ESD Knitted Fabrics from Conductive Yarns Used as Protective Garment for Electronic Industry

Nowadays, interest in protection against electrostatic discharge (ESD), regarded as an important issue, is still growing. ESD may lead to serious economic losses and can also be hazardous to humans. In zones where substances with low values of ignition energy occur, ESD may involve a high risk of fire or explosion. Protective clothing is used to reduce the risk of electrostatic discharge (ESD) in electronics industry as well as in explosive atmospheres. In the manufacturing process of electronic products, significant percentage-related failures due to ESD phenomena that occur on the production line, especially where they are not installed systems and rigorous protection rules, are still recorded. Protective clothing with antistatic properties is designed to prevent the trans- fer of electrical charge from human operator to electronic device during the manufacturing process. In this chapter, a study was conducted about the electrical parameters representative for the control of electrostatic discharges as well as the surface and volume resistivity by applying the current absorption-resorption method and parame- ters of charge decay using the standardized induction method on several knitted conductive fabrics with carbon yarn. Current absorption-resorption method is applied for the first time in research under antistatic and dissipative fabrics.


Introduction
Textile materials that provide comfort, antimicrobial, antiallergenic, and anti-stress protection or shielding for working people in environments with high-risk factors are increasingly required to protect consumers' health, prevent diseases, and reduce environmental impact [1,2].
A new concept has been created to transform the passive role of textile materials to an active role with all their influence for industry and consumers.
To keep up with the strategy for upgrading the textile companies, the researchers' main objective was to achieve high-performance technologies with low impact on the environment and human body and promotion of raw materials using superior hygienic, antibacterial, antiallergenic, and protective properties for people who work in hazardous environments.
In modern electrostatic discharge (ESD) protection systems, protective clothing is provided to prevent accidental ESD events caused by an operator and which can partially or totally destroy electronic devices from polychlorinated biphenyl (PCBs). Neither currently these problems are not completely eliminated. Thus, researchers have identified the need for protective clothing to have two properties at the same time but this is possible only if the garment is made of two layers.
The first property is linked to the need for a low conductivity of material for limiting electric charge processes and transferring related and the second property is linked to the need for an increased conductivity to facilitate dissipation of electrical charges processes on the material [3]. In order to prevent the occurrence of electrostatic fields which produce and induce electric charges in materials [4,5], protective clothing and work surfaces should have electrostatic shielding properties [6]. ESD processes are dependent on temperature and humidity [5].
The conductive fabrics have been considered from their electromagnetic shielding and antielectrostatic properties for various applications in the defense, and electrical and electronic industries [7][8][9][10][11].
The surface resistivity is a principal parameter which determines the ESD protection applications [12]. Generally, the synthetic fibers used for textiles fabrics have an electrical insulation character, with a surface resistivity about 10 15 Ω/□. This value of surface resistivity is very higher for anti-electrostatic and electromagnetic shielding applications.
Many researches show that to obtain good and efficient anti-electrostatic material, a surface resistivity in the range of (10 9 -10 12 ) Ω/□ is necessary, and for statically dissipative material, the surface resistivity values must be in the range of (10 4 -10 9 ) Ω/□ [13].
The research conducted by authors in the field of technical textiles was on knitted bilayer that provides good protection from accidental electrical discharges on the dielectric layer and a drainage of accumulated charges through conductive layer. An image of the bilayer concept is illustrated in Figure 1 [18].
The external layer is predominantly dissipative and it provides protection to short circuit and the limitation of the electrostatic energy that can be dissipated to the work environment, and the internal layer is predominantly conductive, providing controlled drainage of cumulated electrostatic charges. Also, an additional requirement for the internal layer is to provide comfort to the user.
The principal objective of our study consists in the development of a comparative analyzer for several ESD garments with carbon-conductive thread used for electronic industry and the characterization regarding their anti-electrostatic properties. The absorption-resorption measurement method is applied for obtaining the charge decays and surface and volume resistivities, as main parameters of ESD static and dissipative properties of garments.

Surface and volume electrical resistivities and the absorption-resorption current method
The procedure for determining the surface and volume resistivities is based on the current absorption-resorption method. This method was earlier applied to highlight the aging processes of insulating materials [19], but it can significantly also characterize the electrostatic charging-discharging processes in ESD protection materials.
The procedure consists of applying a DC voltage V on a sample, disposed in the measuring cell (with three electrodes, e.g., Keithley 8009 cell) and recording the values of current intensities to coupling source (absorption currents) and then to decoupling source (resorption currents).
Absorption current i a is determined by applying a continuous voltage V across the capacitor (measuring cell), having as dielectric the material sample with conductivity σ and permittivity ε, an absorption current will flow through the circuit.
The absorption current intensity i a (t) is variable in time t and has specific components: where: i 0 (t) is the charging current of vacuum capacitor, i p (t) is the polarization current, i ch (t) is the space charge current, and I σ is the conduction current [20,21].
The charging current of vacuum condenser i 0 (t) decreases rapidly to zero, as the transitional regime is exceeded. Expression of this current is dependent on the time of variation, and the electric field intensity is where ε 0 is the permittivity of vacuum, S is the electrode surface, and E is the electric field intensity.
Polarization current i p (t) is determined by the polarization processes occurring in the material. Depending on the mechanism of polarization (electronic, orientation, interfacial/ dishomogeneity polarizations), this current tends to zero after reaching permanent regime of DC power.
Space charge current i ch (t) stems from the movement of electrically charged structural units (ions, impurities, etc.) under the action of the electric field intensity E established in the material. The electric space charges can occur due to technological processes, in thermal degradation, electrical stresses, and so on. The space charge current can distort readings for conduction current intensity I σ values. Therefore, it is necessary to determine the time constant τ feature for transitory regime of current flowing.
Steady-state regime is characterized by conduction current I σ , given by the free electric charges flow under the action of the applied electric field and showing no change value in time.
Usually, steady-state regime is considered to be achieved after a time of (3-5)τ, where τ is the time constant of the circuit. So, the measurement of conduction current intensity should be taken only after achieving the steady-state regime [22], and the average value of I σ is obtained taking into account the measured values in steady-state regime of current flowing.
Depending on the arrangement of the measuring electrodes, the value of the volume current intensity I V or the value of the surface current intensity I S is determined and, as in the voltammeter method, the volume and surface resistivities are obtained.
When this no longer applies to voltages and the electrodes that are short-circuited, the discharging process begins, and in the material sample a transient current, named resorption current, flows. The intensity of resorption current i r (t) depends on time t and has specific components too: where i d (t) is the discharge current, i dp (t) is the depolarization current, and i ch (t) is the space charge current.
A simplification of the time dependence of the absorption and the resorption current intensities in a polar dielectric is shown in Figure 2.
The absorption current decreases asymptotically toward the steady state, due to dielectric polarization and the sweep of mobile charges to the electrodes. For materials of high resistivity (up to 10 13 Ωm, and 10 12 Ω/□) the steady state is reached in several minutes, hours, and days. For these materials, the time dependency of the volume resistivity is taken into account.
For an antistatic material-surface resistivity is in the range of (10 9 -10 12 ) Ω/□ [13]-the steadystate regime in general is reached within 1 min (Figure 3), and the resistance is then determined after this time of DC voltage supplying. Figures 3 and 4 shows that the steady-state regime in antistatic polymers is established earlier than in polar dielectrics, the absorption current slope i a (t) is steeper and the resorption current i r (t) also has a steep slope.

Comparison of
For dissipative materials with surface resistivity of the order of 10 6 -10 10 Ω/□, the wave forms of absorption and resorption currents differ from those of antistatic or insulating materials [23][24][25].  In materials, the free electric charges-both conduction processes-in volume of material and on the surface-are present, even at low electric field stresses.
Based on these processes, the volume and surface resistivities can be good indicators of ESD antistatic comportment of materials: the surface resistivity of material can characterize the ability of a material to dissipate electrostatic charges; the volume resistivity of a material is useful for evaluating the relative dispersion of a conductive additive throughout the polymer matrix, and it can related to electromagnetic shielding effectiveness in certain conductive fillers.
To determine the volume resistivity ρ V and surface resistivity ρ S, with absorption-resorption current method, the same scheme is used, described in standard SR HD 429 S1 CEI 60093 [26]. The measurement principle of the method is similar to the volt-amperometric method, where single difference positions guard ring electrode.
Measurement scheme for determining the surface resistivity is shown in Figure 4.
In this case, the applied voltage reaches the sample through the guard ring, the read signal by the ammeter coming from the measuring electrode.
Surface resistivity is defined as the quotient of a DC electric field applied between two electrodes on a surface of a specimen and the filiform current density of the current flowing between the electrodes at a given time of electrification: where E is the electric field intensity, in V/m, and J S is the surface current density, in A/m.
The surface resistivity shall be calculated with the following relation: where is the surface resistivity, in Ω/□, R S is the surface resistance, in Ω, p is the effective perimeter of the guarded electrode, in m, g is the distance between the electrodes, in m, U is the applied voltage, in V, and I s is the surface current intensity, in A. The coefficient K s is calculated in the function of the geometry of measurement cell and the particular electrode arrangement.
Measurement scheme for determining the volume resistivity is shown in Figure 5.
In this case, the applied voltage reaches the sample through the upper ring, the signal read by the ammeter coming from the measuring electrode.
Volume resistivity is defined as the quotient of a DC electric field strength applied to a material specimen disposed between two electrodes and the current density J v of the current flowing between the electrodes at a given time of electrification: where E is the electric field intensity, in V/m, and J v is the volume current density, in A/m 2 .
The volume resistivity shall be calculated with the following relation: where ρ v is the volume resistivity, in Ωm, R v is the volume resistance, in Ω, A is the effective area of the guarded electrode, in m 2 , h is the average thickness of the specimen, in m, U is the applied voltage, in V, I v is the volume current intensity, in A. The coefficient K v , given by the effective area A of guard electrode, is calculated in the function of the geometry of measurement cell and the particular electrode arrangement.
In the case of the measuring cell Keithley, the measuring electrode and guard ring are at the bottom of the circuit arrangement.

Parameters of charge decay and measurement methods
A way to characterize the rate of dissipation of electrostatic charge of garment materials is to study charge decay. Charge decay is the process of migration of charge across or through a material leading to a reduction of charge density or surface potential at the point where the charge was deposited.
To monitor the mobility of electrostatic accumulated charges, two methods of measurement are used [28]. In both methods, the charge is monitored by the observation of the electrostatic field it generates and this is done using non-contacting field-measuring instruments. The principal difference between the methods is the technique used to generate the electrostatic charge: (1) triboelectric charging, when the material specimen is in contact with a special rod, rubs together and subsequently separates. The electrical field strength from the charge generated on the test material is observed and recorded using an electrostatic field meter connected to a graphical recording device; (2) induction charging, which involves a field electrode, placed near the surface of a specimen, and which is energized with high voltage. If the specimen contains mobile electric charges, the charge of opposite polarity to the field electrode is induced on the specimen. Induced charge on the test material influences the net field, and this effect is measured and registered with a field-measuring probe, positioned above the test surface.
A step high voltage is applied on field electrode. By electrical induction, in the sample the electrical charges are separated and an electric field of intensity E R is generated in the surrounding area. The electric field generated by electric induction is compared to the electric field generated by the electric field in the absence of a sample.
The electric field strength indicated on the recording device in the absence of the test specimen has maximum value and could be obtained with the electric flux law: where E max is the intensity of the electric field near the measurement electrode in the absence of the specimen, in V/m; ε 0 = 8.855 pF/m is the vacuum permittivity; A is the effective area of the measurement electrode; Q is the accumulated electric charge in the specimen, respectively, in measurement electrode, obtained with the relation: Figure 6. Installation for testing the capacity to dissipate electrical charge for textiles.
In relation (9), C is the capacity of the condenser without the specimen, and U is the voltage applied at the terminals. Capacity C is obtained usually through measurement with bridge measurement systems.
The electric field strength E R indicated on the recording device with the test specimen in the measuring position is also registered in time.
The half-decay time t 50 is defined as the interval of time in which the electric field intensity decreases to the value E R /2. This parameter indicates the electric field strength decay to E R /2 and is an indicator for classification of textiles as static or dissipative.
The shielding factor S is defined by the relationship between E max and E R and is calculated as: [18,27,28] The advantage of using the induction method of charging the specimen is that it allows to determine both parameters-half-decay time and shielding factor, which characterize the ability to dissipate electrical charge of any antistatic or dissipative textile.

Conductive fabrics specimens manufacturing and examination
In order to assure the bilayer structure, the chosen knitting structures were plated plain jersey and plated rib. The knitting technology presumed electronic flatbed knitting machines (Stoll, 7E and 12E gauge). The bilayer knitted variants were made in plaited structures, with parallel evolution of two or more yarns with strictly determined relative position as a result of their settling at different angles (plaiting yarn V at an angle smaller than ground yarn F). In case of jersey structure, the plaiting yarn V appears on the foreground on the front and the ground yarn F, on the foreground on the back of the fabric. In case of rib structure due to alternating of front-back wales, both the plaiting yarn and the ground yarn will be present on the foreground, on each side of the fabric, Figure 7.
• for outer layer: multifilament yarn made from surface-saturated nylon with carbon particles-named yarn type 5. In order to characterize the nine knitted fabric samples, complete sets of analyses have been realized and conducted for the following parameters: weight (g/m 2 ), density (wales/10 cm, rows/10 cm), thickness (mm), air permeability (l/m 2 /s), water vapor permeability (%), thermal conductivity (mW/mK), and thermal resistance (m 2 KW). Experimental data are presented in Table 1, and in Figure 9, few images with analyzed samples are shown.
In Table 2, the composition and structure of knitted fabrics for surface and volume electrical resistivity test and for electrostatic shielding factor are presented.
From the data presented in Table 2, it can be observed that the percentage of conductive wire varies depending on the number of yarns and their composition.

Measurement setups
A. Surface and volume resistivity measurement have a setup composed by Electrometer Keithley 6517A (1-1000V), with Keithley 8009 measure cell, and computer with control soft and data processing shown in Figure 10       The characteristics of the measurement cell is as follows: (1) the size surface coefficient is K s = 53.37 Ω/□ (distance between electrodes is d = 0.3175 cm, and the average diameter D = 5.3975 cm); (2) the size volume coefficient is The application time of the signal is t = 20 s and the read time after cutoff signal is t = 10 s. The total measuring time was 30 s. In the early 1920s, DC voltage was applied, and for the remaining 10 s the signal was cut off and the remaining currents were measured on surface material. One cotton yarn + one yarn type 2 * One cotton yarn + one yarn type 5 ** 4.5 P10 One cotton yarn + 2 yarns type 5 6.0 P11 One cotton yarn + 3 yarns type 5 7.5 P12 One wool yarn + one yarn type 2 One wool yarn + 2 yarns type 5 6.0 P20 One wool yarn + 3 yarns type 5 7.6 P19 Plaited rib One cotton yarn + one yarn type 2 One cotton yarn + 2 yarns type 5 6.0 P14 One cotton yarn + 3 yarns type 5 7.5 P13 One wool yarn + one yarn type 2 One wool yarn + 2 yarns type 5 6.0 P17 One wool yarn + 3 yarns type 5 7.5 P18 * Yarn type 2 content 75% cotton + 25% epitropic yarn (Nm 34/1 carbon coated polyester). ** Yarn type 5 content multifilament yarn made from surface-saturated nylon with carbon particles. Table 2. Composition and structure of knitted fabrics for surface and volume electrical resistivity test and electrostatic shielding factor [28]. The minimum value of applied voltage to textile samples is 1 V and the maximum value applied varies from sample to sample; limitation criteria for applied voltage are given by electrometer. Keithley electrometer used can highlight the current of fA-mA (10 À15 -10 À3 ) order.
From the values obtained for surface conduction current, values of steady state, within the time interval (12-18) s, have been extracted. This was done similarly for volume conduction current.
The values of surface and volume resistivity are calculated using relations (5) and (7).
The average values and mean-square dispersion values have been calculated and corrections have been done: for dispersions greater than 5%, the erroneous values have been eliminated.
In all the samples, it was observed that after about 12 s, the values of absorption current intensities are stabilized.
B. Time decay of electric charge and shielding factor evaluation has a setup built in accordance with standard SR EN 1149-3:2004 used. The image of measurement stand is shown in Figure 11 [ 18,28].
The test facility includes the following elements: 1. Electrostatic generator for inducing electric charge in the sample.

4.
Electrodes for the measurement of electric field intensity.

5.
Stretching system of textile samples.
The apparatus used for electric induction charging is an electrostatic machine type, and for measurement, the following are used: Bridge ESCORT ELC-132A for measuring capacity; Oscilloscope-type Fluke 1968; kilovoltmeter Fluke HP 0-30 kV. The procedure for experimental determination of the half-decay time and the shielding factor using the induction charging method has been applied. For obtaining the electric field intensity value without fabric sample Figure 11. Image of the ESD setup for assessing the ability to dissipate electrical charge.
E max and with sample E R , the following data have been obtained: (1) from generator, a voltage pulse is applied, the measured value is U 0 = 6.9 kV; (2) capacitance between the electrodes without the sample is C 0 = 59 pF; (3) the value of the accumulated electric charge, calculated by relation (9), is Q 0 = 407.1 nC; (4) electric field intensity value determined by relation (8) is E max = 119.54 kV/cm. The electrodes have a diameter of 70 mm and section A = 38.465 cm.
The procedure for establishing the electric field intensity with sample between the electrodes is the following: (1) electrostatic generator induces electric field in a sample fixed on support; (2) the voltage value is recorded using an electronic voltmeter VE; and (3) the capacity of the sample system is measured using the bridge ESCORT ELC-132A.

Surface and volume resistivity
The authors for each weaving technique have chosen a representative sample of the material. For vanish glad-weaving technique, the sample P11 experimental determinations are analyzed, and for vanish patent-weaving technique the sample P14 results are analyzed. The two samples have the same layer of the surface and the same type of conductor wire.

Textile sample P11
The image of P11 is shown in Figure 12.
For different values of DC voltage U applied to the sample, listed in Table 3, the average values of surface absorption current intensity of sample P11 in the steady-state regime are listed.
In Figure 13, the time dependences of the surface absorption current intensities for P11 sample, for different DC applied voltages, are shown.
For different values of DC voltage U applied to the sample, listed in Table 4, the average values of volume absorption current intensity of sample P11 in the steady-state regime are listed. In Figure 14, the time dependences of the surface absorption current intensities for P11 sample, for different DC applied voltage, are shown. Table 3 show that the values of the measured surface current intensities increase with increasing the applied voltage. The order of magnitude of currents measured is between 10 À6 A for an applied voltage of 1 V and 10 À4 A for an applied voltage of 25 V.

Data in
Surface resistivity varies with voltage values having a tendency to decrease with the increase in the applied voltage. The order of magnitude for surface resistivity is between (10 6 -10 7 ) Ω/□ depending on the voltage applied. This sample has static dissipative behavior.  Table 3. Average values of surface absorption current intensity and surface resistivity for P11 sample.   Table 4. Average values of volume absorption current intensity and volume resistivity for P11 sample. Table 4 show that the order of magnitude of the volume absorption current is of 10 À5 A for an applied voltage of 1 V and reach the values of 10 À4 A for an applied voltage of 3 V.

Data in
Volume resistivity value decreases with the increasing applied voltage as in the case of surface resistivity. The order of magnitude for volume resistivity is 10 6 Ω•cm.

Textile sample P14
The image of P14 is shown in Figure 15.
For different values of DC voltage U applied to the sample, listed in Table 5, the average values of surface absorption current intensity of sample P14 in the steady-state regime are  listed. In Table 6, the average values of volume absorption current intensity of sample P14 in the steady-state regime are presented.
In Figures 16 and 17, the time dependences of the surface and volume absorption currents intensities for P14 sample, for different DC applied voltage, are shown. Table 5 show that the values of the surface measured current intensities increase with the increasing applied voltage value. The order of magnitude for surface measured current is between 10 À4 A for an applied voltage of (1-2) V and 10 À3 A for an applied voltage of 3 V.   Table 6. Average values of volume absorption current intensity and surface resistivity for P14 sample. Surface resistivity decreases with increasing applied voltage, and the order of magnitude for surface resistivity is 10 5 Ω/□. This sample does not belong to the category of electrostatic dissipative materials (ρ s < 10 6 Ω/□). Table 6 show that the order of magnitude for volume measured current is 10 À4 A corresponding to an applied voltage of 2 V. For voltage greater than 2 V, pico-ammeter cannot measure volume absorption currents for sample P14. Volume resistivity value decreases with the increasing applied voltage as in case of surface resistivity, and the order of magnitude of volume resistivity is 10 5 Ω•cm.

Data in
Analyzing the composition in terms of the two textile weaving techniques, it can be concluded with certainty that the technique of weaving plaited plain jersey is suitable for making electrostatic discharge protection clothes.
Plaited rib-weaving technique is not appropriate for these types of protective clothing. Resistivity values of surface and volume are not suitable for static dissipative properties of materials rather static conductive [31].

Charge decay and shielding factor
Experimental results obtained for capacity C, voltage U, electric charge on the fabric Q, electric field intensity E R , half time decay of electric charge, and shielding factor are presented in Table 7. A comparative analysis regarding the half-decay time and shielding factor is shown in Figure 18, for the nine textile samples.   Table 7. Half-decay time and shielding factor for textile samples obtained with induction charging method [28]. respectively. Sample 4 (P18) have time decay of electric charge 550 ms and shielding factor 0.82. Samples 3 (P12) and 7 (P20) have time decay of electric charge 700 ms and a shielding factor of 0.81 and 0.73, respectively. In terms of mitigating the electric field intensity, samples 3 (P12) and 7 (P20) have the lowest attenuation compared to other samples.
According to standard SR EN-1149-5:2008, all analyzed samples can be used to manufacture protective clothing, with the following observations: (1) for materials that do not have electrostatic shielding effect, E R = E max ; (2) for materials with electrostatic shielding effect, E R < E max ; (3) if E R < E max /2 is considered that t 50 < 0.01 s; and (4) if value E max /2 is reached in 30 s, t 50 > 30 s is considered.
Samples 5 and 8 show the best times of time decay of electric charge <100 ms and have shielding factor 0.8 and 0.83, respectively. The composition of sample 5 (P17) is one wool yarn + one yarn type 2 for the outer layer/front side of the fabric and one wool yarn + two yarns type 5 for the inner layer/back side of the fabric. The composition of sample 8 (P14) is one cotton yarn + one yarn type 2 for the outer layer/front side of the fabric and one cotton yarn + two yarns type 5 for the inner layer/back side of the fabric. Yarn type 5 is made of nylon filament at the surface saturated with carbon particles.
Both samples were obtained by plaited rib knitted structures, have 6% percentage of conductive yarn, and have the same number of yarns type 5 in composition which distinguishes them as the base yarn.
The authors consider that the fabric with plaited rib-knitted structures together with the type of conductive yarn and the number of conductive yarns used (max. 2) offers the most efficient protection for time decay of electric charge.
The difference of value for electric field intensity (with sample) and time discharge of electric charge may be due to natural yarn structure.

Conclusions
The ESD equipment development was supposed to choose a knitted bilayer structure that can provide good protection from accidental electrical discharges on the dielectric layer and a drainage of accumulated charges through conductive layer.
The presence of the yarn type 2 on the front side determines the performance improvement by using the yarns types 3 and 5 for all knitting configuration; knitting structure does not significantly influence the ability of electrostatic discharge.
The limits of variation for water vapor permeability are between 28.5 and 42.5%, statistical events that agglomerate into optimal zone indicate the presence of the cotton yarn in rib structure. Air permeability causes sensations of warm and cool of clothing products, the best value being obtained by the samples 10, 11, 12 (374-400 l/m 2 /s), characterized by the presence of cotton yarn and conductive yarn element from nylon filament surface saturated with carbon particles.
Simple electrical measurements, like two-point and four-point DC measurements, reveal the good electrical behavior of the yarn and fabric of the analyzed samples, when containing carbon-covered yarns. The measured resistances are in the M-range and are sufficient to avoid electrical charge buildup in the fabric.
Analysis of physical-mechanical and functional characteristics indicates appropriate values for chosen knitting structure designed for ESD protection equipment.
Technical textiles have multiple applications which make possible to conduct further researches to obtain smart textiles.
Determination procedures for evaluating specific performance of textile and their calcification as static or dissipative are surface resistivity, volume resistivity, speed decay of electric charge and shielding factor, and time decay of electric charge which are additional parameters to assess these materials.
From determinations conducted for surface resistivity to samples described in Table 1, two aspects stand out, namely (a) if the percentage of conductive yarns increases, these fabrics become more conductive reaching surface resistivity values less than materials with dissipative properties (ρ s < 10 6 Ω/□); (b) the textile structure (plain jersey and rib) influences the value of surface resistivity due to the presence of air in the textile structure, which makes the knitted samples with plaited rib structure to provide a higher conductivity than the samples with plaited plain jersey structure.
Also, when the voltage applied increases the value of current intensity, thus currents of the order of 10 À3 A were highlighted. This aspect is not negligible in the case of higher voltages that may arise in case of real electrostatic discharges.
From determinations conducted for volume resistivity, it appears that the applied voltage values are lower and conduction processes in material are more intense than to surface. However, there are samples with volume resistivity of the order of 10 7 -10 6 Ω•cm (P11, P12, P19, and P20).
From determinations conducted for time decay of electric charge and electrostatic shielding factor, three aspects stand out, namely (a) plaited rib structures offer the lowest times of decay of electric charge good and good electrostatic shielding coefficients; (b) the number of conductive yarns type 5 (filaments from nylon saturated at the surface with carbon) should not exceed two yarns (6% of conductive yarn) because at a greater number of conductive yarns intensive conducting processes can occur; (c) the aspects mentioned earlier must be correlated with the values obtained for surface and volume resistivity in order to make a complex analysis closer to actual needs and requirements of ESD protection systems.