State of homogeneity of dispersed hc-SWCNTs and SWCNTs with crystal defects.
Carbon nanotubes (CNTs) exhibit chemical stability, thermal conductivity, mechanical strength, and unique properties as a quasi-one-dimensional material with nanoscale needle shape. Field-emission (FE) electron sources appear to be the most promising industrial application for CNTs, and their deployment is approaching practical utilization. So far, efforts to construct an FE cathode with single-walled carbon nanotubes (SWCNTs) have only managed to average out the large FE current fluctuations in a nonhomogeneous electron emitter plane and the short emission lifetime because the crystal defects in the carbon network in CNTs prevent the realization of a stable emission current. The utilization of CNTs to obtain an effective electronic device, one with stable emission and low FE current fluctuations, relies on the high crystallization of CNTs, a task that can be fulfilled by using highly crystalline SWCNTs (hc-SWCNTs). The author could succeed in developing a model of the flow of electrons through the inside of the hc-SWCNTs and SWCNTs with crystal defects to the outside using the fluctuations of the tunneling current. Therefore, we expect that the hc-SWCNTs are used as field emitters with stable emission and low power consumption for saving energy.
- single-walled carbon nanotube
- high crystallization
- field emission
- inelastic electron tunneling
- current fluctuation
In the development regime of electronic devices, carbon nanotubes (CNTs) are expected to represent a promising material because of their unique physicochemical properties—nanoscale needle shape, high chemical stability, thermal conductivity, and mechanical strength—which represent advantages for the fabrication of field emitters. The utilization of single-walled CNTs (SWCNTs) relies on their electronic properties because they can be either metallic or semimetallic, depending on the geometry of how a graphene sheet is rolled into a tube (i.e., diameter and chiral angle) [1, 2, 3]. This controllability is considered to be effective for developing electronic devices based on SWCNTs [3, 4, 5]. SWCNTs also exhibit one-dimensional confinement effects and can be used as coherent quantum wires [6, 7, 8], and the Young’s modulus of SWCNTs is especially high when compared to that of other CNTs . Owing to these properties, SWCNTs have been used in a wide range of applications including field emitters , probes in scanning microscopes , gas-storage materials , and electrode materials for secondary batteries , and they have been studied in a wide range of applied research fields.
However, synthesized CNTs, including SWCNTs, have crystal defects in the carbon network, and the unstable physicochemical properties make it difficult to use CNTs in electronic devices which require high reliability. Tohji et al. improved the purity and crystallinity of SWCNTs synthesized by arc discharge, and they succeeded in obtaining highly pure SWCNTs . Together with Iwata and coworkers, they established a method to analyze, with high resolution, the crystallinity of highly crystalline SWCNTs (hc-SWCNTs) . Based on these developments, a process for synthesizing hc-CNTs has been gradually established; however, a technique to control the crystallinity of hc-SWCNTs has yet to be demonstrated.
The application of hc-SWCNTs as field emitters is industrially promising and is approaching practical utilization. We have carried out basic research to develop field-emission (FE) devices using hc-SWCNTs  and succeeded, for the first time in recorded history, in employing SWCNT field emitters as the cathode of a planar lighting device . These results suggest that hc-SWCNTs will be indispensable for decreasing the driving voltage for FE, increasing the emission lifetime, and improving the homogeneity of planar emission of planar lighting devices .
In the chapter reported here, the effect of the increased crystallinity of SWCNTs on their electrical properties was examined by comparing hc-SWCNTs and SWCNTs with crystal defects. In addition, field emitters were prepared from these SWCNTs, and the effects of the increased crystallinity of hc-SWCNTs on their electrical conductivity and FE current fluctuations were theoretically analyzed by determining their FE properties.
2. Theoretical electron tunneling model of the increased conductivity of hc-SWCNTs as field emitters
The Fowler-Nordheim (F-N) tunneling model shown in Figure 1 is an electron tunneling model represented by Eq. (1). The F-N tunneling model is valid only when electrons in the field emitter are passing into an energy barrier quantum mechanically. We assume that electrons emit from SWCNTs to the outside in case of the FE model discussed in this chapter, and we constructed an FE model including F-N tunneling model by combining the model of inelastic and elastic tunneling electrons passing through the inside of SWCNTs to the outside.
In the quantum electron-tunneling model, the states of the electrons before and after tunneling through an energy barrier can be estimated by considering the energy transfer. According to Laks and Mills , the current density in the current-current correlation can be expressed in the following form:
where is the quantum-mechanical tunneling-current operator and represents the current flow at time
When an electron exists in a sphere Ω,
In Eqs. (8) and (9), is the barrier potential, and
is the power spectrum of the current fluctuation of the tunneling current for the field-emission mechanism:
Ballistic electrons are considered to pass through CNTs without crystal defects. However, when electrons pass through CNTs with crystal defects, the ballistic property is lost; an energy barrier is believed to inhibit the conduction of these electrons. In accordance with the works of Fransen et al.  and Nilsson et al.  on the electron tunneling model, we adopted an inelastic tunneling model through an energy barrier having a rectangular waveform.
2.1 Power spectrum in the inelastic tunneling model
In the inelastic tunneling model, the energy states of electrons passing through an energy barrier can be estimated by the energy transfer before and after electron tunneling. The power spectrum with the flow of FE current for the inelastic tunneling model was proposed by Kirtley et al. , Bardeen , and Watanabe et al.  based on Eqs. (12) and (13):
We attempted to obtain the direct-current (DC) component of the power spectrum of the inelastic electron tunneling model using a rectangular potential barrier and Eq. (13). As mentioned above, the electrons passing through the CNTs without crystal defects are ballistic . The CNTs with crystal defects are reported to have an energy bandgap that depends on the position of the defects, and electrons rarely pass through CNTs without energy loss. In order to analyze the electrical conductivity of SWCNTs, we attempted to obtain the tunneling matrix
The wave functions
The energy transfer between waves-A and -B,
The power spectrum of inelastic electron tunneling, |
2.2 Power spectrum in F-N tunneling regime passing into an SWCNT with crystal defect
The thickness of the rectangular energy barrier and the energy transfer which means the energy difference between the left region and the right region are important factors in this simulation. Results of research on tunnel junction devices indicate that the thickness of the rectangular potential barrier for inelastic electron tunneling is only ∼3 nm . The energy loss caused by the tunneling of electrons through the energy barrier depends on the bandgap associated with the crystal defects . The theoretical value of difference in the energy between waves A and B is calculated by fitting to be 0.027 eV, which corresponds to a temperature of 313 K for the energy loss observed when the electrons pass through SWCNTs with crystal defects.
Eq. (12) should be transformed into a more suitable form for a field-emission cathode using metallic SWCNTs. Field-emission measurements were carried out in the F-N tunneling regime, and a further simplified form is expressed as follows:
where , shown in Figure 3, is the barrier-height potential that indicates the difference between the vacuum-level energy and the energy at the bottom of the Fermi level of metallic SWCNTs; and is the applied electric field on the SWCNTs enhanced by the tip shape. The enhancement factor
where represents the real electric field between the cathode and anode. Moreover, the area of the field-emission site
3. Experimental methods
In this study, the SWCNTs synthesized by arc discharge were annealed at a high temperature of approximately 1200 K in a low pressure of 10−6 Pa to obtain hc-SWCNTs. Figure 4 shows transmission electron microscope (TEM) images of the SWCNTs before and after annealing. As shown in Figure 4(a), we could find that the crystallinity of the SWCNTs after annealing was significantly improved.
The SWCNTs obtained before and after annealing were dispersed in a liquid medium with solvent including, to control the viscosity of the solution, surfactant and an ITO precursor solution, to prepare a coating film. The agitated mixture was sprayed on a silicon substrate to form an ITO film and sintered at approximately 700 K in a vacuum to remove any components in the organic solvents. In addition, to facilitate FE, the ITO film with SWCNTs was scratched with a thin needle to activate the film .
A diode structure fixed to the distance of 1.2 mm between a cathode of the ITO film having SWCNTs and an anode of a phosphor plate was prepared for the FE measurements; Figure 5 shows a schematic of the FE-measurement system.
The sample was set in a vacuum chamber of approx. 10−4 Pa. A supplied voltage with a frequency of 60 Hz was applied across the cathode and the anode to measure the FE characteristics.
4. Field-emission results and discussion
4.1 Field-emission characteristics of hc-SWCNTs
Tunneling electron microscopy and scanning electron microscopy were used to obtain images of the dispersed hc-SWCNT bundles and the ITO film which was subjected to activation treatment. As one can clearly see in the TEM image in Figure 6(a), the hc-SWCNT bundles were well dispersed in the liquid medium. Meanwhile, the SWCNT bundles shown in the SEM image in Figure 6(b) were exposed in the scratched grooves on the activated ITO film and marked within the white circles; the dispersed SWCNTs in a scratched area are also illustrated with the red circles indicating the ends of the SWCNT bundles on the right. The number of dispersed and exposed SWCNTs per unit area could be controlled via the density of the SWCNTs. Table 1 shows the summary of the state of the exposed SWCNTs in terms of (1) the number of SWCNTs protruding from the grooved walls of the scratched ITO film per unit area, (2) the mean diameter of the exposed SWCNT bundles, and (3) the mean distance between neighboring SWCNT bundles for two types of SWCNTs, i.e., SWCNTs with crystal defects and hc-SWCNTs. The states of exposure of the two types of SWCNTs fabricated by our wet-coating process were similar, and they were homogeneously dispersed in the films.
|hc-SWCNTs||SWCNTs with crystal defects|
|Number of SWCNTs exposed at grooved walls of ITO film after activation||Approx. 21 per 100 × 100 μm2||Approx. 26|
|Average diameter of bundled SWCNTs (nm)||Approx. 9||Approx. 10|
|Average distance between neighboring bundled SWCNTs (μm)||Approx. 27||Approx. 21|
Figure 7 shows the relationship between the current density and electric field for the SWCNTs, obtained using the system for FE measurements (Figure 5). The threshold field decreased from 2.01 V μm−1 for the SWCNTs with crystal defects to 1.07 V μm−1 for the hc-SWCNTs. As shown in Table 1, the dispersion density of SWCNTs and the mean diameter of SWCNT bundles in the films were similar for the two types of the SWCNTs. It means that the probability densities of SWCNTs that induced FE were similar for the two types of SWCNTs. Therefore, it can be discussed and assumed that the above improvement in electrical properties was caused by the increase in crystallinity of the SWCNTs.
Figure 8 shows the distribution of bright spots in the hc-SWCNTs and SWCNTs with crystal defects. As can be seen in Figure 7, the threshold and the driving field depended on the crystallinity of the SWCNTs. When the applied field was controlled so that the current density was uniform, the densities of the high- and low-brightness spots on the measured area were almost the same between the hc-SWCNTs and the SWCNTs with crystal defects, respectively. Previous reports showed that in the SWCNTs synthesized by arc discharge, SWCNTs with metallic and semiconductive properties coexisted . Therefore, the high-brightness spots can be attributed to the FE from metallic SWCNTs, and the low-brightness spots can be attributed to the FE from semiconductive SWCNTs; these phenomena and their origins are not discussed in this chapter. When the crystallinity of SWCNTs increased, the chirality of the carbon sheets making up the SWCNTs did not change, and the mixed ratio of metallic to semiconductive SWCNTs remained unchanged [32, 33, 34, 35, 36, 37].
The results in Figure 6 and Table 1 indicate that the diameter, protruded length, and dispersion density of the SWCNT bundles protruding from the grooved ITO film were similar for the two types of the SWCNTs as FE electron sources. However, the difference in the plots of current density versus electric field of Figure 7 is impossible to be analyzed only by the exposed uniformity of the dispersed SWCNTs on the activated ITO film. Therefore, we surmised that the difference in the crystallinity of SWCNTs caused the difference in electric properties of SWCNTs. Fransen et al. and Nilsson et al. find that the interruption of carbon network of an SWCNT with crystal defects originates a local energy band that affects the electrical conductivity by scanning tunneling microscopy (STM) [22, 23]. On the basis of the above results, an electric-physical model in an SWCNT was developed from the inelastic electron tunneling model. Therefore, the energy difference originated by the energy bandgap yielding from the interruption of carbon network in an SWCNT with crystal defects is surmised to become an energy barrier which impedes the electrons pass through the SWCNT.
Figure 9 shows the FE properties obtained by experiment in Figure 7 and simulation. For the hc-SWCNTs, the results obtained by the experiment are represented by red circles and those obtained by simulation using Eq. (12) at
|hc-SWCNTs||SWCNTs with crystal defects|
|Electron-emission site (||1.95 × 10−9|
|Field-enhancement factor (||259,500|
|Effective mass of electron (||1.00|
|Thickness of rectangular inelastic barrier||—||2.9 nm|
|Energy bandgap after passing into the barrier||—||0.148 eV|
|Energy difference between wave A and wave B||—||0.025 eV|
The inelastic electron tunneling through the SWCNTs with crystal defects, as shown in Figure 10, is a phenomenon based on the energy loss associated with the electron transfer in the SWCNTs. Although many researchers have reported that CNTs exhibit ballistic electrical conductivity, such property has not been demonstrated in any experiment that we know of. We can express successfully the first report of the development using an inelastic electron tunneling model for an SWCNT with crystal defects based on the evaluation of FE properties. The hc-SWCNTs are suitable materials for electronic devices to save energy because the energy loss associated with electron transfer in the SWCNT is suppressed.
4.2 Current fluctuations of hc-SWCNTs as field emitters: theoretical predictions versus experimental results
Figure 11 shows the relationship between the current density and electric field for the SWCNTs obtained using the FE-measurement system shown in Figure 5. The threshold field of the metallic SWCNTs was 4.1 V μm−1 at a line-current density of 0.1 mA cm−2, as shown in Figure 11. Moreover, the planar lighting observed at 2 mA cm−2 was homogeneous, as shown in the inset in Figure 11.
Figure 12(a) shows the stability of the FE current of metallic SWCNTs when different values of DC voltage were supplied for 50 s; Figure 12(b) shows the power spectrum of the frequency based on the FE current fluctuations by Fourier transform calculation. The current density obtained from the sample biased using the DC power supply was measured as 1.2 mA cm−2 at 6 kV, 2.0 mA cm−2 at 6.6 kV, 4.6 mA cm−2 at 7.1 kV, and 10 mA cm−2 at 7.6 kV. The FE current fluctuations were observed to be stable owing to the desorption of gases from the SWCNT surface caused by annealing before the FE measurements. Some damped current distributions in the FE current were expected if the annealing of the sample was insufficient. However, Figure 12(a) shows no damping, and the SWCNT surfaces were expected to be clean for the FE measurements. The spectrum of each FE current in Figure 12(a) is normalized by the peak at 0 Hz, and it indicates that periodic fluctuations were recorded. A peak appears at 50 Hz, as shown in Figure 12(b), and it originated from the noise of the DC power supply, which represents the frequency of the commercial power supply in the eastern region in Japan. It can be seen that the stable DC current had alternating values, especially in the low-frequency domain of <100 Hz. Moreover, the spectrum distribution depends on the FE current, and the contents of each spectrum increased with the DC power.
When the experimental results and the theoretical predictions explained in the previous theoretical section are compared, the parameters that determined the tunneling characteristics of the metallic hc-SWCNTs used as field emitters are listed in Table 3. The enhanced field
|1.60 × 10−19 C|
|6.48 × 10−24 m2|
| (, ||6.58 × 10−16 eV s|
|2.56 × 103|
|9.11 × 10−31 kg|
The power spectrum |
Field emission using metallic SWCNTs was modeled as a phenomenon based on inelastic electron tunneling, and the calculated power spectra are shown in Figure 13. Although many researchers have reported that field emitters exhibit F-N tunneling with elastic electrical conductivity, the phenomenon has not been demonstrated in any reported experimental work. This chapter presents successfully the first report of the development of an inelastic electron-tunneling model with WKB approximation for SWCNTs from the FE properties. Moreover, the FE current from electron sources like SWCNTs contains time-depended fluctuations, and the
In this chapter, the author explained the conductive model of electrons flowing in the vicinity of a crystal defect that acts as a rectangular energy barrier based on inelastic electron tunneling model and the current fluctuation model for FE with hc-SWCNTs employing the F-N tunneling phenomenon.
The author could succeed in developing a model of the flow of electrons through the inside of an SWCNT to the outside using the fluctuations of the tunneling current. The electron flow model for an SWCNT with crystal defects was obtained by combining the F-N tunneling model with the power spectrum obtained using the tunneling matrix. From the previous mentioned comment, we could give a brief explanation of the effect of the increased crystallinity of SWCNTs on their electrical conductivity and describe the development of an electron flow model through the crystal defects of an SWCNT. Therefore, we expect that the hc-SWCNTs are used as field emitters with stable emission and low power consumption for saving energy.
The author kindly appreciates to support and give helpful discussions and suggestions by DOWA Holdings Co. Ltd., Japan.
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