Ruthenium complexes for DSSC [26, 27, 28, 29, 30, 31, 32, 33].
Abstract
Ligand with conjugated π systems presents high planar and delocalized electronic density, which allows it to capture the radiations with an energy interval of wavelengths between 400 and 600 nm. The ligands can be linked to inorganic materials favoring the interchange in the system. Lewis acids improve the electronic distribution between donor and acceptor favoring the optical and electronic properties, yielding superior efficiencies. In this chapter, the evolution of the ligands such as Porphyrins, Metal-free organic dyes, and Ruthenium complexes used, and the construction of solar cells is described. In this context, three different small-molecule acceptors-donors are reported; o-PDT, m-PDT and p-PDT, based on phenyldiammine (PD) as spacer, and Thiazole (T) were designed and synthesized. There were estimated electronic, optical and photovoltaic parameters for these molecules. The interaction energies of functional groups for PD and T molecules, with DFT/B3LYP method, gas phase with 6-31g (d, 2p) basis sets, were represented and computed. The best photovoltaic parameters were described for p-PDT with PCE 26.18%, Jsc = 14.79 mAcm2 and ΔE = 2.66 eV. The metal ion influences the electronic properties and decreases the ΔE GAP. The incorporation of the transition metals into hyperconjugated systems provides rigidity and effects of electronic back donation.
Keywords
- photovoltaic cells
- semiconductor
- coordination compounds
- dye-sensitized
1. Introduction
The current environmental problems and the energy crisis have led to creating new technologies. The renewable energies such as: biofuels, biomass, wind, geothermal, hydraulic, solar, tidal, among others become the main source of the energy generation. The use of solar cells represents an alternative among renewable energies. The development of new materials goes from inorganic structures until polymers, small molecules as organic photovoltaic (OPV) and photosensitized organic materials [1].
In this context, the discovery of ultrafast charge transfer between the semiconductor polymer and inorganic semiconductors have allowed that the OPV have passed in a decade of values close to 1% of efficiency until exceeding 10% [2]. This rapid evolution is motivated by its high potential for generating flexible, lightweight and low cost panels changing the classic concept of panels photovoltaic. In the case of the traditional polymers, the electrons are highly localized and require great energy to be excited (>5 eV) converting them into electrical insulators. In contrast, in conjugated polymer and structures the electrons from Z orbitals form π-type bonds that are associated with lower energies, corresponding to the range of ultraviolet and visible radiation. In molecular solids the transition π → π* that occurs between the occupied molecular orbital of higher energy (HOMO) and the lower energy of orbital (LUMO) determine the equivalent to the forbidden band energy of inorganic semiconductors [3, 4]. On the other hand, they had developed sensitized cell from organic dyes. These are also called Grätzel cells. Photoelectrons that introduce into the conduction band of TiO2 that works as a semiconductor, under light illumination [5].
Dye-sensitized cell (DSSC) have been developed as functional biomimetic models of biological process. In the nature exists dyes with electronic properties that allows to purpose design news in solar panel. Chlorophyll, constituted an example in where there is light absorption and charge-carrier transport. The organic molecule is coupled to semiconductor enhancing the Gap band. This electronic transfer promote absorption to the visible region, which increase its applications [6].
The researchers in a world context have designed, developed and synthetized ruthenium complexes, porphyrins, metal-free organic dyes and organic molecules in this field.
1.1 Ruthenium complexes
The efficiency of DSSC depends on different requirements listed below [7, 8]:
Broad and strong absorption, preferably extending from energies greater than 900 nm.
The dye needs to be photochemically, thermally, and electrochemically robust within the DSSC in order to withstand the harsh conditions of a practical module.
Firm, irreversible adsorption to the semiconductor’s surface (TiO2) and strong electronic coupling between its excited state and the semiconductor conduction band.
Reduction potential is sufficiently higher than the semiconductor conduction band Edge in order to enable charge injection.
Chemical stability in the ground and the excited states for rapid dye regeneration and charge-injection processes.
Different types of dyes have been tested in the DSSC setting, including: transition-metal complexes, organic dyes, porphyrins and phthalocyanines [9, 10, 11, 12]; however, in terms of photovoltaic performance and long-term stability, Ru(II) complexes comprise the most successful family of DSSCs sensitizers, shown in Table 1. A study on these champion dyes reveals that majority are derivate of
1.2 Porphyrins
The so-called solar cells sensitized by a dye are a type of hybrid devices that have reached a higher degree of development so far. Within his field, porphyrins represent a very interesting alternative because there is efficient model harnessing sunlight. These systems can be synthetized in bulk heterojunction (BHJ) organic solar cells. The interaction of macrocycles with metal ions such as: Fe2+, Fe3+, Co2+, Co3+, Ni2+, Zn2+, Cu2+, Ru2+, Pd2+ and Pt2+ and hydrogen, alkyl, cycloalkyl, cyclohexyl, cycloheptyl, cyclooctyl, haloalkyl, perhaloalkyl, ether chains have permitted the stabilizations of promising new collections. In dye-sensitized solar porphyrin-based push-pull.
photosensitizers have demonstrated their potential as large and rigid planar conjugated structures, which enhance p-electron delocalization and promote intermolecular π-π interaction, as well charge transport in devices. A problem that they can presents is the effect by lack of light-harvesting beyond 850 nm, thus limiting their cell performance. In the papers, it has been reported that 50% of the total solar phonon flux is located in the red and near-infrared spectra. Zhu and colleagues had reported in 2016 that is quite urgent to develop efficient NIR absorbing molecules for high performance organic solar cells. In the next table, the authors show different publications about the development of new bioinspired porphyrin materials (Table 2).
1.3 Metal-free organic dyes
The DSSC free organic dyes are sensitized molecules whose perspective are aimed at staking, on top of one other in order to obtain panchromatic absorption. Table 3 shows azo, cyano, thiophene, and carbonyl with highly conjugated. A PCE value at 14.7 has been reported by Kakiag et al. [49]. The PCE increase with Voc and Jsc and the best properties were associated with carboxylic group and highly polarizability in the presence of nitrile group.
The extension of the conjugated chain and the substitution of the thiophene groups do not represent a marked difference that allows concluding a relationship between the photovoltaic properties and the structure.
Therefore, this article reports the bibliographic revision for these compounds, specifying the following parameters: Chemical name, abbreviation, structure, power conversion efficiencies (PCE), Jsc (short-circuit-current), Voc (open circuit voltage) electrolyte used and authors.
On the other hand, in this research also have been reported the theoretical studies towards the effect the spacer molecule in macrocycles. The linear molecule designed was a benzothiophene derivate (T) and the spacer selected were
The stationary point was estimated with level of theory reported previously for the authors [64]. Finally, the authors through the Lewis acid incorporation showed an electronic improvement mechanism. The acid Lewis effect, as evaluated considering the tetracoordinated mode around metal center (Figure 2).
2. Material and methods
2.1 Method theoretical
To explore and understand the electronic and optoelectronic properties of photosensitized materials with application in OPV technology, many theories have emerged. One of the most important and common theories is the theory of functional density (DFT), which is a tool that allowed to establish any property used in photosensitized materials, quantum state of atoms, molecules and solids, making modeling and simulation possible of complex systems with millions of degrees of freedom. At present, DFT has grown tremendously and has become one of the main tools in theoretical physics and molecular chemistry. Modeling in the framework of computational chemistry of photosensitized systems made up of electron donors and electron acceptors ultimately influences photo induced electron transfer and energy reactions. Numerous studies using the Density Functional Theory (DFT) methodology to design, evaluate and predict photovoltaic properties of photoactive materials with application in OPV have been published. The approximation of the theory of functional density (DFT) implemented was Gaussian 09 together with the functional correlation (B3LYP) and the base set 6-31g (d, 2p). This calculation allows optimization of geometry without symmetry restrictions for stationary points. In addition, it provided information on the harmonic frequency analysis, which allows the optimized minimum to be verified. The local minimum is identified when the number of imaginary 32frequencies is equal to zero.
The analysis of the changes in electron density for a given electronic transition was based on the electron density difference maps (EDDMs) constructed using the GaussSum suite of programs. Gásquez and co-workers had proposed two different electronegativities (X) for the charge transfer process: one that describes fractional negative charge donation
Thus, the construction of a so-called donor-acceptor map (DAM) has been suggested. A DAM graphic can be constructed by plotting the values of (y-axis) and
The photovoltaic properties are calculated according to the Scharber model, which is an empirical model for predicting the PCE of organic cell solar. HOMO-LUMO as orbital border under solar irradiation with AM 1.5 G (ASTM G173). The PCE was expressed by the following Eqs. (3) and (4), in where Voc is the open circuit voltage, and Jsc is short circuit current.
where
(q = elementary charge, EQE = external quantum efficiency, ϕ = irradiation flow with AM 1.5 G, and λ = wavelength), and Pinc (incident light power).
On the other hand, the valor corresponding ΔEGAP was calculated as, Eq. (5):
3. Results and discussion
3.1 Optical properties of macrocycle molecules
The excitation energies (Es1) presented in Table 4 were relatively small for the PDT molecule ligand, which indicate a shift to visible region in relationship with λmax. The
Molecule | Wavelength λmax | Es1 (eV) | LHE | |
---|---|---|---|---|
432.68 | 2.874 | 2.0217 | 0.9905 | |
425.37 | 2.923 | 2.8755 | 0.9987 | |
465 | 2.67 | 0.07 | 0.14 |
The LHE values were 2.0217, 2.8755 and 0.07 for
The visible light absorption ability may benefit from absorbing more photons and generating high photocurrent, which is a strong advantage of T derivatives. In the previous reports, PD spacers that cannot absorb visible light were observed. It is necessary that T derivate linked to the PD fragment enhances the electronic coupling in the excited state, which operates as a gated wire in π-conjugated systems, as is observed for
3.2 Geometry study for macrocycles with Lewis acid.
The effect of Lewis acid on macrocycle stabilization is shown below. The geometric environment of the metallic center was tetrahedral, considering two positions to the electro donator atoms corresponding to linear and macrocycle molecule; and two water molecules. The incorporation of the metal into the linear chain (ZnT) generates a decrease in the value for GAP around 1.72 eV, a value located in the visible region. However, the effect is more severe when incorporated into the macrocycle, in where; its addition generated a decrease in GAP still 1.55 eV (
The spectra in Figure 5 showed a similar profile for TZn, and
3.3 Photovoltaic properties of macrocycle molecules
The results showed in Table 5 suggested decreased the ΔEGAP in relationship with PCE. These results are congruent with the optical, and electronic properties observed previously. The
Molecule | ΔEGAP (eV) | Jsc (mA/cm2) | Voc (V) | FF | PCE (%) |
---|---|---|---|---|---|
T | 3.07 | 5.36 | 2.77 | 0.75 | 11.12 |
2.66 | 14.79 | 2.36 | 0.75 | 26.18 | |
ZnT | 1.72 | 21.52 | 1.42 | 0.75 | 22.92 |
1.55 | 11.76 | 1.25 | 0.75 | 11.02 |
4. Summary and future perspectives
The purpose of this review of DSSC materials was to compile the information reported to: synthetized ruthenium complexes, porphyrins, and metal-free organic dyes. For researchers, it is important to know parameters such as: PCE, Jsc, and Voc; which help you to diffuse between structures, and propose synthesis strategies that make possible new materials in this field application. Principles for the future development of new molecules can be analyzed and likewise it is interesting support to follow up structure families as a function of time. Although many structures are shown here, there is still a need to optimize the chemical, and physical properties to promote improved solar cells. On the other hand, in this work, the best photovoltaic parameters were described for
Acknowledgments
This work was supported by Universidad Santiago de Cali—DGI Grants 63661. The author acknowledgment to Melissa Suarez for technical support and Hoover Valencia for data acquisition.
References
- 1.
Owusu PA, Asumadu-Sarkodie S. A review of renewable energy sources, sustainability issues, and climate change mitigation. Cogent Engineering. 2016; 3 (1):1167990 - 2.
Wang P, Zakeeruddin SM, Moser JE, Humphry-Baker R, Comte P, Aranyos V, et al. Stable new sensitizer with improved light harvesting for nanocrystalline dye-sensitized solar cells. Advanced Materials. 2004; 16 (20):1806-1811 - 3.
Hara K, Sugihara H, Tachibana Y, Islam A, Yanagida M, Sayama K, et al. Dye-sensitized nanocrystalline TiO2 solar cells based on ruthenium (II) phenanthroline complex photosensitizers. Langmuir. 2001; 17 (19):5992-5999 - 4.
Manivel P, Mohana Roopan S, Nawaz Khan F. Synthesis of O-substituted benzophenones by Grignard reaction of 3-substituted isocoumarins. Journal of the Chilean Chemical Society. 2008; 53 (3):1609-1610 - 5.
Philipps SP, Bett AW, Horowitz K, Kurtz S. Current Status of Concentrator Photovoltaic (CPV) Technology. No. NREL/TP-5J00-65130. Golden, CO (United States): National Renewable Energy Lab. (NREL); 2015 - 6.
Dusastre V. Materials for sustainable energy: A collection of peer-reviewed research, and review articles. Editorial. Nature Publishing Group, World Scientific; 2011 - 7.
O'regan B, Grätzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature. 1991; 353 (6346):737 - 8.
Mathews L, Tidwell C, Bharara P, Stephens G, Su T, Carter A. Copper 5, 10, 15, 20-Tetrakis-(3, 4-dibenzyloxyphenyl) porphyrin. Molbank. 2017; 1 (2017):M931 - 9.
Robertson N. Optimizing dyes for dye-sensitized solar cells. Angewandte Chemie International Edition. 2006; 45 (15):2338-2345 - 10.
Xie P, Guo F. Molecular engineering of ruthenium sensitizers in dye-sensitized solar cells. Current Organic Chemistry. 2007; 11 (14):1272-1286 - 11.
Bessho T, Zakeeruddin SM, Yeh C-Y, Diau EW-G, Grätzel M. Highly efficient mesoscopic dye-sensitized solar cells based on donor–acceptor-substituted porphyrins. Angewandte Chemie International Edition. 2010; 49 (37):6646-6649 - 12.
Schiffmann F, VandeVondele J, Hutter J, Urakawa A, Wirz R, Baiker A. An atomistic picture of the regeneration process in dye sensitized solar cells. Proceedings of the National Academy of Sciences. 2010; 107 (11):4830-4833 - 13.
Nazeeruddin MK, Kay A, Rodicio I, Humphry-Baker R, Müller E, Liska P, et al. Conversion of light to electricity by cis-X2bis (2, 2′-bipyridyl-4, 4′-dicarboxylate) ruthenium (II) charge-transfer sensitizers (X= Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes. Journal of the American Chemical Society. 1993; 115 (14):6382-6390 - 14.
Yu Q, Wang Y, Yi Z, Ningning Z, Zhang J, Zhang M, et al. High-efficiency dye-sensitized solar cells: The influence of lithium ions on exciton dissociation, charge recombination, and surface states. ACS Nano. 2010; 4 (10):6032-6038 - 15.
Duan C, Huang F, Cao Y. Recent development of push–pull conjugated polymers for bulk-heterojunction photovoltaics: Rational design and fine tailoring of molecular structures. Journal of Materials Chemistry. 2012; 22 (21):10416-10434 - 16.
Chen G, Sasabe H, Igarashi T, Hong Z, Kido J. Squaraine dyes for organic photovoltaic cells. Journal of Materials Chemistry A. 2015; 3 (28):14517-14534 - 17.
Xunjin ZHU, Chen S, Wong WY, Wong WK. Design and synthesis of porphyrin materials for highly efficient organic photovoltaics. U.S. Patent Application 15/635,563. 2018 - 18.
Suarez M, Patricia Avila-Torres Y, Caicedo C, Guateque J, Florez-Lopez E. Novel macrocyclic thiazole as potential organic photovoltaic. In: Proceedings of the 10 th European meeting on Solar Chemistry and Photocatalysis: Environmental Applications (SPEA10). 2018. pp. 626-628 - 19.
Frisch MJEA, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, et al. Gaussian 09, Revision a. 02. Wallingford, CT: Gaussian. Inc.; 2009. p. 200 - 20.
Hohenberg P, Kohn W. Inhomogeneous electron gas. Physical Review. 1964; 136 :B864 - 21.
Kohn W, Sham LJ. Self-consistent equations including exchange and correlation effects. Physical Review. 1965; 140 :A1133 - 22.
Astm G. 173-03: Standard Tables for Reference Solar Spectral Irradiances: Direct Normal and Hemispherical on 37 Tilted Surface. West Conshohoken, PA: ASTM International; 2003 - 23.
Lee C, Yang W, Parr RG. Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density. Physical Review B. 1988; 37 :785 - 24.
Williams RM, De Cola L, Hartl F, Lagref JJ, Planeix JM, De Cian A, et al. Photophysical, electrochemical and electrochromic properties of copper-bis (4, 4′-dimethyl-(32)6, 6′-diphenyl-2, 2′-bipyridine) complexes. Coordination Chemistry Reviews. 2002; 230 :253-261 - 25.
Lee S, Seok CH, Park Y, Lee A, Jung DH, Choi SH, et al. Enforced effects of side group substitution position on luminescence properties; synthesis of Bis (dipyrrinato) zinc complex derivatives. Molecular Crystals and Liquid Crystals. 2010; 531 :65-365 - 26.
Fitri A, Benjelloun AT, Benzakour M, Mcharfi M, Hamidi M, Bouachrine M. Theoretical design of thiazolothiazole-based organic dyes with different electron donors for dye-sensitized solar cells. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2014; 132 :232-238 - 27.
Nazeeruddin MK, Pechy P, Renouard T, Zakeeruddin SM, Humphry-Baker R, Comte P, et al. Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells. Journal of the American Chemical Society. 2001; 123 (8):1613-1624 - 28.
Gao F, Wang Y, Dong S, Zhang J, Wang M, Jing X, et al. Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells. Journal of the American Chemical Society. 2008; 130 (32):10720-10728 - 29.
Chen C-Y, Wang M, Li J-Y, Pootrakulchote N, Alibabaei L, Ngoc-le C-h, et al. Highly efficient light-harvesting ruthenium sensitizer for thin-film dye-sensitized solar cells. ACS Nano. 2009; 3 (10):3103-3109 - 30.
Swetha T, Niveditha S, Bhanuprakash K, Singh SP. Panchromatic Ru (II) Dipyrrins as NCS free sensitizers showing highest efficiency for DSSCs. Electrochimica Acta. 2015; 153 :343-351 - 31.
Naik P, Elmorsy MR, Rui S, Babu DD, El-Shafei A, Adhikari AV. New carbazole based metal-free organic dyes with D-π-A-π-a architecture for DSSCs: Synthesis, theoretical, and cell performance studies. Solar Energy. 2017; 153 :600-610 - 32.
Dayan S, Özpozan NK. Performance improvement of RuII complexes pyridinyl backbone on dye-sensitized solar cells (DSSC). Inorganica Chimica Acta. 2018; 474 :81-88 - 33.
Lyu S, Bertrand C, Hamamura T, Ducasse L, Toupance T, Olivier C. Molecular engineering of ruthenium-diacetylide organometallic complexes towards efficient green dye for DSSC. Dyes and Pigments. 2018; 158 :326-333 - 34.
Hsieh C-P, Lu H-P, Chiu C-L, Lee C-W, Chuang S-H, Mai C-L, et al. Synthesis and characterization of porphyrin sensitizers with various electron-donating substituents for highly efficient dye-sensitized solar cells. Journal of Materials Chemistry. 2010; 20 (6):1127-1134 - 35.
Yella A, Lee H-W, Tsao HN, Yi C, Chandiran AK, Nazeeruddin MK, et al. Porphyrin-sensitized solar cells with cobalt (II/III)–based redox electrolyte exceed 12 percent efficiency. Science. 2011; 334 (6056):629-634 - 36.
Yella A, Mai C-L, Zakeeruddin SM, Chang S-N, Hsieh C-H, Yeh C-Y, et al. Molecular engineering of push–pull porphyrin dyes for highly efficient dye-sensitized solar cells: The role of benzene spacers. Angewandte Chemie International Edition. 2014; 53 (11):2973-2977 - 37.
Mathew S, Yella A, Gao P, Humphry-Baker R, Curchod BFE, Ashari-Astani N, et al. Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. Nature Chemistry. 2014; 6 (3):242 - 38.
Duanglaor P, Thiampanya P, Sudyoadsuk T, Promarak V, Pulpoka B. Synthesis and photophysical properties of donor–acceptor system based bipyridylporphyrins for dye-sensitized solar cells. Journal of Energy Chemistry. 2015; 24 (6):779-785 - 39.
Prakash K, Manchanda S, Sudhakar V, Sharma N, Sankar M, Krishnamoorthy K. Facile synthesis of β-functionalized “push-pull” Zn (II) porphyrins for DSSC applications. Dyes and Pigments. 2017; 147 :56-66 - 40.
Martín-Gomis L, Parejo C, Álvarez JC, Fernández-Lázaro F, Sastre-Santos Á. Dye sensitized solar cells (DSSCs) based on bulky tert-octylphenoxy-carboxyphenyl substituted phthalocyanine without the presence of co-adsorbents. Inorganica Chimica Acta. 2017; 468 :327-333 - 41.
Hara K, Tachibana Y, Ohga Y, Shinpo A, Suga S, Sayama K, et al. Dye-sensitized nanocrystalline TiO2 solar cells based on novel coumarin dyes. Solar Energy Materials and Solar Cells. 2003; 77 (1):89-103 - 42.
Hara K, Kurashige M, Dan-oh Y, Kasada C, Shinpo A, Suga S, et al. Design of new coumarin dyes having thiophene moieties for highly efficient organic-dye-sensitized solar cells. New Journal of Chemistry. 2003; 27 (5):783-785 - 43.
Hagberg DP, Edvinsson T, Marinado T, Boschloo G, Hagfeldt A, Sun L. A novel organic chromophore for dye-sensitized nanostructured solar cells. Chemical Communications. 2006; 21 :2245-2247 - 44.
Wang Z-S, Cui Y, Dan-oh Y, Kasada C, Shinpo A, Hara K. Thiophene-functionalized coumarin dye for efficient dye-sensitized solar cells: Electron lifetime improved by coadsorption of deoxycholic acid. The Journal of Physical Chemistry C. 2007; 111 (19):7224-7230 - 45.
Ito S, Miura H, Uchida S, Takata M, Sumioka K, Liska P, et al. High-conversion-efficiency organic dye-sensitized solar cells with a novel indoline dye. Chemical Communications. 2008; 41 :5194-5196 - 46.
Zeng W, Cao Y, Yu B, Wang Y, Shi Y, Zhang M, et al. Efficient dye-sensitized solar cells with an organic photosensitizer featuring orderly conjugated ethylenedioxythiophene and dithienosilole blocks. Chemistry of Materials. 2010; 22 (5):1915-1925 - 47.
Bai Y, Zhang J, Zhou D, Wang Y, Zhang M, Wang P. Engineering organic sensitizers for iodine-free dye-sensitized solar cells: Red-shifted current response concomitant with attenuated charge recombination. Journal of the American Chemical Society. 2011; 133 (30):11442-11445 - 48.
Tsao HN, Yi C, Moehl T, Yum J-H, Zakeeruddin SM, Nazeeruddin MK, et al. Cyclopentadithiophene bridged donor–acceptor dyes achieve high power conversion efficiencies in dye-sensitized solar cells based on the tris-cobalt bipyridine redox couple. ChemSusChem. 2011; 4 (5):591-594 - 49.
Kakiage K, Aoyama Y, Yano T, Oya K, Fujisawa J-i, Hanaya M. Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes. Chemical Communications. 2015; 51 (88):15894-15897 - 50.
Narayanaswamy K, Swetha T, Kapil G, Pandey SS, Hayase S, Singh SP. Simple metal-free dyes derived from triphenylamine for DSSC: A comparative study of two different anchoring group. Electrochimica Acta. 2015; 169 :256-263 - 51.
Massin J, Ducasse L, Abbas M, Hirsch L, Toupance T, Olivier C. Molecular engineering of carbazole-fluorene sensitizers for high open-circuit voltage DSSCs: Synthesis and performance comparison with iodine and cobalt electrolytes. Dyes and Pigments. 2015; 118 :76-87 - 52.
Capodilupo AL, De Marco L, Corrente GA, Giannuzzi R, Fabiano E, Cardone A, et al. Synthesis and characterization of a new series of dibenzofulvene based organic dyes for DSSCs. Dyes and Pigments. 2016; 130 :79-89 - 53.
Demeter D, Melchiorre F, Biagini P, Jungsuttiwong S, Po R, Roncali J. 3, 4-Ethylenedioxythiophene (EDOT) and 3, 4-ethylenedithiathiophene (EDTT) as terminal blocks for oligothiophene dyes for DSSCs. Tetrahedron Letters. 2016; 57 (43):4815-4820 - 54.
Liao Y, Hu J, Zhu C, Liu Y, Xu C, Chen C, et al. Synthesis and photovoltaic performance of novel polymeric metal complex sensitizer with benzodithiophene or carbazole derivative as donor in dye-sensitized solar cell. Journal of Molecular Structure. 2016; 1108 :467-474 - 55.
Park K-W, Serrano LA, Ahn S, Baek MH, Wiles AA, Cooke G, et al. An investigation of the role the donor moiety plays in modulating the efficiency of ‘donor-π-acceptor-π-acceptor’organic DSSCs. Tetrahedron. 2017; 73 (8):1098-1104 - 56.
Chiu KY, Tran TTH, Chang SH, Yang T-F, Yuhlong Oliver S. A new series of azobenzene-bridged metal-free organic dyes and application on DSSC. Dyes and Pigments. 2017; 146 :512-519 - 57.
Elmorsy MR, Rui S, Fadda AA, Etman HA, Tawfik EH, El-Shafei A. Molecular engineering and synthesis of novel metal-free organic sensitizers with D-π-A-π-a architecture for DSSC applications: The effect of the anchoring group. Dyes and Pigments. 2018; 158 :121-130 - 58.
Pati PB, Yang W, Zade SS. New dyes for DSSC containing triphenylamine based extended donor: Synthesis, photophysical properties and device performance. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2017; 178 :106-113 - 59.
Fattori A, Majer R, Mazzanti A, Ottaviani MF, Modelli A, Mantellini F, et al. N-heterocyclic linkers from 1, 2-diaza-1, 3-dienes for dye-sensitized solar cells: DFT calculations, synthesis and photovoltaic performance. Dyes and Pigments. 2017; 145 :246-255 - 60.
Zhang K, Zhang W, Huang J, Pang A, Wong MS. Metal-free photosensitizers based on benzodithienothiophene as π-conjugated spacer for dye-sensitized solar cells. Organic Electronics. 2017; 42 :275-283 - 61.
Rajavelu K, Sudip M, Kothandaraman R, Rajakumar P. Synthesis and DSSC application of triazole bridged dendrimers with benzoheterazole surface groups. Solar Energy. 2018; 166 :379-389 - 62.
Fernandes SSM, Pereira A, Ivanou D, Mendes A, Manuela M, Raposo M. Benzothiadiazole derivatives functionalized with two different (hetero) aromatic donor groups: Synthesis and evaluation as TiO2 sensitizers for DSSCs. Dyes and Pigments. 2018; 151 :89-94 - 63.
Naik P, Babu DD, Rui S, El-Shafei A, Adhikari AV. Synthesis, characterization and performance studies of a new metal-free organic sensitizer for DSSC application. Materials Today: Proceedings. 2018; 5 (1):3150-3157 - 64.
Suarez M, Carolina C, Jimmy M, Edwin F-L, Yenny Á-T. Design, theoretical study and correlation of the electronic and optical properties of diethynylphenylthiophene as photovoltaic materials. Journal of Molecular Structure. 2020; 1201 :127093