The palmprint recognition systems.
\\n\\n
These books synthesize perspectives of renowned scientists from the world’s most prestigious institutions - from Fukushima Renewable Energy Institute in Japan to Stanford University in the United States, including Columbia University (US), University of Sidney (AU), University of Miami (USA), Cardiff University (UK), and many others.
\\n\\nThis collaboration embodied the true essence of Open Access by simplifying the approach to OA publishing for Academic editors and authors who contributed their research and allowed the new research to be made available free and open to anyone anywhere in the world.
\\n\\nTo celebrate the 50 books published, we have gathered them at one location - just one click away, so that you can easily browse the subjects of your interest, download the content directly, share it or read online.
\\n\\n\\n\\n\\n"}]',published:!0,mainMedia:null},components:[{type:"htmlEditorComponent",content:'
IntechOpen and Knowledge Unlatched formed a partnership to support researchers working in engineering sciences by enabling an easier approach to publishing Open Access content. Using the Knowledge Unlatched crowdfunding model to raise the publishing costs through libraries around the world, Open Access Publishing Fee (OAPF) was not required from the authors.
\n\nInitially, the partnership supported engineering research, but it soon grew to include physical and life sciences, attracting more researchers to the advantages of Open Access publishing.
\n\n\n\nThese books synthesize perspectives of renowned scientists from the world’s most prestigious institutions - from Fukushima Renewable Energy Institute in Japan to Stanford University in the United States, including Columbia University (US), University of Sidney (AU), University of Miami (USA), Cardiff University (UK), and many others.
\n\nThis collaboration embodied the true essence of Open Access by simplifying the approach to OA publishing for Academic editors and authors who contributed their research and allowed the new research to be made available free and open to anyone anywhere in the world.
\n\nTo celebrate the 50 books published, we have gathered them at one location - just one click away, so that you can easily browse the subjects of your interest, download the content directly, share it or read online.
\n\n\n\n\n'}],latestNews:[{slug:"intechopen-supports-asapbio-s-new-initiative-publish-your-reviews-20220729",title:"IntechOpen Supports ASAPbio’s New Initiative Publish Your Reviews"},{slug:"webinar-introduction-to-open-science-wednesday-18-may-1-pm-cest-20220518",title:"Webinar: Introduction to Open Science | Wednesday 18 May, 1 PM CEST"},{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"}]},book:{item:{type:"book",id:"597",leadTitle:null,fullTitle:"Crop Production Technologies",title:"Crop Production Technologies",subtitle:null,reviewType:"peer-reviewed",abstract:"Crop production depends on the successful implementation of the soil, water, and nutrient management technologies. Food production by the year 2020 needs to be increased by 50 percent more than the present levels to satisfy the needs of around 8 billion people. Much of the increase would have to come from intensification of agricultural production. Importance of wise usage of water, nutrient management, and tillage in the agricultural sector for sustaining agricultural growth and slowing down environmental degradation calls for urgent attention of researchers, planners, and policy makers. Crop models enable researchers to promptly speculate on the long-term consequences of changes in agricultural practices. In addition, cropping systems, under different conditions, are making it possible to identify the adaptations required to respond to changes. This book adopts an interdisciplinary approach and contributes to this new vision. Leading authors analyze topics related to crop production technologies. The efforts have been made to keep the language as simple as possible, keeping in mind the readers of different language origins. The emphasis has been on general descriptions and principles of each topic, technical details, original research work, and modeling aspects. However, the comprehensive journal references in each area should enable the reader to pursue further studies of special interest. The subject has been presented through fifteen chapters to clearly specify different topics for convenience of the readers.",isbn:null,printIsbn:"978-953-307-787-1",pdfIsbn:"978-953-51-5177-7",doi:"10.5772/1109",price:119,priceEur:129,priceUsd:155,slug:"crop-production-technologies",numberOfPages:290,isOpenForSubmission:!1,isInWos:null,isInBkci:!1,hash:"7f87c31dfd7e38f3e10cf7ec02df2201",bookSignature:"Peeyush Sharma and Vikas Abrol",publishedDate:"January 5th 2012",coverURL:"https://cdn.intechopen.com/books/images_new/597.jpg",numberOfDownloads:60791,numberOfWosCitations:63,numberOfCrossrefCitations:20,numberOfCrossrefCitationsByBook:2,numberOfDimensionsCitations:86,numberOfDimensionsCitationsByBook:7,hasAltmetrics:0,numberOfTotalCitations:169,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"February 22nd 2011",dateEndSecondStepPublish:"March 22nd 2011",dateEndThirdStepPublish:"July 27th 2011",dateEndFourthStepPublish:"August 26th 2011",dateEndFifthStepPublish:"December 24th 2011",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6",editedByType:"Edited by",kuFlag:!1,featuredMarkup:null,editors:[{id:"73200",title:"Dr.",name:"Peeyush",middleName:null,surname:"Sharma",slug:"peeyush-sharma",fullName:"Peeyush Sharma",profilePictureURL:"https://mts.intechopen.com/storage/users/73200/images/system/73200.jpg",biography:"Dr. Peeyush Sharma (born 24th Aug 1975) is a soil scientist who started her career as Assistant Professor in Dryland Research Sub-Station, Sher-e-Kashmir University of Agricultural Sciences and Technology-Jammu in 2004. She received MSc and PhD (Soil Science) degrees from illustrious G.B. Pant University of Agriculture & Technology, Pantnagar, Uttaranchal.\nAwards\n • Awarded Postdoctoral fellowship in prestigious Institute of Soil Water and Environmental Sciences, ARO, Volcani Centre, Israel working on FTIR techniques to ‘characterize the soil organicmatter with the application of different doses of compost in different cropping system’ for one year from (Nov 2013- Nov. 2014)\nExternally funded projects: 02\n • On farm training and demonstration of biochar for carbon sequestration and climate change mitigation in Kandi belt of Jammu: Principal Investigator: NABARD \n • Soil erosion risk mitigation and carbon sequestration potential of climate resilient agriculture practices in foothill Shivaliks –National Innovation in Climate Resilient Agriculture : Co-Principal Investigator\nTechnologies developed: Developed ‘Tilth Index Model’, Tillage, Biochar\nEXTENSION \n • Delivered lectures as Resource person in training programs for farmers and officials\n • Promotion and dissemination of low cost biochar production technology Research Publications (In Journals)\n • European Journal of Soil Science\n • European Journal of Agronomy\n • Soil & tillage research\n • Geoderma\nResearch Skills \n ▪ Tillage and mulching\n ▪ Fourier Transform Infrared Spectroscopy\n ▪ Writing and editing research manuscripts \nReviewer of Research Journals\n • Soil & Tillage Research\n • International Journal of Bio-resource and Stress Management\nBOOKS Published \n ◦ Crop Production Technology. 2011. Peeyush Sharma and Vikas Abrol. \n ◦ Resource Management for Sustainable Agriculture. 2012. Vikas Abrol and Peeyush Sharma. \nFUTURE THURST AREAS\n • Tillage\n • Biochar",institutionString:"Sher-e-Kashmir University of Agricultural Sciences and Technology",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"1",totalChapterViews:"0",totalEditedBooks:"1",institution:{name:"Sher-e-Kashmir University of Agricultural Sciences and Technology of Jammu",institutionURL:null,country:{name:"India"}}}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:{id:"136230",title:"Dr.",name:"Vikas",middleName:null,surname:"Abrol",slug:"vikas-abrol",fullName:"Vikas Abrol",profilePictureURL:"https://mts.intechopen.com/storage/users/136230/images/system/136230.jpg",biography:"Dr. Vikas Abrol (b. Nov 14, 1974), a Soil Scientist, received his PhD degree from Sher-e-Kashmir University of Agricultural Sciences and Technology - Jammu and holds PG Diploma in Ag. Marketing, PG Diploma in Business Management, PG Diploma in Rural Development and Diploma in Computer Application as additional qualification.\nAwards\n • Awarded Postdoctoral research fellowship for one year by Ministry of Agriculture, State of Israel to pursue research “Biochar: Mechanism of action as soil and water conservation agent in agricultural soils” in Volcani Centre, Agricultural Research Organization, Israel. \n • Awarded research fellowship for one academic year in Volcani Centre, Agricultural Research Organization, Israel to pursue research on “Efficacy of synthetic polymers (Anionic PAM) on soil and water conservation”.\n • Best Paper Award 2015, for Best Paper in National Seminar organized by Society for Community Mobilization, IARI, New Delhi \n • Best Research Paper 2015, in Indian Journal of Soil Conservation, in Soil Science and Agronomy\nExternally funded projects: 03\n\nHe started his professional career as Assistant Professor/Jr. Scientist at Dryland Research Substation, Dhiansar and published research accomplishments in the journals of international reputation like the European Journal of Agronomy, European Journal of Soil Science, Journal of Soil and Sediments, Journal of the Science of Food and Agriculture, Agricultural Mechanization in Asia, Africa and Latin America etc., with high impact factor and edited two international books, “Crop Production Technologies” and “Resource Management for Sustainable Agriculture”. He served as reviewer of research articles in international journals like Soil Science Society of America Journal, Agronomy for Sustainable Development, Land Research and Development, Indian Journal of Agricultural Sciences, Indian Journal of Dryland Agricultural Research and Development, Indian Journal of Soil Conservation, Journal of Experimental Biology and Agricultural Sciences and International Journal of Agriculture Sciences etc. His research interests entail using biochar for offsetting climate change by soil carbon aggradation, runoff quality and soil erosion control, soil quality evaluation, soil and water pollution. He holds specialization in using biochar and synthetic polymers (PAM) for erosion control, infiltration improvement and soil structural stabilization. He also served in Krishi Vigyan Kendra (extension services) and conducted trainings to farmers and officials of line departments. He is serving as Resource person for Prasar Bharti, Department of Agriculture, SAMETI, ATMA, National Fertilizer Limited, Indian Potash Association. He has presented papers in national and international conferences and seminars. He is life member of the Indian Journal of Soil Conservation, Indian Journal of Dryland Agriculture and Research, International Biochar Initiative, Friends of Israel Biochar Researchers Network, Biochar India e-group and his future endeavours envisage focuses on research to address two vital natural resources - soil & water and carbon aggradation in resource poor soils of dryland areas.",institutionString:"Sher-e-Kashmir University of Agricultural Sciences and Technology",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"3",totalChapterViews:"0",totalEditedBooks:"2",institution:{name:"Sher-e-Kashmir University of Agricultural Sciences and Technology of Jammu",institutionURL:null,country:{name:"India"}}},coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"311",title:"Plant Genetics",slug:"agronomy-plant-genetics"}],chapters:[{id:"25577",title:"Crop Models as Decision Support Systems in Crop Production",doi:"10.5772/28976",slug:"crop-models-as-decision-support-systems-in-crop-production",totalDownloads:4628,totalCrossrefCites:1,totalDimensionsCites:6,hasAltmetrics:0,abstract:null,signatures:"Simone Graeff, Johanna Link, Jochen Binder and Wilhelm Claupein",downloadPdfUrl:"/chapter/pdf-download/25577",previewPdfUrl:"/chapter/pdf-preview/25577",authors:[{id:"76066",title:"Prof.",name:"Simone",surname:"Graeff",slug:"simone-graeff",fullName:"Simone Graeff"},{id:"77710",title:"Prof.",name:"Wilhelm",surname:"Claupein",slug:"wilhelm-claupein",fullName:"Wilhelm Claupein"},{id:"111048",title:"Dr.",name:"Johanna",surname:"Link",slug:"johanna-link",fullName:"Johanna Link"},{id:"120291",title:"Dr.",name:"Jochen",surname:"Binder",slug:"jochen-binder",fullName:"Jochen Binder"}],corrections:null},{id:"25578",title:"Crop Water Requirements in Cameroon’s Savanna Zones Under Climate Change Scenarios and Adaptation Needs",doi:"10.5772/27803",slug:"crop-water-requirements-in-cameroon-s-savanna-zones-under-climate-change-scenarios-and-adaptation-ne",totalDownloads:2756,totalCrossrefCites:0,totalDimensionsCites:2,hasAltmetrics:0,abstract:null,signatures:"Genesis T. 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Biometric identification has been widely applied in modern society, such as electronic payment, entrance control, and forensic identification. As a reliable solution for identity authentication, biological characteristics refer to the inherent physiological or behavioral characteristics of the human body, including the iris, pattern, retina, palmprint, fingerprint, face and also voiceprint, gait, signature, key strength, etc. In the last decade, we have witnessed the successful employment of recognition systems using fingerprint, iris, and face. With the development of image capture devices and recognition algorithms, palmprint recognition receives more and more attention recently. Palmprint image contains principal lines, wrinkles, ridges, and texture that are regarded as useful features for palmprint representation and can be captured with a low-resolution image [1]. Palmprint recognition has several advantages compared with other biometrics: (1) the line features and texture features in a palmprint are discriminative and robust, which can be easily fused with other hand features (dorsal hand vein, fingerprint, finger knuckle); (2) the pattern of palmprint is mainly controlled by genetic genes, when combined with palm vein information it can achieve high antispoof capability; (3) palmprint image acquisition is convenient and low-cost, and a relative low-resolution camera and a light source are sufficient to acquire the images; (4) the palmprint acquisition is hygienic and user friendly in the real applications. Based on the custom acquisition devices, more information can be retrieved in a multispectral image or 3D palmprint image. A 2D gray scale palmprint example with feature definitions is shown in Figure 1. The purpose of this chapter is to review recent research on palmprint acquisition systems to trace the development of palmprint recognition-based biometric systems. In this chapter, we coarsely divide the devices into three types by acquisition mode: touch-based devices, touchless devices, and portable devices. Touch-based devices usually have pegs to constrain the hand pose and position, which can capture the details of palmprint to the most extent. The illuminating environment is also stable during capturing process. These constrains ensure the captured palmprint images to be high quality. For touchless devices, users can freely place their palms in front of the camera while the hand pose is generally required to spread out the fingers. The environment during the capturing process becomes more complicated, especially the illumination. There are also datasets composed of palmprint images captured in a relatively free fashion. These images may be collected on the Internet which we will not discuss here. Otherwise, collectors use digital cameras or phone cameras to capture palmprint image, and usually, there are no strict conditions forced on the user. In the rest of this chapter, first, we will introduce the representative palmprint acquisition devices, and then study the relationship between the palm distance, image sharpness, hardware parameters, and the final recognition performance. Table 1 summarizes the palmprint acquisition devices.
Palmprint images and feature definitions.
Ref. | Year | Device type | Image type | Description |
---|---|---|---|---|
[1] | 2003 | Touch-based | Gray scale | Adopt low-cost camera to capture low-resolution image palmprint; use pegs as guidance |
[2] | 2007 | Touchless | RGB and IR | Realize noncontact capturing of palmprint images under unconstrained scenes |
[3] | 2008 | Touchless | RGB | Capture palm in real-time video stream using skin-color thresholding |
[4] | 2009 | Touch-based | 3D | Acquire depth information in palm using structured light imaging |
[5] | 2010 | Touch-based | Multispectral | Propose an online multispectral palmprint system |
[6] | 2010 | Touchless | RGB and IR | Capture palmprint and palm vein images simultaneously |
[7] | 2011 | Touch-based | Gray scale and IR | Capture palmprint, palm vein, and dorsal vein images simultaneously |
[8] | 2012 | Portable | Gray scale | Use different portable devices to capture palmprint images |
[9] | 2012 | Touch-based | Gray scale and 3D | Acquire 3D information and 2D texture in palm |
[10] | 2015 | Touchless | RGB | The RGB’s blue and red channels are processed separately for bimodal feature extraction |
[11] | 2016 | Touch-based | Gray scale | Develop a line scanner to capture palmprint images |
[12] | 2017 | Touch-based | Gray scale | Proposed a novel doorknob device to capture the knuckle images |
[13] | 2018 | Touchless | Multispectral | Capture palmprint and palm vein images in the device; established the current biggest publicly available database |
The palmprint recognition systems.
Reference [1] is a pioneer work for palmprint acquisition and recognition that builds the first large-scale public palmprint dataset. The captured palmprint images are low-resolution with 75 pixels per inch (PPI), so that the whole process can be completed in 1 s, which achieves real-time palmprint identification. The palmprint capture device includes a ring light source, charge-coupled device (CCD) camera, a frame grabber, and an analog-to-digital (AD) converter. Six pegs are serving as control points that constrain the user’s hands. To guarantee the image quality, during palmprint image capturing, the device environment is semiclosed, and the ring source provides uniform lighting conditions. After capturing the palmprint, the AD converter directly transmits the captured images by the CCD camera to a computer. The well-designed acquisition system can capture high-quality images, which boosts the performance of the identification algorithm. The experiment result also demonstrates that low-resolution palmprint can achieve efficient person identification. Our palms are not pure planes, and many personal characteristics lie on the palm surface. From this view, 2D palmprint recognition has some inherent drawbacks. On one hand, much 3D depth information is neglected in 2D imaging. The main features in 2D palmprint are line features including principal lines and wrinkles, which is not robust to the illumination variations and contamination influence. On the other hand, the 2D palmprint image is easy to be counterfeited so that the anti-forgery ability of 2D palmprint needs improvement. For capturing depth information in palmprint, [4, 14] explores a 3D palmprint acquisition system that leverages the structured light imaging technique. Compared to 2D palmprint images, several unique features, including mean curvature image, Gaussian curvature image, and surface type, are extracted in 3D images. Many studies have proposed different algorithms that encode the line features on the palm surface; however, the discriminative and antispoof capability of palm code needs to be further improved for large-scale identification. To obtain more biometric information in the palm, in [5] a multispectral palmprint acquisition system is designed, which can capture both red, green, and blue (RGB) images and near-infrared (NIR) images of one palm. It consists of a CCD camera, lens, an A/D converter, a multispectral light source, and a light controller. The monochromatic CCD is placed at the bottom of the device to capture palmprint images, and the light controller is used to control the multispectral light. In the visible spectrum, a three-mono-color LED array is used with red peaking at 660 nm, green peaking at 525 nm, and blue peaking at 470 nm. In the NIR spectrum, a NIR LED array peaking at 880 nm is used. It has been shown that light in the 700 to 1000 nm range can penetrate the human skin, whereas 880–930 nm provides a good contrast of subcutaneous veins. The system is low-cost, and the acquired palmprint images are high-quality. By fusing the information provided by multispectral palmprint images, the identification algorithm achieves higher performance on recognition accuracy and antispoof capacity.
Touch-based devices can easily capture high-quality palmprint images which contribute to high performance in person identification, while their drawbacks also lie in this acquisition mode. Firstly, users may have hygienic concerns since the device cannot be cleaned immediately. Secondly, some users may feel uncomfortable with the control pegs and constrained capture environment. Thirdly, the volume of the device is usually larger than palm, which causes problems of portability and usability. As the first attempt to solve the above issues, [2] presents a real-time touchless palmprint recognition system, and the capture processes are conducted under unconstrained scenes. Two complementary metal-oxide semiconductor (CMOS) web cameras are placed in parallel, one is a near-infrared (NIR) camera, and the other is a traditional red green blue (RGB) camera. A band pass filter is fixed on the camera lens to eliminate the influence of NIR light on the palm. The two cameras work simultaneously, and the resolution of both cameras is 640 × 480. For further hand detection process, during the image capture, users need to open their hands and place palm regions in front of the cameras. Also, the palm plane needs to be approximately flat and orthogonal to the optical axis of cameras. Minor in-plane rotation is allowed. The distance between the hand and device should be in a fixed range (35–50 cm) to ensure the clarity of the palmprint images. In [3], a novel touchless device with a single camera is proposed. The principle of device design is similar to [2]. During the input process, the user places his/her hand in front of the camera without touching the device, and there are no strict constraints on its pose and location. The main difference is that the paddles are placed around the camera to reduce the effect of illumination changes. By these measures, the acquisition process becomes flexible and efficient. [6] presents a touchless palmprint and palm vein recognition system. The structure of the device is similar to that in [3], which mainly contains two parallel mounted cameras with visible light and IR light. The flexibility of this touchless device is further improved. Users are allowed to position their hands freely above the sensor, and they can move their hands during the acquisition process. The acquisition program will give feedback to the user that he/she is placing his/her hand correctly inside the working volume. In this way, the device can capture high-quality palmprint and palm vein images at the same time. In [7], the palmprint, palm vein, and dorsal vein images are simultaneously captured with a touchless acquisition device. In the capturing process, the users are asked to put their hands into the device with five fingers separated. The time cost is less than 1 s. The multimodal images can be fused in the algorithm to boost the identification performance.
With the widespread application of digital cameras and smartphones, more and more portable biometric devices appear to us. To investigate the problem of palmprint recognition across different portable devices and build the available dataset, [8] uses one digital camera and two smartphones to acquire palmprints in a free manner.
As is discussed above, the main parts of palmprint acquisition devices are cameras and light sources. So, the problems we need to consider when designing new devices are as follows:
The resolution of the imaging sensor
The focal length of the lens
The distance range of the palm
The sharpness range of the final palmprint image
The light source intensity
The signal-to-noise ratio of the palmprint image
Many previous works have studied the light sources [15, 16, 17]. Generally, the basic goal is avoiding overexposure and underexposure. Image noise increases under low illumination conditions. Although many new deep learning-based denoising techniques are proposed [18], the most effective solution for palmprint imaging is developing active light sources to provide suitable illumination conditions. In this work, we only focus on the first four problems. We developed three palm image capture devices to test the performance of different hardware frameworks (as is shown in Figure 2). We denote them as
Different palmprint acquisition devices and the palm images generated by them. (a) The touch-based device with a 500 M pixel imaging sensor and a long imaging distance. (b) The touch-based device with a 120 M pixel imaging sensor and a very short imaging distance. (c) The multicamera touchless device with 120 M and 30 M pixel imaging sensors and a long imaging distance. (d) The palm image captured by (a) and the corresponding enlarged local regions. (e) The palm image captured by (b) and the corresponding enlarged local regions. (f) The palm images captured by (c) and the corresponding enlarged local regions.
The imaging model is shown in Figure 3. Let
Imaging model and related notations.
where
in which
where
Hence,
where
where
where N is the image number of the dataset and
Images captured by different lenses. (a) The imaging device and different kinds of lenses. (b) An image captured by long-focus lens. (c) An image captured by standard lens. (d) An image captured by ultrawide-angle lens.
Lens | |||||||||
---|---|---|---|---|---|---|---|---|---|
Long-focus | 3507.05 | 3497.24 | 10.4° | 7.9° | −0.37 | −1.36 | — | −0.0018 | −0.0000 |
Standard | 706.96 | 707.29 | 48.7° | 37.5° | 0.13 | −0.51 | — | 0.0055 | −0.0001 |
Wide-angle | 435.57 | 436.10 | 72.6° | 57.7° | −0.41 | 0.14 | — | 0.0014 | 0.0006 |
Ultrawide | 217.19 | 217.99 | 111.7° | 95.5° | 0.05 | −0.07 | 0.0105 | −0.0002 | −0.0018 |
The calibrated parameters of different camera lenses.
Images obtained at different distances (PPI) using different distortion models.
Palm region size | ×960 | ×840 | ×720 | ×600 | ×480 | ×360 | ×240 | ×180 | ×120 | ×60 |
---|---|---|---|---|---|---|---|---|---|---|
304.8 | 266.7 | 228.6 | 190.5 | 152.4 | 114.3 | 76.2 | 57.2 | 38.1 | 19.1 | |
524.8 | 459.2 | 393.6 | 328.0 | 262.4 | 196.8 | 131.2 | 98.4 | 65.6 | 32.8 | |
166.6 | 145.8 | 125.0 | 104.1 | 83.3 | 62.5 | 41.7 | 31.2 | 20.8 | 10.4 |
Palm region size, palm width, and corresponding
Long-focus | Standard | Wide-angle | Ultrawide | |||||
---|---|---|---|---|---|---|---|---|
EER (%) | EER (%) | EER (%) | EER (%) | |||||
524.8 | 1.445 | 29.0 | 1.539 | 28.6 | 1.508 | 28.1 | 1.634 | 28.4 |
459.2 | 1.477 | 26.5 | 1.634 | 26.3 | 1.571 | 25.9 | 1.602 | 26.1 |
393.6 | 1.445 | 26.1 | 1.619 | 25.9 | 1.553 | 25.5 | 1.634 | 25.8 |
328.0 | 1.414 | 25.4 | 1.571 | 25.3 | 1.550 | 25.1 | 1.631 | 25.3 |
262.4 | 1.414 | 23.7 | 1.602 | 23.6 | 1.508 | 23.4 | 1.539 | 23.6 |
196.8 | 1.477 | 23.9 | 1.571 | 23.5 | 1.539 | 23.1 | 1.602 | 23.2 |
131.2 | 1.508 | 20.2 | 1.783 | 20.0 | 1.634 | 19.7 | 1.627 | 19.8 |
98.4 | 1.571 | 18.4 | 1.759 | 18.3 | 1.728 | 18.1 | 1.728 | 18.2 |
65.6 | 2.177 | 14.8 | 2.136 | 14.7 | 2.325 | 14.6 | 2.262 | 14.7 |
32.8 | 6.346 | 9.9 | 6.313 | 9.8 | 6.274 | 9.8 | 6.535 | 9.8 |
The EERs obtained from different palm width using different lens models.
The relationship between recognition performance, image sharpness, and palm width (in units of pixel).
In the above subsection, based on the imaging model and the capture device, we studied the relationship between palm distance, PPI, and EER. However, the hardware and the parameters of the imaging model are not always available in practice. Besides FOV, depth of focus (DOF) should be considered, since defocus-blur also will affect the final accuracy. DOF is highly related to specific applications. Our previous work [23] shows that the accuracy of palmprint recognition has a relationship with the image sharpness. Here, what we want to know is in which sharpness range the palmprint recognition accuracy is acceptable.
In this section, we try to analyze the palmprint image sharpness based on the Gaussian scale space [24]. The transform function is defined as
where
The palmprint Gaussian scale space.
Scale contributions for key point matching: (a) obtained from COEP, (b) obtained from IITD, (c) obtained from KTU, (d) obtained from GPDS.
In order to analyze the recognition performance variations, we utilize the Gaussian image pyramid to generate palmprint images at different scales. For a given dataset, all the ROI images in it are filtered with Gaussian filter banks, and then 20 scaled datasets are generated. The
where
The curves of
The work reported in [27] shows that there exist a relationship between the recognition performance and the image sharpness. In their work, a sharpness adjustment technique is developed to improve the system EER. Different sharpness induces are tested, and EAV performs better. But only one touch-based palmprint database is tested in their study. In order to ensure the idea is applicable on different databases, devices, and algorithms, we utilize CompCode [28], OLOF [29], and RLOC [30] to further test the recognition accuracy variations on those generated datasets. In this experiment, different databases are used including GPDS [31], IITD [32], KTU [33], and TJU [34]. Figure 10 shows the curves of EER and corresponding
The curves of EER and
When designing a touchless palmprint recognition system, FOV and DOF are two key problems of palmprint imaging. FOV is related to image PPI, and DOF is related to image blur. Figure 11 shows the main idea and framework of our system. In this chapter, we first studied the required image PPI for palmprint identification. Based on it, the minimum and maximum palm distances are determined in the FOV. It also provides a reference for image sensor resolution selection. Then, image blur is taken into consideration; different datasets are generated by Gaussian scale space function. The EER variation curves are obtained by different features on different databases. During the image collection process, when the palm moves out of the DOF, the sharpness of the captured image changes, so
The framework of this chapter.
Based on the findings of this research, when designing new systems, the palm width in the captured image should be larger than 300 pixels; it at least should not smaller than 130 pixels. After the system is deployed, when the user is putting his/her hand, the
This work is supported in part by the NSFC under grant 61332011, in part by the Shenzhen Fundamental Research under grants JCYJ20180306172023949 and JCYJ20170412170438636, in part by the Shenzhen Institute of Artificial Intelligence and Robotics for Society.
Catalysts have a significant impact on contemporary chemical processes. The role of nano-catalysts in the form of metal nanoparticles (MNPs), such as nanoparticles of transition metals and particularly the group VIII metal elements in the fourth period with d-band center electronic structure, is rising significantly in the heterogeneous catalysis, due to their high active surface areas and special electronic properties [1, 2]. For instance, Fe-, Co-, Ni-, Pt-, Rh-, and Pd-based catalysts have been extensively utilized in various processes to produce varieties of fuels and chemicals, consisting of Fischer Tropsch Synthesis, steam and dry reforming, methanation, and CO oxidation [1]. MNPs expose influential activities in various catalytic reactions. One of the main difficulties in using the MNPs is their weak stability in the practical catalytic processes. In recent years, an exquisite and effective strategy has been applied to optimize the performance of MNPs by encapsulating them that provides unique advantages toward catalysis, particularly under harsh conditions by restricting the aggregation and sintering of MNPs. The concept of the encapsulated metals nanoparticles that improve a wide range of catalytic reactions, especially under rough environments has been presented as “chainmail nano-catalyst” in some of the literatures [3].
In addition, Encapsulation adjusted the energy distinctions between the highest occupied molecular orbital to the lowest unoccupied molecular orbital [4]. In fact, inside the encapsulated structure of MNPs, the electron of MNPs can penetrate through the shell to enhance the catalytic performance on the external surface. Therefore, the shell is able to restrict the medium of reactants and products from direct contact by the MNPs and protect the MNPs from damage in harsh conditions. Overall, these encapsulated MNPs represent impressive catalysts that can be applied in numerous catalytic reactions under harsh conditions and also propose a tunable structure alongside unique electronic properties [3].
In this chapter, a comprehensive and compressed presentation of the encapsulated MNPs advantages, a categorization of the encapsulating layers, and some methods of encapsulated nano-catalysts preparation are reported, respectively.
In view of an increasing range of recent research, implementing an encapsulated structure for nano-catalysts is the efficient way to protect these catalysts’ properties from any deactivation agents and prevent them from the decrease of catalytic activity. The advantages of encapsulated structure can be expressed as follows and in going into detail their effective specifications and involved parameters in this structure will be explained.
Provide effective metal-support interactions (MSI)
Prevent from the coalescence nanoparticles
Protect from catalyst deactivation by stabilizing the active metal species in catalysts against sintering
Tandem reactions can be enabled and promoted by encapsulated configuration
Improvement of catalytic selectivity
One of the most crucial characteristics of the encapsulated nano-catalysts is the strong interaction between the MNPs and the encapsulating materials. Interactions between MNPs and support materials, metal-support interaction (MSI), can profoundly enhance the catalytic activity and tunability to selective reactions and products [5]. MSI can modify electronic properties, geometric morphologies, or chemical compositions of MNPs to make active sites have specific properties and catalytic activities [6, 7]. The geometric result of MSI is the decoration of the metal surface, partial coverage or total encapsulation of the metal can be conducted by the support. Since morphological modifications can take place on the catalyst as a result of the MSIs and encapsulated structure paves the way to enhance them by contributing a maximal interfacial area through participating the MNPs in close contact with the encapsulating materials [6, 7, 8]. Furthermore, strong metal-support interaction (SMSI) has been mostly applied to develop bifunctionality at the interface of metal–metal oxides systems. The bifunctional outcome leads to a synergistic effect through an improvement of catalyst activity and selectivity by creating new reaction sites at the interface between the metal and the support, and the spillover phenomenon occurs at the interface by transferring reactants from metal or support to the interface, which all of these phenomena are soared at encapsulated structure [6, 7, 8]. Therefore, the optimized catalytic performance can be gained by the unique MSI among the MNPs and the encapsulating materials [5].
Metal nano-catalysts have a high surface-to-volume ratio, which leads to coalescence during catalysis, especially at high reaction temperatures where this is prone to modification, resulting in a noticeable decrease in active surface areas and, eventually, a reduction in catalytic activity and selectivity [2]. In contrast, encapsulation by encasing of MNPs in nano-shells or nanopores prohibits them from coalescence, therefore, the efficiency of the active nano-catalysts surface area is preserved remarkably.
Catalyst deactivation is a principal difficulty in the heterogenous catalytic processes since the catalyst activity and selectivity will be reduced with time on stream and the catalyst regeneration or replacement will be included at a noticeable rate of time and resources [8, 9]. Therefore, a great number of researches have been conducted to gain long-term stability in heterogeneous catalysis, particularly by applying an optimized structure that includes the maximized performance. In the midst of the principal reasons of catalyst deactivation, sintering of MNPs, which occurs by an irreversible mechanism that significantly reduces catalyst recyclability, has attracted more attention toward preventing it from happening. Catalyst sintering reduces the metal’s active surface area and can occur via particle coalescence or Ostwald ripening [10, 11]. Not only may the MNPs engage in migration and coalescence particularly when they are exposed to severe conditions, but also the deactivation of catalysts via sintering can be intensified. Nevertheless, by encapsulating MNPs in a highly nanopores support, this spatial confinement can dramatically suppress their migration and coalescence and can prevent sintering without limiting the catalysis and thus stabilize MNPs under harsh reaction conditions [2, 8, 9, 10, 11].
Chemical processes are conducted by multiple steps. To minimize energy consumption and economic cost, integrating multiple steps of reactions can be a crucial solution. A tandem catalysis reaction engages sequential reactions within one condition through the coupling of appropriate catalysts in which sequential transformation of the substrate is conducted via two or more mechanistically distinct reaction steps [12, 13, 14]. The encapsulated structure of MNPs provides an integration of various interfaces in one nanostructure in a controllable manner that converts them as effective and principal catalysts in the tandem catalysis reactions. Moreover, encapsulating MNPs in porous shells could promote tandem reactions via modifying the reaction sequences or the molecular-sieving effect [2, 15].
Due to preventing the formation of unwanted products, increasing the waste of chemicals, reducing the essential refinement stages, and optimizing the selective products, it is critical to control the chemical reactions. The heart of a chemical reaction is its catalysts so it is crucial to design an appropriate catalyst to enhance the selectivity. The activity and particularly selectivity of heterogeneous catalysts depend on their surfaces structure and their active sites. First of all, the encapsulated structures in various catalysts support by providing their unique morphology and can act as sieves for molecules that allow the transfer of molecules with selective sizes, resulting in high shape selectivity. In addition, catalytic selectivity of the encapsulated nano-catalysts can be improved by utilizing suitable functional groups in their materials that have a significant influence on the reactant adsorption and reduce the mass transfer limitations by increasing their coefficient diffusions. In addition to the controlled porosity of the encapsulated structures, owing to high active surface areas of the encapsulating materials, there are more sites to involve the suitable functional groups to enhance the selectivity of the catalysts [12, 13, 14, 15, 16, 17, 18].
Although each one of mentioned nano-catalysts encapsulated structure benefits are effective separately, there is a remarkable relationship among their impacts. Indeed, each of them causes the other one or implements it in parallel and intensifies each other.
In contrast, although the encapsulation structures can enhance the catalytic performances, mass transfer may be restricted by this structure to some extent, which is disadvantageous to the catalytic process. This issue should be modified by the precise sketch through the choice of materials and methods synthesis of the catalysts with encapsulation structures [1]. In this chapter, the classification of the encapsulation of catalysts is undertaken with the type of encapsulating materials because some of them can form into two distinct groups of morphologies or exhibit with an individual structure, such as organic materials. Thus, in follow firstly describe each type of morphology and then the encapsulation of catalysts is presented in three comprehensive parts from the view of encapsulating materials: (1) Inorganic Materials, (2) Metal–Organic Frameworks (MOFs), and (3) Organic Materials as it is depicted in Figure 1.
Encapsulation of MNPs as catalyst.
Encapsulation provides a unique catalyst immobilization technique that by encapsulating of MNPs with porous layers creates an impressive porosity for the reactants to be able to reach the metal surface. Various strategies and materials have been utilized to make these layers. An encapsulated structure can conduct by designing and fabricating the unique chainmail catalyst via a wide range of shells [3]. As a result, a vast majority of structural designs and strategies in such encapsulated catalysts have been thrived. Although a large range of various materials, such as metallic state of metals, alloys of metals, metal carbides, metal oxides, metal phosphides, and metal nitrides, can be encapsulated, a variety range of coating layers can be utilized for the shells that contain various forms, such as shells, tubes, sheaths, matrices, and films. In this chapter, the encapsulated catalysts structures on the basis of the morphology are categorized into two main groups: (1) Yolk/Core-Shells, and (2) Mesoporous Structures [1, 2, 3], as shown inFigure 1.
Encapsulation compels the complex of support and MNPs to implement a nonplanar geometry, which leads to a higher reactivity. The core-shell morphology is allocated to the encapsulated structure that encases nanoparticles in a confined case by an outer shell [1]. In contrast, another approach to encapsulate MNPs inside an individual architecture shell which is a state of eggs with a void space between the MNP “yolk” and the porous coating “shell,” this structure has added profits due to their specific role as nanoreactors [19]. Although Yolk-shell is a “core-void-shell” structure, which is similar to the core-shell structure, a void space between the core and the shell depicts the distinction between these two structures [1]. Recently, yolk-shell materials have attracted interest due to their particular combination of high thermal stability with monodisperse and narrow particle-size distributions that convert them to an effective catalyst for heterogeneous catalysis. Not only do these specifications have a significant role in catalyst performance, but also they can facilitate kinetic and mechanistic researches [20].
In these yolk/core-shell catalysts, the vast majority of the catalytic attributes of the throughout catalyst are the same and may include a tiny alteration through the change from active particle to active particle. Thus, in these structures the resulting catalytic activity of the system can be the same all over the surface of the catalysts, in comparison, in traditional solid catalysts there are no homogenous sites and to evaluate the activity of the catalysts, an average of all possible morphologies should be considered. Furthermore, the yolk/core-shell structures provide catalytic particles with a uniform size that leads to an effective SMSI for all the particles. They contribute to the new catalytic sites at the interface of themselves and MNPs and modify their actual catalytic characteristics of them. Therefore, these features cause these kinds of encapsulation structures to be placed at the noticeable position as support of MNPs catalysts and remarkable efforts have been done in synthesizing base-metal yolk/core-shell catalysts in recent years [1, 21]. In addition, there are some significant ways toward the improvement of the design and fabrication, in particular, yolk-shells to produce effective catalysts:
Although the encapsulation of nanoparticles by applying an additional coating layer may decline the adsorption of the reactants on the active phase, the porosity of the shells exhibits a crucial role in the improvement of mass transfer across the shells. Therefore, porosity is an essential specification that should be considered when synthesizing yolk/core-shell catalysts. Various methods to make porose yolk/core-shell, such as layer-by-layer deposition techniques and sacrificial templating procedures, in particular for yolk-shells, have been reported that provide adequate stability even under harsh reaction conditions. Moreover, the “surface-protected etching” is a contemporary strategy that outputs catalysts with porous shells and enhanced stability simultaneously. This process protects the oxide shells, in particular the inner part of the shells, by utilizing a suitable layer of the polymeric ligand as an etching agent. Thus, the oxide shells would have their original size and the selective etching of the interior creates the porous structure [22]. On the other hand, this procedure may have a noticeable restriction in which the metal loading of the catalyst in most cases is placed at a low level. To dispel this drawback, first of all, an inert chemical linker should be utilized to fix the MNPs onto the surface of the initial support with another layer of these inert chemical linkers. Next, the surface-protected etching procedure would be utilized to modify the outer shell into a mesoporous shell that exposes the MNPs to the reactant active species. Silica is one of the most popular inert chemical linkers [22, 23, 24, 25].
In most cases, the various yolk/core-shells that are prepared through the sol–gel deposition method are amorphous. Due to the remarkable effects of the crystalline phases on the performance of catalysts, it is essential to enhance shell crystallinity. The effective pathway to modify the amorphous shells to their crystallized counterparts is calcination at high temperatures. Although calcination would improve the crystalline phases of the shell, it might reduce the porosity of the original amorphous shell considerably. Therefore, to prevent this difficulty, first of all, it is important to conduct another inert chemical layer (such as silica layer) on the top of the shell through a sol–gel process, then the calcination treatment should be applied. Eventually, the final porous morphology that will be a yolk-shell structure can be achieved by scarifying the inert chemical layers through chemical etching [22, 23, 24, 25]. Figure 2 depicts the procedure of fabrication of a porous yolk-shell through employing sacrificed layer, calcination, and etching treatment. Two TEM images of a core-shell (a1) and yolk-shell (a2) are also illustrated in Figure 3 [26].
Synthetic procedure of MNP@Void@M’O2 (M’O2: TiO2, CeO2, ZrO2, …) Yolk-Shell in four steps; 1: Encapsulation with sacrificed shell (m-SiO2) nanoparticles, 2: Encapsulation with exterior shell (M’O2), 3: Calcination, and 4: Etching.
TEM images of (a1) MNP@SiO2 core-shell and (a2) MNP@Void@M’O2 Yolk-Shell. Reprinted with permission from Ref. [
Mesoporous materials are special types of nanomaterials with ordered arrays of uniform nanochannels that are fabricated by participating self-assembly of surfactants and framework precursors. Mesoporous materials include pores with diameters in the range of 2–50 nm that by dispersion of MNPs into this porous matrix a range of heterogeneous catalysts can be formed [2]. These structures by supplying a great surface area provide a dramatic spatial dispersion of the MNPs that leads to stability enhancement in contrast to nanoparticle aggregation and coalescence in a catalytic process. In addition, the prominent porosity of these structures in catalysts paves the way to prepare an effective mass transfer that improves the catalytic performance by facilitating the contact of reactants with the MNPs as active sites of catalysts. Furthermore, the appropriate pore size distribution puts the MNPs adjacent to the mesoporous material, which leads to the enhancement of catalytic activity and stability through boosting the strong MSIs. The mesoporous materials have pores with an adequate size that cause the adsorption of pre-synthesized MNPs with small sizes directly [1, 2]. Meanwhile, the size and volume of the mesopores or in overall the size of the whole mesoporous matrix, and metal charge have a significant impact on the immobilization of metals [27]. Eventually, the specific morphology of the pores in these structures exposes the sites of active metals, which leads to facilitating the catalytic process [1, 2]. Thus, these features of mesoporous materials convert them to outstanding supports that can encapsulate the MNPs in catalysts.
Although the incipient wetness impregnation is a popular strategy for the encapsulation of MNPs in the mesoporous materials as heterogeneous catalysts, the self-assembly-based approach is the other useful strategy [2].
In recent decades, noticeable progress in synthesizing various inorganic nanomaterials to encapsulate the nanoparticles with unique catalytic performance, owing to their principal advantages, such as simplicity of fabrication, tunability of formation, and cost-effectiveness, converts them to popular supports. Although inorganic oxides (SiO2, TiO2, CeO2, ZrO2, etc.) are mostly applied as shell structures in the yolk/core-shell morphology, some of them, in particular silica, exist in mesoporous in some cases. In contrast, zeolite mesoporous structures are the common morphology beside the yolk/core-shell structure of them.
Silica has attracted an increasing number of researcher attention owing to its inimitable physicochemical properties, such as tunable morphology, extensive surface area (≈1500 m2 g−1) and pore volume, adjustable sizes (50–150 nm), shapes (hexagonal, wormhole-like, cubic, and lamellar) and morphologies (spheres, helical fibers, tubules, gyroids, crystals), ease of surface functionalization (both interior as well as exterior), unique topology, colloidal and thermal stabilities, and high dispersity [27]. Silica with each of these desirable features can be achieved through tuning the synthesis conditions, such as the temperature, pH, stirring speed, and type of silica source, and particularly the surfactant [27]. Therefore, these unique attributes of silica besides the simplicity in controlling the SiO2 precursors convert it to a principal and useful inorganic shell for the encapsulation of MNPs. Moreover, owing to SiO2 inert chemical features, its structure would be resistant under harsh conditions that lead to the protection of the size of MNPs under this condition. Furthermore, not only would not the chemical inertness of silica that encapsulates MNPs is influenced by the metal-oxide interactions but also intensify their catalytic properties [1, 3]. Although silica supports due to their chemical inertness have a tiny interaction with reactants that may reduce the adsorption of the reactive molecules, their porosity can restrict the effects of their weakness by intensifying their diffusion across the capsule [1]. Moreover, stability of the metal-silica nanoparticles is an outstanding challenge, particularly in catalytic applications that deal with diverse physicochemical properties especially the features of the final catalyst compounds, such as the type of MNPs, particle size, degree of silica condensation, and chemical functionalization [27].
The principal method to form the silica shells is the sol–gel. The synthesis of the silica shell is conducted through a modified Stober procedure, in which the hydrolysis and condensation of tetra ethyl orthosilicate (TEOS) take place in aqueous ethanol in the presence of a base as a catalyst, such as ammonia, to control the growth of silicate on the surface of the MNPs [1, 2]. To coat some unstable metals, such as Ag, with silica, it is essential to utilize the amines, such as dimethylamine or di-ethylamine, instead of ammonia as the base catalyst [2]. Overall, as opposed to mesoporous silica materials to encapsulate the MNP in the shell spheres of mesopores silica, firstly the metal precursors should be dispersed and the surfactant alongside the silica precursor (TEOS) should be added. This core-shell strategy contributes the best results in encapsulating some metal oxides, such as Mn, Co, and Ni [27].
Although the general configuration of silica shells achieved through the sol–gel process is microporous, the mesopore textures could also be formed that are more appropriate for catalysis applications because this shape of texture rectifies the mass transfer limitations [1, 4]. The encapsulated metal-silica nanostructure gaining through the sol–gel pathway makes a thin shell of silica which owing to the high interfacial energy a fragile interaction exists between silica shell and MNPs. Nucleation of silica prevents from occurring a suitable interaction between silica and MNPs. However, to pave the way and achieve an improved interfacial interaction, utilizing some bridging agents as surface primers is essential [4]. Generally, the surface primers are applied for encapsulation of silica over large MNPs (>10 nm) that can refer to some of them, such as amino propyltrimethoxy silane (APS), methoxy poly (ethylene glycol) thiol (MPEG-SH), and polyvinylpyrrolidone (PVP). PVP is applied for the smooth coating of silica on the MNPs [1, 2]. Despite the fact that surface primers have a critical role to create a stable and homogeneous silica coating, in some cases, they can provide a selective silica coating on the surface [4, 28]. Furthermore, the type of the silica source and the added surfactants have a crucial impact on the size of MNPs and the thickness of the SiO2 shell in yolk/core-shell structures. Although some surfactants, such as PVP, cetyltrimethylammonium bromide, and chloride (CTAB and CTAC), could not be influential on the dispersion of the MNPs, they could have an enhancement effect on the porosity of the SiO2 shells [1, 4].
On the other hand, ultrasmall MNPs (<10 nm) are unstable and have an aggregate tendency in alcoholic solutions. As a result, the formation of a coating of silica cannot be implemented by an appropriate outcome. To get rid of this imperfection, the silica coating should be conducted in a reverse micelles (or microemulsion) system by using polyoxyethylene nonylphenyl ether (Igepal CO-520) as a surfactant [2]. Mostly, owing to there not adequate interaction between silica and the metal surface this technique of coating may have some weaknesses that may lead to an undesirable and imperfection coating. Liu et al. [29] presented an effective procedure, ship-in-a-bottle, to fabricate a robust thin silica coating on the sub-3 nm MNPs in reverse micelles. In this method, the synthesis of MNPs and silica coating in the presence of water/cyclohexane/reverse micelle system will participate simultaneously. The combination of microemulsion system and ship-in-a bottle technique pave the way to achieve a range of various metal-silica core-shell composites [2].
Mesoporous silica nanoparticles are presented as effective support for the encapsulation of MNPs due to their outstanding specifications, such as well-ordered framework, tunable pores, high surface area, stability, and thermally toughness. In addition, they contribute a well-made 3D matrix that provides a monotonous distribution of MNPs and confinement them from aggregating there that lead to noticeably protect against the sintering of them. Moreover, in contrast to the other inorganic supports through the encapsulation of MNPs, the mesoporous silica nanoparticles can represent a wide range of applicable characteristic surfaces in both the exterior (on the surface) and interior (in the mesopore) space, where MNPs can be organized by a chemical linkage or physically immobilized by electrostatic interactions [27].
The mesoporous silica nanoparticles can be synthesized through cooperative self-assembly of surfactant and silica species. The morphology and dimensions of mesoporous silica nanoparticles are significantly influenced by the factors of reaction kinetics of sol–gel chemistry, such as assembly kinetics, silica condensation, nucleation, growth rates, and surfactant-silica interactions, in addition to pH value of the reaction medium, water content, and temperature. Mobil composition of matter (MCM)-41, and the Santa Barbara amorphous type material (SBA)-15 are the famous mesoporous silica nanoparticles that are synthesized by applying quaternary ammonium salts and Pluronic copolymer-based surfactants, respectively [27].
There are two common techniques to encapsulate the MNPs in mesoporous silica materials. First of all, in the way of an incipient wetness impregnation method dealing with the encapsulation of MNPs, a solution of the metal salt is exposed to a powder of mesoporous silica including the same pore volume as the volume of the metal salt solution. Then, the MNPs are transferred from the metal salt solution into the mesopores by utilizing the capillary force. Finally, the implementation of the calcination and reduction in H2 subsequently will pave the way to achieve a mesoporous silica matrix that encapsulates MNPs. In some cases of the incipient wetness impregnation procedures, electrostatic interactions are the main force to conduct the diffusion of MNPs through the meso-channels that can be implemented by modifying the mesopore surface by positively charged quaternary ammonium groups [2].
The other procedure is the participation of self-assembly of the MNPs and silica precursors with a surfactant-mediated condensation technique. Firstly, a dilution of the silica precursor is mixed with the aqueous ammonia including the CTAB surfactant molecules for initial nucleation and on the contrary of the core-shell silica architecture then the desired metal precursor is subsequently added to the mixture. Eventually, to achieve the desired mesoporous silica material, the surfactant can be eliminated by either calcination procedure at high temperatures (550°C) or a variety of chemical solutions, such as acidic ethanol or ammonia in ethanol/isopropanol. Although isopropanol, as a solvent for ammonium nitrate, can be utilized to extract the surfactant, it is able to save the well-order of the mesostructures and create a dramatic impact on the surface area and pore volume of mesoporous silica nanoparticles. Hence, not only there is not any essential tuning in the pore size or volume of the mesoporous silica nanoparticles, but also there is no noticeable change in the final particle size or pore sizes in the presence of the encapsulated MNPs in the siliceous frameworks that leads to uniform encapsulating of metals in mesoporous silica nanoparticles at the basic PH [2, 27].
Among the non-silica coating materials, titania is the most popular metal oxide. Despite the fact that TiO2 is utilized as a coating layer of MNPs in a wide range of catalysts, this combination has illustrated noticeable synergy in various catalytic reactions. The synthetic routes and precursors are the main effective agents to produce a specific architecture of yolk/core-shell. The encapsulation of MNPs in titania nano-shells is the outcome of the direct coating of TiO2 on them. Similar to the method of silica coating, sol–gel procedure is the major process of titania coating. Thus, through this method by applying titanium alkoxides like tetraisopropoxide (TTIP) in a nonaqueous solution while the existence of water, the TiO2 coating will be implemented. Due to titanium alkoxide hydrolyze in water immediately, applying chelating agents like acetylacetone, which is a chelating agent of titanium butoxide (TBOT), controlled hydrolysis can be provided that leads to fabricate a core-shell nanostructure with a stable coating of titania [2].
To develop stable yolk/core-shells of titania, utilizing appropriate precursors have a crucial role. As evidence, a chelated complex of titanium glycolate, which is formed by reacting titanium alkoxide with ethylene glycol and is much more stable than titanium alkoxide, can provide an outstanding precursor for the titania coating of MNPs that can undertake a very controllable sol–gel process to fabricate identical metal@TiO2 core-shell nanoparticles that are catalyzed by acetone. Moreover, this technique is applicable for a controlled coating of titania on small MNPs with a diameter from tiny sizes to 50 nm [2, 4]. Furthermore, to achieve a uniform and thin shell of titania that can be adjusted with the thickness ranging from 3 to 12 nm in the sol–gel process, an acid catalyst like citric acid to hydrolyze the TBOT at the presence of alcohol can be applied [2].
Another suitable precursor that can slow down the hydrolyze in water, titanium (IV) bis (ammonium lactate) dihydroxide (TALH), can provide the titania coating with shell thickness ranging from sub-50 nm on MNPs. Although the TALH in aqueous solutions at room temperature is stable, it can be hydrolyzed at high temperatures (approximately 65°C) that lead to control of the sol–gel process [2].
Although Zeng et al. [30] fabricated a yolk-shell nanostructure of the Au@TiO2 through the hydrolysis of TiF4 at high temperatures (180°C), the most popular pathway to obtain a metal/TiO2 yolk-shell nanostructure forms a coating layer of titania on metal/SiO2 composites, which the silica will be sacrificed [2]. The principal benefit of this procedure of MNPs encapsulation with titania at the presence of sacrificial silica is the easy formation on the contrary of the direct formation of titania nano-shell. In addition, owing to the chemical sympathy between the two oxides to achieve a suitable coating layer of TiO2, it is not essential to implement any rectification on the silica surface to set up the interactions between titanate species and silica. Despite this coating pathway being a successful process, to improve the coating of titania in this way, utilizing a surfactant such as hydroxypropyl cellulose (HPC) is presented that enhances the colloidal dispersion of silica nanoparticles [2].
Finally, similar to encapsulation of ultrasmall MNPs with silica nano-shells, titania coating will be conducted in the same way. First of all, in a reverse micelles system nanoparticles are formed and then a coating of silica on the nanoparticles at the presence of TEOS will be done and the last layer, which is titania, will be formed through applying TBOT. Eventually, the yolk-shell nano-capsule can be achieved by thermal reduction and etching of the silica templates [2].
Another metal oxide that attracted significant interest is cerium oxide. The presence of oxygen vacancies at the terminating of its planes is affected considerably on the adsorption of reactant molecules in the catalytic reactions by controlling the energetics of the surface interactions [31]. Despite the fact that the encapsulation of MNPs in CeO2 nano-shells tackle the sintering of MNPs, it provides strong metal-support interactions (SMSI) that lead to enhancing the stability and the performance of the catalysts at the series of catalytic oxidation reactions, particularly at high temperatures [2].
The core-shell nanoparticles of metal@CeO2 could be synthesized based on the self-assembly procedure by applying a supramolecular [2]. Gorte et al. [32] implemented this strategy by applying a capping ligand of a thiolate (11-mercaptoundecanoic acid, MUA) to fabricate Pd nanoparticles that are mixed in tetrahydrofuran (THF) [2]. The carboxylic groups of MUA conducted the self-assembly of the cerium (IV) alkoxides around the Pd nanoparticles directly by exchanging the alkoxy group on the Ce (IV) salt with the carboxylic group on the surface of the Pd nanoparticles as a result of the presence of the carboxylic group, which is a stronger ligand for Ce (IV) than the alkoxy group. Furthermore, various ranges of metal@CeO2 core-shell nanoparticles can be fabricated by controlling and designing precisely the effective parameters of the self-assembly strategy and the sol–gel process, particularly by utilizing the appropriate chelating agent. So, some of these chelating agents and their role in the encapsulation of MNPs by CeO2 yolk/core shells are presented as follows [2].
Ethylenediaminetetraacetic acid (EDTA) is applied as a chelating agent that chelates Ce (III) salt. Although EDTA slows down the hydrolysis of the Ce3+ ions, due to the negative charges of the EDTA-Ce (III) complex, the electrostatic interactions between the Ce complex precursor and MNPs have a significant role in the self-assembly strategy [2]. Moreover, triethanolamine as a chelating agent to achieve a cerium-atrane precursor has exhibited its effect on fabricating the desired metal@CeO2 core-shell nanoparticles by adjusting the sol–gel kinetics. Another chelating agent for the CeO2 coating on MNPs is citric acid. It puts its effects by controlling the self-assembly way through conducting the adsorption of Ce3+ ions on the MNPs that were gradually oxidized to CeO2 nanoparticles [2].
Another principal approach to synthesize metal@CeO2 core-shell nanoparticles is the auto-redox strategy, which is based on the reduction of the high valence metal species and the oxidation of low-valence Ce (III) species. Some of metal@CeO2 core-shell nanoparticles that are synthesized by utilizing this mechanism depict a “rice-ball” shape-like Ag@CeO2. In addition, to encapsulate the ultrasmall MNPs and construct the uniform metal@CeO2 core-shell nanoparticles, the auto-redox strategy could be undertaken in a reverse micelle system. Furthermore, due to any surfactants not engaged in the auto-redox methods, multicore-shell nanospheres with a diameter larger than 85 nm could be formed. Although CeO2-encapsulated bimetallic MNPs can be formed by applying the auto-redox strategy, the self-assembly approach and the salting-out effect can be influenced the formation of these core-shell nanoparticles [2].
Another ideal encapsulation nanostructure with a hollow space between the metal core and the outer porous CeO2 shell is the yolk-shell architecture that has an effective impact on tackling the aggregation and sintering of tiny noble MNPs in catalytic reactions [2]. To implement this kind of encapsulation, a templating method should be conducted by coating a layer of silica firstly, and then the layer of CeO2 could participate on the MNPs through a sol–gel process. Eventually, the metal@SiO2@CeO2 nanospheres can be modified into multi-yolk-shell metal@CeO2 nanospheres by eliminating the silica template. In addition, through this process, multi-yolk-shell structured nano-catalysts can be formed, for instance, Pd@hm-CeO2, which is presented by Zheng et al. [2, 33]. Despite silica being the most popular sacrificial template, polystyrene (PS) fibers and resorcinol-formaldehyde (RF) can be utilized as a removable template [2].
Zirconium dioxide (ZrO2) is a metal-based inorganic material that is presented as an insulator in some applications. Due to the chemical inert feature of ZrO2, it has outstanding resistance to acids and alkalis environments that convert it to crucial catalyst support at harsh reaction conditions. In addition, it has significant heat stability that is suitable for a high thermal catalytic reaction to encapsulate and support the MNPs. Although it has low thermal conductivity and is utilized as thermal barrier coatings, it has a high refractive index, which is well-suited for various optical applications [34].
Recently, zirconia as catalyst support, particularly in the encapsulation shape, attracts numerous interests. In most cases, MNPs are encapsulated in zirconia nano-shells in the form of yolk-shell [25, 35, 36, 37]. Similar to the other yolk-shell nano-catalysts, metal@ZrO2 yolk-shell can be synthesized which this catalyst with robust zirconia shells illustrates noticeable catalytic activity and outstanding anti-aggregation features during the time of the catalytic process and upon thermal treatment or reduction.
Apart from inorganic oxide shells, encapsulating MNPs in carbon nano-shells participated in numerous investigations. Although the core-shell nanostructures manufactured from inorganic oxide have noticeable advantages, in some conditions they illustrate some weaknesses, for instance, the dissolution of silica coatings at strong basic conditions. In contrast, carbon yolk/core-shells can tackle these difficulties and additionally demonstrate some outstanding specifications, such as high physical and chemical stability under harsh conditions, high surface area, tunable electronic structures, high electrical conductivity, good biocompatibility, and relatively low manufacturing costs. Therefore, they can be one of the best materials to encapsulate the MNPs [1, 2, 38]. With regard to the type of crystallinity of carbon shells, this section is allocated into metal @amorphous carbon and metal @graphitic carbon.
Metal @amorphous carbon can be fabricated by encapsulated MNPs through a polymer coating layer. Due to their low cost, rich chelating groups, and high compatibility with MNPs, these polymers are presented as leading carbon precursors that include resorcinol-formaldehyde (RF) resin, tannic acid, and polydopamine (PDA) [2]. To fabricate a noticeable-performance M@carbon catalysts, carbon precursors should be utilized through a suitable controlled sol–gel process to provide the target coating layer and then carbonization should be implemented which the output would be a carbon shell with appropriate thickness and tunable pore structure. For instance, the carbon nano-shell with 63 wt% would be formed during the carbonization of the RF coating shell under an inert atmosphere [1, 2]. In addition, to adopt the congruity between the inorganic cores and the RF shells, it is essential to modify the surface with CTAB or 3-aminopropyltriethxoysilane (APS) in the coating process [2].
On the other hand, although conducting the coating process after synthesizing MNPs will be yielded a controllable shell, implementing this process through a one-pot in which the formation of MNPs and the polymer coating will be done in a single step leads to achieving a more convenient pathway to synthesis M@RF core-shell nanospheres in the absence of surfactants. Through this procedure first of all, MNPs are formed from metal salts by adding formaldehyde. Next in the presence of the other precursor, ammonia, the polymerization of the RF precursors on the surface of MNPs will be undertaken. The concentration of resorcinol and formaldehyde can control the size and thickness of the RF shells. Moreover, resorcinol can reduce the surface activity of MNPs and prevent them from aggregating. Eventually, M@carbon core-shell nanospheres with a wide range of metals can be obtained after carbonization [2].
Furthermore, impregnation is another principal approach to synthesizing encapsulated MNPs in amorphous carbon. Overall, in this method firstly metal ions could be adsorbed at the sites of amino groups in pre-synthesized mesoporous aminophenol formaldehyde (APF) nanospheres. To create hollow carbon shells which, encapsulate MNPs before conducting carbonization a mesoporous silica layer should be done. Moreover, yolk-shell structures with MNPs can be achieved by coating another layer of APF on the APF@SiO2 nanospheres. This mechanism is flexible and can be used to fabricate monometallic Au, Pt, Rh, and Ru and bimetallic Au-Pt, Au-Rh, and Pt-Rh nanoparticles [2]. What is more, some other sources of carbon such as D-glucose, saccharides including fructose and sucrose, and dopamine can be involved. Dopamine owing to its catechol and amine groups and the ability to self-polymerize on various substrates is considered as a remarkable carbon source, particularly in synthesizing yolk-shell structures containing MNPs in the yolk that encapsulated with carbon nano-shells [1, 2].
Although amorphous carbon represents significant specification in catalysis applications, graphitic carbon has further conductivity and stability, particularly in electrocatalysis. The high-temperature pyrolysis promotes the crystallization of carbon through the process of fabrication of MNPs encapsulated in graphitic carbon nano-shells (M@GC). One of the most common procedures to fabricate the M@GC is the pyrolysis of metal–organic frameworks (MOFs) in an inert or reductive atmosphere directly. During the pyrolysis of MOFs which are the assembly of metal ions as nodes that are linked together through organic ligands as linkers, MNPs are achieved by the reduction of metal nodes, and then these MNPs can catalyze the generation and configuration of graphitic carbon from organic linkers on their surface. In addition, bimetallic alloy nanoparticles could be encapsulated in graphitic carbon through pre-encapsulating noble MNPs or metal salts in MOFs and subsequent pyrolysis [2].
Graphene is a solo layer of graphitic carbon atoms that bonded together in a honeycomb crystal lattice, which this unique structure intensifies its specifications much higher than the other carbon material and converts it to an outstanding material for encapsulating MNPs to improve their catalytic activities. As a result of diffusion restriction and chemical inertness of graphene to a various oxidizing gas, it conducts as a passivation layer to intercept some metal (Cu, Ni, etc.) from oxidation. Although the potential energy surface of graphene can transfer from 0.15 to 1 eV on various metal substrates (Ni, Co, etc.), the principal metal has an influential impact on the electronic structure of the graphene coating layer. The electronic specification of graphitic carbon can exhibit its critical role on the catalytic activity when the shell includes no more than three to four carbon layers. Hence, it is crucial to fabricate carbon encapsulated catalysts with a controllable number of graphene layers which one of the usable procedures is the chemical vapor deposition (CVD) technique [39].
Although through CVD techniques a thin film can be formed on the substrate surface which has a dramatic influence on the fabrication of carbon nano-shells, these methods have multistep synthesis processes, which lead to being complex, expensive, and difficult to implement large-scale commercialization. In addition, to achieve a graphene shell on MNPs through the CVD procedure, it is essential to provide a high temperature above 800°C, this condition may lead to melting the MNPs and gathering them together [39, 40]. Thus, it is essential to utilize a functional synthesis pathway that is presented by an arc-discharge method. Through this technique, MNPs encapsulated in graphene shells have large sizes and extensive distribution of particle sizes, in some cases empty carbon cages and CNTs were achieved simultaneously. To tackle this difficulty, applying a long pulse laser in methane or a mixture of methane and helium at room temperature are presented, the efficiency of this approach is the formation of an ordinary size of 5 nm and appropriate size distribution of 3–10 nm of core-shell structure M@GC [39, 40, 41].
On the other hand, the metal alloy can be encapsulated in highly nitrogen-doped graphene layers by one-step annealing under a nitrogen flow without adding any other carbon sources by utilizing bimetallic complexes with CN- group linkers in the form of metal–organic framework (MOF) precursors [39]. In addition, electrostatic interactions between negatively charged graphene oxide and positively charged metal oxide nanoparticles can be applied for encapsulating metal oxide in graphene shells, which this method can be followed by chemical reduction. First of all, amino propyl-trimethoxy silane (APS) paves the way for the metal oxide nanoparticles to exhibit an oxide surface positively charged. Then, electrostatic interactions put the modified metal oxide nanoparticles with negatively charged graphene oxide together. Eventually, the accumulation of them will chemically be reduced with hydrazine to gain the metal oxide nanoparticles encapsulated in graphene. Because this mechanism can provide all the applicable features, such as simplicity of operation, low cost, and optimal efficiency, it can be a functional strategy to produce a variety of graphene-encapsulated catalysts on a large scale [39, 40].
Zeolites are presented as highlight catalyst supports due to their highly crystalline, well-distributed pore structure and adjustable acidity. In general cases, the zeolite structure embodies TO4 tetrahedra (T defines Si, Al, and P, etc.). Due to adjusting the T-O-T linkage a wide range of zeolite structures can be formed via tuning the synthesis conditions such as the composition of the gel, the nature of the structure-directing agent (SDA), or the temperature [42, 43].
Although the catalytic activity of the catalysts often depends on the host nanoparticles, it can be modified by the zeolite framework features. In particular, the modification of local geometry around active sites which is derived from steric constraints affected by the size of zeolite cavities can effectively influence the reactivity of catalysts [43]. Zeolites based on the size of their pores can be classified into small, medium, large, and extra-large pores. The catalytic activities of zeolites deeply depend on the structural and compositional features, consisting of pore sizes, channel types, and framework compositions. In comparison with the other catalyst supports, zeolites are presented as a shape selective that can selectively interact with reactants, products, and transition-states that this attribute has a significant impact on the catalytic performance of zeolites [42]. Due to zeolites being composed of tetrahedrally [SiO4]4− and [AlO4]5− primary units, to balance the overall electric charge of the zeolitic skeleton, some free cations are accommodated into the channels of the 3D framework, which can be substituted by other cations. Al content in the zeolite framework has the main effect on the ion exchange capacity of zeolites when the cations of zeolites are exchanged by protons, zeolites conducted as solid Brønsted acid catalysts [44]. In addition, the existence of charges in the zeolite framework, as well as extra-framework cations, can have a significant impact on the electronic and redox properties of the encapsulated complex [43]. Despite the fact that zeolites can apply as a shell through the coating of MNPs with layers of zeolite, in some cases, the encapsulation of MNPs can operate in the regular cavities and nanochannels of zeolites [42]. Hence, the encapsulation of MNPs in zeolites is considered in two parts—yolk/core-shells and mesoporous structures.
In the approach of nanotechnology, zeolites can be utilized to make novel nanostructure synthetic materials, zeolite core-shell structured materials being the outstanding structure among them [45]. The capability to synthesize core-shell zeolite composites has depicted the principal importance of chemical adaptability and structural likeness between core and shell crystals, as well as their close crystallization conditions [46]. On one side, a core-shell structure of zeolite can be formed via crystal overgrowth in which an aluminum-free zeolite (core) was coated with aluminum-containing zeolite (shell). Fluoride ions as mineralizers can conduct the accomplished passivation of acid sites on the external surface to minimize the imperfections of the core-shell zeolite structure, so applying them is essential [47]. To increase the selectivity and catalytic activity of the core-shell zeolite with TON structure, a novel high silica zeolite, for skeletal isomerization of n-tetradecane, it is essential to break needle-like particles for the formation of new acid sites on the pore mouths of smaller broken particles since, the acid sites on the side surface of the needle-like particles, which principally catalyzed the cracking of alkanes, were passivated [47]. In addition, through utilizing the techniques of layer by layer self-assembly of polyelectrolyte the core-shell zeolite-zeolite composites consisting of single-crystal core and polycrystalline shells of various zeolite structure types can be fabricated. This approach occurs based on the coulombic forces that lead to enhancing the surface charge of the core particles by coating the layers of zeolite [45]. Moreover, core-shell structures of zeolites can perform as a multi-purpose catalyst that have several impacts in various functions simultaneously. For instance, the shape-selective attribute of zeolite shell provides this ability that a catalytically active nano/micro-sized core encapsulated with a thin selective zeolite shell can be potentially utilized as a tiny membrane reactor. To achieve this purpose, first of all, the catalytic active materials such as metal oxides will be replaced in the core. Then secondary growth will be conducted through a precursor solution to coat a layer of zeolite, subsequently, the growth of this layer can continue until a dense and well-intergrown zeolite shell is formed that can also play its role as a highly efficient zeolite membrane. Not only does this zeolite shell provide a prominent selective mass transfer between the encapsulated core and the extension, but also the participating catalytic reaction on the core can promote each of such zeolite core-shell structured particles into a tiny membrane reactor which can present appropriate potential in a wide range of reaction systems [45].
On the other hand, the other nano-shell catalyst structure of zeolite which can be pointed to it is the yolk-shell zeolite-based catalysts. This structure can be achieved by silica-zeolite core-shell materials. First of all, silica particles are partially dissolved under high pH conditions, then through controlling the recrystallization of the surface of silica spheres by the zeolite, new agglomerated zeolite nanocrystals can be formed which depict hollow capsules. MNPs prior to recrystallization can be located at the core [43]. Overall, to synthesize spherical hollow zeolitic structures should apply the sacrificial templates such as organic polymers or silica whose particles within the core can be removed in the final step respectively by calcination or etching [45].
Zeolites with a mesoporous matrix are a family of porous materials with an effective crystalline framework containing a finite number of well-defined and small cavities with sub-nanometer to 2 nm size. The most interesting attribute of their structures is the possibility to tune and choose the similar size of their micropores with the size of MNPs that would be encapsulated in them. In addition, it can intensify the catalytic selectivity due to enhance the efficiency of reactants and products diffusions [2]. Meanwhile, by encapsulating the MNPs inside the micropores of the zeolite framework they would be effectively enclosed through their interconnected cavities [42, 48]. Not only can mesoporous zeolites perform as an immobilize or stabilize framework to encapsulate the nanoparticle catalysts, but also they represent as a molecular sieve via molecular selecting with the proper size and shape or as a hybrid catalyst for transforming products formed firstly [43].
There are various procedures to implement the encapsulation of MNPs through the zeolite pores which are selected on the basis of nanoparticle size and their nature [43]. Although the formation of MNPs and the growth of zeolites are two parallel pathways, in most synthesis strategies both of them are simultaneously conducted in one process synthesis, due to the pore sizes of most zeolites being too small, less than 2 nm, which is not appropriate for directly encapsulating MNPs [1, 2]. Here some popular approaches to undertake the encapsulation of MNPs in zeolites are presented.
Hydrothermal synthesis strategy is a common procedure that is done under a thoroughly alkali condition. In this technique the metal precursor is directly added to the synthetic solution, to prevent premature reduction or precipitation of the metal salt through the crystallization of the zeolite, a mercaptosilane ligand like 3-mercaptopropyl tri-methoxy silane (MPTMS) should be applied into the hydrothermal synthetic system. Despite the mercapto groups supporting the metal precursors from reducing untimely through the alkaline synthetic solution, the other group of MPTMS that is alkoxysilane prepares an appropriate condition to fabricate crystalline frameworks with silicate and aluminate. Thus, the MPTMS paves the way to conduct the encapsulation of the MNPs in the mesoporous framework of zeolite monotonously. Eventually, the crystalline framework of metal precursor-zeolite which is gained by this procedure should be calcined in air to eliminate the organic agents and reduced in H2 to create novel MNPs through the micropores of zeolite. In addition, LTA-type zeolites including micropores with the approximate size of 0.41 nm are the appropriate option to encapsulate the MNPs through this hydrothermal synthesis strategy. To enhance this hydrothermal procedure with the highest efficiency (>90%) of zeolite-encapsulated MNPs, initially, alcohol is added to eques mixture of the mercaptosilane and metal salt, then a pre-hydrolyze at low temperature will be performed to achieve a uniform gel [2, 48].
Solvent-free crystallization is another popular strategy to encapsulate MNPs in mesoporous zeolites. By exposing a metal/silica/alumina hybrid in the vapor of water at a high temperature the solid-phase transformation of the amorphous silica and/or alumina into a crystalline zeolite that encapsulates MNPs is initiated. Furthermore, this synthesis method can provide a pathway to fully encapsulate the pre-synthesized MNPs inside the zeolite single crystals more reliably [2]. FAU- and MFI-type zeolites are the main mesoporous zeolite types that are applied for this procedure [2, 43]. In particular, Chen et al. [49] utilized nanocrystals of MFI-type zeolite (silicate-1 or S-1) in a strong alkaline environment. The outstanding feature that promoted the crystallization involved the Kirkendall effect which led to growing the pore size of mesoporous inside the S-1 crystals to around 3 nm and may impact on the enhancement of the mass transfer in catalytic applications [2].
The encapsulation of MNPs in zeolites can be involved in the seeded growth of zeolites on zeolite seeds that already include MNPs. This synthetic strategy is implemented in two steps—first of all, the impregnation of the zeolite seeds with a metal salt is implemented, then desiccated the mixture to achieve a dry powder, and next conducted the reduction process at a high temperature in H2 to convert the metal salts to the MNPs, eventually the achievement products are the zeolite seeds included the MNPs. In the second step, a hydrothermal system in the presence of aluminosilicate or silicate gels and the zeolite seeds including the MNPs are involved. Consequently, the encapsulation of MNPs such as Pt, Pd, Rh, and Ag in zeolites like MFI, MOR, and BEA, particularly at the interface between the zeolite seed and sheath could be effectively conducted. Moreover, a great core-sheath interface can enhance the loading amount of MNPs which can be obtained by employing a zeolite type with a high surface area when providing the metal-containing seeds through the synthesis process [2, 48].
Metal–organic frameworks (MOFs) are outstanding microporous materials including two major components: bridging organic linkers and inorganic secondary building units (SBUs) of metal ions or oxo-clusters (3d transition metals, 3p metals, or lanthanides). MOFs provide an exceptional combination of inorganic and organic components with synergistic interactions among them which create great usability for a myriad of purposes. These microporous materials are fabricated by gathering metal ions with organic ligands together in appropriate solvents often during a self-assembly strategy. In addition, the organic linkers are di-topic or polytopic organic ligands like carboxylate, nitrogen-donor groups, sulfonate, or phosphonate that are able to bind with metal-containing SBUs to form crystalline framework structures with open pores. Although MOFs present crystalline structures with dramatic large and uniform internal surface areas, their porosity and chemical features can adjust respectively by tuning the pore size and modifying the organic linkers according to our requirements on various catalytic applications. Moreover, the functional groups of organic ligands such as -NH2, -NO2, -SO3H, -Cl, and -OCH3 groups can be linked on the pore walls through the one-step assembly or post-synthetic modification which can impact on the catalytic performance. As a result, more than 20,000 MOFs with various compositions and topologies have been reported in recent decades. Meanwhile, metal nodes can present Lewis acidity features which are emerged by utilizing transition metals, additionally, they can engage in redox catalysis or support the progression of coupling reactions. Furthermore, metal nodes make various coordination positions by the participation of solvent molecules which can be eliminated through a thermal approach while saving their frameworks [50, 51, 52, 53].
Encapsulating guest particles into MOFs provides a wide range of potential for various applications, particularly in catalysis. A great number of particles can be encapsulated such as inorganic MNPs, coordination complexes, quantum dots, polyoxometalates, enzymes, and polymers through a pre- and post-synthetic strategy. In comparison with the other encapsulating materials, MOFs exhibit confinement effects and shape selectivity in a more effective route, and their synthesis conditions are more moderate. In addition, owing to the existence of a wide range of MOF structures, it is simple to adopt a suitable MOF as the encapsulating material. Hence, the encapsulation of MNPs in MOFs converts them to prominent catalysts that attract considerable attention, due to they present the unique attributes of MOFs alongside the chemical and physical properties of MNPs simultaneously. In addition, this combination of active nanoparticles and functional organic linkers of MOFs can facilitate the charge transfer interactions with active components by coordination or π···π forces, which lead to present a significant enhancement in their catalytic performances [50, 51, 52, 53]. The composites of nanoparticles encapsulated in MOFs can be fabricated through two main strategies—(1) stabilizing pre-synthesized nanoparticles in organic or inorganic agents as core and then enclosed in the shell of MOFs which generate a core-shell structure; (2) utilizing MOFs as mesoporous templates to encapsulate nanoparticles within their cavities [50].
Despite the outstanding attributes of the composites of nanoparticles encapsulated in MOFs being able to conduct the effective catalytic activity, some restricting issues still exist that should be noticed. First of all, the pores can be blocked by the encaged nanoparticles during their growth, thus restricting the diffusion of the reaction medium in the catalytic process. Secondly, the loading of guest particles is limited to them which are smaller than the pore dimensions. Furthermore, the other specifications of guest particles like shape and morphology may not have adequate adoption with the host cavities. Moreover, it is not possible to control the deposition of guests mostly and eventually the guest nanoparticles may leach in liquid phase. To tackle these difficulties, the core-shell encapsulation strategy is offered [53].
The core of a core-shell MOFs-based composite can consist of inorganic nanoparticles like metal oxides, carbon materials, and polymers or other MOFs which are encapsulated in a MOF shell. Although the shape, size, morphology, and composition of the core have a significant effect on the catalytic performance of the catalyst, this structure provides effective encapsulation due to the integration of chemical/physical properties of two distinct materials that lead to the synergetic effects. Recently, the yolk-shell or hollow structures attracted further attention because the properties of core-shell MOF-based architecture are optimized in this type of structure that presented added conductivity, hierarchical porosity, and effective diffusion. These structures can be achieved through a controllable etching of the core materials based on core-shell structures. Although carbonizing techniques at high temperature can destroy the MOFs, by employing this approach yolk-shell or hollow structures can be generated in which their porosity and active sites have been maintained [53].
Growth of MOFs on pre-synthesized MNPs is the main approach to encapsulate MNPs in shell of MOFs which are implemented in three main strategies that are presented in follow. Although the prominent benefit of this approach is the participation of MNPs with various sizes and shapes, the control of the assembly of metal-support interface is a noticeable attribute. In addition, the principal role in fabricating an appropriate core-shell MOFs-based composite in this strategy belongs to the consistency and conformity between the MNP core and the MOF shell [2].
First of all, the pre-synthesized core materials and capping agents/surfactants like PVP which is an amphiphilic nonionic polymer, are simultaneously provided earlier the growth of MOF shell around them due to prevent the aggregation of active NPs and/or the self-nucleation of MOF particles [53]. In addition, capping agents intensify the compatibility between the MNPs and the MOF shell. While PVP is the most popular capping agent for encapsulation of inorganic materials in MOFs, depending on the design process of core materials can be utilized the other type of surfactants like cetyltrimethylammonium bromide (CTAB), tetradecyltrimethylammonium bromide (TTAB), cetylpyridinium bromide (CPB), and sodium dodecyl sulfate (SDS). The CTAB is the optimal surfactant in terms of shape/overgrowth control, as well as PVP, owing to the sizes and shapes of the final composite can be adjusted by changing the growth time and the quantity of CTAB in solution. Overall, despite CAAS being a popular method due to the ability to control the shape, size, and chemical nature of the encapsulated core, the multiple steps of this method restricted its utilization [53].
In this method, firstly, the core material is coated by employing an inorganic material like SiO2 as binding sites for shell MOF, or metal oxide as the metal source for the shell MOF growth, and then synthesis of MOF will be implemented. Although in contrast CAAS procedure applying metal oxide prepare some advantages due to their act as metal source or protection of reactive nanoparticles in the core, there are some restrictions to fabricate wrapped nanoparticles owing to the shell MOF chemical stability will be endangered through the etching of the sacrificing metal oxide. Despite the fact that SiO2 can play as a useful protective layer, it can represent as a sacrificial layer to fabricate a yolk-shell structure by conducting selective etching of SiO2. In addition, in some cases, metal oxide/metal(0) nanoparticles have also been utilized as sacrificing agents to fabricate core-shell architectures [53].
EGS is a synthetic strategy to encapsulate MOF particles as a core with the second layer of MOF. In addition, in most cases, the shell MOF topology is similar to the core MOF and active nanoparticles would be placed at the interface of the two layers prior to the epitaxial growth. Overall, this approach leads to effective integration of MOFs because synergies of various MOFs properties are simultaneously presented by an exceptional composite of MOFs @MOFs. Despite this method presenting a wide range of similarities to the CASS strategy, it can enhance the diffusion of the reaction medium toward the active sites due to the ability to fabricate a super-thin shell with a thickness size less than 10 nm [53, 54].
Not only would MOFs provide a fully available pore space to optimize the diffusion of the reaction medium, but they also support the MNPs by enclosing them in their mesoporous matrix that increases the accessibility of active sites and enhances the catalytic activity [53]. Due to MOFs can play the role of host materials and be able to provide confined spaces for nucleation of MNPs, the encapsulation of MNPs into the cavities or channels of MOF matrix can be conducted by impregnating metal precursors in the pre-synthesized MOFs and subsequent reduction of the metal precursors in the micropores of MOFs [2]. Although the precise control of this encapsulation type of MNPs in MOFs seems to be difficult, the most effective pathway can be achieved by the double-solvent procedure prior to the reduction step. As a result of this double-solvent approach, the capillary force intensifies the mass transfer of metal precursors into the micropores of MOFs, which prevents from aggregation of MNPs and minimizes the dispersion of them on the outer surface of MOF [52].
The effective route to utilize noble metals (Pd, Ru, or Pt) in the MOFs-based catalysts is in the form of alloys with low-cost transition metals (Cu, Co, or Ni) owing to decreasing the essential amount of expensive noble metals during the catalyst’s fabrication. Furthermore, the atomic and electronic specifications of their structures can be adjusted which leads to improved catalyst activity. In this approach, firstly low-cost transition MNPs are impregnated in the pre-synthesized MOFs and then are reduced by NaBH4. In the next step, the salts of noble metals were exposed into a solution of MOF in which the galvanic replacement reaction with the transition MNPs with the help of an excitement process like sonication can be started. Finally, it leads to the fabrication of alloy nanoparticles like Co-Ru which is encapsulated in MOF [2, 55].
One of the most effective approaches of ultrasmall MNPs encapsulation with meticulously composed sizes in catalysts is the encapsulation of them in organic materials, which is presented in two parts as follows [2]:
Organic capsules, such as dendrimers, which are a family of hyperbranched polymers, have a spherical structure, which is compressed on the exterior and creates hollow space in the interior. By applying organic groups, such as tertiary amines, the interior cavity can be put into particular operation, such as interception of metal ions from the solution through encapsulating them. In addition, the dendrimers can provide a monodic encapsulation of MNPs due to form mono dispersing of them with appropriate adjustment of ultrasmall sizes. Not only can dendrimers operate as effective encapsulating materials owing to the consuming amount of them being approximately the same as the metal ions amount, but also they are able to present a stable form that is unchanged for some months. Thus, these specifications convert them as useful stabilizers in the catalytic process to prepare a monotonous dispersion of nano-catalysts particles with suitable stability [2].
Polyamidoamine (PAMAM) is the most used dendrimer for encapsulating the ultrasmall MNPs. Not only can dendrimers, particularly PAMAM, provide homogeneous catalysis, but an effectual mass transfer will also happen at their exterior surface that leads to a significant improvement in the catalytic activity of the ultrasmall MNPs. To present applicable heterogeneous catalysts of encapsulated ultrasmall MNPs in dendrimers, it seems essential to utilize mesoporous supports, such as silica. Not only do they supply high surface area, but also they prepare constructive enclosures to intensify the stabilization of ultrasmall MNPs in harsh catalytic processes. When applying the silica mesoporous matrix as support, the electrostatic interaction and hydrogen bonding between silica molecules and dendrimers enforce MNPs@ dendrimers into the mesopores of the silica matrix. Not only do these supported catalysts without removing the dendrimer present highlighted stability, selectivity, and activity in a range of catalysis processes, they illustrate adjustable catalytic specifications that are possible to alter in order to enhance the catalyst activity by modifying the active groups on dendrimers, for instance, the tertiary amines can improve the activity of the catalyst due to their electron enrichment attributes. In addition, the unique spatial morphology of dendrimers in the shape of tree may have a significant impact on the reaction substrate stability, including reactant molecules or intermediate species that can lead to decrement of the level of activation energy and improve the turnover frequency [2, 19, 56]. Furthermore, click dendrimers consist of a great ratio of triazole rings, are the other type of dendrimers that can be fabricated from the azide-alkyne cyclo addition. Their rings provide an appropriate situation to accomplish the encapsulation by adsorbing metal ions and grafting the MNPs. In addition, by adding triethylene glycol (TEG) termini to the click dendrimer convert them to an effective soluble one in aqueous solutions which are suitable to fabricate the encapsulation of ultrasmall monometallic or bimetallic like Pt-Co in water solution. Thus, the yield of catalyst performance in an aqueous solution will dramatically enhance [2].
POCs with intrinsic porosity have prominent attributes, such as high surface areas, shape durability, structural adjustability, and in particular including active practical groups in their cavities that lead them to encapsulate ultrasmall MNPs in an effective way. Moreover, POCs can exhibit either in a crystalline or an amorphous structure. Furthermore, the heterogeneous catalysts that are formed by encapsulating ultrasmall nanoparticles in these POCs would be homogenized in the solutions and have a significant influence on the enhancement of the performance of catalysts. Their specifications can be modified or developed through post-synthetic modification strategies, such as polymorph selection, modular co-crystallization, and the fabrication of composite materials. Not only does the cage wrapping significantly impact porosity, during this route by employing various crystalline polymorphs distinctive physical properties can be exhibited. In addition, to fabricate a cage in the correct form, at least it is essential to provide precursors with proper and precise geometry, for instance, a mild alter in bond angles of the precursors can lead to a distinct cage that might be in size and stoichiometry [2, 57, 58].
To fabricate POGs with polyhedral organic molecules, triamine is utilized to form the top and bottom prism that include a dialdehyde with a long alkyl chain and a thioether group at the three peripheral sides. Although the long alkyl chain provides a cage profoundly soluble in an oil phase due to thriving their hydrophobic properties, the thioether group leads the cage to adsorb the metal ions and prepare suitable sites to graft the MNPs. Therefore, these specifications develop POGs capability to utilize as promising catalysts, particularly in catalyzing organic reactions [2].
A very special thanks to Mohammadreza Joharkesh, who helped to depict schemes 1, and 2.
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On September, 29th 2006 he has won a post PhD fellowship from the university of Bologna (from October 2006 to October 2008), at the competitive examination he was ranked first in the industrial engineering area. He extensively served as referee for several international journals. He is author/coauthor of more than 100 research papers. He has been involved in some projects supported by MURST and European Community. 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Delac received his B.Sc.E.E. degree in 2003 and is currentlypursuing a Ph.D. degree at the University of Zagreb, Faculty of Electrical Engineering andComputing. His current research interests are digital image analysis, pattern recognition andbiometrics.",institutionString:null,institution:{name:"University of Zagreb",country:{name:"Croatia"}}},{id:"557",title:"Dr.",name:"Andon",middleName:"Venelinov",surname:"Topalov",slug:"andon-topalov",fullName:"Andon Topalov",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/557/images/1927_n.jpg",biography:"Dr. Andon V. Topalov received the MSc degree in Control Engineering from the Faculty of Information Systems, Technologies, and Automation at Moscow State University of Civil Engineering (MGGU) in 1979. He then received his PhD degree in Control Engineering from the Department of Automation and Remote Control at Moscow State Mining University (MGSU), Moscow, in 1984. From 1985 to 1986, he was a Research Fellow in the Research Institute for Electronic Equipment, ZZU AD, Plovdiv, Bulgaria. In 1986, he joined the Department of Control Systems, Technical University of Sofia at the Plovdiv campus, where he is presently a Full Professor. He has held long-term visiting Professor/Scholar positions at various institutions in South Korea, Turkey, Mexico, Greece, Belgium, UK, and Germany. And he has coauthored one book and authored or coauthored more than 80 research papers in conference proceedings and journals. 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Developing nations are a broad term that includes countries that are less industrialised and have lower per capita income levels than developed countries. This chapter will discuss clean water for drinking water purposes. Pollution concerns of water in developing countries will be categorised in terms of physical, chemical and biological pollutants such as turbidity, organic matter and bacteria. Natural and anthropogenic pollution concerns linking with seasonal factors will be outlined. The multi-barrier approach to drinking water treatment will be discussed. Abstraction points used will be researched. Water treatment systems, medium- to small-scale approaches, will be discussed. The processes involved in removing the contaminants including physical processes such as sedimentation, filtration such as slow-sand filtration, coagulation and flocculation, and disinfectant processes such as chlorination will be reviewed. Other important methods including solar disinfection, hybrid filtration methods and arsenic removal technologies using innovative solid phase materials will be included in this chapter. Rainwater harvesting technologies are reviewed. Safe storage options for treated water are outlined. Challenges of water treatment in rural and urban areas will be outlined.",book:{id:"6682",slug:"the-relevance-of-hygiene-to-health-in-developing-countries",title:"The Relevance of Hygiene to Health in Developing Countries",fullTitle:"The Relevance of Hygiene to Health in Developing Countries"},signatures:"Josephine Treacy",authors:[{id:"238173",title:"Dr.",name:"Josephine",middleName:null,surname:"Treacy",slug:"josephine-treacy",fullName:"Josephine Treacy"}]},{id:"44219",doi:"10.5772/54973",title:"Disaster Management Discourse in Bangladesh: A Shift from Post-Event Response to the Preparedness and Mitigation Approach Through Institutional Partnerships",slug:"disaster-management-discourse-in-bangladesh-a-shift-from-post-event-response-to-the-preparedness-and",totalDownloads:4117,totalCrossrefCites:4,totalDimensionsCites:27,abstract:null,book:{id:"3054",slug:"approaches-to-disaster-management-examining-the-implications-of-hazards-emergencies-and-disasters",title:"Approaches to Disaster Management",fullTitle:"Approaches to Disaster Management - Examining the Implications of Hazards, Emergencies and Disasters"},signatures:"C. Emdad Haque and M. Salim Uddin",authors:[{id:"163390",title:"Dr.",name:"C. Emdad",middleName:null,surname:"Haque",slug:"c.-emdad-haque",fullName:"C. Emdad Haque"},{id:"168399",title:"Mr.",name:"Mohammed S",middleName:null,surname:"Uddin",slug:"mohammed-s-uddin",fullName:"Mohammed S Uddin"}]},{id:"59705",doi:"10.5772/intechopen.74943",title:"Augmented Reality Trends in Education between 2016 and 2017 Years",slug:"augmented-reality-trends-in-education-between-2016-and-2017-years",totalDownloads:2502,totalCrossrefCites:19,totalDimensionsCites:27,abstract:"The aim of this chapter is to review literature regarding using augmented reality (AR) in education articles published in between 2016 and 2017 years. The literature source was Web of Science and SSCI, SCI-EXPANDED, A&HCI, CPCI-S, CPCI-SSH, and ESCI indexes. Fifty-two articles were reviewed; however, 14 of them were not been included in the study. As a result, 38 articles were examined. Level of education, field of education, and material types of AR used in education and reported educational advantages of AR have been investigated. All articles are categorized according to target groups, which are early childhood education, primary education, secondary education, high school education, graduate education, and others. AR technology has been mostly carried out in primary and graduate education. “Science education” is the most explored field of education. Mobile applications and marker-based materials on paper have been mostly preferred. The major advantages indicated in the articles are “Learning/Academic Achievement,” “Motivation,” and “Attitude”.",book:{id:"6543",slug:"state-of-the-art-virtual-reality-and-augmented-reality-knowhow",title:"State of the Art Virtual Reality and Augmented Reality Knowhow",fullTitle:"State of the Art Virtual Reality and Augmented Reality Knowhow"},signatures:"Rabia M. Yilmaz",authors:[{id:"225838",title:"Dr.",name:"Rabia",middleName:null,surname:"Yilmaz",slug:"rabia-yilmaz",fullName:"Rabia Yilmaz"}]},{id:"45760",doi:"10.5772/56967",title:"Parenting and Culture – Evidence from Some African Communities",slug:"parenting-and-culture-evidence-from-some-african-communities",totalDownloads:9624,totalCrossrefCites:10,totalDimensionsCites:25,abstract:null,book:{id:"3440",slug:"parenting-in-south-american-and-african-contexts",title:"Parenting in South American and African Contexts",fullTitle:"Parenting in South American and African Contexts"},signatures:"Patricia Mawusi Amos",authors:[{id:"162496",title:"Mrs.",name:"Patricia",middleName:"Mawusi",surname:"Mawusi Amos",slug:"patricia-mawusi-amos",fullName:"Patricia Mawusi Amos"}]}],mostDownloadedChaptersLast30Days:[{id:"58890",title:"Philosophy and Paradigm of Scientific Research",slug:"philosophy-and-paradigm-of-scientific-research",totalDownloads:14074,totalCrossrefCites:9,totalDimensionsCites:17,abstract:"Before carrying out the empirical analysis of the role of management culture in corporate social responsibility, identification of the philosophical approach and the paradigm on which the research carried out is based is necessary. Therefore, this chapter deals with the philosophical systems and paradigms of scientific research, the epistemology, evaluating understanding and application of various theories and practices used in the scientific research. The key components of the scientific research paradigm are highlighted. Theories on the basis of which this research was focused on identification of the level of development of the management culture in order to implement corporate social responsibility are identified, and the stages of its implementation are described.",book:{id:"5791",slug:"management-culture-and-corporate-social-responsibility",title:"Management Culture and Corporate Social Responsibility",fullTitle:"Management Culture and Corporate Social Responsibility"},signatures:"Pranas Žukauskas, Jolita Vveinhardt and Regina Andriukaitienė",authors:[{id:"179629",title:"Prof.",name:"Jolita",middleName:null,surname:"Vveinhardt",slug:"jolita-vveinhardt",fullName:"Jolita Vveinhardt"}]},{id:"74550",title:"School Conflicts: Causes and Management Strategies in Classroom Relationships",slug:"school-conflicts-causes-and-management-strategies-in-classroom-relationships",totalDownloads:2328,totalCrossrefCites:1,totalDimensionsCites:10,abstract:"Conflicts cannot cease to exist, as they are intrinsic to human beings, forming an integral part of their moral and emotional growth. Likewise, they exist in all schools. The school is inserted in a space where the conflict manifests itself daily and assumes relevance, being the result of the multiple interpersonal relationships that occur in the school context. Thus, conflict is part of school life, which implies that teachers must have the skills to manage conflict constructively. Recognizing the diversity of school conflicts, this chapter aimed to present its causes, highlighting the main ones in the classroom, in the teacher-student relationship. It is important to conflict face and resolve it with skills to manage it properly and constructively, establishing cooperative relationships, and producing integrative solutions. Harmony and appreciation should coexist in a classroom environment and conflict should not interfere, negatively, in the teaching and learning process. This bibliography review underscore the need for during the teachers’ initial training the conflict management skills development.",book:{id:"7827",slug:"interpersonal-relationships",title:"Interpersonal Relationships",fullTitle:"Interpersonal Relationships"},signatures:"Sabina Valente, Abílio Afonso Lourenço and Zsolt Németh",authors:[{id:"324514",title:"Ph.D.",name:"Sabina",middleName:"N.",surname:"Valente",slug:"sabina-valente",fullName:"Sabina Valente"},{id:"326375",title:"Prof.",name:"Abílio Afonso",middleName:"Afonso",surname:"Lourenço",slug:"abilio-afonso-lourenco",fullName:"Abílio Afonso Lourenço"},{id:"329177",title:"Dr.",name:"Zsolt",middleName:null,surname:"Németh",slug:"zsolt-nemeth",fullName:"Zsolt Németh"}]},{id:"52475",title:"Teenage Pregnancies: A Worldwide Social and Medical Problem",slug:"teenage-pregnancies-a-worldwide-social-and-medical-problem",totalDownloads:8293,totalCrossrefCites:6,totalDimensionsCites:8,abstract:"Teenage pregnancies and teenage motherhood are a cause for concern worldwide. From a historical point of view, teenage pregnancies are nothing new. For much of human history, it was absolutely common that girls married during their late adolescence and experienced first birth during their second decade of life. This kind of reproductive behavior was socially desired and considered as normal. Nowadays, however, the prevention of teenage pregnancies and teenage motherhood is a priority for public health in nearly all developed and increasingly in developing countries. For a long time, teenage pregnancies were associated with severe medical problems; however, most of data supporting this viewpoint have been collected some decades ago and reflect mainly the situation of per se socially disadvantaged teenage mothers. According to more recent studies, teenage pregnancies are not per se risky ones. A clear risk group are extremely young teenage mothers (younger than 15 years) who are confronted with various medical risks, such as preeclampsia, preterm labor, and small for gestational age newborns but also marked social disadvantage, such as poverty, unemployment, low educational level, and single parenting. In the present study, the prevalence and outcome of teenage pregnancies in Austria are focused on.",book:{id:"5392",slug:"an-analysis-of-contemporary-social-welfare-issues",title:"An Analysis of Contemporary Social Welfare Issues",fullTitle:"An Analysis of Contemporary Social Welfare Issues"},signatures:"Sylvia Kirchengast",authors:[{id:"188289",title:"Prof.",name:"Sylvia",middleName:null,surname:"Kirchengast",slug:"sylvia-kirchengast",fullName:"Sylvia Kirchengast"}]},{id:"58060",title:"Pedagogy of the Twenty-First Century: Innovative Teaching Methods",slug:"pedagogy-of-the-twenty-first-century-innovative-teaching-methods",totalDownloads:8832,totalCrossrefCites:17,totalDimensionsCites:22,abstract:"In the twenty-first century, significant changes are occurring related to new scientific discoveries, informatization, globalization, the development of astronautics, robotics, and artificial intelligence. This century is called the age of digital technologies and knowledge. How is the school changing in the new century? How does learning theory change? Currently, you can hear a lot of criticism that the classroom has not changed significantly compared to the last century or even like two centuries ago. Do the teachers succeed in modern changes? The purpose of the chapter is to summarize the current changes in didactics for the use of innovative teaching methods and study the understanding of changes by teachers. In this chapter, we consider four areas: the expansion of the subject of pedagogy, environmental approach to teaching, the digital generation and the changes taking place, and innovation in teaching. The theory of education, figuratively speaking, has two levels. At the macro-level, in the “education-society” relationship, decentralization and diversification, internationalization of education, and the introduction of digital technologies occur. At the micro-level in the “teacher-learner” relationship, there is an active mix of traditional and innovative methods, combination of an activity approach with an energy-informational environment approach, cognition with constructivism and connectivism.",book:{id:"5980",slug:"new-pedagogical-challenges-in-the-21st-century-contributions-of-research-in-education",title:"New Pedagogical Challenges in the 21st Century",fullTitle:"New Pedagogical Challenges in the 21st Century - Contributions of Research in Education"},signatures:"Aigerim Mynbayeva, Zukhra Sadvakassova and Bakhytkul\nAkshalova",authors:[{id:"201997",title:"Dr.",name:"Aigerim",middleName:null,surname:"Mynbayeva",slug:"aigerim-mynbayeva",fullName:"Aigerim Mynbayeva"},{id:"209208",title:"Dr.",name:"Zukhra",middleName:null,surname:"Sadvakassova",slug:"zukhra-sadvakassova",fullName:"Zukhra Sadvakassova"},{id:"209210",title:"Dr.",name:"Bakhytkul",middleName:null,surname:"Akshalova",slug:"bakhytkul-akshalova",fullName:"Bakhytkul Akshalova"}]},{id:"58894",title:"Research Ethics",slug:"research-ethics",totalDownloads:3371,totalCrossrefCites:2,totalDimensionsCites:2,abstract:"Research ethics is closely related to the ethical principles of social responsibility. This research covers a wide context of working with people, so the researchers raised a task not only to gain confidence in the respondents’ eyes, to receive reliable data, but also to ensure the transparency of the science. This chapter discusses the theoretical and practical topics of research, after evaluation of which ethical principles of organization and conducting the research are presented. There is a detailed description of how and what ethical principles were followed on the different stages of the research.",book:{id:"5791",slug:"management-culture-and-corporate-social-responsibility",title:"Management Culture and Corporate Social Responsibility",fullTitle:"Management Culture and Corporate Social Responsibility"},signatures:"Pranas Žukauskas, Jolita Vveinhardt and Regina Andriukaitienė",authors:[{id:"179629",title:"Prof.",name:"Jolita",middleName:null,surname:"Vveinhardt",slug:"jolita-vveinhardt",fullName:"Jolita Vveinhardt"}]}],onlineFirstChaptersFilter:{topicId:"23",limit:6,offset:0},onlineFirstChaptersCollection:[{id:"83014",title:"Culture: A Pillar of Organizational Sustainability",slug:"culture-a-pillar-of-organizational-sustainability",totalDownloads:0,totalDimensionsCites:0,doi:"10.5772/intechopen.106523",abstract:"Sustainability is a concern that permeates all levels of society and is premised on meeting the needs of the present without compromising the ability of future generations to meet theirs. More recently, policies and research have emerged that guide organizations to align their activities with the broader sustainable development agendas, including cultural issues, not just economic, social, and environmental ones. Culture is the material and immaterial attribute of society. It incorporates social organizations, literature, religion, myths, beliefs, behaviors and entrepreneurial practices of the productive segment, use of technology, and expressive art forms on which future generations depend. Thus, cultural sustainability is a fundamental issue and is configured as the fourth pillar of sustainability, equal to social, economic, and environmental issues, which has to do with the ability to sustain or continue with cultural beliefs and practices, preserve cultural heritage as its entity, and try to answer whether any culture will exist in the future. The importance of cultural sustainability lies in its power to influence people. Their beliefs are in the decisions made by society. Thus, there can be no sustainable development without including culture.",book:{id:"11429",title:"Sustainability, Ecology, and Religions of the World",coverURL:"https://cdn.intechopen.com/books/images_new/11429.jpg"},signatures:"Clea Beatriz Macagnan and Rosane Maria Seibert"},{id:"82949",title:"Corruption and Deterioration of Democracy: The Brazilian Lesson",slug:"corruption-and-deterioration-of-democracy-the-brazilian-lesson",totalDownloads:1,totalDimensionsCites:0,doi:"10.5772/intechopen.106194",abstract:"Although it has emerged, nationally and internationally, as one of the largest investigations against political corruption, Operation Car Wash—at its peak of popular prestige—cleared the path for the political rise of Jair Bolsonaro to the Presidency of the Republic of Brazil. And by doing so, to a certain extent, it paved the way for a set of arbitrary practices that today threaten and weaken the main Brazilian democratic institutions. Brazilian democracy today pays a high price for the Judiciary’s lethargic and condescending response to the unorthodox and illegal practices of Federal Judge Sérgio Moro during the golden years of Operation Car Wash (2014–2018). The lesson that the Brazilian episode brings to the international legal community is that the constant disrespect for the rules of due criminal procedure in large cases of corruption erodes the institutional bases that support the proper confrontation of this type of crime. The pertinent fight against corruption in a democracy can only take place in strict obedience to the law.",book:{id:"11772",title:"Corruption - New Insights",coverURL:"https://cdn.intechopen.com/books/images_new/11772.jpg"},signatures:"Fabio Roberto D’Avila and Theodoro Balducci de Oliveira"},{id:"82903",title:"Walking Accessibility to Primary Healthcare Services: An Inequity Factor for Olders in the Lisbon Metropolitan Area (Portugal)",slug:"walking-accessibility-to-primary-healthcare-services-an-inequity-factor-for-olders-in-the-lisbon-met",totalDownloads:3,totalDimensionsCites:0,doi:"10.5772/intechopen.106265",abstract:"This chapter discusses the walking accessibility to primary healthcare by the olders in Lisbon Metropolitan Area (LMA), Portugal, and its contribution for age-friendly environments as a factor of inequity. Constrains emerged from the collation of the supply approach, represented by service catchment areas based on walking distance time, and the demand approach, through a survey. The location and density of primary health network are a major factor, as it is related to distinct land use patterns within the LMA. The settlement structure influences the potential walkability to primary healthcare. The discrepancy between the potential walking accessibility and the real options is notorious, as olders` choices are diversified in terms of transportation modes and destinations, but mostly keeping relatively short time distances. This phenomenon is also influenced by factors such as personal preference, difficulty to walk, negative perceptions about the surroundings, and insufficient care support. This debate is already an effective concern of local authorities with spatial planning, social and health competences, insofar as solutions in terms of service flexibility and new travel solutions adapted to the specific needs of the olders are a growing reality in the LMA, promoting more age-friendly, health, and inclusive environments, and hence an equitable metropolis.",book:{id:"11479",title:"Social Aspects of Ageing - Selected Challenges, Analyses, and Solutions",coverURL:"https://cdn.intechopen.com/books/images_new/11479.jpg"},signatures:"Eduarda Marques da Costa, Ana Louro, Nuno Marques da Costa, Mariana Dias and Marcela Barata"},{id:"82834",title:"Perspective Chapter: Social Work Education in University Curricula for Sustainable Development",slug:"perspective-chapter-social-work-education-in-university-curricula-for-sustainable-development",totalDownloads:4,totalDimensionsCites:0,doi:"10.5772/intechopen.106246",abstract:"Universities of both global North and South have been changing from the traditional teaching-learning centers to cater to sustainability issues of those countries. Yet, there is a remarkable difference between the universities in the developed and the developing world. It has been found out that the different disciplines of university curricula can be integrated to address and minimize the adverse effects of unsustainability issues. The graduates of the universities will be the future leaders who have to cater to the needs and cope with the challenges of the next generation. There is a dearth of professional social workers to provide the necessary services as numerous catastrophes occur. The global society needs individuals who are equally sound in the knowledge of theory and the experience of practice. As the contemporary global issues become complex, the world needs competent social workers who can serve in different fields of practice. Social work could be the pivotal discipline in understanding common tragedies of the people to apply problem-solving model with the practitioners who are equipped with twenty-first century skills. Social work has to take a transition from a unidisciplinary to a multi- and trans-disciplinary perspective in achieving this objective.",book:{id:"11095",title:"Social Work - Perspectives on Leadership and Organisation",coverURL:"https://cdn.intechopen.com/books/images_new/11095.jpg"},signatures:"Upul Lekamge"},{id:"82190",title:"Effects of the Changes of Curriculum on the Coverage of Environmental Content in Geography",slug:"effects-of-the-changes-of-curriculum-on-the-coverage-of-environmental-content-in-geography",totalDownloads:3,totalDimensionsCites:0,doi:"10.5772/intechopen.104988",abstract:"The South African education sector has experienced several shifts in the curriculum since 1994, thus affecting the coverage, teaching and examination of environmental impact topics in the South African Further Education and Training Phase (FET) phase. This chapter evaluates the effects of changes in curriculum on the coverage of education for sustainable development content in Geography. A qualitative research approach using an interpretative paradigm was employed in the documents used by Geography teachers in South Africa. The chapter used Margaret Archers, Realist Social Theory as a theoretical framework that guides data analysis and interpretation. Document analysis was the only method used where policy documents and examination papers were the instruments evaluated. The results show that environmental impact topics are covered in varying degrees in the South African CAPS curriculum. The level of coverage of environmental impact topics in the examination question papers fluctuates, sometimes to levels below those stipulated in the CAPS documents. The conclusion that can be reached is that the variable coverage of environmental impact topics in the examinations may have a negative effect on the way teachers address the topics of Geography. This resulted in an emergence of structural and cultural morphogenesis in the teaching of environmental content in Geography.",book:{id:"11429",title:"Sustainability, Ecology, and Religions of the World",coverURL:"https://cdn.intechopen.com/books/images_new/11429.jpg"},signatures:"Sikhulile Bonginkosi Msezane"},{id:"82093",title:"Perspective Chapter: Pedagogical Approaches and Access to Education Among Early Childhood Education Learners with Disabilities in Africa During the COVID-19 Pandemic - Review of Available Literature",slug:"perspective-chapter-pedagogical-approaches-and-access-to-education-among-early-childhood-education-l",totalDownloads:11,totalDimensionsCites:0,doi:"10.5772/intechopen.104921",abstract:"The COVID 19 pandemic suddenly hit the world disrupting access to education especially in Sub-Saharan Africa, threatening the future of millions of learners. This chapter discusses the effects of COVID-19 on early childhood education (ECE) for learners with disabilities in Africa, focusing on three questions: (1) What pedagogical approaches were used to enable access to education among ECE learners with disabilities during the COVID 19 pandemic? (2) How was access to education for ECE learners with disabilities, and what challenges and opportunities were experienced? (3) How can access to quality and equitable learning for ECE learners with disabilities during the crisis be improved? Literature revealed that the pandemic aggravated the hardships in accessing learning programs among learners with disabilities widening the gap between them and their counterparts. Countries resorted to remote and digital pedagogical approaches to enable continuity of learning; however, many did not cater for learners with disabilities. Where disabilities were catered for, the reach and utilization were limited by lack of resources and capacity. Concerted efforts promoting effective inclusive learning are critical for the current and future pandemics. Barriers to provision of equitable education, and long-term effects of COVID 19 on in ECE learners with disabilities should be investigated.",book:{id:"10912",title:"Psychosocial, Educational, and Economic Impacts of COVID-19",coverURL:"https://cdn.intechopen.com/books/images_new/10912.jpg"},signatures:"Margaret Nampijja, Lillian Ayiro and Ruth Nalugya"}],onlineFirstChaptersTotal:144},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:90,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:107,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:33,numberOfPublishedChapters:330,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:14,numberOfPublishedChapters:145,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:9,numberOfPublishedChapters:139,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:122,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:112,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:21,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:10,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:"2753-6580",doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}},{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}}]},series:{item:{id:"14",title:"Artificial Intelligence",doi:"10.5772/intechopen.79920",issn:"2633-1403",scope:"Artificial Intelligence (AI) is a rapidly developing multidisciplinary research area that aims to solve increasingly complex problems. In today's highly integrated world, AI promises to become a robust and powerful means for obtaining solutions to previously unsolvable problems. This Series is intended for researchers and students alike interested in this fascinating field and its many applications.",coverUrl:"https://cdn.intechopen.com/series/covers/14.jpg",latestPublicationDate:"July 5th, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:9,editor:{id:"218714",title:"Prof.",name:"Andries",middleName:null,surname:"Engelbrecht",slug:"andries-engelbrecht",fullName:"Andries Engelbrecht",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRNR8QAO/Profile_Picture_1622640468300",biography:"Andries Engelbrecht received the Masters and PhD degrees in Computer Science from the University of Stellenbosch, South Africa, in 1994 and 1999 respectively. He is currently appointed as the Voigt Chair in Data Science in the Department of Industrial Engineering, with a joint appointment as Professor in the Computer Science Division, Stellenbosch University. Prior to his appointment at Stellenbosch University, he has been at the University of Pretoria, Department of Computer Science (1998-2018), where he was appointed as South Africa Research Chair in Artifical Intelligence (2007-2018), the head of the Department of Computer Science (2008-2017), and Director of the Institute for Big Data and Data Science (2017-2018). In addition to a number of research articles, he has written two books, Computational Intelligence: An Introduction and Fundamentals of Computational Swarm Intelligence.",institutionString:null,institution:{name:"Stellenbosch University",institutionURL:null,country:{name:"South Africa"}}},editorTwo:null,editorThree:null},subseries:{paginationCount:6,paginationItems:[{id:"22",title:"Applied Intelligence",coverUrl:"https://cdn.intechopen.com/series_topics/covers/22.jpg",isOpenForSubmission:!0,editor:{id:"27170",title:"Prof.",name:"Carlos",middleName:"M.",surname:"Travieso-Gonzalez",slug:"carlos-travieso-gonzalez",fullName:"Carlos Travieso-Gonzalez",profilePictureURL:"https://mts.intechopen.com/storage/users/27170/images/system/27170.jpeg",biography:"Carlos M. Travieso-González received his MSc degree in Telecommunication Engineering at Polytechnic University of Catalonia (UPC), Spain in 1997, and his Ph.D. degree in 2002 at the University of Las Palmas de Gran Canaria (ULPGC-Spain). He is a full professor of signal processing and pattern recognition and is head of the Signals and Communications Department at ULPGC, teaching from 2001 on subjects on signal processing and learning theory. His research lines are biometrics, biomedical signals and images, data mining, classification system, signal and image processing, machine learning, and environmental intelligence. He has researched in 52 international and Spanish research projects, some of them as head researcher. He is co-author of 4 books, co-editor of 27 proceedings books, guest editor for 8 JCR-ISI international journals, and up to 24 book chapters. He has over 450 papers published in international journals and conferences (81 of them indexed on JCR – ISI - Web of Science). He has published seven patents in the Spanish Patent and Trademark Office. He has been a supervisor on 8 Ph.D. theses (11 more are under supervision), and 130 master theses. He is the founder of The IEEE IWOBI conference series and the president of its Steering Committee, as well as the founder of both the InnoEducaTIC and APPIS conference series. He is an evaluator of project proposals for the European Union (H2020), Medical Research Council (MRC, UK), Spanish Government (ANECA, Spain), Research National Agency (ANR, France), DAAD (Germany), Argentinian Government, and the Colombian Institutions. He has been a reviewer in different indexed international journals (<70) and conferences (<250) since 2001. He has been a member of the IASTED Technical Committee on Image Processing from 2007 and a member of the IASTED Technical Committee on Artificial Intelligence and Expert Systems from 2011. \n\nHe has held the general chair position for the following: ACM-APPIS (2020, 2021), IEEE-IWOBI (2019, 2020 and 2020), A PPIS (2018, 2019), IEEE-IWOBI (2014, 2015, 2017, 2018), InnoEducaTIC (2014, 2017), IEEE-INES (2013), NoLISP (2011), JRBP (2012), and IEEE-ICCST (2005)\n\nHe is an associate editor of the Computational Intelligence and Neuroscience Journal (Hindawi – Q2 JCR-ISI). He was vice dean from 2004 to 2010 in the Higher Technical School of Telecommunication Engineers at ULPGC and the vice dean of Graduate and Postgraduate Studies from March 2013 to November 2017. He won the “Catedra Telefonica” Awards in Modality of Knowledge Transfer, 2017, 2018, and 2019 editions, and awards in Modality of COVID Research in 2020.\n\nPublic References:\nResearcher ID http://www.researcherid.com/rid/N-5967-2014\nORCID https://orcid.org/0000-0002-4621-2768 \nScopus Author ID https://www.scopus.com/authid/detail.uri?authorId=6602376272\nScholar Google https://scholar.google.es/citations?user=G1ks9nIAAAAJ&hl=en \nResearchGate https://www.researchgate.net/profile/Carlos_Travieso",institutionString:null,institution:{name:"University of Las Palmas de Gran Canaria",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null},{id:"23",title:"Computational Neuroscience",coverUrl:"https://cdn.intechopen.com/series_topics/covers/23.jpg",isOpenForSubmission:!0,editor:{id:"14004",title:"Dr.",name:"Magnus",middleName:null,surname:"Johnsson",slug:"magnus-johnsson",fullName:"Magnus Johnsson",profilePictureURL:"https://mts.intechopen.com/storage/users/14004/images/system/14004.png",biography:"Dr Magnus Johnsson is a cross-disciplinary scientist, lecturer, scientific editor and AI/machine learning consultant from Sweden. \n\nHe is currently at Malmö University in Sweden, but also held positions at Lund University in Sweden and at Moscow Engineering Physics Institute. \nHe holds editorial positions at several international scientific journals and has served as a scientific editor for books and special journal issues. \nHis research interests are wide and include, but are not limited to, autonomous systems, computer modeling, artificial neural networks, artificial intelligence, cognitive neuroscience, cognitive robotics, cognitive architectures, cognitive aids and the philosophy of mind. \n\nDr. Johnsson has experience from working in the industry and he has a keen interest in the application of neural networks and artificial intelligence to fields like industry, finance, and medicine. \n\nWeb page: www.magnusjohnsson.se",institutionString:null,institution:{name:"Malmö University",institutionURL:null,country:{name:"Sweden"}}},editorTwo:null,editorThree:null},{id:"24",title:"Computer Vision",coverUrl:"https://cdn.intechopen.com/series_topics/covers/24.jpg",isOpenForSubmission:!0,editor:{id:"294154",title:"Prof.",name:"George",middleName:null,surname:"Papakostas",slug:"george-papakostas",fullName:"George Papakostas",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002hYaGbQAK/Profile_Picture_1624519712088",biography:"George A. Papakostas has received a diploma in Electrical and Computer Engineering in 1999 and the M.Sc. and Ph.D. degrees in Electrical and Computer Engineering in 2002 and 2007, respectively, from the Democritus University of Thrace (DUTH), Greece. Dr. Papakostas serves as a Tenured Full Professor at the Department of Computer Science, International Hellenic University, Greece. Dr. Papakostas has 10 years of experience in large-scale systems design as a senior software engineer and technical manager, and 20 years of research experience in the field of Artificial Intelligence. Currently, he is the Head of the “Visual Computing” division of HUman-MAchines INteraction Laboratory (HUMAIN-Lab) and the Director of the MPhil program “Advanced Technologies in Informatics and Computers” hosted by the Department of Computer Science, International Hellenic University. He has (co)authored more than 150 publications in indexed journals, international conferences and book chapters, 1 book (in Greek), 3 edited books, and 5 journal special issues. His publications have more than 2100 citations with h-index 27 (GoogleScholar). His research interests include computer/machine vision, machine learning, pattern recognition, computational intelligence. \nDr. Papakostas served as a reviewer in numerous journals, as a program\ncommittee member in international conferences and he is a member of the IAENG, MIR Labs, EUCogIII, INSTICC and the Technical Chamber of Greece (TEE).",institutionString:null,institution:{name:"International Hellenic University",institutionURL:null,country:{name:"Greece"}}},editorTwo:null,editorThree:null},{id:"25",title:"Evolutionary Computation",coverUrl:"https://cdn.intechopen.com/series_topics/covers/25.jpg",isOpenForSubmission:!0,editor:{id:"136112",title:"Dr.",name:"Sebastian",middleName:null,surname:"Ventura Soto",slug:"sebastian-ventura-soto",fullName:"Sebastian Ventura Soto",profilePictureURL:"https://mts.intechopen.com/storage/users/136112/images/system/136112.png",biography:"Sebastian Ventura is a Spanish researcher, a full professor with the Department of Computer Science and Numerical Analysis, University of Córdoba. Dr Ventura also holds the positions of Affiliated Professor at Virginia Commonwealth University (Richmond, USA) and Distinguished Adjunct Professor at King Abdulaziz University (Jeddah, Saudi Arabia). Additionally, he is deputy director of the Andalusian Research Institute in Data Science and Computational Intelligence (DaSCI) and heads the Knowledge Discovery and Intelligent Systems Research Laboratory. He has published more than ten books and over 300 articles in journals and scientific conferences. Currently, his work has received over 18,000 citations according to Google Scholar, including more than 2200 citations in 2020. In the last five years, he has published more than 60 papers in international journals indexed in the JCR (around 70% of them belonging to first quartile journals) and he has edited some Springer books “Supervised Descriptive Pattern Mining” (2018), “Multiple Instance Learning - Foundations and Algorithms” (2016), and “Pattern Mining with Evolutionary Algorithms” (2016). He has also been involved in more than 20 research projects supported by the Spanish and Andalusian governments and the European Union. He currently belongs to the editorial board of PeerJ Computer Science, Information Fusion and Engineering Applications of Artificial Intelligence journals, being also associate editor of Applied Computational Intelligence and Soft Computing and IEEE Transactions on Cybernetics. Finally, he is editor-in-chief of Progress in Artificial Intelligence. He is a Senior Member of the IEEE Computer, the IEEE Computational Intelligence, and the IEEE Systems, Man, and Cybernetics Societies, and the Association of Computing Machinery (ACM). Finally, his main research interests include data science, computational intelligence, and their applications.",institutionString:null,institution:{name:"University of Córdoba",institutionURL:null,country:{name:"Spain"}}},editorTwo:null,editorThree:null},{id:"26",title:"Machine Learning and Data Mining",coverUrl:"https://cdn.intechopen.com/series_topics/covers/26.jpg",isOpenForSubmission:!0,editor:{id:"24555",title:"Dr.",name:"Marco Antonio",middleName:null,surname:"Aceves Fernandez",slug:"marco-antonio-aceves-fernandez",fullName:"Marco Antonio Aceves Fernandez",profilePictureURL:"https://mts.intechopen.com/storage/users/24555/images/system/24555.jpg",biography:"Dr. Marco Antonio Aceves Fernandez obtained his B.Sc. (Eng.) in Telematics from the Universidad de Colima, Mexico. 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He previously worked as a post-doctoral fellow at the Ben-Gurion University of Negev, Israel; University of the Free State, South Africa; and Central University of Technology Bloemfontein, South Africa. He obtained his Ph.D. in Organic Chemistry from Nagaoka University of Technology, Japan. He has published more than seventy-four journal articles and attended several national and international conferences as speaker and chair. Dr. Kendrekar has received many international awards. He has several funded projects, namely, anti-malaria drug development, MRSA, and SARS-CoV-2 activity of curcumin and its formulations. He has filed four patents in collaboration with the University of Central Lancashire and Mayo Clinic Infectious Diseases. His present research includes organic synthesis, drug discovery and development, biochemistry, nanoscience, and nanotechnology.",institutionString:"Visiting Scientist at Lipid Nanostructures Laboratory, Centre for Smart Materials, School of Natural Sciences, University of Central Lancashire",institution:null},{id:"428125",title:"Dr.",name:"Vinayak",middleName:null,surname:"Adimule",slug:"vinayak-adimule",fullName:"Vinayak Adimule",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/428125/images/system/428125.jpg",biography:"Dr. Vinayak Adimule, MSc, Ph.D., is a professor and dean of R&D, Angadi Institute of Technology and Management, India. He has 15 years of research experience as a senior research scientist and associate research scientist in R&D organizations. He has published more than fifty research articles as well as several book chapters. He has two Indian patents and two international patents to his credit. Dr. Adimule has attended, chaired, and presented papers at national and international conferences. He is a guest editor for Topics in Catalysis and other journals. He is also an editorial board member, life member, and associate member for many international societies and research institutions. His research interests include nanoelectronics, material chemistry, artificial intelligence, sensors and actuators, bio-nanomaterials, and medicinal chemistry.",institutionString:"Angadi Institute of Technology and Management",institution:null},{id:"284317",title:"Prof.",name:"Kantharaju",middleName:null,surname:"Kamanna",slug:"kantharaju-kamanna",fullName:"Kantharaju Kamanna",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/284317/images/21050_n.jpg",biography:"Prof. K. Kantharaju has received Bachelor of science (PCM), master of science (Organic Chemistry) and Doctor of Philosophy in Chemistry from Bangalore University. He worked as a Executive Research & Development @ Cadila Pharmaceuticals Ltd, Ahmedabad. He received DBT-postdoc fellow @ Molecular Biophysics Unit, Indian Institute of Science, Bangalore under the supervision of Prof. P. Balaram, later he moved to NIH-postdoc researcher at Drexel University College of Medicine, Philadelphia, USA, after his return from postdoc joined NITK-Surthakal as a Adhoc faculty at department of chemistry. Since from August 2013 working as a Associate Professor, and in 2016 promoted to Profeesor in the School of Basic Sciences: Department of Chemistry and having 20 years of teaching and research experiences.",institutionString:null,institution:{name:"Rani Channamma University, Belagavi",country:{name:"India"}}},{id:"158492",title:"Prof.",name:"Yusuf",middleName:null,surname:"Tutar",slug:"yusuf-tutar",fullName:"Yusuf Tutar",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/158492/images/system/158492.jpeg",biography:"Prof. Dr. Yusuf Tutar conducts his research at the Hamidiye Faculty of Pharmacy, Department of Basic Pharmaceutical Sciences, Division of Biochemistry, University of Health Sciences, Turkey. He is also a faculty member in the Molecular Oncology Program. He obtained his MSc and Ph.D. at Oregon State University and Texas Tech University, respectively. He pursued his postdoctoral studies at Rutgers University Medical School and the National Institutes of Health (NIH/NIDDK), USA. His research focuses on biochemistry, biophysics, genetics, molecular biology, and molecular medicine with specialization in the fields of drug design, protein structure-function, protein folding, prions, microRNA, pseudogenes, molecular cancer, epigenetics, metabolites, proteomics, genomics, protein expression, and characterization by spectroscopic and calorimetric methods.",institutionString:"University of Health Sciences",institution:null},{id:"180528",title:"Dr.",name:"Hiroyuki",middleName:null,surname:"Kagechika",slug:"hiroyuki-kagechika",fullName:"Hiroyuki Kagechika",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/180528/images/system/180528.jpg",biography:"Hiroyuki Kagechika received his bachelor’s degree and Ph.D. in Pharmaceutical Sciences from the University of Tokyo, Japan, where he served as an associate professor until 2004. He is currently a professor at the Institute of Biomaterials and Bioengineering (IBB), Tokyo Medical and Dental University (TMDU). From 2010 to 2012, he was the dean of the Graduate School of Biomedical Science. Since 2012, he has served as the vice dean of the Graduate School of Medical and Dental Sciences. He has been the director of the IBB since 2020. Dr. Kagechika’s major research interests are the medicinal chemistry of retinoids, vitamins D/K, and nuclear receptors. He has developed various compounds including a drug for acute promyelocytic leukemia.",institutionString:"Tokyo Medical and Dental University",institution:{name:"Tokyo Medical and Dental University",country:{name:"Japan"}}},{id:"94311",title:"Prof.",name:"Martins",middleName:"Ochubiojo",surname:"Ochubiojo Emeje",slug:"martins-ochubiojo-emeje",fullName:"Martins Ochubiojo Emeje",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/94311/images/system/94311.jpeg",biography:"Martins Emeje obtained a BPharm with distinction from Ahmadu Bello University, Nigeria, and an MPharm and Ph.D. from the University of Nigeria (UNN), where he received the best Ph.D. award and was enlisted as UNN’s “Face of Research.” He established the first nanomedicine center in Nigeria and was the pioneer head of the intellectual property and technology transfer as well as the technology innovation and support center. Prof. Emeje’s several international fellowships include the prestigious Raman fellowship. He has published more than 150 articles and patents. He is also the head of R&D at NIPRD and holds a visiting professor position at Nnamdi Azikiwe University, Nigeria. He has a postgraduate certificate in Project Management from Walden University, Minnesota, as well as a professional teaching certificate and a World Bank certification in Public Procurement. Prof. Emeje was a national chairman of academic pharmacists in Nigeria and the 2021 winner of the May & Baker Nigeria Plc–sponsored prize for professional service in research and innovation.",institutionString:"National Institute for Pharmaceutical Research and Development",institution:{name:"National Institute for Pharmaceutical Research and Development",country:{name:"Nigeria"}}},{id:"436430",title:"Associate Prof.",name:"Mesut",middleName:null,surname:"Işık",slug:"mesut-isik",fullName:"Mesut Işık",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/436430/images/19686_n.jpg",biography:null,institutionString:null,institution:{name:"Bilecik University",country:{name:"Turkey"}}},{id:"268659",title:"Ms.",name:"Xianquan",middleName:null,surname:"Zhan",slug:"xianquan-zhan",fullName:"Xianquan Zhan",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/268659/images/8143_n.jpg",biography:"Dr. Zhan received his undergraduate and graduate training in the fields of preventive medicine and epidemiology and statistics at the West China University of Medical Sciences in China during 1989 to 1999. He received his post-doctoral training in oncology and cancer proteomics for two years at the Cancer Research Institute of Human Medical University in China. In 2001, he went to the University of Tennessee Health Science Center (UTHSC) in USA, where he was a post-doctoral researcher and focused on mass spectrometry and cancer proteomics. Then, he was appointed as an Assistant Professor of Neurology, UTHSC in 2005. He moved to the Cleveland Clinic in USA as a Project Scientist/Staff in 2006 where he focused on the studies of eye disease proteomics and biomarkers. He returned to UTHSC as an Assistant Professor of Neurology in the end of 2007, engaging in proteomics and biomarker studies of lung diseases and brain tumors, and initiating the studies of predictive, preventive, and personalized medicine (PPPM) in cancer. In 2010, he was promoted to Associate Professor of Neurology, UTHSC. Currently, he is a Professor at Xiangya Hospital of Central South University in China, Fellow of Royal Society of Medicine (FRSM), the European EPMA National Representative in China, Regular Member of American Association for the Advancement of Science (AAAS), European Cooperation of Science and Technology (e-COST) grant evaluator, Associate Editors of BMC Genomics, BMC Medical Genomics, EPMA Journal, and Frontiers in Endocrinology, Executive Editor-in-Chief of Med One. He has\npublished 116 peer-reviewed research articles, 16 book chapters, 2 books, and 2 US patents. His current main research interest focuses on the studies of cancer proteomics and biomarkers, and the use of modern omics techniques and systems biology for PPPM in cancer, and on the development and use of 2DE-LC/MS for the large-scale study of human proteoforms.",institutionString:null,institution:{name:"Xiangya Hospital Central South University",country:{name:"China"}}},{id:"40482",title:null,name:"Rizwan",middleName:null,surname:"Ahmad",slug:"rizwan-ahmad",fullName:"Rizwan Ahmad",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/40482/images/system/40482.jpeg",biography:"Dr. Rizwan Ahmad is a University Professor and Coordinator, Quality and Development, College of Medicine, Imam Abdulrahman bin Faisal University, Saudi Arabia. Previously, he was Associate Professor of Human Function, Oman Medical College, Oman, and SBS University, Dehradun. Dr. Ahmad completed his education at Aligarh Muslim University, Aligarh. He has published several articles in peer-reviewed journals, chapters, and edited books. His area of specialization is free radical biochemistry and autoimmune diseases.",institutionString:"Imam Abdulrahman Bin Faisal University",institution:{name:"Imam Abdulrahman Bin Faisal University",country:{name:"Saudi Arabia"}}},{id:"41865",title:"Prof.",name:"Farid A.",middleName:null,surname:"Badria",slug:"farid-a.-badria",fullName:"Farid A. Badria",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/41865/images/system/41865.jpg",biography:"Farid A. Badria, Ph.D., is the recipient of several awards, including The World Academy of Sciences (TWAS) Prize for Public Understanding of Science; the World Intellectual Property Organization (WIPO) Gold Medal for best invention; Outstanding Arab Scholar, Kuwait; and the Khwarizmi International Award, Iran. He has 250 publications, 12 books, 20 patents, and several marketed pharmaceutical products to his credit. He continues to lead research projects on developing new therapies for liver, skin disorders, and cancer. Dr. Badria was listed among the world’s top 2% of scientists in medicinal and biomolecular chemistry in 2019 and 2020. He is a member of the Arab Development Fund, Kuwait; International Cell Research Organization–United Nations Educational, Scientific and Cultural Organization (ICRO–UNESCO), Chile; and UNESCO Biotechnology France",institutionString:"Mansoura University",institution:{name:"Mansoura University",country:{name:"Egypt"}}},{id:"329385",title:"Dr.",name:"Rajesh K.",middleName:"Kumar",surname:"Singh",slug:"rajesh-k.-singh",fullName:"Rajesh K. Singh",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/329385/images/system/329385.png",biography:"Dr. Singh received a BPharm (2003) and MPharm (2005) from Panjab University, Chandigarh, India, and a Ph.D. (2013) from Punjab Technical University (PTU), Jalandhar, India. He has more than sixteen years of teaching experience and has supervised numerous postgraduate and Ph.D. students. He has to his credit more than seventy papers in SCI- and SCOPUS-indexed journals, fifty-five conference proceedings, four books, six Best Paper Awards, and five projects from different government agencies. He is currently an editorial board member of eight international journals and a reviewer for more than fifty scientific journals. He received Top Reviewer and Excellent Peer Reviewer Awards from Publons in 2016 and 2017, respectively. He is also on the panel of The International Reviewer for reviewing research proposals for grants from the Royal Society. He also serves as a Publons Academy mentor and Bentham brand ambassador.",institutionString:"Punjab Technical University",institution:{name:"Punjab Technical University",country:{name:"India"}}},{id:"142388",title:"Dr.",name:"Thiago",middleName:"Gomes",surname:"Gomes Heck",slug:"thiago-gomes-heck",fullName:"Thiago Gomes Heck",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/142388/images/7259_n.jpg",biography:null,institutionString:null,institution:{name:"Universidade Regional do Noroeste do Estado do Rio Grande do Sul",country:{name:"Brazil"}}},{id:"336273",title:"Assistant Prof.",name:"Janja",middleName:null,surname:"Zupan",slug:"janja-zupan",fullName:"Janja Zupan",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/336273/images/14853_n.jpeg",biography:"Janja Zupan graduated in 2005 at the Department of Clinical Biochemistry (superviser prof. dr. Janja Marc) in the field of genetics of osteoporosis. Since November 2009 she is working as a Teaching Assistant at the Faculty of Pharmacy, Department of Clinical Biochemistry. In 2011 she completed part of her research and PhD work at Institute of Genetics and Molecular Medicine, University of Edinburgh. She finished her PhD entitled The influence of the proinflammatory cytokines on the RANK/RANKL/OPG in bone tissue of osteoporotic and osteoarthritic patients in 2012. From 2014-2016 she worked at the Institute of Biomedical Sciences, University of Aberdeen as a postdoctoral research fellow on UK Arthritis research project where she gained knowledge in mesenchymal stem cells and regenerative medicine. She returned back to University of Ljubljana, Faculty of Pharmacy in 2016. She is currently leading project entitled Mesenchymal stem cells-the keepers of tissue endogenous regenerative capacity facing up to aging of the musculoskeletal system funded by Slovenian Research Agency.",institutionString:null,institution:{name:"University of Ljubljana",country:{name:"Slovenia"}}},{id:"357453",title:"Dr.",name:"Radheshyam",middleName:null,surname:"Maurya",slug:"radheshyam-maurya",fullName:"Radheshyam Maurya",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/357453/images/16535_n.jpg",biography:null,institutionString:null,institution:{name:"University of Hyderabad",country:{name:"India"}}},{id:"418340",title:"Dr.",name:"Jyotirmoi",middleName:null,surname:"Aich",slug:"jyotirmoi-aich",fullName:"Jyotirmoi Aich",position:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000038Ugi5QAC/Profile_Picture_2022-04-15T07:48:28.png",biography:"Biotechnologist with 15 years of research including 6 years of teaching experience. Demonstrated record of scientific achievements through consistent publication record (H index = 13, with 874 citations) in high impact journals such as Nature Communications, Oncotarget, Annals of Oncology, PNAS, and AJRCCM, etc. Strong research professional with a post-doctorate from ACTREC where I gained experimental oncology experience in clinical settings and a doctorate from IGIB where I gained expertise in asthma pathophysiology. A well-trained biotechnologist with diverse experience on the bench across different research themes ranging from asthma to cancer and other infectious diseases. An individual with a strong commitment and innovative mindset. Have the ability to work on diverse projects such as regenerative and molecular medicine with an overall mindset of improving healthcare.",institutionString:"DY Patil Deemed to Be University",institution:null},{id:"349288",title:"Prof.",name:"Soumya",middleName:null,surname:"Basu",slug:"soumya-basu",fullName:"Soumya Basu",position:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000035QxIDQA0/Profile_Picture_2022-04-15T07:47:01.jpg",biography:"Soumya Basu, Ph.D., is currently working as an Associate Professor at Dr. D. Y. Patil Biotechnology and Bioinformatics Institute, Dr. D. Y. Patil Vidyapeeth, Pune, Maharashtra, India. With 16+ years of trans-disciplinary research experience in Drug Design, development, and pre-clinical validation; 20+ research article publications in journals of repute, 9+ years of teaching experience, trained with cross-disciplinary education, Dr. Basu is a life-long learner and always thrives for new challenges.\r\nHer research area is the design and synthesis of small molecule partial agonists of PPAR-γ in lung cancer. She is also using artificial intelligence and deep learning methods to understand the exosomal miRNA’s role in cancer metastasis. Dr. Basu is the recipient of many awards including the Early Career Research Award from the Department of Science and Technology, Govt. of India. She is a reviewer of many journals like Molecular Biology Reports, Frontiers in Oncology, RSC Advances, PLOS ONE, Journal of Biomolecular Structure & Dynamics, Journal of Molecular Graphics and Modelling, etc. She has edited and authored/co-authored 21 journal papers, 3 book chapters, and 15 abstracts. She is a Board of Studies member at her university. She is a life member of 'The Cytometry Society”-in India and 'All India Cell Biology Society”- in India.",institutionString:"Dr. D.Y. Patil Vidyapeeth, Pune",institution:{name:"Dr. D.Y. Patil Vidyapeeth, Pune",country:{name:"India"}}},{id:"354817",title:"Dr.",name:"Anubhab",middleName:null,surname:"Mukherjee",slug:"anubhab-mukherjee",fullName:"Anubhab Mukherjee",position:null,profilePictureURL:"https://intech-files.s3.amazonaws.com/0033Y0000365PbRQAU/ProfilePicture%202022-04-15%2005%3A11%3A18.480",biography:"A former member of Laboratory of Nanomedicine, Brigham and Women’s Hospital, Harvard University, Boston, USA, Dr. Anubhab Mukherjee is an ardent votary of science who strives to make an impact in the lives of those afflicted with cancer and other chronic/acute ailments. He completed his Ph.D. from CSIR-Indian Institute of Chemical Technology, Hyderabad, India, having been skilled with RNAi, liposomal drug delivery, preclinical cell and animal studies. He pursued post-doctoral research at College of Pharmacy, Health Science Center, Texas A & M University and was involved in another postdoctoral research at Department of Translational Neurosciences and Neurotherapeutics, John Wayne Cancer Institute, Santa Monica, California. In 2015, he worked in Harvard-MIT Health Sciences & Technology as a visiting scientist. He has substantial experience in nanotechnology-based formulation development and successfully served various Indian organizations to develop pharmaceuticals and nutraceutical products. He is an inventor in many US patents and an author in many peer-reviewed articles, book chapters and books published in various media of international repute. Dr. Mukherjee is currently serving as Principal Scientist, R&D at Esperer Onco Nutrition (EON) Pvt. Ltd. and heads the Hyderabad R&D center of the organization.",institutionString:"Esperer Onco Nutrition Pvt Ltd.",institution:null},{id:"319365",title:"Assistant Prof.",name:"Manash K.",middleName:null,surname:"Paul",slug:"manash-k.-paul",fullName:"Manash K. Paul",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/319365/images/system/319365.png",biography:"Manash K. Paul is a Principal Investigator and Scientist at the University of California Los Angeles. He has contributed significantly to the fields of stem cell biology, regenerative medicine, and lung cancer. His research focuses on various signaling processes involved in maintaining stem cell homeostasis during the injury-repair process, deciphering lung stem cell niche, pulmonary disease modeling, immuno-oncology, and drug discovery. He is currently investigating the role of extracellular vesicles in premalignant lung cell migration and detecting the metastatic phenotype of lung cancer via machine-learning-based analyses of exosomal signatures. Dr. Paul has published in more than fifty peer-reviewed international journals and is highly cited. He is the recipient of many awards, including the UCLA Vice Chancellor’s award, a senior member of the Institute of Electrical and Electronics Engineers (IEEE), and an editorial board member for several international journals.",institutionString:"University of California Los Angeles",institution:{name:"University of California Los Angeles",country:{name:"United States of America"}}},{id:"311457",title:"Dr.",name:"Júlia",middleName:null,surname:"Scherer Santos",slug:"julia-scherer-santos",fullName:"Júlia Scherer Santos",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/311457/images/system/311457.jpg",biography:"Dr. Júlia Scherer Santos works in the areas of cosmetology, nanotechnology, pharmaceutical technology, beauty, and aesthetics. Dr. Santos also has experience as a professor of graduate courses. Graduated in Pharmacy, specialization in Cosmetology and Cosmeceuticals applied to aesthetics, specialization in Aesthetic and Cosmetic Health, and a doctorate in Pharmaceutical Nanotechnology. Teaching experience in Pharmacy and Aesthetics and Cosmetics courses. She works mainly on the following subjects: nanotechnology, cosmetology, pharmaceutical technology, aesthetics.",institutionString:"Universidade Federal de Juiz de Fora",institution:{name:"Universidade Federal de Juiz de Fora",country:{name:"Brazil"}}},{id:"219081",title:"Dr.",name:"Abdulsamed",middleName:null,surname:"Kükürt",slug:"abdulsamed-kukurt",fullName:"Abdulsamed Kükürt",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/219081/images/system/219081.png",biography:"Dr. Kükürt graduated from Uludağ University in Turkey. He started his academic career as a Research Assistant in the Department of Biochemistry at Kafkas University. In 2019, he completed his Ph.D. program in the Department of Biochemistry at the Institute of Health Sciences. He is currently working at the Department of Biochemistry, Kafkas University. He has 27 published research articles in academic journals, 11 book chapters, and 37 papers. He took part in 10 academic projects. He served as a reviewer for many articles. He still serves as a member of the review board in many academic journals. He is currently working on the protective activity of phenolic compounds in disorders associated with oxidative stress and inflammation.",institutionString:null,institution:{name:"Kafkas University",country:{name:"Turkey"}}},{id:"178366",title:"Dr.",name:"Volkan",middleName:null,surname:"Gelen",slug:"volkan-gelen",fullName:"Volkan Gelen",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/178366/images/system/178366.jpg",biography:"Volkan Gelen is a Physiology specialist who received his veterinary degree from Kafkas University in 2011. Between 2011-2015, he worked as an assistant at Atatürk University, Faculty of Veterinary Medicine, Department of Physiology. In 2016, he joined Kafkas University, Faculty of Veterinary Medicine, Department of Physiology as an assistant professor. Dr. Gelen has been engaged in various academic activities at Kafkas University since 2016. There he completed 5 projects and has 3 ongoing projects. He has 60 articles published in scientific journals and 20 poster presentations in scientific congresses. His research interests include physiology, endocrine system, cancer, diabetes, cardiovascular system diseases, and isolated organ bath system studies.",institutionString:"Kafkas University",institution:{name:"Kafkas University",country:{name:"Turkey"}}},{id:"418963",title:"Dr.",name:"Augustine Ododo",middleName:"Augustine",surname:"Osagie",slug:"augustine-ododo-osagie",fullName:"Augustine Ododo Osagie",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/418963/images/16900_n.jpg",biography:"Born into the family of Osagie, a prince of the Benin Kingdom. I am currently an academic in the Department of Medical Biochemistry, University of Benin. 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She is a fellow member of the Royal Society of Chemistry UK and the American Chemical Society of the United States.",institutionString:"King Saud University",institution:{name:"King Saud University",country:{name:"Saudi Arabia"}}},{id:"49848",title:"Dr.",name:"Wen-Long",middleName:null,surname:"Hu",slug:"wen-long-hu",fullName:"Wen-Long Hu",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/49848/images/system/49848.jpg",biography:"Wen-Long Hu is Chief of the Division of Acupuncture, Department of Chinese Medicine at Kaohsiung Chang Gung Memorial Hospital, as well as an adjunct associate professor at Fooyin University and Kaohsiung Medical University. Wen-Long is President of Taiwan Traditional Chinese Medicine Medical Association. He has 28 years of experience in clinical practice in laser acupuncture therapy and 34 years in acupuncture. He is an invited speaker for lectures and workshops in laser acupuncture at many symposiums held by medical associations. 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