1,hash:null,bookSignature:"Esteban Tlelo-Cuautle",publishedDate:"February 2nd 2011",coverURL:"https://cdn.intechopen.com/books/images_new/75.jpg",numberOfDownloads:46397,numberOfWosCitations:42,numberOfCrossrefCitations:17,numberOfCrossrefCitationsByBook:10,numberOfDimensionsCitations:26,numberOfDimensionsCitationsByBook:8,hasAltmetrics:0,numberOfTotalCitations:85,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"May 18th 2010",dateEndSecondStepPublish:"June 15th 2010",dateEndThirdStepPublish:"September 20th 2010",dateEndFourthStepPublish:"November 19th 2010",dateEndFifthStepPublish:"February 2nd 2011",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6,7",editedByType:"Edited by",kuFlag:!1,featuredMarkup:null,editors:[{id:"17479",title:"Dr.",name:"Esteban",middleName:null,surname:"Tlelo-Cuautle",slug:"esteban-tlelo-cuautle",fullName:"Esteban Tlelo-Cuautle",profilePictureURL:"https://mts.intechopen.com/storage/users/17479/images/101_n.jpg",biography:"Esteban Tlelo-Cuautle received a B.Sc. degree from Instituto Tecnológico de Puebla in 1993. He then received both M.Sc. and Ph.D. degrees from Instituto Nacional de Astrofísica, Óptica y Electrónica (INAOE), in 1995 and 2000, respectively. In 2001 he was appointed as professor-researcher at INAOE. From 2009-2010, he served as a Visiting Researcher in the department of electrical engineering at the University of California Riverside, USA. He has authored seven books, fifteen book chapters, 56 journal articles and around 100 conference papers. He is an IEEE Senior Member and a member of the National System for Researchers (SNI-México). He serves in the editorial board of Nonlinear Science Letters B: Chaos, Fractal and Synchronization; Trends in Applied Sciences Research; and Journal of Applied Sciences. He regularly serves as a reviewer in about 22 journals and 15 international conferences. His research interests include systematic synthesis and behavioral modeling and simulation of linear and nonlinear circuits and systems, chaotic oscillators, symbolic analysis, multi-objective evolutionary algorithms, and analog/RF and mixed-signal design automation tools.",institutionString:null,position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"2",totalChapterViews:"0",totalEditedBooks:"3",institution:{name:"National Institute of Astrophysics, Optics and Electronics",institutionURL:null,country:{name:"Mexico"}}}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"735",title:"Circuit Design",slug:"circuit-design"}],chapters:[{id:"13827",title:"Analog CMOS Design Automation Methodologies for Low-Power Applications",doi:"10.5772/14316",slug:"analog-cmos-design-automation-methodologies-for-low-power-applications",totalDownloads:4311,totalCrossrefCites:0,totalDimensionsCites:0,hasAltmetrics:0,abstract:null,signatures:"Alessandro Girardi and Lucas C. 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These definitions often evoke different concepts such as “energy saving,” “rational use of energy,” “efficient use of resources,” “reduction of consumptions,” etc., in an amalgam shadowed by ambiguous interpretations. The Energy Efficiency Plan 2011 of the European Commission [3] quotes, for example:
According to IEA [6], “energy efficiency” is a concept that can be difficult to define since it can mean different things to different people. One difference of opinion usually lies in whether energy efficiency encompasses only the technical efficiency of an energy service, i.e., the energy consumed as a result of a technological performance, or whether non-technical factors such as behavior are included in the interpretation of energy efficiency.
Directives 2006/32/EC and 2012/27/EU contain their own definitions of “energy efficiency” and “energy saving,” but ambiguity between the terms persists. This paper proposes a clarification of the different expressions by defining their functional and conceptual boundaries and interrelationships, focusing the attention on the energy aspects, and leaving out other dominions that might govern or accompany that variable, such as, sustainability, competitiveness, economy, etc. The issue is not merely lexical or taxonomic. In fact, the strict definition of a concept defines its area of interest, and the decision-maker, when issuing a measure, should choose from his portfolio of available tools only those consistent with the involved domain. There would otherwise be the risk of using resources to promote “efficiency” using “energy-saving” tools possibly insufficient or even incompatible with the desired goal.
The lack of strict definitions in the field of the rational use of energy is, on one side, a source of uncertainty in the identification of targets, in their degree of achievement and selection of most suitable policy tools, and, on the other side, a reason of unwilled policy bias toward specific option and result [7, 8]. The main weaknesses of the energy policies developed in these conditions are the lack of criteria for monitoring performance, the lack of adequate financial assistance, and inappropriate communication in terms of message as well as targeted audience.
An example of great importance that corroborates our position is linked to the effects of the Green Deal (GD) [9], a vast plan to promote energy saving in homes launched in the UK in 2013, and which has shown signs of suffering since the first year of application (e.g., compared to a target of 2 million homes to be retrofitted each year, only 6000 had been retrofitted every year by the end of 2016). The vast literature produced in this regard has identified the following, among the various causes:
The GD did not require that the financeable efficiency measures should achieve given levels of energy savings nor provide criteria for monitoring the performances, thereby introducing uncertainties on the degree of achievement of the targets and on the corrective measures to be introduced (an energy saving must be measurable).
In a first phase (2013–2014), no state subsidies were envisaged that would make the efficiency improvement measures profitable (the net present value of energy savings must be positive).
In a second phase (2014–2015), state funds were made available, but not to the extent required by demand or in a long-term perspective (energy savings must be stable over time).
The government team that introduced the GD was composed of generalist officials with no experience in the field of energy efficiency, and above all without experts in the social-psychological, marketing, and communication fields (a given goal should require dedicated professionalism).
The GD could finance energy efficiency measures (e.g., insulation of walls), energy waste reduction (e.g., draft proofing), and use of renewable sources (e.g., solar panels) altogether. These actions aim at conceptually different goals and should have required different tools to be implemented.
A proper definition of the terms “energy saving,” “efficiency,” and “rational use” will therefore make correlations possible like
as support for the policy-makers when establishing the principles of an action plan and for the analysts to check the results and the inner consistency between the goals and the means used to achieve them.
In recent decades many pieces of legislation on the issue of energy conservation at EU and national levels have been produced. Their stated goal is the improvement of the use of energy by end users through both prescriptive standards and direct/indirect financial support. Over time, such legislative tools have limited temperature in homes at 20°C, provided tax deductions for energy-saving interventions in buildings, granted energy efficiency certificates for measures in the industry sector, introduced labeling and energy performance certification, stimulated the market for the ESCOs, stated the appointment of an energy manager, supported the practice of energy audits and energy performance contracts, etc., thus creating a fertile ground for the identification of additional areas—in productive activities and in social life—of improvement. This legislative and regulatory process [10] is still in progress, and Italy and the EU Member States consider it as a cornerstone of their energy policy. On the other hand, energy can be saved even when turning off the lights when leaving a room, recovering heat in a production process, buying four-star appliances, installing a cogeneration plant, joining the local district heating, using stairs instead of elevators or bikes instead of cars, eliminating drafts under doors at home, connecting an inverter to an electric motor, becoming vegetarians, funding ads and documentaries on TV to create awareness among consumers, inserting the chapter “How to Use energy” in the books for elementary schools, and installing smart meters or modifying the wing profile of an aircraft or favoring the recycle of glass. Given the current regulatory framework, it would be difficult to identify, between those listed above, the “rational use of energy” or “energy-saving” or “energy efficiency” measures. The task we want to deal with in the next chapter is the survey of these families but also of other and different ones, in which the various measures listed above are logically contained.
Any kind of measures able to save energy, e.g., those listed in the previous chapter, could belong to two classes: technical and nontechnical measures. All the initiatives related to plants or machineries with better performance than those previously installed may belong to the first family, while initiatives derived from behaviors of certain social classes (e.g., public employees, workers, students, families) or from the way certain productive processes are managed may belong to the second. The family of the technical measures could be further subdivided by the energy carrier (electricity, steam, fuel, etc.), by the primary source saved (natural gas, oil, coal, biomass, etc.), etc.
Another possibility is to classify the measures according to the kind of approach, whether top-down or bottom-up. Top-down measures “command and control” imposed by a higher authority; bottom-ups are those stemming from a free decision of the final users.
Another criterion might be related to the kind of final uses, for example, buildings (walls or the HVAC plants), industry (the utilities or the process), the tertiary sector, and transports and, again according to the production chains (paper, glass, textile, etc.), by types of services provided (by schools, offices, retail, etc.) or kind of transport means (land, air, naval).
Other methods could address the complexity of the measures (from “no cost good housekeeping” practices such as turning off lights to complex project with relevant financial implication)
The criteria partially exposed above, in the absence of a unifier element, seem, however, biased toward a simple cataloging, able in case to put order in the great family of “measures to limit energy consumptions” but unable to provide added values for the decision-maker/legislator when establishing an integrated policy.
A new method based on a classification by areas of interest is presented below; uniform measures will be referred to any given field, to be implemented with consistent and dedicated resources and tools.
Let’s start from the “energy-saving” concept through a clear and precise definition interpreting the expectation of a given policy, namely, an available and effective tool for the reduction of the energy consumptions in a framework of increased competitiveness, sustainability, and alleviation of the trade balance with foreign countries.
First of all let’s ask ourselves if, reducing the energy consumption in a given context from a value E1 to a value E2, one could call “energy saving” the difference of E1-E2. We think it is possible as far as the following conditions are met.
First, “energy saving” should be voluntary and programmable. As such, it must come from a plan considering the final users’ consumption profile, the technological offer, and the trend of energy markets. If a reduction of the demand came from nonvoluntary factors instead—for example, thanks to the favorable climatology or to the market dynamics making low-energy products or services more attractive in certain periods—such reduction might constitute a lucky contingency, but it couldn’t be called “energy saving” because the feature of planning, linked to any policy action, would be missing.
Second, “energy saving,” meaning the difference between an ex ante and an ex post consumption, must be measurable: the decision-maker, whether public or private, must be able to precisely determine the quantitative effect E1-E2 that the chosen initiative, once realized, will be able to produce in order to assess the adequacy to achieve a given objective, to follow the evolution of the results produced in time and to compare the actual results against the amount of resources fielded. In this regard, let’s consider the typical asymmetry between the ex ante and ex post measurements: when implementing an initiative to rationalize a given device, consumptions ex ante are certainly measurable, while the future ones will only be alleged and uncertain, and, if possible, they can only be estimated using engineering formulas. However, when the initiative is put in place at present, consumptions ex post are surely measurable; the effects are then determined (in the absence of a meter already installed on the machine), counting ex ante consumptions through empirical and/or statistical methods. The lack of a meter measuring ex ante or ex post consumptions necessarily causes uncertainty in the calculation of actual savings.
From the need to measure energy savings, one can argue that the technological initiatives, whose ex ante and ex post consumptions are certainly measurable, fall certainly within the definition; it will not be so easy for non-technological initiatives (it can be difficult to measure the energy saving derived form an increased “energy culture” of the end users or produced by an information campaign etc.).
Third, “energy saving” should produce net positive energy savings compared to the ex ante situation. While measurability is a precondition, it is also necessary that the balance between ex ante and ex post consumptions is positive, and therefore it should always be E1-E2 > 0. This condition is apparently tautological (talking about “savings” the difference of E1-E2 should de facto be greater than zero) because the assessment of the energy balance of the initiative must not only take into account the consumption of the unit or the system improved but even all the changes in power consumption that the initiative has caused in the associated context (cross-media effects). For example, a heat recovery through an exchanger between two streams increases the load losses in the circuits, and therefore the energy consumption of pumps or fans increases. When planning the measure, such components have to be identified and calculated, in order to prevent their occurrence possibly nullifying the operation, causing an increase of the global consumptions: E2 > E1. The absolute ex post consumption may increase rather than decrease when there was a change in the flow of products or services provided after the implementation of the measure; in such a case, a normalization procedure, according to EU Directive 06/32 “whilst ensuring normalization for external conditions that affect energy consumption” [11], is mandatory.
Fourth, the reduction of the energy consumption obtained after the energy-saving operation should remain stable over time. A new and effective measure implemented should become the new benchmark or the new baseline for the same type of energy use and the same final user; since the decision-maker can’t accept that, in the midterm, consumptions increase again, nullifying the resources (always scarce and precious) used to implement the measure: a legislative decree, or a company policy, must necessarily induce lasting effects considering the resources invested.
Fifth, the cost-benefit analysis of an energy-saving initiative should provide positive results. The measure must, in fact, be capable to generate, for a number of years established by the decision-maker, a cash flow able to offset the investment necessary for the implementation of the measure itself and to produce an extra advantage, the net present value (NPV). Since the NPV is determined as present money, it can be used to finance further energy-efficient initiatives showing positive NPVs, thus triggering a virtuous spiral. If the energy-saving measure showed a negative NPV instead, the final result would be the loss of money, the value of the total energy saved not being able to pay back the initial investment, making it impossible to trigger any virtuous spiral. This fifth condition moves “energy saving” from the domain of energy to the domain of economy, fixing an inescapable two-way relationship between energy and economy: there is no energy saving if there is no money saving.
In conclusion, “energy saving” can be defined as an operation due to a voluntary and programmable action put in place by the decision-maker, producing a stable, positive, and measurable reduction of energy consumptions between an ex ante and an ex post situation, profitable under an economic point of view.
We have just seen the features for an initiative to be called “energy saving.” Let’s now see the possible ways to reduce energy consumptions, to discriminate among them only those deserving the “energy-saving” status.
If in a given context it is necessary to submit energy uses to a deep assessment due to consumptions increasing uncontrollably or to associated costs verging on unsustainability1, possible implementable measures will be the following:
Improvement of energy efficiency.
In intrinsic way.
Via technology.
Via management.
Joint replacement.
Technological standards.
Energy waste reduction.
Behavioral change.
Energy rationing.
We go now to describe respective meanings and operation fields.
Before getting into the description of this measure, it would be appropriate to clarify the meaning of “energy efficiency,” and it would be better to remain in the technical-scientific field, since the concept of “efficiency” comes from the concept of thermodynamic “output.” To this purpose it seems consistent what the 2006/32 EC Directive states: energy efficiency is “the ratio of output of (1) performance, (2) service, (3) goods or (4) energy, to the input of energy” (figures added by the author). It is tacit that output and energy input are referred to the same time period, which could be instantaneous (then the efficiency is a ratio between powers) or as long as you like. We can mention the following examples:
Performance: for an organization delivering administrative services, energy efficiency could be the ratio between the number of files issued and the energy used as resulting from energy bills.
Service: for transport of passengers, it is the ratio between the “number of passengers × kilometers traveled” and the consumption of fuel and/or electricity.
Goods: for a paper mill, it is the ratio between the tons of paper produced and the cubic meters of natural gas used in the production process.
Energy: for a heat generator, it is the ratio between the thermal energy produced (and fed into the distribution system) and the consumption of primary energy fed to the burner. By definition, the latter type of efficiency coincides with the first principle of thermodynamic output related to the process taking place in the heat generator.
The measure “improving energy efficiency” is composed of three subsets: the intrinsic improvement, joint replacement, and technological standards.
If the efficiency of a process improves thanks to a planned measure, energy saving will be produced, which is therefore the effect of the improvement of efficiency. Let’s suppose a given process (see Figure 1) which, thanks to the input of energy E, produces the stream of goods or services P. By definition, the energy efficiency of the process is given by.
Energy efficiency as the ratio of goods-services provided and the energy input.
If the efficiency of the process improves from ε1 to ε2 (ε2 > ε1), the energy savings achievable, R, will be given by
The formula gives essence to the difference between the increase of efficiency and the energy saving: efficiency is a ratio between two quantities that, in the case where the output consists of a supply of energy, becomes a pure number between zero and one. Energy saving is a physical amount of energy instead (measurable in toe, kWh, MJ, etc.), no longer consumed thanks to the increased efficiency. So, increase in efficiency and energy saving are not concepts alternative to one another or possibly overlapping: the first is the cause, the second the effect.
Given the definition of “efficiency” as the ratio ε = P/E, it follows that the inverse of the efficiency is the specific consumption cs = E/P.
The intrinsic increase of the efficiency is obtained via technology when the set of physical equipment driving the process has a better efficiency than the ex ante situation. This occurs, for example, in the presence of IE3 class electric motors instead of IE1-IE2 classes, inverters driving electric motors connected to variable loads, heat exchangers to recover energy from exhaust, steam recompression, turbo expanders in place of lamination valves of gases or steam, etc.
Efficiency can be increased by changing not the hardware but (1) the nature of the stream of matter/energy as the process input/output and (2) different management methods. Obviously the current configuration (machineries and the way they are managed) must be an average reference, or baseline, and the possible solution must be a real innovation, not just a realignment with what is already consolidated in the same production sector (we would otherwise fall into the “joint replacement” described in section 5.1.2). Management measures are, for instance:
The adoption of raw materials with lower energy requirements for a change of state (lower temperatures for melting/boiling) or for pumping (lesser viscosity/density fluids) and use of additives in raw materials conferring the previous properties (e.g., thinners in the production of paper, low-melting additives for the production of glass, etc.)
The production of lower-energy intensity goods or services (e.g., lighter bricks, lesser-thickness glass containers, avoiding to print documents in favor of dematerialization, etc.)
The adoption of different management modalities of the process, e.g., “tuning” the different production phases eliminating intermediate stations and queues, using of dedicated software for automation/optimization of process parameters, etc.
Joint replacement savings are obtained when a device of a given residual life is replaced by a new one, belonging to the same technological series. The resulting savings are transitional and could even go to zero.
In fact, the efficiency of a new equipment, left to itself, would degrade naturally over time from the rated value ε1 to ε1, f at the end of the use. If at time t1 it was replaced by a new equipment, but belonging to the same technological series of ε1 efficiency, energy savings that could be achieved through the formula (1) would have a purely illusory character (see Figure 2A) because, through a normal maintenance, the efficiency would remain at its rated value and consequently the achievable saving would be next to zero (Figure 2B).
Type of savings. (A) Illusory savings: when ε1-ε1, f degradation due to lack of maintenance. (B) With proper maintenance saving should be next to zero. (C) The saving is given by an intrinsic improvement of efficiency.
As we will see in section 5, the energy savings resulting from an intrinsic increase in the energy efficiency (Figure 2C) are the only “additional,” resulting as marginal quantity of energy corresponding to the value given by (R1), and really saved.
Some decision-making authority may impose minimum performance standards for energy equipment, excluding the circulation in the market of not compliant solutions. The obligations imposed by regulations on energy performance in buildings [12, 13] or the minimum standards established by the Ecodesign regulations [14] for different kinds of wide diffusion devices (light bulbs, electric motors, boilers, etc.) belong to this kind of measures.
The reduction of energy waste comes from the “normal” behavior and it does not need the design of a specific energy project. It simply consists in the realignment to the normal situation at rated consumption, starting from a previous high-energy consumption situation. The energy waste should never be confused with the low efficiency of an appliance, intrinsic or due to wear, which can be increased by substitution with a better device: energy waste is due to negligence, and as such it should not be tolerated and should not be hosted in the country of energetics. If one was currently seeing a “free” degradation of energy, for example, neglected losses of compressed air, steam, and water; lights, printers, and monitors unnecessarily left switched on after office hours; wasted fuel caused by unnecessary travels of the vehicle; etc., the share in case recovered after an initiative of restoration would have the same meaning of the “due” mending of the purse from which a trickle of coins is happening: once the purse is mended, no one should consider as “saved” the money that it is now able to retain.
Metaphors aside, the savings associated with a limitation of wasted energy are illusory: this form of recovery cannot be counted as revenue, and the manager of the local plant is responsible for such a loss.
When an energy-saving behavior is adopted, we are dealing with a non-technological measure, related to sociocultural cycles having a complex, long-lasting, unpredictable dynamics difficult to quantify even in ex post conditions. Such an approach exploits the deep motivations of users—citizens—and associates, to a behavior oriented to saving energy, acceptability by the reference community, or the satisfaction of inner instances of public participation, making an active social role evident.
Consumptions of energy can be limited by imposing restrictions on energy uses (reducing available streams or the periods of use) or decreasing the quality of performance. This usually happens after serious crises threatening the continuity or security of energy supply or following traumatic increases in energy prices. This kind of tools are typically policies of austerity (i.e., the 1973 Yom Kippur oil crisis) [15, 16] as well as those regulations limiting the temperature in homes.
Given the different measures seen so far to limit consumptions, the following measures belong to the definition of “energy saving” claimed before and substantiate it:
Intrinsic improvement of efficiency.
Joint replacement.
Technological standards.
Energy rationing whose requirements remain in force in the medium term.
Recovering energy wastes should not strictly be an operation of “energy saving” since it doesn’t produce net savings (third condition); on the other hand, the behavioral change and energy rationing measures, the prescriptions of which are in force for a short period of time, do not ensure the stability of savings for years to come (fourth condition).
Savings induced by energy rationing policies are not obtained under the same conditions as before, since the end user is encouraged to accept a downgrading of energy performance, for example, using energy only in certain periods of time, having reduced available thermal power, enduring lower temperatures in winter compared to average comfort conditions, higher temperatures—and higher humidity—during summer, etc. Saving energy by increasing efficiency involves, however, the same conditions between ex ante and ex post situations, thus at the same degree days, humidity, services, goods produced, etc. using conventional normalization methods. For example, an operation increasing the efficiency of a process from ε1 to ε2, with increased production from P1 to P2, would produce, at the same production ex post P2, an energy saving given by
Since the saving is positive (in respect of the third condition), it follows that ε2 > ε1, which produces a further tautological condition:
stating the following rule: in order to have positive energy savings as a result of an increase in efficiency and production, the relative increase in production must be more than proportional to the relative increase in energy consumption.
The same applies in the event of increase in efficiency with reduction of production.
Of all the ways to save energy, only the intrinsic increase of efficiency has the characteristics of additionality. For instance, as defined in Annex A to document 9/11 of the Italian Authority for Electricity, Gas and Water System, [17] savings are additional when “purified of all not additional energy savings, i.e., those that would have happened anyway as a result of technological, regulatory and market evolution.” When, therefore, some savings are achieved because of mandatory legislation, or after installing a “market average” device (even though more efficient than the replaced device), or if providing a service that the market demands with a given minimal performance, all that cannot be considered additional and, in some contexts, may not receive incentives (e.g., in the Italian system of White Certificates).
When a policy boosts improvements in energy efficiency imposing technological standards, the consequent energy savings cannot be considered additional at end-user level, but they can at the national level.
Let’s now jump to the next level and ask ourselves the best definition of “rational use of energy.”
For example, the Italian 10/91 law reported the following definition: “set of organic actions intended to promote energy conservation, appropriate use of energy sources (i.e., avoid waste), improvement of technological processes using or transforming energy (i.e., increasing energy efficiency), the development of renewable sources of energy, the replacement of imported energy sources (i.e., the development of indigenous energy sources).” In practice, the rational use of energy is part of the strategy the country adopts to face the energy challenge, whose motivation and urgency comes from the need of security of energy supplies and from the gradual rise of energy prices due to the depletion of fossil fuels. However, the definition of the 10/91 law, in the light of the above, seems inadequate and ambiguous. It considers energy saving and increased efficiency at the same level, officially weaving the two concepts perhaps for the first time. Moreover, the definition does not mention non-technical aspects such as the behavioral change.
We might then reformulate the concept of “rational use of energy” as the “set of organic actions aimed at reducing consumptions through (1) promotion of energy conservation, energy waste reduction, and behavioral change; (2) development and use of renewable energy sources; and (3) development and use of domestic sources of energy,” in such a manner of explicitly identifying as many fields of action, conceptually not interfering with one another, each one deserving a specific promotional policy-making use of dedicated tools; in fact it seems logical that a strategy for increasing, e.g., intrinsic efficiency, should leverage instruments different than those for behavioral change, joint replacement, etc.
Figure 3 summarizes the proposed definition, depicting the various fields of interest for a policy of rational use of energy.
Rational use of energy: the fields of interest.
The diagram shows that energy efficiency is a subset of the family of higher-level “energy saving,” an instrument of the class “limitation of consumptions,” measure per se of rational use of energy. This should definitely clarify the respective positions and meanings of “efficiency” and “saving.”
The proposed subdivision segregates different areas of activity, each one needing dedicated operational tools and skills. Referring to the diagram in Figure 3, it is the case at this point to catalog such instruments according to the areas, limiting the analysis to consumption-reducing measures, thus not considering the development and use of renewable and endogenous energy sources.
This specific energy-saving measure stands on the planning abilities of the end user—in terms of choice between a number of available technological options or between a range of projects—privileging the solutions with the best efficiency, after assessing them with ad hoc cost-benefit analyses. If the end user has no choice, since the market offers, or the law requires, or customers want only specific equipment or processes, we should not strictly call this measure as “efficiency” for it is not characterized by additionality. Some energy efficiency measures could be as follows: (1) some specific policy granting incentives, for example, based on White Certificates, recognized only if additionality of the energy saved is proven; (2) companies could impose the internal use of efficient equipment and adopt remote and automated control systems; and (3) politics could operate on the demand but even on the offer side, getting industries to produce efficient equipment and granting incentives for process and/or product innovation; etc. To implement policies aiming at increasing energy efficiency, decision-makers must gather mainly technical (researchers and experts in energetics, industrial processes, efficient technologies) and economy-finance skills for the assessment of project profitability.
This measure should not be subject to specific programs or incentives, since it deals with “average market” practices to be normally adopted at the end of the devices’ lifetime and when the efficiency is constantly kept at the rated level thanks to normal maintenance cycles. When, however, the ordinary maintenance is made, but the efficiency of the component degrades necessarily in time, energy saving is obtained by inducing a more frequent renewal of such components (see Appendix). In this regard the Italian Law n. 10/91, Art. One states: “In order to improve the energy transformation processes [...] the provisions of this Title shall promote and encourage [...] a more rapid replacement of systems in particular in the areas with higher energy consumptions” [18]. The implementation of this measure demands technicians and analysts to know the diagrams of decay of the efficiencies in time for the different devices (see, e.g., the decay of the luminous flux for LED lamps [19] in Figure 4) and to determine the optimal replacement time through the application of cost-benefit analyses.
Decay probability of the luminous flux over time: LED lamps (gray area), source ETAP, LED dossierOctober 2014.
Energy saving is achieved by eliminating low-efficiency equipment from the market and allowing only the trade of equipment having an efficiency higher than a given level. European Ecodesign Directives (2005/32/EC, 2009/125/EC, and subsequent regulations) for home and industrial appliances (light sources, digital receivers, electric motors, etc.) leverage this specific item of energy saving. Other measures belong to this category, i.e., imposition of minimum values of transmittance for the building envelope, carrying out of energy audits in large companies, and annual refurbishment of 3% of the buildings of the central public administration (12/27 EED Directive); the requirement for new buildings owned or occupied by public government as of 1 January 2019 has to be “nearly zero energy,” while other new buildings will follow the prescription since 1 January 2021 (90/2013 Italian Act).
Such a measure is intended for wide diffusion devices, the number of which constitutes the driver in the country, more than the quantitative increase in efficiency. Efficiency standards are set at EU or Member State level and require the involvement of staff where technical, economic, market knowledge, production processes, protocols for measuring energy consumptions, etc. skills coexist.
These are measures to be adopted during energy crises involving rapid increases in prices and difficulties in getting supply. When necessary, to achieve drastic reductions of consumptions at whole country, tariffs are increased and energy rationed. For instance, during the 1973–1974 austerity period [20, 21, 22], the following measures were adopted in Italy: (1) ban of motorized vehicles (including aircraft and boats) during holidays; (2) end of TV broadcasts at 10:45 pm and evening news moved from 8:30 to 8:00 pm; (3) shops closed at 7:00 pm with the obligation not to hold lightened signs, advertising signs, and shop windows; (4) bars and restaurants closed by h. 00:00 am; (5) cinemas and theaters closed by h. 11:00 pm; (6) immediate increase by 30% in fuel prices; (7) obligation to reduce public lighting by 40%; and (8) reduction of speed on roads to 50 km/h in urban areas, to 100 km/h on country roads, and to 120 km/h on motorways. In other countries the crisis of 1973 was the opportunity to introduce the daylight-savings time [5, 23], while in the USA the bike race Daytona 200 was competed for 180 miles.
In Japan [24, 25], following the tsunami that damaged the Fukushima nuclear power plant (2011), the government implemented a series of measures such as turning off air conditioning and escalators in the subway, turning off the large advertising screens in city centers, decreasing the speed of trains, and reshaping the hours of work, including hours of weekend when the electrical load on the network was lower. Part of these measures were spread by the movement of opinion Setsuden (see Figure 5, a poster aimed at private households encouraging energy-saving behavior from unplugging appliances vs. standby mode to turning lights off when not needed and switching to LED lights). Some were removed in late 2011, but part of them was incorporated permanently in the habits of Japanese citizens and companies.
Banner of the movement of opinion Setsuden (energy saving).
Options foreseen in national laws on energy uses in buildings, for example, limiting the temperature inside homes or in industrial mills during winter and the length of the heating seasons for households, can be considered as belonging to the energy rationing measures.
Planning this instrument primarily requires skills in the field of social psychology, mass psychology, and communication.
There are no specific rules in this field because of the difficulty to conduct ex post controls to evaluate the results; however, there are more general measures able to induce at end-user level, among other effects, also an attitude aimed at reducing losses, for instance, a policy accompanying the introduction of energy management systems, possibly compliant with the ISO 50001 Standard [26]: in fact a management system, having among its cornerstones the “continuous improvement,” necessarily has to address the problem of energy wastes and the identification of the measures for their reduction. Awareness of the problem of energy waste is also catalyzed by the increase in energy prices. The imposition of limits not to be exceeded for energy-specific consumption at end-user level is aimed at the same goal. This last measure has never been implemented so far, and, especially in the industry sector, it would be with great difficulty because of the enormous variety and peculiarities of different production cycles and the impossibility to identify and agree with stakeholders the specific energy consumption benchmarks.
Policies to reduce the energy waste, rather than by the central authorities, should be implemented by end users themselves, using local technicians who are familiar with the current consumption profiles, with industry benchmarks to compare energy performances and, of course, with the technical “weaknesses” of their plant. In the end, it is a matter of common sense.
The behavior of end users regarding the conscious use of energy should be addressed toward proactive attitudes and not toward the trivial (and already due) waste energy reduction. Such a policy should not be therefore aimed at turning the lights off when leaving the living room (or office or department), or shutting the windows when the HVAC plant is switched on, or avoiding the use of compressed air to wipe floors or clothes, or preferring public transport to private cars. Similar fields should already have been fixed by the reasonable user, who knows that unnecessary consumption of electricity or gasoline or methane is a money trickling down; using common sense to prevent similar drippings is enough: there is no need of a law but the law of nature to know that energy—meaning money—shouldn’t be wasted. Behavior should change in a proactive way instead, i.e., toward attitudes able to predict the effects of our choices or behaviors about the variable “energy” and then to act accordingly. As a consequence one should consider the energy class label when purchasing a piece of appliance; use elevators and escalators as little as possible and use stairs instead; go walking or cycling for short trips instead of using motorized vehicles; prefer “0 km” products (with same quality and price) and avoid the consumption of fruit and vegetables out of season (greenhouses operating off season must be conditioned, and energy consumptions increase); keep the electrical consumption of the dwelling under control, possibly with automatic meters showing in real time the power requested in that very moment; encourage conference calls or video conferences instead of face-to-face meetings; introduce new summer dress codes in offices, in favor of light and informal clothes (getting rid of jacket-tie suits); learn how to build a solar panel; understand the principles of thermodynamics—stating that (a), once used, the energy can’t be created once again and (b) electricity should never be converted into heat; etc. To achieve such goals, an intense, extensive, and prolonged public information/training plan should be launched, favoring the spread of best practices and involving schools at all levels [9]. Therefore, skills in communication and marketing are mainly needed.
The following table summarizes the most important skills needed in all areas of interest.
Area of interest | Competences | |
---|---|---|
Energy efficiency improvement | Intrinsic improvement | Energetics, industrial processes, efficient technologies, management systems, economy, finance |
Joint replacement | Technical knowledge of performances of energy components, economy | |
Technological standards | Energetics, engineering, economy, knowledge of markets, of productive processes, and of energy consumptions measurement protocols | |
Energy rationing | Social psychology, mass psychology, communication | |
Energy waste reduction | Common sense | |
Behavioral change | Communication, marketing |
Behavioral change: skill vs. areas of interest.
The definitions and the areas of interest shown so far for the different measures to limit energy consumption have a universal value, not necessarily the one that the different regulations define in terms of “energy saving,” “efficiency,” “rational use of energy,” etc. The distinction proposed between the individual measures by level, areas of interest, and competence requirements can contribute to a better integration of the various regulatory measures and to an optimal identification and customization of planning and implementation tools, while avoiding overlapping and duplications.
The word “energy” has, for the ordinary citizen, a range of meanings: there are vital, moral, mental, psychic, internal, emotional, etc. “energies.” These are pure abstract concepts, inhabitants of the world of ideas. The object of policies is, instead, that “energy’ is—always abstract but measurable—dealing with the two principles of thermodynamics2—and that pragmatically warms us during winter and cools us during summer, making refrigerators and cars run. The policies refer to this energy as a “tangible” energy that burns and gives electric shocks and that can be measured and billed, and that is why the energy efficiency dealt with by the policies should remain restricted to a technical-scientific domain. An invasion of collective areas—behavior modification, increasing awareness, the maturation of a culture or motivational domains, “I feel myself realized” or “If everyone did like me...”—is desirable, but in view of an increased social sensitivity, not of an increase in efficiency, since between the two aspects there is not necessarily a two-way relationship: when sensitivity to energy efficiency is high, the efficiency of the context is normally low (e.g., in energy crisis times), whereas when efficiency is high, sensitivity is low (as in current times). This phase shift may be another form in which we experiment the rebound effect [27, 28, 29, 30, 31].
The lack of strict definitions in the field of the rational use of energy has been identified as the main reason for the failure of energy policies aiming at conceptually different goals but with an incoherent bias toward a specific tool to be implemented. When a large-spectrum policy is aimed at different targets, policy-makers should moreover be reminded of the Tinbergen’s rule, stating that when trying to achieve multiple economic targets, at least one policy tool for each policy target is needed: the achievement of a target can preclude the achievement of another one.
Another context that the analysis can help to clarify lies in the semantics of the term “energy efficiency.” In recent years, the European Union has issued a series of acts in the field of energy conservation: action plans, green papers, directives, framework programs, decisions, etc. These have always invoked the concept of “energy efficiency,” and that address was reflected on individual Member States during the adoption of the various acts and directives. This may seem incongruous since, as seen so far, the increase in efficiency is only one of the ways in which energy can be saved.
One answer may lie in semantics.
The main conceptual contender of efficiency is, as seen so far, “energy saving,” the instrument that, by virtue of its large domain of intervention, should be invoked in general policies. The concept of “saving” might however not be well received by the end users (nor by the legislature), if recalling—consciously or unconsciously—pauper horizons in which to engineer oneself, having to tighten belts, giving up opportunities, and accepting a lower quality of life. Other terms often used in this context, such as “limitation,” “containment,” “reduction,” and “conservation,” remind similar scenarios. Instead the word “efficiency,” from the semantic point of view, resonates the positive concept of improvement related to the advent of futuristic technologies: it does not foreshadow some arduous and colorless future overshadowed by attitudes of thrift and saving, but it contains an unlimited, optimistic, and enthusiastic confidence in technology. We do certainly prefer being branded as “efficient” rather than “thrifty.” In the collective imagination, efficiency is Thomas Alva Edison, saving is Scrooge. Saving is the bear, efficiency is the bull.
One could say that the choice of the word “efficiency” itself can be seen as the first and most powerful measure of behavioral change that, internalized by European citizens, may have a significant impact in the socioeconomic system.
Let’s naturally decrease the efficiency ε of a given device “1” over time. In Figure 6 the curve A-B-C represents the evolution in time of the specific power consumption Ps (= 1/ε). During the life (at time H), the device would consume the energy represented by the A-C-H-F area. If device “1” is replaced with one identical “2” at half of its life (time G), the new consumption of the process would be represented by A-B-D-E-H-F area, and the area B-C-E-D would represent the energy saved in this way.
Power consumption profile of energy-saving solution.
To become an effective energy-saving option, the initiative has to achieve at least the economic parity, so the discounted cash value of the saved energy (black area) in the life of the project must equal the difference between the value of equipment “2” installed at the time G and the residual discounted values of equipment “1” disposed at time G and equipment “2” disposed at time H.
Biochemically, tannins are sort of secondary metabolites predominantly available in the plant-based foods and beverages. The name “tannin” is originated from the industrial process of “leather tanning,” in which animal hides are converted into leather through downstream processing. It is worthwhile to mention that tannins were used in this process from historic times. On the basis of their presence, various parts of plants such as bark, wood, leaves, seeds, roots, and even the plant galls are the major sources of tannin extractions used for various purposes (Table 1). Algae is also rich source of tannin-based compounds such as phlorotannins which comprise of antioxidant, antidiabetic, anti-inflammatory, and antitumor properties evaluated in the case of human [1, 2]. In addition to health benefits, phlorotannins isolated from brown seaweeds have been used in the cosmetics also [3]. Some researchers have defined tannins as “Any phenolic compound of sufficiently high molecular weight containing sufficient hydroxyls and other suitable groups (i.e., carboxyls) to form effectively strong complexes with protein and other macromolecules under the particular environmental conditions being studied” [4].
\nS. no. | \nName of plant species | \nPlant parts | \nMajor components | \nMedicinal use | \n
---|---|---|---|---|
1. | \nRoot | \nTannic acid, rhataniatannic acid, peculiar acid principle, krameric acid, phlobaphene, phloroglucin, and proanthocyanidins | \nChronic diarrhea, menorrhagia, urinary diseases, bleeding from the bowels, bad throat, and antibacterial agents for the eyes, nose, and gums | \n|
2. | \nRoots | \nPentadigalloylglucose, pedunculagin, epigallocatechin, catechins, and proanthocyanidins | \nInflammations, wound healings, diarrhea, inflammation of bowel bacterial, fungal, and viral infections | \n|
3. | \nRoot | \nSanguiin H-6 | \nDysentery and insect bites | \n|
4. | \nAerial parts | \nAgrimoniin and potentillin | \nDiarrhea, cough, lymphadenitis, and hepatitis | \n|
5. | \nBark | \nCorilagin and related ellagitannins | \nBad throat, asthma, dysentery, and ulcers | \n|
6. | \nBark | \nGrandinin, castalagin, and glucogallin | \nDiarrhea, itching, and burning | \n|
7. | \nLeaves, stem, and bark | \nGeraniin, phenazine derivative of geraniin, Corilagin, and furosin. | \nWound healing | \n|
8. | \nLeaves | \nGeraniin | \nIntestinal disorders | \n|
9. | \nLeaves | \nCatechins and other condensed tannins | \nGastritis and ulcers | \n|
10. | \nPod | \nGallocatechin-gallate, methyl gallate, catechin, catechin gallate, galloylglucose, and epicatechin | \nFever, diabetes, and gum diseases | \n|
11. | \nFruit | \nProanthocyanidin oligomers based on catechin, gallocatechin, catechin-3-O-gallate, and gallocatechin-3-O-gallate | \nAntiseptic and cardiovascular diseases | \n|
12. | \nGall | \nTannic acid | \nBacterial, fungal, and viral infection | \n
Plant species containing tannins and their medicinal use.
Note: Table indicates that tannin and its components are present in most of the parts of the plants which offered great level of medicinal sources or pharmaceutical agents [59].
Plant tannins are a large group of natural phenolic compounds which contain a range of molecular weight between 500 and 3000 Da. Currently, they have been divided into three main subgroups: (1) hydrolysable tannins, (2) condensed tannins, and (3) phlorotannins. Hydrolysable tannins are highly soluble in water; biochemically, they consist of a central core of a carbohydrate (D-glucose) with its hydroxyl groups or polyol esterified with phenolic compounds such as gallic acid (3,4,5-trihydroxybenzoic acid) or hexahydroxydiphenic acid, which also known as ellagic acid (ellagitannin). Hydrolysable tannins mainly originated from Pentagalloylglucose (2-O-digalloyl-1, 3, 4, 6-tetra-O-galoyl-α-D-glucopyranose), which is a basic structural unit of hydrolysable tannins. The main source of structural diversity among the hydrolysable tannins is the presence of diverse types of oxidative linkages that give rise to oligomeric compounds with molecular weight between 2000 and 5000 Da [5]. Characteristic examples of hydrolysable tannins are (1) gallic acid; (2) hexahydroxydiphenic acid; (3) ellagic acid; and (4) pentagalloylglucose, which contain a central glucose molecule as the core attached with multiple gallic acid units, while ellagitannins are associated to hexahydroxydiphenic acid. Hydrolysable tannins are mainly present in angiosperm and dicotyledons. Both gallotannins and ellagitannins may synthesize individually or in the form of a mixture in plants. Gallic acid has been extracted from plant families, for example, Ericaceae, Geraniaceae, or Fagaceae; whereas, ellagic acid is available in Hamamelidae, Dilleniidae, and Rosidae species [6].
\nNaturally occurring condensed tannins are polyphenolic bioflavonoids, are polymers of polyhydroxy flavan-3-ol units, for example, (+)-catechin and (−)-epicatechin-2, (+)-gallocatechin, and flavan-3, 4-diols. They are also known as proanthocyanidins (PA) that ascribed to their hydrolysis to anthocyanidins in heated ethanol treatment. Due to presence of stereoisomerisms in hydroxylation patterns at three chiral centers, bond positions, and type of interflavan bond; proanthocyanidins are present in variety of active forms, for example, (1) (+)-catechin; (2) (−)-epicatechin; (3) (+)-gallocatechin; (4) (−)-epigallocatechin; and (5) (−)-epigallocatechin gallate. Among them, (+) catechin and (−) epicatechin are predominantly present in nature [7]. There are several plant species which offer rich source of proanthocyanidins (see Table 1). Proanthocyanidins can be obtained from red wine, green tea, cocoa, and chocolate. However, condensed tannins can further be classified on the basis of reaction rate like, slow reacting tannins like quebracho and mimosa and fast reacting tannins like pine and pecan (
After the industrial revolution, most of the synthetic chemicals were used in the diverse types of industries including food, pharma, beverage, leather, and other industries. But prolonged applications of synthetic chemicals in the area of health and other industries left a myriad of adverse effects on environment and human health. Therefore, current focus has been shifted on alternative natural compounds like tannins that can be exploited in the form of functional food, nutraceutical, cosmetology, and pharmaceutical industries.
\nThe global tannin market is expanding very rapidly; according to estimation, 1076.3 kilotons tannin was required in 2015 which expected to rise with CAGR of 5.8% from 2016 to 2025. The demand was mainly in the wine, leather, pharmaceuticals, and wood industries. In case of USA, approximately 282.4 kilotons tannins were produced; its 62.3% is used in leather industries alone. Europe is another emerging market for tannins and tannin-based products. It is due to large scale wine production, which is accounted for 38% revenue generations in Europe. Hence, global market size for tannin related industries may increase up to $3.3 billion by 2025. The applications of condensed tannins are expected to increase up to 424.8 kilotons by 2025 in comparison of 242.9 kilotons in 2015 [9].
\nBut, there are several unresolved issues linked with applications of tannins such as antinutrient effect, resistance to enzymatic hydrolysis, and lack of complete information about their interactions with other biomolecules and mode of actions in human and animals. The aim of this chapter is to present a brief discussion on the application of tannins in modern industries and to review their positive and negative aspects. It also shows that tannins are being used as sustainable raw material with other green materials in new emerging industries.
\nCurrently, hydrocarbon-based raw materials are exploited in different petrochemical industries ranging from fuel to cosmetology. It leads to the widespread deficiency of raw material eventually that creates high inflations, environmental degradation, and adverse effects on human and animal health. This necessitates to explore new alternative natural biopolymers such as polylactic acid, chitosan, lignin, and tannins for replacing with currently used hydrocarbon based polymers. Tannins can be the best natural raw material for emerging and traditional industries. This is attributed to tannin’s unique natural properties, chemical structure, and commercial properties [10]. Tannins provide several advantages like being as good biomaterial, antimicrobial, antioxidant, pharmaceutical, biopesticide, and nutraceutical agent. Tannins can be tapped for their applications in food, wood, leather, pharma, and other industries as possible raw material, as given below.
\nTannins are the secondary metabolites present in a substantial amount in plant-based food products. Due to their positive effects on the food as antibacterial and antioxidants, they are the major constituent of foods. Tannins are used as food preservatives, packaging materials, and food enhancements which owe to their protective nature.
\nCurrently, most of the food items available in the market are wrapped in the packing materials which are plastic, polyethylene, and low-density polyethylene (LDPE) and linear low-density polyethylene (LLDPE) due to their lightness, inertness, and easy availability. In fact, packaging increases the shelf-life and prevents physical damage, contamination, and deterioration in view of environmental contaminants. But these synthetic materials pose great level of environmental and health hazards. Hence, the concept of natural and active packaging has been introduced and there being continuous efforts to make packing materials from biological sources like, chitosan, starch, gelatin, tannins, and methylcellulose [11, 12]. In view of consumer awareness and knowledge, it becomes essential to develop new wrapping material for food items. However, nitrocellulose-based package are already in use in food industry, but currently the “active packaging” also introduced. Active packaging is a better option which protects the food material, simultaneously it also acts as an additive to improve antioxidant properties of foods and absorb unwanted substances such as heavy-metals or exhausted oils and to protect against oxidation, UV, and moisture-based degradation.
\nRecently, a packaging material was prepared by introducing tannins into cellulose nanofibrils in a single step process of mechanical fibrillation. This newly developed packaging film offers high density, and enhanced surface hydrophobicity which resulted in almost six times improvement in air-barrier and antioxidants properties. Simultaneously, nanocellulose-tannin-based films are active packaging materials which also provide a green, sustainable, nontoxic packaging source for food and pharmaceutical products [11, 12].
\nTwo perishable food items, Cherry tomatoes (
Generally, chitin is used as packing material, but its poor antibacterial and antioxidant abilities make it unsuitable for food packaging; therefore, tannic acid was introduced in the chitin film via single step process of interfacial assembly. Tannins addition to packaging has significantly improved the antibacterial and antioxidant properties of chitin-based packaging film. Improved quality of chitin-based film is mainly attributed to hydrogen and hydrophobic bond formation between chitin and tannins [14].
\nProtein is a major component of food, and its protection is of utmost significance in packed foods. So far, tannin- and carbohydrate-based packaging films were prepared. But, a soluble dietary fiber (SDF) and tannin-based nanocluster assembly is prepared by introducing calcium ions that creates a cross-linking nucleus in membrane. Linkage between nanoassembly and proteins offer additional advantages such as high level of antimicrobial properties and excellent cell biocompatibility which was proved by FT-IR, XRD, and DSC tests [15]. Tannin-based packing materials thus offer green, sustainable, and ecofriendly alternative that can be used in the food preservation and biomedical fields.
\nMicroorganism, fungus, yeasts, virus, pollens, and chemicals are the biggest threat to food’s shelf-life in home as well as in food markets. Biochemically, proanthocyanidins and gallic acid are flavonoid monomers by nature and are major food constituents isolated from pomegranate, strawberry, blackberry, raspberry, walnuts, almonds, and seeds. Various studies have proved that tannins prevent growth of microorganisms. Tannins are quite effective against the resistant methicillin-resistant
Food-based viral infection is another major health problem in human and animals. Currently, blueberry proanthocyanidins were tested against human norovirus growth in apple juice (AJ) and milk with 2% fat tannin-rich fraction from pomegranate rind (TFPR) inhibited the growth of human norovirus [18]. Hence, hydrolysable tannins are potential antiviral agents that used can be used in the food preservation to make food items more safe and preserve for prolonged period by using natural compounds.
\nGuava is a major tropical fruit which is also considered as a model system to study climacteric and non-climacteric fruit ripening process. Hence, it provides enough opportunities to understand post-harvest management of perishable fruits. In order to improve the shelf-life of fruits, various types of wax films, coating, and chemical treatments are used for long time. Tannins isolated from various natural sources act as preservatives due to their antibacterial and antioxidant properties. A coating material of tannic acid cross-linked with zein protein was used for coating on the guava fruit. Actually, zein is a prolamin (protein) isolated from aqueous alcohol-soluble fraction of corn (
Normal food components mainly provide the energy and essential nutrients for the growth and development for animals including human, but food also consist of bioactive molecules or phytochemicals and their inclusion in the appropriate quantity can act as possible therapeutically active agents also known as nutraceuticals, for example, (poly) phenol-rich tannins [20]. Currently, study of molecular mechanisms and pathways such as cell proliferation, apoptosis, inflammation, differentiation, angiogenesis, DNA repair pathway, and carcinogens activation offer new therapeutic targets. The application of tannins has great potential as a nutraceuticals in order to prevent various diseases such as cancer, cardiovascular, kidney diseases, and diabetes. Major sources of tannins are fruits, vegetables, bark, wood, leaves, and seeds such as green tea, apples, cocoa, chocolate, grapes, apricots, and cherries. Among them, role of tannins present in the tea and coffee to prevent the cancers have been studied by large number of scientists. The green tea contains condensed tannin namely epigallocatechin gallate (EGCG) and epicatechin gallate (ECG), which have shown anticancerous activity in terms of inflammatory and antioxidant properties both in vivo and in vitro experimental systems [21]. Actually, EGCG decrease activation of NF-kB and (AP-1) TNF-α pathways simultaneously which ultimately reduced the production of IFN-γ. It can also enhance the apoptosis process through suppression of COX-2 enzyme that leads to the production of PGE2 (prostaglandins) in various types of cell lines of colon cancer cells, such as SW837, HT-29, and HCA-7 cells. Being a polyphenol, EGCG is a strong antioxidant that reduces the activity of nitric oxide (NO) and malondialdehyde (MDA) and conversely increases superoxide dismutase (SOD) activity in case of colonic mucosa. Hence, EGCG can improve the effect of cancer chemopreventive potency by preventing the cell proliferation, migration, and invasion of tumor in cancer patients [20].
\nIn last two decades, a great interest has been emerged in the protective role of tannins against free radicals and reactive oxygen species produced inside cells, which caused degenerations and diseases such as cancer, atherosclerosis, and cardiovascular ailments. Proanthocyanidins have cardiovascular protective effect due to their antioxidant activity, inhibition of LDL oxidation, ability of vasodilation, antiplatelet activity, and protection against ischemia-reperfusion injury. Another tannin-based compound, gallic acid (3,4,5-trihydroxybenzoic acid), a naturally occurring with low molecular weight, plays very important in the protection of cardiovascular health through rejuvenating the antioxidant system which include large number of enzymes such as SOD, CAT, GPx, GRx, and GST which constitutes a scavenging system against the free radicals [22].
\nDiabetes mellitus, associated with high level of glucose concentration in the blood, is harmful for whole tissues in human body. Several investigations have shown that it can be reduced or managed by adding the appropriate amount of tannins in the nutrition or supplements of patients [23]. Because, tannins improve the glucose uptakes in body cell and simultaneously reduce the synthesis of adipocytes, hence act as the potential therapeutic agents. In a highly significant study, it shows that epigallocatechin gallate increases the glucose uptake by regulating insulin-signaling pathways, such as PI3K (phosphoinositide 3-kinase) and p38 MAPK (mitogen-activated protein kinase) activation and GLUT-4 translocation [24]. Tannins help reduction of blood glucose levels and offer antioxidants effects [23]. Therefore, it can be concluded that tannin-based foods are potential agents used as either nutraceutical or supplementary agents in food or medicine. A dimer of proanthocyanidin acts against the hyperglycemia that was created by sucrose feeding and by inhibiting the activity of α-glucosidase enzyme. The efficacy of proanthocyanidin has also been proved by molecular docking and strong inhibitory activity experiments.
\nIt is already mentioned that nutraceuticals or functional foods have the health promoting effect on the human and animal health. Several epidemiological studies have clearly established a relationship between (poly) phenol-rich food items and human health. It has substantially enhanced consumer awareness about the tannin-rich diet, and their disease prevention capability; therefore, there is high demand of functional foods. A large number of tannin-based compounds are isolated and characterized from fruits and vegetables (Table 1). But, despite high cost incurred on extraction and separation of tannin, it offer only low yield which is a major cause of concern [25]. Additionally, it does not provide the pure content which hindered to test the efficacy and absorption of tannin-based foods in human subject. Grape-seed proanthocyanidins (GSP) were lyophilized to improve their in vivo absorbability. It was achieved by esterification of the water-soluble GSP and immobilized lipase. Lipophilicity was tested by 1-octanol/water partition coefficient as the absorbability parameter. Further, it was observed that GSP derivatives, 3′,5′-2-O-lauroyl epigallocatechin, 3′-O-lauroyl catechin, 3′-O-lauroyl epicatechin, and 3′,3″,5″-3-O-lauroyl epicatechin gallate show high level of radical scavenging activity; hence, it can be used as the strong antioxidant in food to prevent the major degenerative diseases and aging, which are generally caused by the free radicals in the tissues [25]. Recently, B-type proanthocyanidins were isolated and purified from fruits of elephant apple (
Wood is the inseparable part of the furniture and several important industries. Wood contains organic acids, tannins, and lignocellulosic material which are most susceptible to biological, chemical, and physical decaying agents. Therefore, wood requires a large number of synthetic adhesives, glues, antitermite chemicals, and other coating materials in order to protect it. However, these materials have tremendously benefitted the wood industry, but they adversely affect the environment conditions. Because synthetic phenolics, amino resins, and formaldehyde used in wood industries are generally carcinogenic in nature. To overcome this problem, scientists are investigating natural materials of herbal or animal origins, such as tannins, that can be the best option or alternative material to be used in the wood industries [27].
\nIn recent years, a lot of attempts have been made to improve the bio-durability and commercial properties of wood and wood-based furniture by using tannin-based preservatives. Although both condensed and hydrolysable tannins are used as adhesive, but mimosa tannin is proved to be the most effective wood glue, which attributed to good cross-linking, auto-condensation, poly condensations reactions, and hyper activity. Tannin-based adhesive is proved to be harder than pure synthetic adhesive due to great level of bonding with other aldehydes or different non aldehyde hardeners (glyoxal, furfuryl alcohol, hexamine, etc.) and lignocellulosic materials. Several industries in South Africa and America are using the mimosa and quebracho-based tannins that could reduce the formaldehyde-based emission from the industries. A similar technology has been used to produce the interior and exterior grade particle board largely used in the furniture industry [28]. Apart from this, catechin and gallic acid-based epoxide adhesives and starch-based adhesives from tannins were also produced. Epoxy adhesives are produced by reactions between catechin and epichloridrin via alkylation in the presence of unsaturated halogenated compound that leads to the oxidation. Tannin-based adhesives have been used for grinding wheels, angle grinder disks, and automotive brake pads matrices also.
\nCoating material is extremely useful to prevent wood surface from biotic and abiotic adversities like, rain, winter, and summer, and insects and microorganisms. Generally, coating material comprises of polyurethane and isocyanates. The urethane-based coating material is prepared by using the lignin and lignosulfonate/hydroxypropylate. Recently, Pinus tannins and di-isocyanates were used to prepare more effective coating material by exploiting hydroxypropylation and hydroxybutylation reactions which enhanced the bonding patterns between hydroxyl groups provided by tannins (flavonoids) and isocyanates [29]. However, tannins and isocyanate-based adhesives are good and environmental friendly, but these should be replaced with more bio-based material like tannins because they are naturally designed to protect wood against fungal attacks and natural decaying process of wood.
\nAfter the industrial revolution, large numbers of synthetic chemicals were used as drug molecules to treat numerous diseases but they left several adverse effects on the human and environment. Therefore, attention has been shifted to identify new alternative natural compounds that are to be clinically effective and create minimum adverse effects. A large number of natural compounds such as polyphenolic-based secondary metabolites, for example, tannins, are isolated and characterized as preventive therapeutic agents, which can be isolated from fruits, vegetables, or plants or expressed in the microorganism by metabolic engineering. Many studies have clearly shown that tannins are natural antioxidants linked with the prevention of degenerative diseases such as atherosclerosis, cardiovascular diseases, neurodegenerative diseases, and certain types of cancers by acting as antioxidants and antibacterial.
\nReactive oxygen species such as, hydroxyl radical (HO•), superoxide anion (O2•−), and peroxyl radical (ROO•) and the non-radicals like, hydrogen peroxide (H2O2) and hypochlorous acid (HOCl) are produced in biological systems. They adversely affect cellular protective systems which are responsible for many degenerative diseases in human. In order to overcome toxic effects of reactive oxygen species (ROS), tannins can be used as ROS scavenging agents. Actually, tannins have the ability to donate electron to a free radical or ROS and make them more stable compounds therefore, render less harmful effects on cellular environment [22, 30, 31]. Tannins also help by supporting antioxidant enzymes involved in the ROS scavenging activities, simultaneously inactivating the metal ions produced by free radicals. Many tannin-based products such as gallic acid (GA) (3,4,5-trihydroxybenzoic acid), proanthocyanidins, epigallocatechin gallate (EGCG), and ellagic acid-4-O-α-D-xylopyranoside have been tested and found highly effective as antioxidants. Gallic acid, isolated from many plant extracts, shows strong antioxidant properties responsible for the antioxidant and anticancer activities. Moreover, gallic acid derivatives (GADs) are present in large number of herbal medicines and formulations used for variety of diseases. Tannin derivatives like mucic acid gallate, mucic acid lactone gallate, monogalloylglucose, gallic acid, digalloylglucose, putranjivain A, galloyl-HHDP-glucose, elaeocarpusin, and chebulagic acid isolated from fruits of
Synthetic antibiotics are being used as antibacterial agents for a long time in medical and animal sciences. But prolonged application of antibiotics lead to the development of resistance against the antimicrobial agents among the bacterial species attributed to selective evolutionary processes, a problem being faced by researcher world over. Nowadays, methicillin-resistant
However, many antibiotic resistance mechanisms are prevailed in the resilient microbial strains, but the mechanisms studied in
Tannins have been used against the ATCC 43300 and MRSA clinical strains as membrane pump inhibitors and their mode of action was studied by using next-generation sequencing (NGS) in order to get deep understanding of antibacterial mechanisms at genome, transcriptome, and protein synthesis level. This investigation indicates that tannins mainly disrupt protein synthesis mechanisms by bringing major changes in ribosome pathways, which further caused a change in the translation processes in MRSA cells eventually leading to reduction in bacterial growth. Hence, tannins can be used as potential tools against the anti-MRSA agents in clinical application particularly, in antiseptic body solutions and antibacterial cream [31]. More recently, three ellagitannin-based tannins and isorugosin-A extracted in acetone from the fresh leaves of
Tannin and its derivatives show great antibacterial properties which are used against a large number of bacterial species such as
The antibacterial properties of tannins are not only studied in animals but in plants too. Several microorganisms cause the substantial loss in the fruit, vegetable, and plant species resulting in great economic loss. After the green revolution, huge amount of pesticides were used to prevent the bacterial and insect attacks in crops which lead to the environmental pollution and soil contamination. But bio-based pesticides or natural products can be the best option of chemical-based antibacterial agents. Recently, crude methanol extract of
The growth of fungi such as
Immune system plays a very significant role to cope up with infectious agents like bacteria, virus, fungus, pollens, and parasites. Some experiments show that tannins modulate human immune system in a highly positive manner, thus tannins act as immunomodulatory agents in the battle against infectious diseases. Leishmaniosis, a disease that caused by parasitic protozoan’s complex, comprise of more than 20 different species of
Bacterial and fungal infection is also a threat to the poultry, livestock, and animal husbandry which is responsible for high level of mortality. To overcome this problem, several antibiotics have been used for decades that proved to be very effective; consequently, it improves animal and poultry production in the world. But it is well known that extreme application of antibiotics promotes the antibiotic-resistant among the microorganisms in cattle [37, 38, 39]. Therefore, in-feed antibiotics and plant-based antibacterial agents, such as phytogenic compounds (e.g., tannin), have been discovered and promoted, which have great promises in future. In recent past, great attention has been given to antibacterial activities of tannins and their effects as dietary source in animal [37]. It has been concluded that tannins with saponins and essential oils can be used as in-feed antibiotics against bacteria, fungi, and yeasts. Because, tannins are toxic to bacteria and potentially inhibit growth of
Tannins can also act as the antinutrients in rumens of livestock due to their binding to vital biomolecules in biological systems. Several adverse effects such as availability of nutrients, metal ions chelation, binding with proteins and hinder the growth of beneficial microflora have been observed in the cattle gut. To test the adverse effect of tannin as diet component on lamb gut microflora and fermentation was studied. Both types of tannins, that is, hydrolysable and condensed with 4% extract of chestnut (
Cancer is a fatal disease and its occurrence in the human population is the major cause of concern. However, the role of tannins as chemopreservants in the cure of cancer has been widely discussed by many researchers [42]. The chemoprevention “is a means of cancer management by which the occurrence of the disease can be entirely prevented, slowed, or reversed via administration of one or more naturally occurring and/or synthetic compounds” [43]. Currently, target-based delivery of anticancer agents to the site of cancer or tumor is major challenge. In order to target tumor at nanolevel, cancer nanotechnology has made tremendous progress in last one decade. It is assumed that, if drug is delivered at nanolevel at site of tumor with a high level of specificity so that cancer can be better managed. Nanoparticles of various tannin-based compounds are also prepared but their toxicity to normal body cells left major side effects. Therefore, encapsulation of many types of tannin like, epigallocatechin-3-gallate in chitosan-tripolyphosphate nanoparticles was investigated for target-based delivery to tumor. It is well known that (−)-epigallocatechin-3-gallate, (−)-epigallocatechin, (−)-epicatechin-3-gallate and (−)-epicatechin act as anticancer and antioxidant agents. The nanoemulsions and liposomes of tannins have proven highly effective in target-based delivery of anticancer drugs in case of HepG2 cells [44]. So far, nanoencapsulation method is proved only in in vitro studies and animal models but it is rarely proved effective in normal and cancerous cells.
\nIn current era, viral infection is the major threat to the human and animal population. Tannins also show antiviral activity in case of several diseases such as HIV, herpes simplex virus 2 (HSV-2). In case of herpes simplex virus 2 silver nanoparticles with tannic acid (TA-AgNPs) act as microbicide by preventing adsorption of viral particle in the body. Additionally, tannins also provide the better adjutant properties for example, substantial improvement of production of IFN-gamma+ CD8+ T-cells, activated B cells, and plasma cells. In case of spleen also, tannins promotes production of higher amount of IFN-gamma+ NK cells and effector-memory CD8+ T-cells particularly, in case of second challenge against HSV-2 immune response [45].
\nFree-living protozoa species of
In leather industry, tannins are generally used to convert animal hide into leather. Here, the main role of tannins is to protect leather from microorganism and heat related deterioration [47]. Tanning industry is thought to be the oldest industry and was started in north western regions of Europe after the Roman conquest [48]. Tannins bind with the skin proteins and protect it from petrification, which is owed to the antibacterial property of tannins. This is due to the chemical bonds established between collagen, the main constitutive protein of skin, for example, collagens, and the tannins present in the vegetable materials. It is estimated that about 15–45% tannins binds with collagens per dry weight. After the industrial revolution, chromium-based tanning was introduced to achieve fast and speedy leather production. But chromium is a potentially carcinogenic and creates high level of pollution and soil contamination. Additionally, it limits recovery and reuse of wastes from leather industries. Water from leather industry creates more pollution, and increase biological oxygen demand (BOD) and chemical oxygen demand (COD) in polluted water. In order to overcome this problem, plant-based tannins can be substitute for chromium in leather processing. It is already mentioned that vegetable tannins were used in the leather industry since historical times. But now, tannins from different parts of plants have been utilized in leather productions [49]. Plant tannins offer many benefits such as high quality and thermal stable leather products.
\nIn addition to above mentioned applications, tannins are also used in diverse types of industries, such as paper industry where high pressure mimosa tannin impregnated alpha cellulose paper is prepared. This impregnated paper offer more abrasive resistance, adhesion properties, water vapor resistance, and staining properties [50]. Recently, natural tannin-based foam without any formaldehyde is prepared that used as acoustic absorbers, metal ion adsorption, panels crash protection, packaging, etc., but low mechanical strength of tannin foams is major impediment in its further applications [51].
\nBeverage industry is well known for tannins applications particularly, in case of the wine making. Like leather industry, wine making is also very old industry since historic time. Tannins are used in wine to provide color formations, antioxidants, aroma, proteins precipitations, and flavor development. The source of tannins in the wine is grapes skin, seeds, and addition of oak flakes which add market values to wine [52].
\nTannins are phenolic-based secondary metabolites that are present in the plant kingdom, including algae. Actually, tannins produced in the plant body and involved in the plant protections and act as antimicrobial, antiparasitic, anthelmintic, antiviral, antioxidant, and deferred cattle. Hence, they help plants to fight various types’ infections. In addition to biological roles, they also play very important roles in industrial sector, animal feeding, mining, chemical industry, and tanning industry. But there are several limitations associated with the tannins. The main negative effect of tannins as food is their absorptions and binding with various types of biomolecules such as proteins, starch, and metal ions in the digestive system, hence hinders their nutritional availability to human and animals, for example, proanthocyanidins. Some experiments show that complex of tannins and proteins are resistant to various types of proteases in animal digestive system that make proteins unavailable for livestock nutrition. Dietary tannins bind with the proline-rich proteins and as result two types of soluble and insoluble complexes formed which is responsible for astringent sensation [53]. The astringency feeling is perceived by the tongue in the form of diffuse feeling associated with extreme dryness and roughness in mouth [54]. Some experiments also show that tannins also decrease activities of intestinal microflora, consequently less absorption of organic matter and soluble fiber that attributed to damage the mucosal lining of the digestive system. Moreover, high dose of tannins like catechin used in supplements can cause renal failure, hepatitis, fever, hemolytic anemia, thrombocytopenia, and skin disorders. Due to the structural complexities, tannins are also considered as potential pollutants in industries, where tannins are used as the major substrate.
\nSingle-meal bioavailability studies have shown major antinutrient activity of tannins is metal ions chelation that cause severe deficiency of essential minerals in human. In this series iron deficiency is most prevalent in population particularly in the developing countries. Recently, single-meal studies in case of hydrolysable and oligomeric catechin and epicatechin tannins (tea and tannic acid) have conducted. It shows reduced iron bioavailability in diet particularly in long term, but it needs more investigation by using appropriate animal model systems in order to study antinutritional role of tannins [55]. Moreover, tannins not only affect iron availability, but also iron metabolism; the ferritin, an iron transport protein, is adversely affected by tannin binding in soybean seed ferritin (SSF) and consequently changes the tertiary/quaternary structure of the protein.
\nIn view of current scientific investigation, it has now become possible that tannins can be exploited in a better way because they are major sustainable raw materials for green chemistry in future. Recently, several tannase or tannin acyl hydrolase enzymes have isolated, characterized, and classified from microorganism and fungi, hence toxic effect of tannins is reduced through hydrolysis and oxidation [56, 57]. Various species of filamentous fungi that produced tannase are used for bioremediation in leather tannin industries.
\nSeveral studies have been conducted to overcome the adverse effect of tannins in the food item like, fruit and vegetable. In a major breakthrough, lactic acid bacteria fermentation-like incubation is exploited in
Tannins are phenolic-based secondary metabolites that are present in the plant kingdom, including algae. Actually, tannins produced in the plant body involved in the plant protections and act as antimicrobial, antiparasitic, anthelmintic, antiviral, antioxidant, and deferred cattle. Hence, they help plants to fight various types of infections. In addition to biological roles, they also play very important roles in industrial sector, animal feeding, mining, chemical industry, and tanning industry. But there are several limitations associated with the tannins applications. The main negative effect of tannins as food are their absorptions and binding with various types of biomolecules such as, proteins, starch, and metal ions in the digestive system; hence, they hinder their nutritional availability to human and animals.
\nI would like to thank to my Institution, GGD SD College (Panjab University) India, for providing me all the facilities and support for preparation of this manuscript.
\nAuthors declare no conflict of interest.
Authors also acknowledge the contribution of publications which could not be included in the reference section due to lack of space.
\nproanthocyanidins
\npolyethylene and low-density polyethylene
\nlinear low-density polyethylene
\nwater vapor permeability
\nsoluble dietary fiber
\nmethicillin-resistant
tannin-rich fraction from pomegranate rind
\nepigallocatechin gallate
\nelectron spray ionization and matrix-assisted laser desorption ionization time of flight mass
\nsilver nanoparticles with tannic acid
\nherpes simplex virus 2
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His studies in robotics lead him not only to a PhD degree but also inspired him to co-found and build the International Journal of Advanced Robotic Systems - world's first Open Access journal in the field of robotics.",institutionString:null,institution:{name:"TU Wien",country:{name:"Austria"}}},{id:"441",title:"Ph.D.",name:"Jaekyu",middleName:null,surname:"Park",slug:"jaekyu-park",fullName:"Jaekyu Park",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/441/images/1881_n.jpg",biography:null,institutionString:null,institution:{name:"LG Corporation (South Korea)",country:{name:"Korea, South"}}},{id:"465",title:"Dr",name:"Christian",middleName:null,surname:"Martens",slug:"christian-martens",fullName:"Christian Martens",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:null},{id:"479",title:"Dr.",name:"Valentina",middleName:null,surname:"Colla",slug:"valentina-colla",fullName:"Valentina Colla",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/479/images/358_n.jpg",biography:null,institutionString:null,institution:{name:"Sant'Anna School of Advanced Studies",country:{name:"Italy"}}},{id:"494",title:"PhD",name:"Loris",middleName:null,surname:"Nanni",slug:"loris-nanni",fullName:"Loris Nanni",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/494/images/system/494.jpg",biography:"Loris Nanni received his Master Degree cum laude on June-2002 from the University of Bologna, and the April 26th 2006 he received his Ph.D. in Computer Engineering at DEIS, University of Bologna. On September, 29th 2006 he has won a post PhD fellowship from the university of Bologna (from October 2006 to October 2008), at the competitive examination he was ranked first in the industrial engineering area. He extensively served as referee for several international journals. He is author/coauthor of more than 100 research papers. He has been involved in some projects supported by MURST and European Community. His research interests include pattern recognition, bioinformatics, and biometric systems (fingerprint classification and recognition, signature verification, face recognition).",institutionString:null,institution:null},{id:"496",title:"Dr.",name:"Carlos",middleName:null,surname:"Leon",slug:"carlos-leon",fullName:"Carlos Leon",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"University of Seville",country:{name:"Spain"}}},{id:"512",title:"Dr.",name:"Dayang",middleName:null,surname:"Jawawi",slug:"dayang-jawawi",fullName:"Dayang Jawawi",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",biography:null,institutionString:null,institution:{name:"University of Technology Malaysia",country:{name:"Malaysia"}}},{id:"528",title:"Dr.",name:"Kresimir",middleName:null,surname:"Delac",slug:"kresimir-delac",fullName:"Kresimir Delac",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/528/images/system/528.jpg",biography:"K. Delac received his B.Sc.E.E. degree in 2003 and is currentlypursuing a Ph.D. degree at the University of Zagreb, Faculty of Electrical Engineering andComputing. His current research interests are digital image analysis, pattern recognition andbiometrics.",institutionString:null,institution:{name:"University of Zagreb",country:{name:"Croatia"}}},{id:"557",title:"Dr.",name:"Andon",middleName:"Venelinov",surname:"Topalov",slug:"andon-topalov",fullName:"Andon Topalov",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/557/images/1927_n.jpg",biography:"Dr. Andon V. Topalov received the MSc degree in Control Engineering from the Faculty of Information Systems, Technologies, and Automation at Moscow State University of Civil Engineering (MGGU) in 1979. He then received his PhD degree in Control Engineering from the Department of Automation and Remote Control at Moscow State Mining University (MGSU), Moscow, in 1984. From 1985 to 1986, he was a Research Fellow in the Research Institute for Electronic Equipment, ZZU AD, Plovdiv, Bulgaria. In 1986, he joined the Department of Control Systems, Technical University of Sofia at the Plovdiv campus, where he is presently a Full Professor. He has held long-term visiting Professor/Scholar positions at various institutions in South Korea, Turkey, Mexico, Greece, Belgium, UK, and Germany. And he has coauthored one book and authored or coauthored more than 80 research papers in conference proceedings and journals. His current research interests are in the fields of intelligent control and robotics.",institutionString:null,institution:{name:"Technical University of Sofia",country:{name:"Bulgaria"}}},{id:"585",title:"Prof.",name:"Munir",middleName:null,surname:"Merdan",slug:"munir-merdan",fullName:"Munir Merdan",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/585/images/system/585.jpg",biography:"Munir Merdan received the M.Sc. degree in mechanical engineering from the Technical University of Sarajevo, Bosnia and Herzegovina, in 2001, and the Ph.D. degree in electrical engineering from the Vienna University of Technology, Vienna, Austria, in 2009.Since 2005, he has been at the Automation and Control Institute, Vienna University of Technology, where he is currently a Senior Researcher. 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De Oliveira, D.A.C. Albuquerque, T.G.S. Cruz, F.M. Yamaji and F.L. Leite",authors:[{id:"1164",title:"Dr.",name:"Fabio",middleName:"Lima",surname:"Leite",slug:"fabio-leite",fullName:"Fabio Leite"},{id:"136651",title:"MSc.",name:"Ricardo",middleName:null,surname:"De Oliveira",slug:"ricardo-de-oliveira",fullName:"Ricardo De Oliveira"},{id:"136652",title:"M.Sc.",name:"Diego",middleName:"Aparecido Carvalho",surname:"Albuquerque",slug:"diego-albuquerque",fullName:"Diego Albuquerque"},{id:"136653",title:"Prof.",name:"Tersio",middleName:null,surname:"Cruz",slug:"tersio-cruz",fullName:"Tersio Cruz"},{id:"136657",title:"Prof.",name:"Fabio",middleName:null,surname:"Yamaji",slug:"fabio-yamaji",fullName:"Fabio Yamaji"}]},{id:"63161",doi:"10.5772/intechopen.80495",title:"Modelling of Adsorption Kinetic Processes—Errors, Theory and Application",slug:"modelling-of-adsorption-kinetic-processes-errors-theory-and-application",totalDownloads:3916,totalCrossrefCites:27,totalDimensionsCites:85,abstract:"Adsorption has become a competitive method in the field of wastewater and air treatment. Adsorption kinetics is one of the main factors that must be understood before the applicability of any adsorbent. In every adsorption process, linear or non-linear analysis of the kinetics is applied. The goodness of fit index (coefficient of correlation or sum of squares) is applied to access the best model. The usage of linear or non-linear from of the adsorption kinetics has an impact on the distribution of error function. Almost in every adsorption study, linear forms have been used to conclude the best kinetic model that influence the adsorption mechanism—which might be an error. Therefore, this review highlights the mistakes in the usage of linear and non-linear models. The applicability of the adsorption kinetics in wastewater treatment is also illuminated.",book:{id:"7486",slug:"advanced-sorption-process-applications",title:"Advanced Sorption Process Applications",fullTitle:"Advanced Sorption Process Applications"},signatures:"George William Kajjumba, Serkan Emik, Atakan Öngen, H. Kurtulus Özcan\nand Serdar Aydın",authors:[{id:"26340",title:"Dr.",name:"Kurtulus",middleName:null,surname:"Ozcan",slug:"kurtulus-ozcan",fullName:"Kurtulus Ozcan"},{id:"250972",title:"Associate Prof.",name:"Serdar",middleName:null,surname:"Aydin",slug:"serdar-aydin",fullName:"Serdar Aydin"},{id:"251149",title:"Dr.",name:"Serkan",middleName:null,surname:"Emik",slug:"serkan-emik",fullName:"Serkan Emik"},{id:"251150",title:"Dr.",name:"Atakan",middleName:null,surname:"Öngen",slug:"atakan-ongen",fullName:"Atakan Öngen"},{id:"251152",title:"Mr.",name:"George William",middleName:null,surname:"Kajjumba",slug:"george-william-kajjumba",fullName:"George William Kajjumba"}]},{id:"62303",doi:"10.5772/intechopen.79374",title:"Modified Titanium Dioxide for Photocatalytic Applications",slug:"modified-titanium-dioxide-for-photocatalytic-applications",totalDownloads:3975,totalCrossrefCites:34,totalDimensionsCites:73,abstract:"Titanium dioxide (TiO2) has been widely used as a photocatalyst in many environmental and energy applications due to its efficient photoactivity, high stability, low cost, and safety to the environment and humans. However, its large band gap energy, ca. 3.2 eV limits its absorption of solar radiation to the UV light range which accounts for only about 5% of the solar spectrum. Furthermore, the photocatalytic activity of TiO2 is also limited by the rapid recombination of the photogenerated electron-hole pairs. When used in water treatment applications, TiO2 has a poor affinity toward organic pollutants, especially hydrophobic organic pollutants. Several strategies have been employed to reduce its band gap energy, its electron-hole recombination rates as well as enhance its absorption of organic pollutants. In this chapter, we review some of the most recent works that have employed the doping, decoration, and structural modification of TiO2 particles for applications in photocatalysis. Additionally, we discuss the effectiveness of these dopants and/or modifiers in enhancing TiO2 photoactivity as well as some perspective on the future of TiO2 photocatalysis.",book:{id:"7478",slug:"photocatalysts-applications-and-attributes",title:"Photocatalysts",fullTitle:"Photocatalysts - Applications and Attributes"},signatures:"John Moma and Jeffrey Baloyi",authors:[{id:"250026",title:"Dr.",name:"John",middleName:null,surname:"Moma",slug:"john-moma",fullName:"John Moma"},{id:"250963",title:"Mr.",name:"Jeffrey",middleName:null,surname:"Baloyi",slug:"jeffrey-baloyi",fullName:"Jeffrey Baloyi"}]}],mostDownloadedChaptersLast30Days:[{id:"68496",title:"Moisture Sorption Isotherms and Isotherm Model Performance Evaluation for Food and Agricultural Products",slug:"moisture-sorption-isotherms-and-isotherm-model-performance-evaluation-for-food-and-agricultural-prod",totalDownloads:1960,totalCrossrefCites:6,totalDimensionsCites:13,abstract:"Moisture sorption characteristics of agricultural and food products play important roles in such technological processes as drying, handling, packaging, storage, mixing, freeze-drying and other processes that require the prediction of food stability, shelf life, glass transition and estimation of drying time and texture and prevention of deteriorative reactions. They are useful in the computation of thermodynamic energies of moisture in the products. An understanding of moisture sorption phenomena in products, moisture sorption isotherm (MSI) determination techniques and moisture sorption isotherm model evaluation procedures would be useful in the development or selection, modeling and controlling as well as optimization of appropriate processes to make for enhanced efficiency. The phenomena addressed in this chapter are equilibrium moisture content (EMC)-water activity (aw) relationships and MSI types, temperature influence on isotherms and occurrence of moisture sorption hysteresis. MSI measurement techniques highlighted are the gravimetric, vapor pressure manometric (VPM), hygrometric and inverse gas chromatographic and the use of AquaLab equipment. Commonly used moisture sorption isotherm models (BET, GAB, modified GAB, Hailwood-Horrobin, modified Hailwood-Horrobin, modified Halsey, modified Henderson, modified Chung-Pfost and modified Oswin) were selected, and their evaluation procedures using moisture sorption data were outlined. Static gravimetric technique involving the use of saturated salt solution appears to be the most widely used and recommended method of determining the EMC of agricultural and food products. Most of the MSI models can be fitted to moisture sorption data thorough linearization by logarithmic transformation, while others can be solved using such expression as second-order polynomial. Model goodness of fit can be determined using standard (SE) error of estimate, coefficient of determination (R2), mean relative percentage deviation (P) and fraction explained variation (FEV). The acceptance of a model depends on the nature of its residual plots. A model is considered acceptable if the residual plots show uniform scatter around the horizontal value of zero showing no systemic tendency towards a clear pattern. A model is better than another model if it has lower SE, lower P, higher R2 and higher FEV. Although it appears as if a generalized MSI model is yet to exist, it is recommended that the Ngoddy-Bakker-Arkema (NBA) model should be given thorough going and extensive testing on the MSI of different categories of food as it could prove true to its generalized model posture due to the fundamental nature of its derivation.",book:{id:"8012",slug:"sorption-in-2020s",title:"Sorption in 2020s",fullTitle:"Sorption in 2020s"},signatures:"Ndubisi A. Aviara",authors:[{id:"303694",title:"Prof.",name:"Ndubisi",middleName:null,surname:"Aviara",slug:"ndubisi-aviara",fullName:"Ndubisi Aviara"}]},{id:"63788",title:"Disinfection Methods",slug:"disinfection-methods",totalDownloads:3200,totalCrossrefCites:1,totalDimensionsCites:3,abstract:"Water must be made safe to drink, and an important step in ensuring water safety is disinfection. Disinfectants are added to water to kill disease-causing microorganisms. Ground water sources can be disinfected by “The Water Treatment Rule,” which requires public water systems for disinfection. Chlorination, ozone, ultraviolet light, and chloramines are primary methods for disinfection. However, potassium permanganate, photocatalytic disinfection, nanofiltration, and chlorine dioxide can also be used. Organic material is naturally present in water. Certain forms of chlorine can react with these organic materials and result in the formation of harmful by-products; the U.S. Environmental Protection Agency has anticipated maximum levels for these contaminants.",book:{id:"7478",slug:"photocatalysts-applications-and-attributes",title:"Photocatalysts",fullTitle:"Photocatalysts - Applications and Attributes"},signatures:"Muhammad Saqib Ishaq, Zobia Afsheen, Amjad Khan and Amjad\nKhan",authors:[{id:"228353",title:"Dr.",name:"Muhammad Saqib",middleName:null,surname:"Ishaq",slug:"muhammad-saqib-ishaq",fullName:"Muhammad Saqib Ishaq"},{id:"246559",title:"Dr.",name:"Zobia",middleName:null,surname:"Afsheen",slug:"zobia-afsheen",fullName:"Zobia Afsheen"},{id:"246561",title:"Mr.",name:"Amjad",middleName:null,surname:"Khan",slug:"amjad-khan",fullName:"Amjad Khan"},{id:"271289",title:"Dr.",name:"Amjad",middleName:null,surname:"Khan",slug:"amjad-khan",fullName:"Amjad Khan"}]},{id:"41887",title:"Microbial Techniques for Hydrocarbon Exploration",slug:"microbial-techniques-for-hydrocarbon-exploration",totalDownloads:6504,totalCrossrefCites:3,totalDimensionsCites:6,abstract:null,book:{id:"2351",slug:"hydrocarbon",title:"Hydrocarbon",fullTitle:"Hydrocarbon"},signatures:"M.A. Rasheed, D.J. Patil and A.M. Dayal",authors:[{id:"143475",title:"Dr",name:"Mohammed Abdul",middleName:null,surname:"Rasheed",slug:"mohammed-abdul-rasheed",fullName:"Mohammed Abdul Rasheed"},{id:"144630",title:"Dr.",name:"Dayal",middleName:null,surname:"Anurodh",slug:"dayal-anurodh",fullName:"Dayal Anurodh"}]},{id:"58999",title:"The DFT+U: Approaches, Accuracy, and Applications",slug:"the-dft-u-approaches-accuracy-and-applications",totalDownloads:4446,totalCrossrefCites:20,totalDimensionsCites:41,abstract:"This chapter introduces the Hubbard model and its applicability as a corrective tool for accurate modeling of the electronic properties of various classes of systems. The attainment of a correct description of electronic structure is critical for predicting further electronic-related properties, including intermolecular interactions and formation energies. The chapter begins with an introduction to the formulation of density functional theory (DFT) functionals, while addressing the origin of bandgap problem with correlated materials. Then, the corrective approaches proposed to solve the DFT bandgap problem are reviewed, while comparing them in terms of accuracy and computational cost. The Hubbard model will then offer a simple approach to correctly describe the behavior of highly correlated materials, known as the Mott insulators. Based on Hubbard model, DFT+U scheme is built, which is computationally convenient for accurate calculations of electronic structures. Later in this chapter, the computational and semiempirical methods of optimizing the value of the Coulomb interaction potential (U) are discussed, while evaluating the conditions under which it can be most predictive. The chapter focuses on highlighting the use of U to correct the description of the physical properties, by reviewing the results of case studies presented in literature for various classes of materials.",book:{id:"6193",slug:"density-functional-calculations-recent-progresses-of-theory-and-application",title:"Density Functional Calculations",fullTitle:"Density Functional Calculations - Recent Progresses of Theory and Application"},signatures:"Sarah A. Tolba, Kareem M. Gameel, Basant A. Ali, Hossam A.\nAlmossalami and Nageh K. Allam",authors:[{id:"175824",title:"Dr.",name:"Nageh",middleName:"K.",surname:"Allam",slug:"nageh-allam",fullName:"Nageh Allam"},{id:"398157",title:"Dr.",name:"Sarah A.",middleName:null,surname:"Tolba",slug:"sarah-a.-tolba",fullName:"Sarah A. Tolba"},{id:"398158",title:"Dr.",name:"Kareem M.",middleName:null,surname:"Gameel",slug:"kareem-m.-gameel",fullName:"Kareem M. Gameel"},{id:"398162",title:"Dr.",name:"Basant A.",middleName:null,surname:"Ali",slug:"basant-a.-ali",fullName:"Basant A. Ali"},{id:"398163",title:"Dr.",name:"Hossam A.",middleName:null,surname:"Almossalami",slug:"hossam-a.-almossalami",fullName:"Hossam A. Almossalami"}]},{id:"40233",title:"Ammonia as a Hydrogen Source for Fuel Cells: A Review",slug:"ammonia-as-a-hydrogen-source-for-fuel-cells-a-review",totalDownloads:9263,totalCrossrefCites:15,totalDimensionsCites:39,abstract:null,book:{id:"2795",slug:"hydrogen-energy-challenges-and-perspectives",title:"Hydrogen Energy",fullTitle:"Hydrogen Energy - Challenges and Perspectives"},signatures:"Denver Cheddie",authors:[{id:"141157",title:"Dr.",name:"Denver",middleName:null,surname:"Cheddie",slug:"denver-cheddie",fullName:"Denver Cheddie"}]}],onlineFirstChaptersFilter:{topicId:"86",limit:6,offset:0},onlineFirstChaptersCollection:[{id:"81502",title:"Investigation of Synthesis Methods for Improved Platinum-Ruthenium Nanoparticles Supported on Multi-Walled Carbon Nanotube Electrocatalysts for Direct Methanol Fuel Cells",slug:"investigation-of-synthesis-methods-for-improved-platinum-ruthenium-nanoparticles-supported-on-multi-",totalDownloads:14,totalDimensionsCites:0,doi:"10.5772/intechopen.104541",abstract:"This book chapter reports on various catalyst synthesis methods (impregnation, polyol, modified polyol, and microwave-assisted modified polyol methods) to determine which method would result in the most electrochemically active platinum-ruthenium (PtRu) electrocatalyst supported on multi-walled carbon nanotubes (MWCNTs) for methanol oxidation reaction in an acidic medium. Different techniques were used to characterize the synthesized catalysts, including the high-resolution transmission electron microscope used for morphology and calculating particle sizes, and X-ray diffraction for determining crystalline sizes. The electroactive catalyst surface area, ECSA of the electrocatalysts was determined using cyclic voltammetry (CV), while the electroactivity, electron kinetics, and stability of the electrocatalysts towards methanol oxidation were evaluated using CV, electrochemical impedance spectroscopy, and chronoamperometry, respectively. The microwave-assisted modified polyol method produced the PtRu/MWCNT electrocatalyst with the most enhanced electrocatalytic activity compared to other PtRu/MWCNT catalysts produced by the impregnation, polyol, and modified polyol methods.",book:{id:"10381",title:"Electrocatalysis and Electrocatalysts for a Cleaner Environment - Fundamentals and Applications",coverURL:"https://cdn.intechopen.com/books/images_new/10381.jpg"},signatures:"Adebare Nurudeen Adewunmi, Sabejeje Akindeji Jerome, Su Huaneng and Lindiwe Eudora Khotseng"},{id:"79547",title:"Nickel Foam Electrode with Low Catalyst Loading and High Performance for Alkaline Direct Alcohol Fuel Cells",slug:"nickel-foam-electrode-with-low-catalyst-loading-and-high-performance-for-alkaline-direct-alcohol-fue",totalDownloads:149,totalDimensionsCites:0,doi:"10.5772/intechopen.100287",abstract:"Nickel foam has a unique three-dimensional (3-D) network structure that helps to effectively utilize catalysts and is often used as an electrode support material for alkaline direct alcohol fuel cells. In this chapter, first, the effect of nickel foam thickness on cell performance is explored. The results show that the thickness affects both mass transfer and electron conduction, and there is an optimal thickness. The thinner the nickel foam is, the better the conductivity is. However, the corresponding three-dimensional space becomes narrower, which results in a partial agglomeration of the catalyst and the hindrance of mass transfer. The cell performance of 0.6 mm nickel foam electrode is better than that of 0.3 and 1.0 mm. Secondly, to fully exert the catalytic function of the catalyst even at a lower loading, a mixed acid-etched nickel foam electrode with lower Pd loading (0.35 mg cm−2) is prepared then by a spontaneous deposition method. The maximum power density of the single alkaline direct ethanol fuel cell (ADEFC) can reach 30 mW cm−2, which is twice the performance of the hydrochloric acid treated nickel foam electrode. The performance improvement is attributed to the micro-holes produced by mixed acids etching, which enhances the roughness of the skeleton and improves the catalyst electrochemical active surface area.",book:{id:"10381",title:"Electrocatalysis and Electrocatalysts for a Cleaner Environment - Fundamentals and Applications",coverURL:"https://cdn.intechopen.com/books/images_new/10381.jpg"},signatures:"Qian Xu, Jiajia Zhang and Chunzhen Yang"},{id:"77862",title:"Characterization, Photoelectric Properties, Electrochemical Performances and Photocatalytic Activity of the Fe2O3/TiO2 Heteronanostructure",slug:"characterization-photoelectric-properties-electrochemical-performances-and-photocatalytic-activity-o",totalDownloads:107,totalDimensionsCites:0,doi:"10.5772/intechopen.98759",abstract:"The Fe2O3/TiO2 nanocomposite was synthesized on FTO subtract via hydrothermal method. The crystal structure, morphology, band structure of the heterojunction, behaviors of charge carriers and the redox ability were characterized by XRD, HR-TEM, absorption spectra, PL, cyclic voltammetry and transient photocurrent spectra. The as-prepared Fe2O3/TiO2 photocatalysts with distinctive structure and great stability was characterized and investigated for the degradation of methylene blue (MB) dye in aqueous solution. The ability of the photocatalyst for generating reactive oxygen species, including O2− and.OH was investigated. It was revealed that the combination of the two oxides (Fe2O3 and TiO2) nano-heterojunction could enhance the visible response and separate photogenerated charge carriers effectively. Therefore, the remarkable photocatalytic activity of Fe2O3/TiO2 nanostructures for MB degradation was ascribed to the enhanced visible light absorption and efficient interfacial transfer of photogenerated electrons from to Fe2O3 to TiO2 due to the lower energy gap level of Fe2O3/TiO2 hybrid heterojunctions as evidenced by the UV–Vis and photoluminescence studies. The decrease of the energy gap level of Fe2O3/TiO2 resulted in the inhibition of electron–hole pair recombination for effective spatial charge separation, thus enhancing the photocatalytic reactions. Based on the obtained results, a possible mechanism for the improved photocatalytic performance associated with Fe2O3/TiO2 was proposed. The Fe2O3/TiO2 nanocomposite has a specific capacity of 82 F.g−1 and shows a higher capacitance than Fe2O3.",book:{id:"10381",title:"Electrocatalysis and Electrocatalysts for a Cleaner Environment - Fundamentals and Applications",coverURL:"https://cdn.intechopen.com/books/images_new/10381.jpg"},signatures:"Salah Kouass, Hassouna Dhaouadi, Abdelhak Othmani and Fathi Touati"},{id:"76150",title:"Heterogeneous Electrocatalysts for CO2 Reduction to Value Added Products",slug:"heterogeneous-electrocatalysts-for-co-sub-2-sub-reduction-to-value-added-products",totalDownloads:221,totalDimensionsCites:1,doi:"10.5772/intechopen.97274",abstract:"The CO2 that comes from the use of fossil fuels accounts for about 65% of the global greenhouse gas emission, and it plays a critical role in global climate changes. Among the different strategies that have been considered to address the storage and reutilization of CO2, the transformation of CO2 into chemicals and fuels with a high added-value has been considered a winning approach. This transformation is able to reduce the carbon emission and induce a “fuel switching” that exploits renewable energy sources. The aim of this chapter is to categorize different heterogeneous electrocatalysts which are being used for CO2 reduction, based on the desired products of the above mentioned reactions: from formic acid and carbon monoxide to methanol and ethanol and other possible by products. Moreover, a brief description of the kinetic and mechanism of the CO2 reduction reaction) and pathways toward different products have been discussed.",book:{id:"10381",title:"Electrocatalysis and Electrocatalysts for a Cleaner Environment - Fundamentals and Applications",coverURL:"https://cdn.intechopen.com/books/images_new/10381.jpg"},signatures:"M. Amin Farkhondehfal and Juqin Zeng"},{id:"74671",title:"C-H Activation/Functionalization via Metalla-Electrocatalysis",slug:"c-h-activation-functionalization-via-metalla-electrocatalysis",totalDownloads:220,totalDimensionsCites:0,doi:"10.5772/intechopen.95517",abstract:"In conventional methods, C−H activations are largely involved in the use of stoichiometric amounts of toxic and expensive metal & chemical oxidants, conceding the overall sustainable nature. Meanwhile, undesired byproducts are generated, that is problematic in the scale up process. However, electrochemical C−H activation via catalyst control strategy using metals as mediators (instead electrochemical substrate control strategy) has been identified as a more efficient strategy toward selective functionalizations. Thus, indirect electrolysis makes the potential range more pleasant, and less side reactions can occur. Herein, we summarize the metalla-electrocatalysis process for activations of inert C−H bonds and functionalization. These Metalla-electrocatalyzed C−H bond functionalizations are presented in term of C−C and C−X (X = O, N, P and halogens) bonds formation. The electrooxidative C−H transformations in the presence of metal catalysts are described by better chemoselectivities with broad tolerance of sensitive functionalities. Moreover, in the future to enhance sustainability and green chemistry concerns, integration of metalla-electrocatalysis with flow and photochemistry will enable safe and efficient scale-up and may even improve reaction times, kinetics and yields.",book:{id:"10381",title:"Electrocatalysis and Electrocatalysts for a Cleaner Environment - Fundamentals and Applications",coverURL:"https://cdn.intechopen.com/books/images_new/10381.jpg"},signatures:"Guilherme M. Martins, Najoua Sbei, Geórgia C. Zimmer and Nisar Ahmed"},{id:"74780",title:"Recent Trends in Development of Metal Nitride Nanocatalysts for Water Electrolysis Application",slug:"recent-trends-in-development-of-metal-nitride-nanocatalysts-for-water-electrolysis-application",totalDownloads:251,totalDimensionsCites:1,doi:"10.5772/intechopen.95748",abstract:"Nanocatalysts for sustainable water electrolysis is strongly desirable to promote the commercialization of H2 as the alternate clean energy source for the future. The goal is cheaper hydrogen production from sea and low grade water by minimizing the energy consumption and using low cost cell components & non-noble metal catalysts. The conductivity of metal nitrides and their ability to carry out Hydrogen Evolution Reaction and Oxygen Evolution Reaction at relatively low overpotential render these one of the frontline candidates to be potentially utilized as the catalyst for low cost H2 production via electrolysis. In this chapter, the potential of metal nitride catalyst towards fulfilling the above objective is discussed. The synthesis of various metal nitride catalysts, their efficiency towards electrode half reactions and the effectiveness of these class of nanocatalyst for electrolysis of sea water is elaborated. A review of recent literature with special reference to the catalyst systems based on non-noble metals will be provided to assess the likelihood of these nanocatalyst to serve as a commercial grade electrode material for sea water electrolysis.",book:{id:"10381",title:"Electrocatalysis and Electrocatalysts for a Cleaner Environment - Fundamentals and Applications",coverURL:"https://cdn.intechopen.com/books/images_new/10381.jpg"},signatures:"Akhoury Sudhir Kumar Sinha and Umaprasana Ojha"}],onlineFirstChaptersTotal:8},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:89,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:104,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:31,numberOfPublishedChapters:314,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:11,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:11,numberOfPublishedChapters:141,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:8,numberOfPublishedChapters:129,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:113,numberOfOpenTopics:3,numberOfUpcomingTopics:1,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:105,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:18,numberOfOpenTopics:2,numberOfUpcomingTopics:1,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:5,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:0,numberOfPublishedChapters:14,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:null,doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}},{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}}]},series:{item:{id:"25",title:"Environmental Sciences",doi:"10.5772/intechopen.100362",issn:"2754-6713",scope:"\r\n\tScientists have long researched to understand the environment and man’s place in it. The search for this knowledge grows in importance as rapid increases in population and economic development intensify humans’ stresses on ecosystems. Fortunately, rapid increases in multiple scientific areas are advancing our understanding of environmental sciences. Breakthroughs in computing, molecular biology, ecology, and sustainability science are enhancing our ability to utilize environmental sciences to address real-world problems.
\r\n\tThe four topics of this book series - Pollution; Environmental Resilience and Management; Ecosystems and Biodiversity; and Water Science - will address important areas of advancement in the environmental sciences. They will represent an excellent initial grouping of published works on these critical topics.
\r\n\tSustainable development focuses on linking economic development with environmental protection and social development to ensure future prosperity for people and the planet. To tackle global challenges of development and environment, the United Nations General Assembly in 2015 adopted the 17 Sustainable Development Goals. SDGs emphasize that environmental sustainability should be strongly linked to socio-economic development, which should be decoupled from escalating resource use and environmental degradation for the purpose of reducing environmental stress, enhancing human welfare, and improving regional equity. Moreover, sustainable development seeks a balance between human development and decrease in ecological/environmental marginal benefits. Under the increasing stress of climate change, many environmental problems have emerged causing severe impacts at both global and local scales, driving ecosystem service reduction and biodiversity loss. Humanity’s relationship with resource exploitation and environment protection is a major global concern, as new threats to human and environmental security emerge in the Anthropocene. Currently, the world is facing significant challenges in environmental sustainability to protect global environments and to restore degraded ecosystems, while maintaining human development with regional equality. Thus, environmental sustainability with healthy natural ecosystems is critical to maintaining human prosperity in our warming planet.
",coverUrl:"https://cdn.intechopen.com/series_topics/covers/94.jpg",hasOnlineFirst:!0,hasPublishedBooks:!1,annualVolume:11978,editor:{id:"61855",title:"Dr.",name:"Yixin",middleName:null,surname:"Zhang",slug:"yixin-zhang",fullName:"Yixin Zhang",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002aYWJgQAO/Profile_Picture_2022-06-09T11:36:35.jpg",biography:"Professor Yixin Zhang is an aquatic ecologist with over 30 years of research and teaching experience in three continents (Asia, Europe, and North America) in Stream Ecology, Riparian Ecology, Urban Ecology, and Ecosystem Restoration and Aquatic Conservation, Human-Nature Interactions and Sustainability, Urbanization Impact on Aquatic Ecosystems. He got his Ph.D. in Animal Ecology at Umeå University in Sweden in 1998. He conducted postdoc research in stream ecology at the University of California at Santa Barbara in the USA. After that, he was a postdoc research fellow at the University of British Columbia in Canada to do research on large-scale stream experimental manipulation and watershed ecological survey in temperate rainforests of BC. He was a faculty member at the University of Hong Kong to run ecological research projects on aquatic insects, fishes, and newts in Tropical Asian streams. He also conducted research in streams, rivers, and caves in Texas, USA, to study the ecology of macroinvertebrates, big-claw river shrimp, fish, turtles, and bats. 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