Nanyang Technological University Singapore
Vanadium dioxide is a promising thermochromic material, seemed as the great candidate for smart window applications. The real application of VO2 requires high visible transmission (Tlum) as well as large solar modulating abilities (∆Tsol), which could not be achieved by pristine VO2 materials due to the trade-off between Tlum and ∆Tsol. Here in, the porosity design is thoroughly reviewed from the effect on modulating the thermochromic performance to the porous control and preparation. To begin with, the history, advantages, challenges and approaches to tackle the issues comprised of antireflection multilayer structure, nanothermochromism, patterning and porous design is introduced in detail. Then, the effect of porosity on improving the thermochromic performance of VO2 thin films is demonstrated using the newest experimental and simulation results. In the following, the porous control and structural synthesis, including the polymer-assisted deposition (PAD), freeze-drying, colloidal lithography as well as the dual phase transformation is summarized. Fourthly, the characterization methods, composed of scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray diffraction (XRD), Raman spectroscopy as well as UV-Vis-NIR spectroscopy are demonstrated. Finally, the challenges that the porous design faces and possible approaches to optimize the performance are presented.
Part of the book: Porosity