Open access peer-reviewed chapter

Essential Oils

By Lubna Abdul Muttalib Al-Shalah, Nada Khazal Kadhim Hindi and Israa Harjan Mohsen

Submitted: October 22nd 2019Reviewed: March 21st 2020Published: September 9th 2020

DOI: 10.5772/intechopen.92216

Downloaded: 386

Abstract

Modern science has tended to use several natural substances that have little or no side effects in daily use or to treat many diseases. Among these materials are essential oils that represent one of the secondary metabolic products of many plants such as Terpenes and Terpenoids, Alkaloids, and the Phenolic compounds, which are extracted by special methods from different parts of the plants. Several applications were using the essential oils such as in the nutrition, cosmetic manufacture, and alternatives to synthetic medication that uses to treatment several infections and diseases as disinfection, as an anti-inflammatory, mouthwashes, as well as in cleaning and calm mood and pesticides. This review describes essential oils, methods of their extraction, and ways of utilization and their application.

Keywords

  • essential oils
  • extraction
  • health benefit
  • antibacterial activity

1. Introduction

Plants produce thousands types of chemicals materials and included two types of metabolites (primary and secondary). Primary metabolites are macromolecules like carbohydrates, fats, proteins, nucleic acids, chlorophylls, hemes this molecular are required for their basic metabolic processes [1] plants, fungi and bacteria of definite genera and families create a number of organic compounds which are not included in primary metabolism that important in essential activity of organism (photosynthesis, respiration, and protein and lipid metabolism) and seem to have no function in growth and development of them [2]. Such compounds are called secondary metabolites (secondary plant products or natural products), there are other name which known as Phytogenic feed additives (PFA) or phytobiotics and botanicals, are commonly defined as various plant secondary compounds (PSC) and metabolites with beneficial effects on animal health and production, including feed and animal products. These compounds are accessary rather than central to the functioning of the plants in which they are found. These compounds are produced in small quantities and their extraction from the plant is difficult and expensive.

There important product of plant secondary metabolites as natural products: Terpenes and Terpenoids (25,000 types), Alkaloids (12,000 types) and the Phenolic compounds (8000 types) [3].

Essential oils (EOs) represent a major group of phytogenic feed additives (PFA). Plant oils and extracts have been used for a wide variety of purposes for many thousands of years [4], Due to their strong aromatic features and bioactivity, EOs have been widely used since ancient times in aromatherapy, as flavor and fragrances in cosmetics and foods, and more recently as pharmaceuticals, natural preservatives, additives, and biopesticides [5, 6, 7]. There are many defines of EO, like EO is a mixture of low molecular weight constituents that are responsible for its characteristic aroma, or Essential oils are concentrated liquids of complex mixtures of volatile compounds and can be extracted from several plant organs [8]. The chemistry of EO constituents includes terpenoid and non-terpenoid hydrocarbons and their oxygenated derivatives [5, 9, 10]. Essential oils are concentrated plant extracts that retain the natural smell and flavor, or “essence,” of their source Essential oils, also called volatile odoriferous oil, are aromatic oily liquids extracted from different parts of plants, for example, leaves, peels, barks, flowers, buds, seeds, and so on [11].

They may be found in different parts of the plant. Some EOs could be found in leaves (oregano), seed (almond), flower (jasmine), peel (bergamot), berries (juniper), rhizome (galangal ginger), root (angelicaarchangelica), bark (sassafras), wood (agar wood), resin (frankincense), andpetals (rose) [12].

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2. How do essential oils work

Essential oils include biological compounds like growth factors, hormones, and neurotransmitters that are concentrated from the plant. Several researches have been performed on PEOs in order to confirm their biological efficacy against bacteria and fungi [13]; PEOs have an antibacterial activity where they cause damage to cells via an interface with plasma membrane components which lead to leak the most important compounds and damage the transportation channels, especially of potassium ion [12, 13]. Volatiles from PEOs not only work on single target site in the cell but also they bind to protein structures of the cell. Some of the PEOs and their volatiles are found to be responsible in inhibiting the enzymatic proteins in some bacterial pathogens [14, 15, 16].

Essential oils used all over the world for disinfection, as anti-inflammatory, relaxing, and stimulating substances, and with potential and modern exploitation in clinical medicine are most commonly used in the practice of aromatherapy, in which they are inhaled, or be swallowed, or can interact with your body in several ways when applied to your skin, some plant chemicals are absorbed also commonly used in food and cosmetic industries [17] (Figure 1).

Figure 1.

Schematic illustration for the effect of essential oils on bacteria cell. Source: Ref. [10].

3. Extraction of essential oils

Essential oils are produce from valuable plant products, generally of complex composition including the volatile principles contained in the plant and the more or less modified during the preparation process. The earliest recorded mention of the techniques and methods used to produce essential oils is believed to be that of Ibnal-Baitar (1188–1248). The oil droplets being stored in the oil glands or sacs can be removed by either accelerate diffusion through the cell wall or crush the cell wall [17, 18, 19, 20]. The assumed techniques depend on the part of the plants where the oil is to be extracted, the stability of the oil to heat and susceptibility of the oil constituents to chemical reactions. An extract is derived when the plant material is soaked in a substance such as water, alcohol or other liquid for long periods of time so that its flavor, aroma or medicinal properties, infuses into the liquid [11].

Common techniques used for the extraction of essential oils are:

  • Hydrodistillation

  • Hydrodiffusion

  • Effleurage

  • Cold pressing

  • Steam distillation

  • Solvent extraction

  • Microwave Assisted Process (MAP)

  • Carbondioxide extraction

3.1 Hydrodistillation

Hydrodistillation represents one of the most used traditional and a commonly methods of extraction used method of extracting essential oils from plant samples (wood and flower). This method may be further classified into the subcategories of steam distillation, water distillation, or a combination of water and steam distillation. Hydrodistillation include saturation of the powdered wood in the water in the first step, while the next step is to use the steam that result from the heating of the water reservoir then finally gather the oil that result after the reservoir cold. The advantage of this technique is that the required material can be distilled at a temperature below 100°C. There are many studies provided that the different extraction processes on yield and properties of essential oil from rosemary (Rosmarinus officinalisL.) by HD and solvent-free microwave extraction (SFME) [21]. While Golmakani and Rezaei (2008) [22] researched the microwave-assisted HD (MAHD), which is an advanced HD technique utilize a microwave oven in the extraction procedure.

MAHD was preferable in extraction time (75 min, compared to 4 h in HD). Ohmic-assisted HD (OAHD) is another advanced HD technique [23]. OAHD method had the extraction time of 24.75 min, while HD took 1 h for extraction of essential oil. No changes in the compounds of the essential oils obtained by OAHD were found in comparison with HD.

3.2 Hydro diffusion

Hydro Diffusion method for extraction of oils is a type of steam distillation and is only different in the way in which steam enters the container of the still. This method is preferred when the plant material has been dried and is not deteriorate at boiling temperature [24]. The steam in this method is drenched from the topmost onto the phytophagous matter and thus leads to impregnate the plants even more and less time. Hydrodiffusion method is superior to steam distillation because of shorter processing time and a higher oil yield with less steam used [11].

3.3 Steam distillation

One of the most widely used methods of extracting essential oils from their sources is steam distillation, and it is one of the preferred methods due to its low cost. In this method, the essential oil and aromatic components of the plant are gathered by utilize heating water or vapor and thus cause damage to plant cells and lead to release these materials [21, 25]. This method is applied in isolation of essential oils at temperatures approach to 100°C, and next with condensation to produce an immiscible fluid that can clarify it to isolate the oil, so it is used in the conservation of compounds that might rupture at elevated temperatures [23, 26, 27].

3.4 Solvent extraction

In this method, the extraction of the essential oil occur after utilization of a hydrocarbon solvent which is acts as dissolving material when added to the plant and leads to the formation of mixture contain the essential oil with other material. The next step includes purification by concentration and filtration of the mixture and then added of absolute alcohol that when evaporate left the oil behind it. This method represents the best in the formation of big amounts from the product oil because of the least display to high temperatures or air but on the other hand the residue that results by the way after the extraction had bad effects on the health and immunity [28].

3.5 Cold pressing

Uses large machinery to either grind the seeds/fruits to squeeze out the oil or pierce the rind and peel of the fruit while it is rotating to extract the oil. Cold pressing is used to extract the essential oils from citrus rinds such as orange, lemon, grapefruit and bergamot. In this method the heat is generated internally where it result from the revolving of the mixture and the friction lead to disconnect of the oil from the mixture and the next step include filtration of the oil to discard any residue and ensure the purification process [29].

3.6 Enfleurage

An intense and classical method of elicit essential oil from petals of flowers. The procedure includes coating fats above petals of the flower which act on the soak up the oils, and then utilize alcohol to isolate the essential oils from the fat, then let alcohol be evaporated and thus the essential oils are gathered [29].

3.7 Carbondioxide extraction

This method is traditional where it uses the liquid CO2 via pressurized it and the essential oils of the plants dissolved in this liquid. The next step includes return back of CO2 to the state of gases thus gathered left the oil, so the positive feature of this method was kept the essential oil from damage by high temperatures [29].

4. List of essential oils

This list is organized alphabetically by the common essential oil name (Table 1).

NO.Essential oilsNO.Essential oils
1Allspice (Pimento Berry, Jamaica Pepper)23Cassia
2Amyris (Torchwood, West Indian Sandalwood)24Catnip
3Angelica Root25Cedarwood Atlas
4Anise (Aniseed)26Cedarwood Himalayan
5Arborvitae (Western Red Cedar)27Cedarwood Virginian
6Balsam Peru (Peru Balsam)28Celery Seed
7Basil (Sweet Basil, Basil Linalool29Cilantro (Coriander Leaf)
8Bay Leaf30Cinnamon Bark
9Bergamot31Cinnamon Leaf
10Bergamot Mint32Cistus (Labdanum, Rock Rose)
11Birch (Sweet Birch)33Citronella
12Black Pepper34Clary Sage
13Black Spruce35Clementine
14Blue Cypress Blue Tansy36Clove Bud
15Buddha Wood (Desert Rosewood)37Coffee
16Blue Tansy (Moroccan Blue Chamomile)38Copaiba (Copaiba Balsam)
17Cajeput (Cajuput, White Tea Tree)39Coriander Seed
18Camphor (White Camphor, Camphor Laurel)40Cumin
19Cannabis41Cypress
20Caraway Seed42Davana
21Carrot Seed43Dill Weed/Dill Seed
22Cardamom44Douglas Fir
NO.Essential oilsNO.Essential oils
45Elemi73Juniper Berry (Juniper)
46Eucalyptus dives74Key Lime
47Eucalyptus globulus75Kunzea
48Eucalyptus radiata76Labdanum
49Eucalyptus smithii77Laurel Leaf (Bay Leaf, Bay Laurel, Sweet Bay)
50Everlasting (see Helichrysum)78Lavandin
51Fennel (Sweet Fennel)79Lavender
52Fir Balsam(Canadian Fir Needle)80Lavender (Spike Lavender)
53Fir Needle (Siberian Fir)81Lemon Balm
54Frankincense (Olibanum)82Lemon Eucalyptus
55Galangal Root (Greater Galangal, Siamese Ginger)83Lemongrass
56Galbanum84Lemon Myrtle
57Geranium85Lemon Tea Tree
58Geranium Bourbon86Lime Expressed
59German Chamomile (Blue Chamomile)87Lime Distilled
60Ginger88Mandarin
61Gingergrass89Manuka (New Zealand Tea Tree)
62Goldenrod90Marjoram (Sweet Marjoram)
63Grapefruit91May Chang (Litsea)
64Helichrysum (Everlasting, Immortelle)92Melaleuca
65Hemlock (Spruce Hemlock, Tsuga)93Melissa (Lemon Balm)
66Hemp (Cannabis)94Mountain Savory (Winter Savory)
67Ho Leaf95Myrrh
68Ho Wood96Myrtle
69Hyssop97Neroli (Orange Blossom)
70Immortelle98Niaouli
71Jack Pine99Nutmeg
72Jasmine Absolute100Opoponax (Sweet Myrrh, Opopanax)
NO.Essential oilsNO.Essential oils
101Orange (Blood Orange)127Spearmint
102Orange Blossom128Spikenard (Nard, Jatamansi)
103Orange (Sweet Orange, Wild Orange)129Spruce Hemlock
104Oregano130Star Anise
105Palmarosa131Sweet Myrrh
106Palo Santo132Tangerine
107Patchouli133Tarragon
108Peppermint134Tea Tree
109Petitgrain135Thyme (Thyme Linalool,Thyme Thymol)
110Pine (Scotch Pine, Scots Pine)136Tsuga
111Pink Pepper137Turmeric
112Plai138Valerian
113Ravensara139Vanilla Absolute (Vanilla Oleoresin)
114Ravintsara (Ho Leaf)140Verbena (Honey Verbena, Wild Verbena)
115Rock Rose141Vetiver
116Rosalina (Lavender Tea Tree)142White Fir
117Rose Absolute (Rose Otte, Bulgarian Rose, Damask Rose)143Wintergreen
118Rose Absolute (Provence Rose, Cabbage Rose)144Winter Savory
119Rose Geranium145Yarrow
120Rosemary146Ylang Ylang
121Rosewood (Bios de Rose)147Yuzu
122Sage (Dalmatian Sage, Common Sage)
123Sandalwood
124Saro (Mandravasarotra)
125Siberian Fir
126Silver Fir (Silver Fir Needle, Silver Spruce, White Fir)

Table 1.

The most common name of the essential oil.

4.1 The application of oils essential

There were several applications using the essential oils such as in the nutrition, cosmetic manufacture and alternatives to synthetic medication that uses to treatment several infections and diseases [28]. Essential oils were used all over the world for disinfection, as anti-inflammatory, relaxing, and stimulating substances, and with potential and modern exploitation in clinical medicine and oil can act as antibacterial agent against a wide spectrum of pathogenic bacteria strains including: Listeria monocytogenes, Listeria Linnocua, Salmonella typhimurium, Shigella dysenteriae, Bacillus cerus, and Staphylococcus aureus. Mouth washes containing essential oils could also be used as part of plaque-control routine since they can penetrate the plaque biofilm and kill pathogenic-wall. It is also had antibacterial activity especially versus the pathogenic bacteria in dental and mouth and this feature help in adding the essential oil in washes of the mouth to keep the oral health and improve the odor of mouth, especially when mixed with chlorhexine gluconate which is an act in preventing the transmission of pathogenic bacteria.

Essential oil with high concentration of thymol and carvacrol e.g., oregano, savory and thyme, usually inhibit gram positive more than gram-negative pathogenic bacteria.However the antibacterial activity against gram- negative Haemophilus influenza and Pseudomonas aeruginosarespiratory pathogens, while gram-positive streptococcus pyrogens was the most resistant to the oil.

Recently, the sciences show several danger effects of the synthetic flavoring and preservatives materials in the food onto the human health so they directed to utilize alternatives such as essential oils as natural materials for its features in preservatives the food for long time, antibacterial effects, and decrease food deterioration [29]. Pathogenic microbes in storage food or food products are responsible to degrade or deteriorate the quality of food products, resulting in the emerging foodborne diseases in various regions of the world [30]. It is well known that some essential oils exert antimicrobial and antioxidant properties. Significant variations in the chemical composition of rosemary essential oils have been reported in relation to the geographic origin [27, 28]. Moreover, variations in the antioxidant and antimicrobial properties of rosemary oils from natural populations were also detected. Its applications are represented in the medicinal and therapeutics, such as aromatherapy, phytotherapy, antibacterial and antifungal uses, hypolipidemic, antitumor, etc.

5. Ways of utilization

The chemical structure of the essential oils is different from one the other and this feature influences their utilization ways and leads to variation in their absorption and the ways of their uses by the body. So, essential oils are generally used in four ways as follows.

5.1 Aromatically

In this way, the oils are inhaled via diluted and then using the diffuser which is act on lightening the oil and make it easy to broad into the air so, this help in treated the external respiratory passage, improve the emotional and mental state and decrease of anxiety, where some researches indicated that the inhalation of some essential oils such as lavender act as quite sedatives where it incorporated with cells of the brain via the receptors of smell or have effects on some hormones and enzymes and do its works as a relaxer, Uplifting Mood, Calm Mood and Meditation [31, 32].

5.2 Topically

This method includes applying the essential oil on the skin where it is absorbed easily. Some oils must be diluted before using while others need a carrier oils. The topical ways used in the support of stress when it used in massage and also it is used in the beauty products such as lotions and wax, but it may cause allergies to some peoples who suffering from skin sensitive so must be careful when using it and applied in small area of the skin after taking advice of the physician [32].

5.3 Internally

Some essential oils have medication features when ingested orally, that is, it act internally where it transported via the stream of blood to various parts of the body, they may acts as an anti-inflammatory, treats digestive disorders, improves digestion, and as a gas expeller. Efficient ways of internal implementation are by mixed the essential oils with some water or milk or by ingesting it as a capsule or in cooking [32].

5.4 Externally

The external way that uses essential oils (i.e., around the home) such as cleaning the home or dishes by add drops from the oil with the cleaning product for its activity as detergents, more effective in cleaning clothes, add nice smell and some act as expeller of insects [32].

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6. Conclusions

Essential oils are natural substances extracted from several parts of plants by various methods. They are safe as food preservatives because they do not have side effects on human health. In addition, its bactericidal characteristics encourage utilizing them as medications and in beauty care products.

© 2020 The Author(s). Licensee IntechOpen. This chapter is distributed under the terms of the Creative Commons Attribution 3.0 License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Lubna Abdul Muttalib Al-Shalah, Nada Khazal Kadhim Hindi and Israa Harjan Mohsen (September 9th 2020). Essential Oils, Essential Oils - Bioactive Compounds, New Perspectives and Applications, Mozaniel Santana de Oliveira, Wanessa Almeida da Costa and Sebastião Gomes Silva, IntechOpen, DOI: 10.5772/intechopen.92216. Available from:

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