Compared intrinsic properties of main TiO2 polymorphs.
Mesoporous TiO2 thin films (MTTFs), thanks to their particularly high surface area, controlled porosity, high flexibility in composition, and surface design, are promising candidates in different application fields such as sensors, self-cleaning coatings, lithium-ion batteries (LIBs), photocatalysis, and new-generation solar cells. This chapter is focused on the synthetic and post-synthesis aspects that can affect the TiO2 mesoporous structure and consequently the MTTF properties. In particular, after a brief summary of TiO2 properties, all experimental conditions to prepare MTTFs are reviewed as well as the main characterization techniques employed to study their physicochemical and photocatalytic properties. An overview of the main applications of MTTFs is also proposed, mainly focused on the use of MTTFs in sensors and LIBs.
- mesoporous TiO2 thin films
- X-ray diffraction
- rutile and brookite
Crystalline mesoporous metal oxide materials are potential candidates for a number of applications, such as battery electrodes , fuel cells [2, 3], optoelectronic devices , photovoltaic devices , and photocatalysis , due to their variable oxidation states and unusual magnetic, electronic, and optical properties compared to silicates. In particular, titania-based mesoporous materials have been extensively investigated since titania is transparent in the visible region, nontoxically biocompatible, and photocorrosion-free and can be fabricated by relatively cheap methods. For these numerous properties, titania is employed for various applications in diverse scientific fields, ranging from self-cleaning coatings , lithium-ion batteries (LIBs) , photocatalysis , new-generation solar cells , and membrane  to antibacterial applications . However, to design efficient systems and devices for the above-cited uses, stable materials with a well-defined crystalline structure, highly controlled crystallite size and shape, as well as high available surface area and accessible pore networks able to ensure contact with catalytic substrates, polymers, or nanospecies are required . Although the early mesoporous materials were produced in the form of powders, some applications, such as membranes, low-dielectric-constant interlayers, optical sensors, and optoelectronic devices, require ultralow-k dielectrics and low-refractive-index materials with a good mechanical stability and of hydrophobic nature. These requirements led to the preparation of mesoporous thin films [14, 15, 16]. After a brief description of the different TiO2 polymorphs and properties, the present chapter will therefore be dedicated to mesoporous TiO2 thin films (MTTFs), reviewing the different preparation methods reported throughout the literature, the main characterization techniques employed to study the structure and the morphology of the prepared thin films, and finally the description of their most successful applications.
2. Intrinsic properties of TiO2
Titanium belongs to the IVA group of elements and, as many other metals, is able to form a wide range of oxides. Titanium(IV) dioxide (titania) exists in three common crystalline phases: rutile, which is the thermodynamically stable phase, and the metastable phases anatase and brookite. Anatase and rutile have more extensive applications because they are more stable than brookite (Figure 1). In all three forms, titanium (Ti4+) atoms are coordinated to six oxygen (O2−) atoms, forming “TiO6” octahedra. Anatase and rutile have a tetragonal geometry, differently from brookite, which has an orthorhombic geometry. In rutile, the “TiO6” octahedron is slightly distorted, while anatase consists of strongly distorted octahedral units. In the rutile structure, each octahedron is surrounded by ten close octahedrons; instead, in the anatase polymorph, each octahedron is in contact with eight neighbors. Interatomic distances also differ between the polymorphs. For anatase, with respect to rutile, the Ti-Ti distances are lengthier and, instead, the Ti-O distances are shorter. These differences in lattice structures cause different mass densities and electronic band structures between the two forms of TiO2. Due to its intrinsic properties, the anatase phase is the most interesting one for applications.
|Molecular weight (g mol−1)||79.88|
|Melting point (°C)||1825|
|Boiling point (°C)||2500–3000|
|Refractive index ||2.52||2.72||2.63|
|Crystal structure [19, 20]||Tetragonal||Tetragonal||Orthorhombic|
|Lattice constant (Å)||a = b = 3784
c = 9515
|a = b = 4593
c = 2959
|a = 9184 b = 5447 c = 5145|
|Density (g cm3)||3.79||4.13||3.99|
Titania is an n-type semiconductor since, like other metal transition oxides, the oxygen vacancies represent the predominant defect type in TiO2. Indeed, every crystal has various structural defects; for example, point defects, which are empty sites (vacancies), where constituent atoms are missing within the structure and interstitial atoms occupy the space between the regular atomic sites. The point defects contribute to the electrical conductivity in two ways: they can provide ionization, and they can also move in response to an electric field producing an ionic current. An oxygen vacancy is formed by the transfer of an oxygen atom on a normal site to the gaseous state. These oxygen vacancies act as electron donors, so the material contains an excess of electrons resulting in an increase of the electrical conductivity.
TiO2 exhibits photocatalytic oxidation (PCO) and photoinduced superhydrophilicity (PSH) when it is illuminated with UV light, making TiO2 a good candidate for photocatalyst materials and self-cleaning surfaces in air.
The PCO property is activated by absorption of UV photons of energy greater than TiO2 bandgap energy. For anatase phase this energy is 3.2 eV; therefore, UV light (λ ≤ 387 nm) is required, while rutile phase has energy of 3.0 eV (λ = 400 nm). The absorption of a photon excites an electron to the conduction band (eCB −) generating a positive hole in the valence band (hVB +), so that photoexcitation produces electron-hole pairs.
The charge carriers can migrate to the catalyst surface and initiate redox reactions with adsorbates. The redox potential for hole in VB is +2.53 V, which is sufficiently oxidizing to overcome the binding energy of electron in OH− to form a hydroxyl radical from water. The hydroxyl radical can subsequently oxidize organic species with mineralization producing mineral salts, CO2, and H2O. Similarly, an electron in CB (E= −0.52 V) is sufficiently reductive to react with O2 to form O2•− (superoxide radical anion), which can react with H+ to produce hydroperoxide radical contributing to the degradation of organic molecules (Figure 2) . The main drawback in the use of titania as photocatalyst is its high electron-hole recombination rate, but several methods to improve photocatalytic activity by promoting separation of the electron-hole pair have been developed, such as doping and heterojunction coupling.
The PSH property consists in the alteration of the TiO2 wettability under UV irradiation and in the formation of a highly hydrophilic surface state. One possible explanation of the PSH property is that electrons reduce Ti(IV) cation sites in Ti(III) and holes oxidize O2− anions to molecular oxygen. The expulsion of O2 molecules creates surface vacancies on which water can adsorb as OH groups, giving to the TiO2 surface its superhydrophilic character. Indeed, when illuminated, titania surface exhibits amphiphilicity caused by the creation of alternating hydrophilic/hydrophobic domains. It was found that in the absence of UV illumination, the water contact angle for TiO2 was
3. Preparation of MTTFs
3.1. Synthetic aspects
TiO2 nanomaterials can be classified according to their shape and dimension: 0D nanomaterials refer to nearly spherical nanoparticles (quantum dots); 1D refers to nanowires, nanobelts, and nanorods; and 2D materials correspond to thin films, while 3D is used to indicate porous nanostructures.
Mesoporous thin films have very peculiar features, particularly high surface area, controlled porosity, high flexibility in composition, and surface design . For practical applications, mesoporous thin films must possess a number of general features: (i) they must be continuous and free of crack; (ii) crystalline walls are highly desirable in order to process into functional materials; and (iii) pores must be accessible, preferably from the film surface . As a matter of fact, unlike powder, the internal space of a mesoporous thin film may not be accessible unless there are pores opening at the surfaces .
Mesoporous materials can form various pore structures including hexagonal (
The first mesoporous thin films, which have been the object of extensive studies, were essentially silica-based and structure-directing agents, such as surfactants, were used for their synthesis. The formation mechanism of these materials involves the self-assembly of the templates in supramolecular structures, such as micelles, with the inorganic species associated to their hydrophilic portions. Simultaneously, the inorganic precursor undergoes hydrolysis and condensation reactions .
In general, the synthesis of mesoporous materials of transition metal oxides is more difficult than that of silica. A reason may be found in the fact that the hydrolysis and condensation reactions of transition metal ions are much faster (often hard to control due to the excessive rate) with respect to silicon-based precursors. Consequently, the inorganic precursor is prevented to effectively associate with the templates during condensation, and often mesoscopic disorder is obtained in the resulting material . This high reactivity of transition metal precursors, compared to silicates, is attributed to the lower electronegativity of the metal and to its ability to exhibit several coordination states, so that the coordination expansion occurs spontaneously upon reaction with water or other nucleophilic reagents . In order to minimize this problem, the precursor solution of Ti is often strongly acidic enough to suppress the hydrolysis and condensation reactions, so that the film material forms a liquid crystal-like state .
The synthetic approach adopted for mesoporous titania thin films (MTTFs) is often a combination between the sol-gel chemistry of an inorganic precursor and the self-assembly process of an organic template (evaporation-induced self-assembly (EISA)). The sol-gel process is a synthesis route which involves the preparation of a “sol” and the subsequent gelation upon the solvent removal. A “sol” consists of a liquid with colloidal particles which are not dissolved, but do not agglomerate or sediment. A gel consists of a three-dimensional continuous network, which includes a liquid phase. Sol-gel syntheses can use either a metal-organic precursor or an inorganic precursor. In both cases, a dilute, usually an acidic solution of precursor and an amphiphilic organic template, is introduced in a volatile solvent containing a specific amount of water. The solution is spin- or dip-coated onto virtually any type of substrate. Upon evaporation of the organic solvent, the system self-organizes to form a periodic inorganic-organic composite. As a matter of fact, surfactants can spontaneously self-assemble in micelles when their concentration in a given solvent is higher than the critical micellar concentration (CMC). At higher concentration, micelles can assemble in liquid crystalline arrays. A thermal posttreatment is often used to proceed to the cross-linking of the inorganic framework together with the removal of the organic template, leading, in turn, to the formation of the mesoporous thin film. The two more often encountered pore structures are either a cubic lattice displaying three-dimensionally interconnected pores or channel-like pores arranged in a hexagonal array . Adjustment of the pore architecture of mesoporous materials strongly affects their properties, such as adsorption affinity toward guest molecules and photocatalytic properties of materials .
3.2. The TiO2 precursor candidates
Two classes of precursor for the preparation of mesoporous thin films can be used: (i) inorganic precursors and (ii) metal-organic precursors.
Inorganic precursors are salts that produce in water-solvated cations. The charge transfer from the bonding orbitals of water molecules to empty the orbitals of transition metals makes the water molecules more acidic. Different water complexes can form depending on the magnitude of this electron transfer. A condensation may take place via olation in which a hydroxyl bridge is formed between two metal centers. Olation occurs by a nucleophilic substitution (SN) where the hydroxyl group is the nucleophile and water is the leaving group; however, oxolation can also occur in which an oxo bridge is formed between two metal centers. Oxolation proceeds through two consecutive steps: the first step is a nucleophilic addition between hydroxy precursors, and the second step is water elimination .
Metal-organic precursors are usually metal alkoxides which are more reactive due to the presence of highly electronegative OR groups that stabilize the metal center in the highest oxidation state and render it more susceptible to nucleophilic attack. Hydrolysis and condensations occur by nucleophilic substitution involving a nucleophilic addition followed by a proton transfer and removal of protonated species (via olation or oxolation mechanisms).
In order to prepare MTTFs, titanium chloride (TiCl4), titanium alkoxides (mostly used tetraisopropoxide or tetraethoxide), and tetrabutyl titanate (TBT) are often used as titanium sources. Handling titanium chloride requires careful attention since it reacts violently with water and high humidity atmosphere in fast exothermic hydrolysis reactions. In this case, alcoholysis or hydrolysis processes release protons that acidify the solution, a necessary step to promote polymerization. Titanium alkoxides are highly reactive and highly hygroscopic precursors requiring to be handled within a moisture-free environment. To induce the polymerization of the inorganic framework, in the case of titanium alkoxides, addition of strong acid such as HCl required, or in alternative, the use of specific chelating agents. HCl is, however, the preferred choice for the production of MTTFs since its high volatility does not impede the efficiency of the evaporation-assisted deposition .
3.3. The templating agents
A variety of templates, such as alkyl phosphate anionic surfactants , quaternary ammonium cationic templates [32, 33], primary amines [34, 35], and poly(ethylene oxide)-based surfactants [29, 36], have been used to manipulate the pore structures of titania. Nonetheless, to direct and control the morphology of the inorganic framework for the preparation of mesoporous thin films, block copolymers seem to be the more frequently chosen templating agents since their self-assembly properties are driven by evaporation. However, the choice and combination between the Ti source and the templating agent are the crucial steps for the successful preparation of highly organized mesoporous TiO2 thin films . Hard- and soft-templating syntheses are the two most widely used methods to prepare these porous materials. A comprehensive description of both routes is given in the excellent book chapter written by Bonelli et al. , to which interested readers are referred.
The mostly employed soft-template-assisted route takes advantage of the self-assembly properties of organic ionic surfactants or neutral polymeric surfactants allowing to access to a diversity of supramolecular structures ranging from spherical micelles to hexagonal rods and lamellar liquid crystals. The formation of these supramolecular assemblies is governed by non-covalent weak interactions in particular hydrogen bonding, van der Waals forces, and electrostatic interactions. These assemblies are in situ used as soft templates allowing the tuning of the pore size and organization within the resulting porous materials. PEO (polyethylene oxide)-based templates have been extensively used in soft-template synthesis of mesoporous thin films. A study by Stucky  suggested that non-hydrolytic reactions take place in their low-water-content systems, allowing the oxide network to be built in a more controlled way. The proposed mechanism suggested that, once the metal center is trapped by the PEO or PPO fragments, nucleophilic reactions occur between the cationic immobilized species, leading to the formation of oligomers attached to the polymer chains. These oligomers are anchoring points for the growing inorganic phase .
PEO containing block copolymers are often chosen as the preferred templates since they can easily be produced in variable lengths, allowing in turn to generate differently shaped templates. Furthermore, PEO blocks are highly hydrophilic and favorably interact with Ti-oxo hydrophilic species in solution stabilizing upon drying the inorganic/organic interface at the shell of the formed micelles . Indeed, the relative size of the hydrophilic and hydrophobic domains is in great part responsible for the symmetry of the pore array. After mixing with surfactant followed by casting into thin films, this mixture turns into a liquid crystal-like state, which, in due course, self-assembles into mesostructures on aging under controlled temperature and humidity conditions .
The choice of the surfactant is also an influence on the type of mesostructure obtained. It was reported that while Brij 58 –(EO)20–C16H33– leads to an
In a recent study, Lee et al.  investigated the influence of the surfactant concentration and reported that a concentration equal to 9% wt for Brij 58 led to an
3.4. Depositions techniques
Two main deposition techniques have been widely used to prepare MTTFs, namely, spin-coating or dip-coating.
Spin-coating is a simple process for a rapid deposition of thin films onto flat substrates. The substrate to be covered is held by some rotatable fixture (often using vacuum to clamp the substrate into place), and the coating solution is spread onto the surface; the action of spinning causes the liquid to spin radially outward by the centrifugal force until the thin film is formed. The initial volume of the fluid distributed onto the rotating substrate and the delivery rate have both a minor effect onto the final film thickness. On the other hand, the resulting viscosity of the fluid to be deposited and the chosen ultimate rotation velocity are both parameters that mainly control the resulting thickness of the film. High angular speed produces thinner film. At a constant speed, the film thickness initially rapidly decreases, but this decrease slows at longer times. Typical coating thickness values are often below 1 μ when spin-coating is used.
Dip-coating is a technique based on the deposition of a wet liquid film by withdrawal of a substrate from a liquid coating medium. This process is very simple, flexible, and economically advantageous. Nevertheless, it is necessary to make provisions for cleanliness in order to obtain a high-quality deposition. Dip-coating is one of the few techniques that allow a simultaneous double-sided coating which may be regarded as an advantage especially in production of optical filters. Typically, film thickness obtained with dip-coating ranges from a few nanometers to 200 nm for oxide coatings. The thickness of the liquid film depends mainly on two factors: (i) the viscosity of the solution and (ii) the speed rate used during the substrate withdrawn from the solution.
In dip-coating, mesoscale ordering is achieved almost instantly after the covered substrate is withdrawn from the solution. Even if the self-assembled structure may form by spin-coating, the degree of ordering cannot be as high as in the case of dip-coating. This is probably due to the faster solvent evaporation occurring during spin-coating leading to a more viscous film deposit, which, in turn, makes the rearrangement of the titania and surfactant species in solution that is too sluggish to achieve a high degree of ordering in a short period of time .
3.5. Aging conditions
Several parameters such as temperature, aging period, and relative humidity have to be taken into account during the aging phase. Indeed, they all have important effects onto the final mesoporous structure in titania-based system. The evaporation process during the aging period after the spin- or dip-coating deposition plays a critical role not only for the formation of ordered porosity but also to direct the symmetry displayed by the pore arrays . During the last decade, many research groups have reported the effects of the aging conditions onto the mesostructure of titania thin films, and they confirmed that high humidity conditions are a requisite to access highly ordered mesostructure in titania thin films [29, 43, 44].
During the aging phase, the titania species and the surfactant molecules are in a liquid crystal-like state, and the mesoscopic ordering is achieved through the rearrangement of these species. The moisture inside the as-synthesized film materials plays a dual role. Kinetically, it is a lubricant to facilitate the rearrangement, and, thermodynamically, it is a structural ingredient to form the mesostructures. According to Lee et al. , it is important to keep the moisture of the as-synthesized film at a certain level (70%) until the full ordering is achieved. However, it has been observed that too prolonged treatments at humidity rates higher than 70% can be detrimental to the meso-ordering due to excessive water swelling . Ozin et al.  have reported that a high humidity level (
The aging temperature plays also an important role and is often chosen equal to 18°C, as reported in several studies [25, 27]. However, using ethanolic solutions of TiCl4 and F127 as surfactants, the mesostructure could be tuned from cubic to hexagonal by aging at 18C or 35°C, respectively .
In contrast to most studies, Oveisi et al.  recently reported that highly ordered mesostructures can be reached when the condensation reaction of metal alkoxides is occurring after the formation of the liquid crystal thin-film covering (after complete evaporation of solvents). This hypothesis was confirmed by working under non-usual aging conditions: lower temperature (−20°C) and lower humidity (20% RH).
3.6. Thermal posttreatment
After the aging phase, titania thin films are calcinated at high temperature. In this step, a sequence of transformations takes place: evaporation of the remaining solvent and acid (T < 200°C) which activates consolidation of the framework (this step is accompanied by an uniaxial shrinkage of the mesostructure along the z axis); template pyrolysis (T= 250–300°C), which generates the porosity; and crystallite nucleation and growth on walls (T > 300°C) .
Typically with mesoporous TiO2, the thermal posttreatment effectuated to convert the amorphous titania walls into crystalline walls usually results in the partial or total collapse of the mesoporous network [46, 47]. To circumvent such a drawback, several post-synthesis treatments have been developed mainly devoted to increase the thermal stability of the mesoporous TiO2. In particular, Cassiers et al.  reported that the posttreatment of an uncalcinated mesoporous titania powder with ammonia resulted in the formation of mesoporous crystalline titania with thermal stability up to 600°C. Sanchez and coworkers  claimed that the mesoporous anatase network could be retained with a porosity of 35% above 650°C by applying a specific post-synthesis delayed rapid crystallization (DRC) treatment. Another study demonstrates that the thermal stability of these crystalline films can be enhanced, up to 850°C, by posttreatment of the film in supercritical carbon dioxide (sc-CO2) with the presence of a small amount of precursor, such as tetramethoxysilane (TMOS) .
The thermal posttreatment has to be therefore carefully done and monitored especially if a specific TiO2 polymorph is sought. Most of the reported literature data available are dedicated to the preferential formation of anatase vs. the rutile polymorph. Although through the literature a large inhomogeneity in temperature range over the control of a selected polymorph is present and reflects the influence of secondary important factors such as the Ti precursor, the template, the deposition technique, and the experiment conditions used to form the TiO2 mesoporous material , most of the reports agree in the temperature range of 350–450°C to promote the exclusive crystallization of the anatase polymorph, while at higher temperature, the rutile phase transformation initiate [42, 52].
3.7. Alignment of the pores
As previously mentioned, the pores of the thin films must be accessible. Indeed, many potential applications of mesoporous thin films are relying on the accessibility of the pores from the surface. Owe to interfacial orientation preferences between the substrate and the material, the 2D hexagonal mesoporous thin films present their pore channels parallel to the surface . For this reason, many research groups have struggled to synthesize cubic mesoporous thin films, which present, regardless of the orientation, pore openings from their surfaces owe to their intrinsic geometry [44, 49, 50, 51, 52, 53]. Often, the solution resides in the optimization of the composition of the precursor solution performed by varying the ratios between quantity of surfactant and inorganic precursor [25, 54, 55]. In this context, Koganti et al.  showed that a modification of the substrate surface with a Pluronic block copolymer could lower the surface energy and induce the channels to tilt away from the substrate plane. Other groups have varied the aging temperature to form cubic structures . Lee et al.  reported the preparation of MTTFs with vertical pores using TiCl4 as source of titanium, F127 as surfactant, and by applying a specific heat treatment to direct the formation of the 3D network in a cubic phase. Zhou et al.  formed MTTFs with vertical pores, by calcination of the film at 450°C, so that the 3D hexagonal mesostructure was transformed to a grid-like mesostructure with quasi-perpendicular porosity through sintering-diffusion and pore merging along the c-axis. Richman et al.  used another approach: they synthesized mesoporous films through nanometer-scale epitaxy. They prepared a titania thin film with cubic symmetry and used it as a patterned substrate to direct a hexagonal top silica mesostructured with vertically oriented pore channels. Finally, Yamauchi et al. applied a very strong magnetic field (10T) in mesoporous silica films to align the channels, but the alignment was not homogeneously perfect, and such method remains rather impractical for large areas .
4. MTTF characterizations
Beyond the synthesis of MTTFs, it is necessary to deeply characterize their structure, in particular the type of pore arrays, the film thicknesses, the porosity (pore volume, pore size distribution, interconnectivity, and specific surface area), the surface topography, the chemical composition, and the crystallinity grade. The most commonly used characterization techniques for MTTFs are microscopies such as SEM, TEM, or AFM; spectroscopic techniques such as UV-Visible spectroscopy or ellipsometry (E), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy; X-ray absorption techniques like XANES and EXAFS; and powder or small-angle X-ray diffraction (XRD).
Spectroscopic ellipsometry (E) is an optical measurement technique based on the change in polarization occurring at many wavelengths. Ellipsometry is often highly sensitive to the properties of 1 nm to 10 μ thick films. The spectral response provides information about the sample properties, such as film thickness, surface conditions such as surface roughness (or the presence of surface contaminants), film thickness uniformity, anisotropy, and some important physical properties, such as refractive index . Fourier transform infrared spectroscopy (FTIR) is a fast, contactless, and nondestructive technique used to control the complete removal of the template and the presence of organic groups. Raman spectroscopy is a useful technique used to determine titania crystalline phase by analyzing the Ti-O-Ti vibrations in the 200–600 cm−1 region. XANES and EXAFS had been used to accurately probe and characterize the Ti(IV) environment in solution and within the final material.
Electron microscopies SEM and TEM are local techniques and should be used as complementary techniques to diffraction. Scanning electron microscopy (SEM) is perhaps the most widely employed thin film and coating characterization instrument. It shows the surface pore arrangement giving information on the MTTF surface morphology. Atomic force microscopy (AFM) provides imaging topography of the sample surface, so it is a local but a very useful technique. The use of a very sharp probe that is scanned across the thin-film surface allows to produce very high-resolution topographic images at the sub-nanometer scale. Many different imaging modes are available in AFM, such as contact mode imaging which works in the repulsive regime because the probe remains in contact with the sample at all times, noncontact mode which works in the attractive regime because the probe is very close to the sample surface without touching it, and tapping mode which works in both the regimes. Tapping mode AFM is the most used mode in the case of titania thin films, whereby a sharp tip (typically, a silicon or silicon nitride crystal) is oscillated above the surface of a sample. Specifically, tapping mode overcomes major problems associated with friction, adhesion, electrostatic forces, and other tip-sample-related issues (Figure 4).
X-ray diffraction in Bragg-Brentano geometry is a noncontact and nondestructive technique that provides information about crystallinity, phase, crystallite size, and orientation. Comparison of the obtained XRD profile in the medium and wide-angle region (from 2θ = 10 to 80°) with reference patterns allows to determine the crystalline phase of the MTTFs as well as possible preferential orientational order through the increase in intensity of specific reflection peaks. The XRD patterns of the three main crystalline phases of TiO2 are reported in Figure 5.
The analysis of XRD patterns must be carefully performed to correctly identify the crystalline phase of the MTTFs, especially when polymorphic forms are present within the film. This task is also often complicated by the presence of the wide halo of the amorphous substrate onto which the MTTF films have been deposited and/or the superposition of the reflection peaks relative to the eventual semicrystalline nature of the substrate used (e.g., when the TiO2 thin film is deposited on ITO). In Figure 6 an XRD pattern of a dense anatase TiO2 thin film deposited on a glass substrate is reported , clearly showing the broadening of the background level due to the halo generated by the amorphous support.
While there are no difficulties in discriminating between the anatase and the rutile phases since the first two reflection peaks are well separated (2θ = 25.28° for d101 of anatase vs. 2θ = 27.44° for d110 of rutile), spotting the difference between anatase and brookite might be more tricky. Only, the reflection peaks at 2θ = 30.81° relative to the d121 of the brookite phase or at 2θ = 62.57° relative to d204 of the anatase phase can help in making such a difference and/or recognize the presence of both the polymorphic forms in an XRD pattern .
A small-angle diffraction pattern, instead, could reveal the eventual presence of an ordered array of mesopores within the MTTFs, allowing the determination of its geometry, i.e., cubic lamellar or hexagonal [44, 62], as shown in Figure 7.
4.1. Evaluation of the photocatalyst activity
The activity of a photocatalytic titania mesoporous thin film can vary considerably depending on many factors, such as crystallinity, surface-to-volume ratio, pore accessibility, film thickness, and roughness. The photocatalytic activity of MTTFs can be determined evaluating the decomposition of stearic acid (SA), used as probe, under UV illumination (λ = 256 nm). This fatty acid is usually chosen for its high stability under UV illumination in the absence of suitable photocatalyst film. Furthermore, a thin layer of stearic acid can easily be deposited through dip- or spin-coating onto the film from a methanol or chloroform solution. SA provides a reasonably good model compound for solid films since it undergoes oxidative mineralization and this process can be monitored as a function of time :
SA decomposition can be demonstrated, for example, by FTIR spectroscopy through the monitoring of the asymmetric C-H stretching mode of the CH3 group at 2958 cm−1 and the asymmetric and symmetric C-H stretching modes of the CH2 group at 2923 and 2853 cm−1, respectively (Figure 8) .
The photocatalyst activity of titania can also be evaluated via photocatalytic oxidation of methylene blue (MB) under UV illumination. MB is often used as model for recalcitrant azo-dye pollutant, and, being a highly colored organic molecule, its photodecomposition can easily be detected in situ through spectrophotometric methods .
5. Applications of MTTFs
Mesoporous TiO2 thin films have attracted researchers among various fields of applications spanning from sensors, self-cleaning coatings, lithium-ion batteries (LIBs), photocatalysis, and new-generation solar cells. For interested readers, three comprehensive reviews, on the photocatalytic applications of mesoporous TiO2-based materials , on the use of TiO2-ordered materials for solar radiation applications , and on the self-cleaning applications of TiO2 , have recently been published. The present section will therefore only cover the applications of mesoporous TiO2 in sensor and LIB applications.
A good sensor requires high sensitivity, fast response, and good selectivity. Furthermore, low-cost materials and easy fabrication processes are important advantages for practical uses. Mesoporous titania thin films are excellent candidates for sensing applications because of the enhancement of the sensing signal due to the increased surface. Nevertheless, the MTTF sensitivity is also affected by the pore size and the carrier’s diffusion length. The sensing mechanism includes three steps: initially, TiO2 surface binds the analyte molecules; subsequently, a specific chemical or biochemical reaction takes place at the interface and gives rise to a chemical signal, converted, in the third step, into an electronic signal in turn amplified and detected. TiO2 sensors can detect several gases, including either oxidative gas (O2, NO2) or reductive gas (H2, CO, NH3). The working principle of these sensors relies on the changes of the electronic resistance, due to the interaction of TiO2 with the surrounding environment. The vacancies on TiO2 surface play an important role, since oxygen is adsorbed on these surface vacancies when the film is exposed to air forming anionic oxygen. When a gas molecule is in contact with a gas sensor based on MTTFs, first this molecule is physisorbed on TiO2 surface through van der Waals forces and dipole interactions; immediately after, the gas molecule is chemisorbed via a strong chemical bond formed between the gas and the surface atoms of TiO2. In this step, a charge transfer induced by the redox reaction between titania and the gas molecule occurs . When a reducing gas (e.g., CO) is detected by a chemical sensor, the following reaction takes place:
In this case, CO molecules react with adsorbed oxygen ions on the mesoporous film surface, which results, in turn, in an overall decrease of the electrical resistance of the metal oxide thin films. On the contrary, if a chemical sensor is exposed to an oxidation gas (e.g., NO2), the following oxidizing reaction may take place:
In this example, NO2 molecules cause a depletion of electrons from the TiO2 surface, which results in an increase of electrical resistance. The conductivity change can be easily transferred into resistance signal, which is the best-known sensor output signal.
Titania nanostructured materials are good candidates also for biosensing, because TiO2 is able to form coordination bonds with the amine and the carboxylic groups of biomolecules, such as enzymes, while maintaining the enzyme’s biocatalytic activity. Furthermore, TiO2 is characterized by high stability and biocompatibility. A biosensor is an analytical device, which converts a biological response into readable or quantified signal. Biosensors can be applied to analyze a variety of samples including body fluids, food samples, and cell cultures . The biosensing mechanism is based on a biochemical reaction. Typically in (bio-)electrochemistry, a measurable current (amperometric), a measurable potential, or a charge accumulation (potentiometric) will be generated upon the alteration of the conductive properties of a medium between electrodes when the sensing takes place.
Titania mesoporous thin films have been also used as sensors for
5.2. Lithium-ion batteries (LIBs)
Lithium-ion batteries (LIBs) are rechargeable batteries widely used in laptop, mobile phones, and electric vehicles. These batteries are characterized by high-energy density, low maintenance, little self-discharge, and no memory effect, which means that it is not necessary to completely discharge them before charging. In a conventional LIB cell, lithium metal oxide (e.g., LiCoO2) is used as cathode, while graphite is used as preferred anode. The two electrodes are separated by a porous membrane and soaked in a nonaqueous liquid electrolyte. During insertion (or intercalation), ions move into the electrode. During the reverse process, extraction (or de-intercalation), ions move back out. Upon charging, the lithium ions move from the cathode to enter the anode, while in the discharging phase, the reverse phenomenon takes place. A variety of metal oxides, in particular TiO2, have been investigated as potential electrode materials for LIBs. Compared with the currently commercialized graphite anode, these metal oxide materials have demonstrated various advantages, such as very high capacity, widespread availability, good stability, and environmental benignity. Generally, the reversible reaction between Li and TiO2 can be expressed by the following equation:
where x is the mole fraction of Li in TiO2. This redox reaction typically takes place at around 1.7 V vs. Li+/Li. Lithium ions reversibly insert/extract into/from the interstitial vacancies of the TiO2 framework, with a specific percentage depending on the TiO2 crystalline form and morphology. Specifically, anatase is probably the most electrochemically active form of TiO2 for this purpose . Moreover, it has been demonstrated that anatase exposing (001) facets exhibits efficient Li+ ion diffusion along this direction (c-axis) facilitating a fast lithium insertion/extraction .
TiO2 presents many advantages in its usage as anode material for LIBS, such as the low-volume expansion upon lithiation (<4%), good stability, and lack of lithium plating. However, TiO2 is also characterized by some limitations, including a limited Li+ ion diffusion, low capacity, and low electrical conductivity . A possibility to overcome these drawbacks is represented by the nanostructuration of TiO2, which provides a higher specific surface area and shorter diffusion pathways for electrons and Li+ ions, compared to the corresponding bulk materials . In this context, vertically oriented TiO2 nanotubes have been exploited as anode materials for LIBs by many groups [73, 74, 75]. However, the preparation of nanostructured TiO2 in the form of mesoporous thin films could offer some advantages, such as higher specific surface area and thinner walls than a TiO2 nanotube array . For example, Ortiz et al. prepared mesoporous titania thin films on titanium substrates, with a hexagonally ordered porous structure, and they tested these samples as anode materials for LIBs, reporting an improved electrochemical performance, without the necessity of additives to enhance the transport properties of the electrode . The enhanced electrochemical activity was ascribed to the higher area and volumetric capacity of these films due to the presence of the 3D-ordered mesostructure.
6. Conclusions and perspectives
Undeniable great progresses have been made in recent years in the design and synthesis of mesoporous TiO2 thin films featuring novel and well-designed structures and morphologies as well as to further explore and enhance their applications. Nevertheless, challenges are remaining in developing cheap, low toxic, and reproducible synthetic approaches for achieving an easy and precise control over the pore size, wall thickness, surface area, morphology, and crystallinity.
For optoelectronic applications, the main concern resides into the deposition of organized MTTFs onto semiconductive electrodes such as ITO or FTO keeping a homogenous disposition of the pores on the whole device electrode, and although some preliminary attempts have been made [52, 78], it remains a challenging issue owned to the wettability difference between ITO and Si wafers. Moreover, while small-sized devices have been tested, on large scale, difficulties are encountered to maintain such uniform orientation of the pores, especially in the case of vertically aligned pore arrays, the most suited geometry for efficient optoelectronic devices. For these reasons, scientists are investigating also the possibility of depositing nanotubes of TiO2 from anodization of sputtered titanium onto different substrates. The best results have been so far obtained for depositions performed onto quartz. However, in the case of semiconductive substrates, several problems are arising, the most important one being the easy loss of contact between the formed TiO2 nanotubes and the semiconductive layer, which will definitely require further and intense research activities to circumvent such a drawback.
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