Properties and applications of MgO bulk, nanoparticles and thin films.
In this chapter, we present an overview of synthesis of MgO nanoparticles and thin films by using top-down and bottom-up approaches. The bottom-up approaches are generally utilized to grow nanoparticles by the methods that involve chemical reactions. Sometimes, methods based on these reactions are also able to grow thin films. The top-down approaches are preferred for growing thin films where bulk material is used for depositions. The methods, which are frequently used, are radio frequency sputtering, pulsed lased deposition, and molecular beam epitaxy and e-beam evaporation. Sometimes, methods like mechanical milling and high energy ball milling are used to grow nanoparticles.
- bottom-up approaches
- top-down approaches
Nanoparticles and thin films are very common form of materials for utilization in different applications [1, 2, 3, 4]. Synthesis approaches play vital role to determine characteristics of nanoparticles  and thin films . Thus, a number of methods are being developed to synthesize either nanoparticles [7, 8, 9] or thin films [10, 11, 12]. The motive behind to explore numerous methods is to look for reproducibility and cost effectiveness in terms of industrial utilization [13, 14]. Researchers are also working to get deep insights of involved phenomena during growth which persists a way to optimize for particular application [15, 16, 17, 18]. The factors, which are considered during nanoparticle growth, are size , shape [20, 21] and size distribution [22, 23]. In case of thin films, these factors are nature of growth, morphology, stress, strain developed across films substrate interface [24, 25, 26].
While growing nanoparticles, one need to take care annealing treatment [27, 28] and stoichiometry [29, 30], however, process is rather typical in case of thin film technology. Choice of substrate , annealing temperature [32, 33], base pressure , target to substrate distance , deposition pressure [36, 37] and nature of gas during growth determine the nature of film . Textured of grown thin film , stoichiometry  and nature of surface [41, 42] are another important parameter, which are considered during deposition. Thus, keeping in mind the necessity and challenges in the synthesis, synthesis approaches for growing nanoparticles and thin films are discussed by taking a simple inorganic system. However, magnesium oxide is known from long time  but recent advances in application of this material motivated us to discuss these approaches for MgO . In Table 1, a summary of properties of MgO are depicted [45, 46, 47].
While keeping in mind the importance of this material, we attempt to give an overview of synthesis of MgO nanoparticle and thin film. To grow nanoparticles, two kinds of approaches are used: (1) bottom-up approach and (2) top-down approach [48, 49]. These approaches are explained on the basis of following schematic diagram. In general, bottom-up approach is meant by synthesis of nanoparticles by means of chemical reactions among the atoms/ions/molecules (Figure 1a). Whereas top-down involves the mechanical methods to crush/breaking of bulk into several parts to form nanoparticles (Figure 1b). In the next section both kind of approaches for growth of MgO nanoparticles and thin films are grown.
2. Bottom-up approaches
2.1 MgO nanoparticles
To initiate chemical reaction among the involved atoms/ions/molecules certain salts are taken as starting materials. These salts are mixed with each other to form a homogeneous solution along with a suitable chelating agent. Control of nature of solution also plays important role during synthesis process . Thus, various methods are being developed by researchers to minimize annealing treatment, nature of chelating agent, pH value of solution. Some of these methods are depicted here.
Thus, combustion synthesis is able to produce nanoparticle of various materials both at research purposes as well as at industrial scale [51, 53, 54, 55, 56, 57]. Various kind of nanoparticles like titanates , ferrites , carbonates , hydroxide  and oxides  are grown using this approach. Combustion synthesis is utilized for growing different kind of MgO nanostructures [63, 64] and its derivative [65, 66, 67].
Our group utilizes, this method to synthesize MgO nanoparticles using combustion synthesis while taking magnesium nitrate as an oxidizer and citric acid as fuel . This method shows reproducibility . The following equation is expected during synthesis process.
Figure 2 depicts schematic diagram of synthesis process. It is clear that synthesis takes place at low temperature, which reduces cost of synthesis. Figure 3 shows representative X-ray diffraction (XRD) pattern of the nanoparticle synthesized at 500°C for 1 h. The method is able to produce nanoparticle with pure phase and no other crystalline phases are observed .
2.2 MgO thin films
3. Top-down approaches
Top-down approaches are mostly utilized to grow thin films of inorganic materials. Some of these methods are discussed here.
3.1 MgO nanoparticle
3.2 MgO thin films
Top-down approaches for growing MgO thin films are depicted in this section.
Figure 7 shows the MgO thin films on fused quartz substrate along with MgO powder. Both the films of thickness around 5 and 50 nm reveal almost amorphous nature. Optical absorption spectra of MgO thin films exhibit onset of film formation (Figure 8). This method is also utilized to grow MgO thin films on Si substrate. Films grown on this substrate exhibits polycrystalline nature .
The main advantage of PLD is the stoichiometric transfer from the multicomponent target to the thin film form, which otherwise is hard to achieve with any other thin film growth technique such as thermal evaporation or sputtering. The pulsed nature of PLD allows precise control on the film growth rates. Some drawbacks of the PLD technique are small area deposition, growth of macroscopic particles (particulates) during the ablation process, defects produced during growth, etc.
MgO films on Si substrate are grown by number of researchers [129, 130] as well as by our group [42, 131]. Films grown on Si substrate are both amorphous [132, 133] and crystalline [134, 135] in nature depending upon the deposition time and annealing temperature. Figure 11 shows the XRD pattern of the MgO thin film grown at substrate temperature of 350°C, deposition time of 400 min and annealing temperature of 800°C for 1 h followed by 300°C and 24 h.
Thus, an overview of bottom-up and top-down approaches for synthesis of MgO nanoparticles and thin films is depicted in this chapter. Chemical methods are effective to grow nanoparticles, however, later is successful to grow thin films.
JPS is helpful to Prof Ik-Jae Lee, Pohang Accelerator Laboratory, South Korea, for providing access to RF sputtering setup. GP is highly thankful to Dr. Deependra Kumar Jha, Vice Chancellor, UPES, Dehradun, for providing necessary research facilities to carry out present research work at UPES.
Conflict of interest
The authors declare no conflict of interest.
Thanks to the editor for inviting one of authors JPS for submission of chapter. JPS and GP are thankful to the publisher to waive off the article processing charges for the chapter.