Chapters authored
Microemulsion Route for the Synthesis of Nano-Structured Catalytic Materials
Owing to their unique properties, use of microemulsion‐based synthetic techniques for the generation of shape‐controlled nanocatalyst is an area of great current interest. Nanocatalysts of any specific shape, morphology, surface area, size, geometry, homogeneity and composition are widely being prepared using the soft techniques of microemulsion. Easy handling, inexpensive equipment and mild reaction conditions make microemulsion an attractive reaction medium. Herein, a nanosized precursor reactant can be incorporated, leading to the formulation of a highly monodispersed metal nanoagglomerate with controlled size, shape and composition. Several factors such as presence of electrolyte, molar ratio of water to surfactant, nature and concentration of surfactant and solvent, size of water droplets and concentration of reducing agents influence the size of the nanoparticles. The reverse micelle method can be used for the fabrication of several nanosized catalysts with a diverse variety of suitable materials including silica, alumina, metals (e.g. Au, Pd, Rh, Pt), metal oxides, etc. The morphology, size distribution and shape of the nanocatalysts make them useable for a wide range of applications, for example, fuel cells, electrocatalysis, photocatalysis, environmental protection, etc. The recovery of nanoparticles from the reaction mixture is a challenge for the researchers. This chapter discusses the preparation of nanoparticles using microemulsion techniques, widely being used for the synthesis of nanocatalysts from a wide range of materials.
Part of the book: Properties and Uses of Microemulsions
Applications of Carbon Based Materials in Developing Advanced Energy Storage Devices
With the increasing pressure of population, the energy demand is growing explosively. By 2050, it is expected that the world population may reach to about 9 billion which may result in the increase of energy requirement to about 12.5 trillion watts. Due to increasing pressures of population, industries and technology, concerns to find possibilities to cope with increasing demand of energy resources, arise. Although the renewable energy resources including fossil fuels, wind, water and solar energy have been used for a long time to fulfill the energy requirements, but they need efficient conversions and storage techniques and are responsible for causing environmental pollution due to greenhouse gases as well. It is thus noteworthy to develop methods for the generation and storage of renewable energy devices that can replace the conventional energy resources to meet the requirement of energy consumption. Due to high energy demands, the sustainable energy storage devices have remained the subject of interest for scientists in the history, however, the traditional methods are not efficient enough to fulfill the energy requirements. In the present era, among other variety of advanced treatments, nano-sciences have attracted the attention of the scientists. While talking about nano-science, one cannot move on without admiring the extraordinary features of carbon nanotubes (CNTs) and other carbon based materials. CNTs are on the cutting edge of nano science research and finding enormous applications in energy storage devices. Excellent adsorption capabilities, high surface area, better electrical conductivity, high mechanical strength, corrosion resistance, high aspect ratio and good chemical and physical properties of CNTs have grabbed tremendous attention worldwide. Their charge transfer properties make them favorable for energy conversion applications. The limitation to the laboratory research on CNTs for energy storage techniques due to low specific capacitance and limited electrochemical performance can be overcome by surface functionalization using surface functional groups that can enhance their electrical and dispersion properties. In this chapter, ways CNTs employed to boost the abilities of the existing material used to store and transfer of energy have been discussed critically. Moreover, how anisotropic properties of CNTs play important role in increasing the energy storage capabilities of functional materials. It will also be discussed how various kinds of materials can be combined along CNTs to get better results.
Part of the book: Carbon Nanotubes