Percentage of collapsed or severely damaged buildings according to number of storeys in Mexico City after the earthquake of 1985.
\r\n\t
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The titled of her thesis was 'Electrical Properties of Polystyrene”. She received her PhD from Physics Engineering at İstanbul Technical University in 2011. The title of the thesis was 'Phase Transitions in Composite Gels”. She worked as an Assistant Professor between 2011 and 2018, and she is currently working as an Assosciate Professor at Pîrî Reis University, Istanbul, Turkey. She has been engaged in various academic studies in the fields of composites and their mechanical, optical, electrical, and acoustic properties. She has authored more than 60 SCI articles, 92 proceedings in national and international journals, respectively. 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He became Associate Professor at Hacettepe University in 1979. \nHe visited ICTP Trieste, Italy as Visiting Scientist between June and August 1980. Between 1980 and 1981 he was a Visiting Scientist at the Technical University of Gdansk, Poland. \nHe worked as Visiting Professor at the Department of Chemistry, University of Toronto, Canada between 1981 and 1988. \nHe was appointed as full Professor at the Department of Physics, Istanbul Technical University, Turkey and worked there between 1988 and 2005. \nHe became an Elected Member of the Turkish Academy of Sciences (TÜBA) in January 1995. \nHe became the Dean of School of Arts and Sciences at the Istanbul Technical University in 1997. \nHe received the Science Award from the Scientific and Technological Research Council of Turkey (TÜBİTAK) in 1998. 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Churchill, Maja Dutour Sikirić, Božana Čolović and Helga Füredi Milhofer",coverURL:"https://cdn.intechopen.com/books/images_new/8812.jpg",editedByType:"Edited by",editors:[{id:"219335",title:"Dr.",name:"David",surname:"Churchill",slug:"david-churchill",fullName:"David Churchill"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"6851",title:"New Uses of Micro and Nanomaterials",subtitle:null,isOpenForSubmission:!1,hash:"49e0ab8961c52c159da40dd3ec039be0",slug:"new-uses-of-micro-and-nanomaterials",bookSignature:"Marcelo Rubén Pagnola, Jairo Useche Vivero and Andres Guillermo Marrugo",coverURL:"https://cdn.intechopen.com/books/images_new/6851.jpg",editedByType:"Edited by",editors:[{id:"112233",title:"Dr.Ing.",name:"Marcelo Rubén",surname:"Pagnola",slug:"marcelo-ruben-pagnola",fullName:"Marcelo Rubén Pagnola"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}}]},chapter:{item:{type:"chapter",id:"58374",title:"Mexico City after September 2017: Are We Building the Right City?",doi:"10.5772/intechopen.72499",slug:"mexico-city-after-september-2017-are-we-building-the-right-city-",body:'On September 19, 2017, a 7.1-magnitude earthquake shook Mexico City, which was known to happen because of the determinants of its territory, but it was not known when or the size of the disaster. Due to its evacuation protocols and the coincidence of the day commemorating 32 years of one of the most devastating earthquakes in this city (September 19, 1985), the citizenship mobilized nimbly to attend the emergency stage.
The open city was immediately occupied: streets, squares, gardens and street lane dividers; first as safe places to safeguard life as a reaction during the earthquake and then became centers for the collection of tools for rescuers, food and medicine collection, healthcare centers, psychological assistance to citizens with information on missing persons, centers for the collection of food for pets, veterinary care for rescue dogs and pets found, digital attention, but they also became a life opportunity as temporary shelters.
On the other side, in the post-disaster phase, one of the most surprising and astonishing situations was buildings that were damaged or collapsed by the earthquake, but which had been recently constructed. These had been built 9 months up to 12 years before, and others were still not inhabited. These housing buildings have been the result of the so-called real estate boom that has been changing on the one hand the verticality of the city and, on the other, the occupation of the territory, which has been monopolized without leaving sufficient reserves of open spaces; so it seems that the risk conditions have been being built.
For this reason, some questions arise as: How are these new urban forms being created in Mexico City? That is, are the policies for the growth of the City not being respected or are these the ones that are allowing this verticality with little public space? Are we creating safe and habitable cities or are we exchanging safety for built space at high costs? And, in this sense, is our public space inclusive or exclusive, so that in case of disaster is useful to citizens? Is 32 years sufficient to dilute the memory of the disaster and the preventive aspects: density and role of public space in the event of disaster?
The objective of this chapter is to analyze the condition of the public space in Mexico City in quantitative and qualitative terms, understanding public space as parks, public squares and walks. Hence, some public spaces are compared, evaluating the instruments, actions and public interventions for the creation and improvement of them.
To undertake this analysis, we take as case study the neighborhoods Granada and Ampliación Granada, both located in the Municipality of Miguel Hidalgo in Mexico City, that since the end of the first decade of this century have had a reconfiguration in their use from industrial land to residential use. A contrasting case is Polanco, an adjoining neighborhood of success since its creation in the early twentieth century, which supports the new real estate image of the mentioned neighborhoods.
In the recent reconfigured areas, there was an opportunity to create habitable public spaces, but especially the opportunity to enhance public space as an eventual resource in the emergency and reconstruction phase of the city—given its seismic nature and propensity to flood—but this was not done.
We depart from the hypothesis that the recomposition of territories of opportunity in Mexico City has been based on the adoption of trends supported by the economy, rather than in the needs of the population, resulting in exclusionary and uninhabitable public spaces in case of disaster.
In 1985, an 8.1-magnitude earthquake shook Mexico City leaving an official balance of more than 3000 fatalities and hundreds of buildings collapsed. As many factors came into play, we limit here to underline the relationship between the natural hazard (seismic waves) and the physical vulnerability reflected in one of the most characteristic morphological features of the city, its verticality and the existence and/or absence of public spaces as a support resource in the emergency and recovery phase.
According to Meli [1], the statistical analysis of damages after 1985 revealed that the collapse of buildings was not at random. Regardless of age, materials and structure of buildings, there were certain types of buildings that particularly collapsed, having in common the number of floors (see Table 1): buildings between 7 and 12 floors had more collapses than low-rise buildings. Such a finding made sense when the natural conditions of the soil were revised.
Number of storeys | Cases of damage (percentage of that range of buildings) |
---|---|
1–2 | 0.9 |
3–5 | 1.3 |
6–8 | 8.4 |
9–12 | 13.6 |
7–12 | 10.5 |
Percentage of collapsed or severely damaged buildings according to number of storeys in Mexico City after the earthquake of 1985.
Source: Meli [1], p. 135.
The area of the largest number of collapsed buildings had been the area of the former lake. That is, the lacustrine nature of Mexico City (it was founded on a lake which was later artificially dried out) impregnated the soil with certain characteristics, resulting in an area with three types of soils: (a) the area of the lake (where the lake was formerly located); (b) a transition zone (with part of hard and soft ground) and (c) a zone of hills (with a high resistance capacity) (see Figure 1).
Seismic zoning of Mexico City published after the September 2017 earthquake showing the damaged zones in 1985 and 2017. Source: Own elaboration based on the official map of seismic zoning (
The seismic waves that affected Mexico City in 1985 were produced in the coast of the State of Michoacán and traveled 400 km, but upon arriving in Mexico City and coming into contact with the clay soil area, the oscillation period of the waves was amplified. After the earthquake of 1985, the studies carried out on the collapse of the buildings revealed that the causes of this collapse were not so much a function of the age of the construction and the type of structure, but of the height itself due to a natural phenomenon known as “resonance” [1, 2], which causes the seismic movement to be amplified due to the coincidence of the frequency of vibration of the ground with that of the building. By matching the periods of oscillation of ground and buildings, the waves were amplified (reinforced), resulting in inertial forces that ended up causing the collapse of buildings of certain heights.
As a consequence of this phenomenon, the construction regulations in Mexico City were modified, making sure that the buildings were calculated considering the oscillation periods depending on the type of soil. When deciding the number of levels of the buildings (with a more or less constant period of oscillation per floor), this number of floors and its corresponding period of oscillation should not coincide with the period of oscillation of the soil in that area to avoid the phenomenon of resonance.
On the other hand, the structure of the building should be sufficiently “flexible” and “ductile” enough to dissipate the seismic energy (thereby making the building less vulnerable). If high-rise buildings were built in a soft ground, engineering design should ensure that energy dissipates—with the help of seismic dampers for example—before the higher floors begin to oscillate, a fact that was achieved in the buildings that could afford this technology.
The earthquake on September 19, 2017 of 7.1 degrees, −which caused 228 fatalities and the collapse of 38 buildings1, brought more elements and hypothesis to be added about the damage to occur. One of the points of discussion and analysis was that the most impacted area was not the one of the former lake as it was in 1985. On this time, although the earthquake was of lesser magnitude, the epicenter was located closer to Mexico City (120 km away), causing the amplification of the waves not in the area of the lake but in the area of transition, causing the collapse of buildings from four to seven levels, thus revealing “a complex pattern of movement and very variable in the space [3]. To the latter, it should be added the question about the correct application of land use zoning and dubious authorizations for the construction of buildings for residential use, since many of the collapsed and damaged buildings were just beginning their useful life (see Table 2).
Municipality/address | Number of storeys | Approximated time of being inhabited | Type of damage | Explicative hypothesis of the damage |
---|---|---|---|---|
Benito Juarez/General Emiliano Zapata 56 | 7 | 9 months | The back part of the building collapsed | Corruption in the process of land use permission and the number of storeys was higher than the authorized |
Benito Juárez/Bretaña 90 | 7 | 4 months | One of the towers collapsed and the other was severely damaged | Two seven-storey towers were built above old existent buildings (one with more than 50 years old). The number of storeys was higher than the authorized |
Benito Juárez/Calzada de Tlalpan 1234 | 10 | 11 months (departments still on sale) | Partial damages and cracks | It was built with low quality construction materials and the number of storeys was higher than the authorized |
Benito Juárez/Benito Juárez 29 | 6 | 4 years | Partial damages, collapse of roofs and balconies, cracks in the walls | It was built with low quality construction materials and the number of storeys was higher than the authorized |
Benito Juárez/Calzada de Tlalpan 550 | 17 | 5 years | Severe fractures in the building and cracks in the walls. | Failure to comply with the buildings regulations. The number of storeys was higher than the authorized |
Benito Juárez/Eje Central 521 | 8 | Departments were not sill inhabited. | Sever fractures in the building | Failure to comply with the buildings regulations. The number of storeys was higher than the authorized |
Gustavo A. Madero/Insurgentes 1260 | 12 | 2 years | Visible cracks | It was built with low quality construction materials and the number of storeys was higher than the authorized |
Cuauhtémoc/San Antonio Abad 66 | 11 | 2 years | Severe fractures in the building and cracks in the walls | It was built with low quality construction materials and the number of storeys was higher than the authorized |
Residential use buildings damaged or collapsed during the earthquake of September 19, 2017 in Mexico City.
Source:
On the other hand, public space played again a fundamental role both in the emergency phase and in the reconstruction stage. It is no coincidence that the spaces that were used in 1985 and 2017 correspond to projects where public space was, from the beginning, the most important component. An example of this balance between housing and public space is the Colonia Hipódromo Condesa, built in 1926 and designed by the architect José Luis Cuevas Pietrasanta (see Figure 2). The land was an old racecourse and the architect simply continued with its original shape giving a radial structure and at the center a large park and a green belt. Despite the densification that this area has been subject to, public space remains as an invaluable resource at the time of the emergency. In September 2017, this space was used to organize search and rescue activities, medical service, psychological care, pet care and collection of donations (food, tools, etc.). At the same time, other damaged areas of the city and recent real estate development projects lacked these spaces, making especially difficult the moment of evacuation (see Figure 3). The configuration of such new projects is the combination of several factors and conditions described below.
España Park plan (top left); process of verticalization 1932–2016 (at the center) and the use of the park during the earthquake of September 2017 (bottom). Image of damages (top right). Photos by the authors. Own drawings based on aerial photographs from Fondo Aerofotográfico Acervo Histórico Fundación ICA.
Collapsed buildings in Mexico City in the September 2017 earthquake. Despite the density of the buildings, the absence of public space in the surroundings is evident. Photo: Rosa Lilia Pedraza Vázquez.
In the case of Mexico City, the last decades of the twentieth century brought a change in public policies and a depopulation of the central parts, especially due to the process of deindustrialization and the earthquake of 1985. This meant a reinvention of the city for this century, through standards that call for a redensification and the opportunity to occupy spaces that were attractive to the private sector during the first decade. This meant that the city exceeded its limits, gentrifying spaces and consequently producing poorly rehabilitated residual public spaces or the creation of reduced spaces.
The instrument for urban development policies called “Bando Dos,” proposed to redensify the city with the specific objective of ordering the urban growth of Mexico City, preventing the construction of more housing in the outskirts of the city. The instrument was presented on December 7, 2000 by the then head of government (Andrés Manuel López Obrador). It had different objectives for the ordering of Mexico City, such as: to stop disordered growth; to safeguard the preservation of soil of the then Federal District (now Mexico City DOF ), preventing the growth of the urban areas and thus avoiding covering the recharge zones of aquifers. It was determined that the districts that had suffered considerable depopulation were mainly four: Cuauhtémoc, Benito Juárez, Miguel Hidalgo and Venustiano Carranza, all located in the central area of the city. It was also assessed which had been disorderly populated, predominating the south and east. It was determined that there is little infrastructure in the city for a strong real estate development [5].
Among the policies implemented was the promotion of population growth toward the districts of Benito Juárez, Cuauhtémoc, Miguel Hidalgo and Venustiano Carranza to take advantage of the infrastructure and services that are currently underutilized, and the construction of housing for the lower income classes [5]. However, in these central districts, such as Benito Juárez, the project did not work as expected. At first, there was a real estate boom, but if it was not successful it was because of the high cost of housing and the poor infrastructure. In different neighbors, there was a wild transformation of the city landscape by cutting down trees and constructing big buildings: where there had been houses for six to eight people, now there appeared buildings with eight to ten floors for many families. In these new buildings, however, not all apartments were sold.
As a part of the first consequences, in 2010, the government of the Federal District at the time, together with the Ministry of Social Development (SEDESOL), the National Council of State Housing Entities (CONOREVI), The Autonomous University of Mexico (UNAM), the Housing Fund of the Institute of Security and Social Services for State Workers (FOVISSSTE), the National Workers Housing Fund Institute (INFONAVIT) and the Federal Mortgage Society (SHF), published the Guide for residential redensification in the internal city [6], in which they present a methodology to identify redensification scenarios, as well as instruments to favor it so as to join the smart city growth system and position Mexico in the international environment in this respect, for which they are planned to address a series of issues, such as increase in the costs of displacements of the inhabitants of said areas; greater consumption of fuels and greater production of emissions polluting the atmosphere; loss of preservation areas, aquifer recharge zones and agricultural production areas; higher costs of urbanization that represent a significant burden for local governments and social and economic segregation of urban space [6].
The approximate 10-year delay for this guide to be published—to take measures on matters of redensification policies—caused for constructions to be carried out during that time in different zones that lack integration with the social fabric, for it has been seen that elite zones are created, which keeps the population dissatisfied and afraid of being displaced. There was an unlimited number of claims derived from the implementation of the Bando 2, caused by the fear of the modification of the environment, decrease of the quality of life, of safety, of the value of real estate, feelings of dispossession or feelings of injustice, for decisions were made that affected the territory without the main interested parties being informed, taken into account or heard, a loss of confidence of the population in the authorities and experts that promoted the project, above all when there is a tradition of local organization and mobilization, risk perception and a feeling of uncertainty. The technical and scientific studies that validated the project were questioned [7].
With the economic opening abroad with the 1988 free trade agreement, there was a shift in the activities of the manufacturing industry that caused a process of deindustrialization. The industries were moved toward the outskirts of the city or even toward other territories [8]. This process is not yet finished. There are still areas of the city with disappearing industries. With this movement and the change toward a tertiary economy, the reconfiguration of the city was affected on one hand due to the opportunity of land within the city, seized by the real estate power, and on the other hand due to the change of policies that did not work as expected. In Mexico City, some of the areas that have passed through the process of deindustrialization at the end of the twentieth century were the municipalities (delegaciones) Benito Juárez, Cuauhtémoc, Miguel Hidalgo, Venustiano Carranza, as well as Azcapotzalco and Gustavo A. Madero [9]. In recent years, the mass production of housing has captured some of these areas, leading them to transformations that are a result of the inclusion-exclusion struggle that is reflected in the absent public space. An example of this is the case of the neighborhoods Granada and Ampliación Granada, in the Miguel Hidalgo delegation, which has been a categorical place throughout History. From an economic point of view, we could say that it has gone through three sectors: agricultural, industrial and tertiary.
In 1920, the lands of the Hacienda de los Morales were divided, playing a significant role in the urbanization of the city of Mexico due to the fact that part of the space was used for the colonia Polanco assigned to upper middle housing, in which the neighborhood project of the first half of the twentieth century was based on public space. This was a key as it grew until it was divided into five sections, sharply contrasting the neighborhoods Granada and Ampliación Granada, which began to be industrially established without public spaces. The following were some of the factories in the place: the General Motors Factory in 1923; the Mexico glass factory in that same year; the Modelo Brewery and the General Popo in 1925; the Tabiques La Universal Factory, whose year of establishment is unknown; the Chrysler Factory in 1939 and thereafter until 1961; the Palmolive Factory; the Halaxtoc textile factory; Laminadora LMMSA; pharmaceutical industries; Factory in Lago Andrómaco Street; Bolt Factory; factories in lake Neuchatel; Furniture and Steel Factory and another Cotton factory [10].
In Mexico, there are various governmental instances responsible for intervening in or making public space such as The Department of Urban Development and Housing (SEDUVI), the Public Space Authority (AEP) or the different municipalities (former Delegaciones). However, when public space shows specific characteristics and values for which it has been cataloged as equity, the instances for intervening in it change or they are accompanied by certain strict guidelines for their regeneration, such as the INAH (National Institute for Anthropology and History), the INBA (National Institute for Fine Arts), the Historical Center Authority or the UNESCO, according to the case. Each one of the aforementioned instances intervenes in public space from different perspectives and with various actors. The Department of urban Development and Housing, for example, is responsible for designing policies applicable to the city, attempting for them to integrate society when acting and interacting with it, so as to transform the city in an inclusive manner. It creates the Programs of Delegations, Partial Programs and the Urban Development Program for the purpose of ordering the city in all its aspects: mobility, public space, housing, urban infrastructure, basic services, always with the idea of improving and positioning it as a safe city.
On the other hand, there is the Public Space Authority (AEP), which is a decentralized entity of the SEDUVI. It not only designs policies to apply them to urban space but also directly intervenes through the design of the space and the contracting and subcontracting of construction and design companies. Some of its programs and projects are as follows: Ecopark, Bajo puentes (underbridges), Pasos seguros (safe steps), publicidad exterior (advertising), Parques de Bolsillo (pocket parks) and Parques lineales (linear parks), among others. The AEP was created in 2008. It works on the various projects with different companies, for example, CTS Embarq with the Model street, GABANA engineering and GCB Construcciones y Servicios for the refurbishment of the street Torcuato Tasso, Proyecsa e Ingenieros, ANACE Construcciones, Grupo Q and B and Servicios integrados RUBE for the regeneration of the Alameda Central, Grupo Velasco, JM Constructora, Kassar Construcciones, 128 Arquitectura and Diseño Urbano para Espacios Públicos de Bolsillo, to mention a few.
With respect to the organization of the Historic Center of Mexico City, there is another decentralized entity called the Historic Center Authority, created in 2007, which proposes public policies for integration and promotes the refurbishment of public spaces located in this square. However, there are various actors that participate in the intervention and construction of public space. Even when the aforementioned entities are present, the participation of the citizens is already contemplated in almost the majority. Participating in the modifications of the urban environment means a social commitment more than a political one, but the action surpasses that which is social, political and economic.
Concerning the programs for public space in Mexico City, since the first decade of the 21st century, a series of urban projects were implemented by the Department of Urban Development and Housing (SEDUVI) and the Public Space Authority (AEP) to create or intervene in spaces with characteristics of deterioration and abandonment in some cases, including economic activity, which addressed the demands of the inhabitants. On the one hand, among the newly created public space projects were those that had a renewed design, with the minimum characteristics necessary to be used and enjoyed, such as low bridge projects, public pocket parks or bonds of friendship. On the other hand, are the projects of improvement and refurbishment of public spaces, in which there are improvements of spaces with an inclusive design, refurbishment of heritage spaces, pedestrianization and semi-pedestrianization of streets, illuminate your city program and ecoparq and refurbishments of monuments (see Table 3).
Newly created public space programs | Public space refurbishment programs | ||
---|---|---|---|
Public pocket parks | Design of social interaction, identity and economic activity, in remaining streets or spaces between buildings | Refurbishment of monuments | Its purpose is to rescue sculptural monuments, integrate them harmoniously into public space and recover them for interaction |
Bonds of friendship | Project in the development of cultural and political relationships between the two countries, through the donation of a sculpture placed in a newly created public space | Improvement of spaces with inclusive design | Improve pedestrian accessibility and the vehicular flow of the avenue that was inadequately designed for the intense pedestrian and automobile capacity |
Underbridges | This seeks to rescue abandoned or under-used public spaces, providing them infrastructure with high technical specifications to address the basic needs of the population, including spaces for commerce. | Illuminate your City Program | This unifies public lighting in primary and secondary roads to prevent the “zebra effect” from being produced, which is a phenomenon that creates variations in the intensity of the lighting of the streets |
Pedestrianization and semi-pedestrianization | Consolidate the pedestrian section of Public space of the Historic Center, promote sustainable mobility, optimize vehicular and pedestrian travel times, provide universal accessibility and optimize the heritage value of the area | Ecoparq | Recovery of public spaces through the installation of parking meters. This improves the mobility of the city |
Mobile park | Spaces assembled in trailer parks, equipped with game tables for children, a rest area, green areas, with natural vegetation and chairs called Parkes. These are placed in spaces that are generally used as parking lots | Refurbishment of heritage spaces | This complements the recovery of public spaces of the historic center, and additionally promotes the use of heritage spaces by optimizing their social function and spacing in benefit of the inhabitants |
Public space programs activated in the twenty-first century in Mexico City.
Source: SEDUVI.
By the start of the nineteenth century, the neighborhoods Granada and Ampliación Granada were changing their morphology, land use and population. The main change was the use of industrial land to residential land, which was attractive for real estate developers, who saw that its potential was supported by the urban image of the bordering sector Polanco. The two neighborhoods were given different informal names following the first interventions: Ampliación Polanco, Polanco Bis, Polanco II or the Nuevo Polanco; however, a series of contrasts have been seen between Polanco and the more recently built neighborhoods (Granada and Ampliación Granada). The most significant difference between said neighborhoods is the type of public space. In spite of the luxurious residential buildings that broke the specification of the Bando Dos and the norm 26 to create housing construction of social and popular interest on urban land and thereby redensify the zones of Mexico City in which there is a certain lack of population, they lost the opportunity to create housing with high quality public spaces (see Figure 4).
Urban transformations occurred in the twenty-first century in the territory of Ampliación Granada (expansion of Granada Neighborhood) and Granada Neighborhood in the period between 2001 and 2016. Source: Own elaboration based on Google Earth images from 2001 to 2007. Information from 2008 to 2016 is based on own field survey illustrated on Google Earth maps.
Due to the rapid and disordered growth in some areas of Mexico City, in 2013, the implementation of the norm that proposed the redensification was detained due to the abuse of the land use and its changes in the type of housing that should be implemented. However, in that same year, the Action through Cooperation System (SAC) was created, which is an instrument to manage and create policies that include public action, the intervention of the State, as well as the private party, that is, the participation of land owner companies to interact with each other in the interest of improving the city for which the Department of Urban Development and Housing (SEDUVI) is responsible.
One of the main characteristics of the area is that, at its pace of development, it has not only been activated housing for the elites, but commercial and service activity has also been developed, creating large office buildings or shopping centers with foreign brand stores. It has become common in the area for small shopping centers with convenience stores, mini-supers, restaurants, cafes and bars to be built in the lower part of housing buildings. The main problem was that there were no public spaces. However, far from providing a solution, due to the new constructions, trees have also had to be cut down, and trees have been changed for ornamental plants that represent consequences for the environment and deterioration in life quality. Thus, the place only has what are now the public spaces of the twenty-first century, such as pocket parks (three on the Cuernavaca Railroad), linear parks (that of the Cuernavaca Railroad) and low bridges (that of San Joaquín Avenue at the intersection with Moliere Street). On the opposite case we find wide parks and walkways in the area of Polanco (see Figure 5).
Public spaces in the neighborhoods of Granada (left at the top) and Polanco (left at the bottom) and their location. Source: Own elaboration.
With the assumption that it is essential for urban studies to include different approaches and to pay attention to the processes that transform the city, three views are taken into account for the understanding and analysis of the public space: 1. The habitability of public space, i.e. the human condition of public space. 2. The vision of inclusion regarding physical and social aspects of public space. 3. A vision in the globalized sense of the trends reflected in the space. At the end of the section, we present the main variables that could be the basis of a model to analyze the quality of public space in this city. This model is applied then to the above-mentioned case with the intention to compare the qualities of different public spaces of neighbor areas but produced in different historical periods.
When we talk about desirable public spaces, it could be seen as something subjective. Each human being thinks differently and according to their cultural characteristics, and to that extent, needs could vary. But even in the same country, the geographical or economic situation of each family would imply different demands. Something is very certain, however, and that is that we all have the need to co-inhabit. Each species on this planet has its natural habitat, fishes in the water, monkeys in the jungles and forests and lions in the savannahs. Habitat is the space where species are born, grow, reproduce and die, that is, the space on earth where they meet all their needs. Even when human beings are governed by this general rule, there are two fundamental elements that make them different from other species: the first and most important is that their habitat is not natural, but artificial; and secondly, apart from the physiological needs they need to satisfy, they are also creative beings [11].
Habitability is defined here as the capacity of a place to meet human needs [12], and although several authors consider that habitability refers only to the material and structural conditions of built spaces [13, 14, 15], without taking into account the social aspect in the outside [16], habitability for man would be as much within the architectural element as outside of it. Habitability goes beyond the door of the house to the street, toward the public space, where the social function, the community, comes into play, because it is there where “the expression and social identification of the others is built,” based on the expression and symbolic construction of the space [17], we leave our house behind to find a huge machinery concentrating the totality of our culture, but which also encapsulates international movements and trends we must incorporate during our journey.
The habitable public space is one that maintains a balance between the material and immaterial elements that intervene in the places of free access for all human beings, regardless of gender, religion, race or social class in order to satisfy the collective needs. Elements of habitability in the public space can be measured and diminished, as appropriate, taking into account the global and local transformations, and the determinants of type of settlement, but … How do we know if the public space is to a greater or lesser extent livable? For this, we consider three theories:
According to the theory of human need by Len Doyal and Ian Gough, cited by Reyes [18], needs are constructed socially and derived from the cultural environment. The authors take into account indices to measure the welfare between nations based on the needs of: appropriate health care, security, economic safety, clean water, adequate food, shelter as a mean of protection from the elements, relationships of recognition, safe working environments and relationships of recognition and belonging. The needs proposed by this theory are general and can be considered basic in different territories and different social groups. It should be taken into account, however, that the cultural and natural environment, the new technologies and even the policies for urban space make human requirements more complex and even different. This is the case of multicultural cities and the public space should regard it as a principle to meet the needs mentioned above.
Based on Max Neef’s theory about human needs, Reyes [18] analyzes the habitability of public space and combines criteria from existential and axiological categories, where existential categories focus on needs of being referred to personal or collective attributes, having, which contains the mechanisms and laws required, doing, as personal or collective actions, and being, in those spaces of action and construction of needs, satisfactors and economic goods; while the axiological categories cover the requirements of subsistence, protection, affection, understanding, participation, creation, identity and freedom. This refers us, in terms of the existential category, to social action that allows us to build axiological relations that give meaning to space.
Schiller’s theory, cited by Valladares et al. [19], is that of the qualities of the habitable public space where, from variables with a specific meaning and value, he measures the habitable public space, and the qualities space should cover for habitability are as follows: permeability to allow open connections in the urban fabric by measuring them according to the size of typical urban blocks and the elements that can limit them such as railroad tracks or other types of barriers; vitality as a characteristic of the spaces to be places of social interaction measured through the activity there; variety to encourage the complementary uses of the city, variation of typologies and uses; readability to facilitate social and spatial relations from the variable use and density of those who use the city; and robustness which allows an adequate combination and variety of uses at any time of the day with the ability to adapt the space.
According to the theories above, analysis of the habitable public space must be made taking into account physical elements and the design of the space and also considering the social elements of basis subsistence and even the more complex ones such as identity and legal duty. Therefore, we can examine the public space in two dimensions, where the different needs of humans can be encapsulated for the analysis of habitability in the public space, the first, the physical or material dimension, and the second, the intangible dimension, which goes from the social to the spiritual.
In the physical or material dimension, it is possible to concentrate the tangible and quantitative elements that are presented in the urban space, such as public water services, drainage and light, street furniture, transport infrastructure with subway systems, rapid transit busses, light rails, suburban trains, busses, collective transport, bicycle-taxis, bicycles, recreation areas, roads, streets, avenues, circuits, highways, communications infrastructure, public telephones, internet, police officers, security modules and road safety. It is important to mention that the city also has infrastructure for housing, education and health, among others. Similarly, in the immaterial dimension, which goes from the social to the spiritual, it would be the one where we find intangible elements such as the urban social identity, symbolic interactionism, perception of security, culture and social exchange.
The ‘inclusive’ public space is the place where activities and discussions are open to all. It is the place where authorities have the responsibility to guarantee the existence of a public space where people express their opinions, assert their claims and use it for their purposes [20]. However, if there is this concern about inclusion, it means that there are elements that make cities exclusionary so that inclusion-exclusion are studied in a dual way. To this end, two aspects of study are taken into account: 1. social inclusion by exclusion and 2. physical or design inclusion.
Ramírez Kuri and Ziccardi identify discriminatory practices in the labor market, such as access to goods and services; the weakening of social cohesion; luxury consumption activities that can be dissolved by making effective economic, social, cultural and sustainable rights which encourage the integration of the society with the city; informal activities and social conflicts [22].
And on the other hand, we have
In the design of inclusive public spaces, it is essential to take into account the physical components that foster social integration. From the perspective of Sergio Zermeño, the following are identified as components of exclusion: inaccessible primary and secondary roads; public spaces of richer classes appropriated by needy sectors; crossroads, roads, squares, parks, sidewalks, etc. which operate as frontiers, excess of surveillance and corridors watched by guards, police officers and cameras, and he also identifies social components such as high risk of violence and virtual walls [23].
Public-owned spaces must be able to adapt and survive to global transformations, which by their very contrasting nature absorb these changes in different ways, depending on their environments and the impacts public places are constantly having. Globalization, one of the strongest influences on a city in every sense, whether to its society, space or culture, reinvents them as great scenarios with strong economic and political rather than cultural and social alterations which irreversibly impact on the city’s inhabitants. In this sense, the overall composition of the public space is witnessed in two aspects: The public space as an alienable resource, in the sense of appropriation and privatization; and the public space affected by its constructions, in the sense of transformations.
It is evident that the production of public space in current cities has changed, the measures for its construction and even its activities are different, but, what is the cause? Although the causes can be many, there is still an ongoing search for the logic that gives us elements to understand the urban transformations that have been tried to be defined with names that are sometimes even difficult to pronounce, composed or decomposed words or more than one to name what is happening: redensification, urbanization, consolidation, gentrification, multiculturalism, and people participation, among others.
In Latin America, the study of processes such as gentrification is recent. Although it is true that the bases defining this concept are not new, the term itself is relatively young, invented by the British sociologist Ruth Glass [25], who observed the differences in social structure from the establishment of higher cost housing in specific areas of Central London, thus examining the invasion of middle and upper classes on working class neighborhoods, displacing and changing the social fabric.
Later, the sociologists Bruce London and John Palen in 1984 tried to explain gentrification by means of five theories that involve different aspects of the life in the city: the ecological-demographic theory, which refers to population and generational statistical aspects (baby boomers); the sociocultural theory, seen from the values, feelings, attitudes, ideas and beliefs of society; the political economic theory, which is based on two approaches: the traditional and the Marxist ones; the community network theory: the community lost and the community gained and finally the theory of social movements and the influence of counter movements [26].
On the other hand, in 1987, Neil Smith’s view proposed two theories to explain gentrification by observing the phenomenon from the economic and social point of view with the “production-side theory” and the “consumption-side theory.” These theories address the problem of the automobile, urban expansion, changes in lifestyles, depopulation of the city center, transport and pedestrian spaces, where human relations are diminished, but above all, he focuses his research on the results of increased employment in business districts. The interest of this geographer in these elements is an answer to the very elements that have caused the greatest problems in recent decades and have been part not only of gentrification but also of the processes of redensification, rehabilitation and the numberless patches made cities [27].
For gentrification to exist, it must be in a specific geographical space and it is considered to be happening when there is a process of investment and reinvestment of capital, when there are a series of transformations in the urban landscape due to the settlement of higher income social groups in these specific geographies and when there is a direct or indirect displacement of the existing social groups [28]. In the current debate, Michael Janoschka addresses gentrification with six points: 1. Neo-liberal policies of Gentrification, all types of public policies that establish an alliance with the capital that is invested in the city. 2. Supergeneration, when a place has been gentrified at two different historical moments. 3. Gentrification of new areas, industrial areas or ports where there is no gentrification by direct expulsion, but through all the indirect processes that occur around these neighborhoods. 4. New geographies of gentrification: spaces that have not previously been identified as spaces of gentrification, rural and suburban neighborhoods. 5. Symbolic gentrification: virtual sale and placement of new economies. 6. Resistance to gentrification: the congregation of the community to prevent the inflow of foreign capital [28]. Thus, the integration of different urban processes affects constructions and make up, renews and transforms the city and affects the dynamics, practices and design of urban spaces, which is a witness of the reinvention of the city in smaller scales.
With the history of the importance of public space in the City and the influence that urban interventions for luxury housing have had in recent years, as well as the recent public space programs, a Model is created to evaluate the quality of public space in terms of inclusion or exclusion, measured using the following variables and instruments applied in the area of study of Granada, Ampliación Granada and Polanco (see Table 4 and 5).
Variable | Importance of the variable in case of disaster | Instrument to collect the information |
---|---|---|
Plan or lines of public transportation (metro, bus, collective transport), plan for taxi sites, plan for bicycle sites, plan of virtual accessibility and crosstab plan | ||
It has been observed that | Land use plan (diversity of uses), residential land use plan, adjacent housing plan with real heights (2 levels, 3 levels, 5 levels, etc.), closed neighborhoods plan and Aerial Photography | |
A good level of | Heights of buildings, luminaries, terrestrial photography, aerial photography, lux meter and thermometer | |
Plans of the public spaces chosen with details of furniture, urban infrastructure plan of the space, adjacent urban infrastructure plan, terrestrial photography and aerial photography | ||
A positive | Photography, interviews, graphs and charts | |
Physical elements of | Security camera record plan, security module record plan, photographic record of human elements of security and interviews |
Variables and instruments for analyzing the quality of public space.
Source: Own elaboration.
No. | Type / Name of public space | Variables to analyze the quality of public space (quantitative value from 0 to 2) | |||||
---|---|---|---|---|---|---|---|
Accessibility | Balanced residential adjacency | Lighting, temperature and humidity | Urban furniture and infrastructure | Perception of urban space | Control | ||
Neighborhood Polanco | |||||||
1 | Lincoln Park | 2 | 1 | 2 | 2 | 1.5 | 0.5 |
2 | Las Américas Park | 1.5 | 2 | 2 | 1.5 | 2 | 2 |
3 | Uruguay Park | 2 | 0.5 | 1 | 1.5 | 1 | 1 |
4 | Antonio Machado Park | 1.5 | 1.5 | 2 | 1.5 | 1.5 | 1 |
5 | Lineal walking space Horacio | 1.5 | 1.5 | 2 | 1.5 | 2 | 1.5 |
6 | Lineal Park Ferrocarril de Cuernavaca | 1.5 | 0.5 | 0.5 | 0 | 1 | 0.5 |
7 | Pocket Park Juan Vázquez Mella | 0 | 0.5 | 1 | 0.5 | 0 | 0 |
8 | Pocket Park Masaryk and Mariano E. | 1 | 1 | 1 | 0 | 1 | 0.5 |
9 | Underbridge Masaryk and Periferico | 0 | 0 | 0 | 0 | 0 | 0 |
Neighborhoods Granada and Ampliación Granada | |||||||
10 | Pocket Park Ferrocarril de Cuernavaca | 1 | 1.5 | 0 | 1.5 | 0.5 | 1 |
11 | Pocket Park Moliere and Ferrocarril de C. | 1 | 0 | 0 | 0 | 0.5 | 1 |
12 | Lineal Park Ferrocarril de Cuernavaca | 0 | 0 | 0 | 1 | 0.5 | 0.5 |
13 | Pocket Park Ferrocarril (Rio San Joaquín) | 1 | 0.5 | 0 | 1.5 | 0.5 | 1 |
Analysis of the quality of public space in the Neighborhoods Polanco, Granada and Ampliación Granada. Source: Own elaboration.
For clear representation, the results are shown in a graph in a model of six concentric axes, forming two hexagons on the same axes. The perimeter of the hexagon is the coordinate zero, while the perimeter of the external hexagon is the coordinate +2 (a very inclusive space). The center of either of the two hexagons shall therefore represent a very high exclusion. In other words, the more covered the area of the hexagon is, the more inclusive that public space will be. The model was applied in all spaces of Polanco and Granadas (see Table 5 and Figure 6).
Comparative analysis of inclusion and exclusion characteristics of public spaces of the twentieth and twenty-first centuries in the Polanco and Granadas neighborhoods. Source: Own elaboration.
The main result was that in the neighborhood Granadas, although they had the determinants for their space to be recomposed through public spaces as the base of the project, this was done in an isolated manner, causing for the new pocket public spaces and linear parks determined by the economic tendencies to be places of exclusion, due to the fact that, for example:
A lack of accessibility is seen as there are no free internet networks in the public space and there is no bicycle parking as opposed to Polanco, in which there are. Although there is public transportation near the place, it has become exclusive due to the saturation of its use.
The residential adjacency is not balanced; although the land use is variable, the residential complexes in the area are very high and gated neighborhoods are dominant.
They show records of temperature, humidity and lighting that are not comfortable in shade, since in some cases they have little exposure to the sun, and the sun directly in others. All of them are highly humid and the records go from the lower to the upper limit, due to their low vegetation and the material of their environment.
In general, their urban furniture and infrastructure are normal, for they have benches. However, they do not have trash bins, much less fountains, sculptures or playgrounds. However, although they do not have their own luminaries, they have exercise machines.
An urban space is perceived in low conditions for use and enjoyment due to the previous determinants. They feel that it is unsafe and feel excluded from some parts by the physical barriers that are in the place, such as the cyclone wire fencing that divides it.
In general, personal control systems and surveillance cameras are excessive in some parts.
The implementation of urban phenomenon, such as redensification and gentrification, must be treated with more care and with plans of action for all. Failure to do so may cause:
A change of identity after a short time, the loss of neighborhood values, the displacement of neighbors, an abstract public space, a collective trademark image, insufficient urban equipment, vanishing of traditional trade, a lack of roads, scarce and exclusive public spaces, change of land use and excessive trash, among others.
The need to produce and intervene in the public space is going to be determined based on the type of urban growth of the city. In other words, if it is a disordered growth, the functioning of the public space will be directly affected and it will be socially weakened.
Interventions in the city in an unplanned manner can cause problems, for example, of communication in the social and spatial sense, of urban infrastructure and of insufficient public spaces.
The creation and intervention of public spaces in Mexico City of the twenty-first century have been governed by economic, political and social determinants immersed in a global world in search of publicly owned spaces that have inclusive characteristics.
On the other hand, the production of public spaces in this century has been resulting in residual or nook spaces that have undermined spaces that make them have a struggle between the inclusion-exclusion duality.
The results show that on the one hand, there is no quantitative similarity in the characteristics of public spaces, since they are dramatically reduced as a consequence of the lack of urban planning and the lack of political intention to create habitable public spaces for any case, but especially in case of disasters. That is to say, there is no urban design. On the other hand, qualitatively, we have not seen the concern that the spaces of new creation are inclusive and open to the general population with the intention of integration; urban projects predominate not to favor urban fabric, but to delimit territories.
In this sense, if we look at the role of public space in the earthquake of 1985 and the use in 2017, we can have the minimum indicators required to be taken into account in the adaptation of existing spaces or, where appropriate, in new spaces and that should be revalued in the institutional way of thinking and deciding on public space, mainly in the developing territories within Mexico City (see Figure 7).
Public spaces in Mexico City used to collect food and other emergency supplies right after the earthquake of September 19, 2017. Photos by the authors.
The authors would like to thank the reviewer for his valuable comments and suggestions of this manuscript. This article is a product of the research project IPN-SIP 20172147, funded by the Secretaría de Investigación y Posgrado del Instituto Politécnico Nacional, México.
Biosourced furan derivatives such as furfural, furfuryl alcohol, and hydroxymethyl furfural have been a focus of research in the last 10 to 15 years in several different application fields. This chapter deals with three topics: (1) fire-resistant furan-based foams, (2) the co-reaction to prepare wood panel bioadhesives of furanic materials with renewable and environmentally friendly materials, and (3) the preparation of hard plastics by reacting different natural and environmentally friendly renewable materials with furanics. A considerable level of research activity has been recorded in all these areas.
In this section we discuss the preparation of almost totally biobased tannin-furanic foams via expansion/blowing of the foam by chemical exothermal reactions caused by the heat generated under acid conditions of the self-condensation of furfuryl alcohol. Then, we discuss tannin-furanic foams in which isocyanate is added in the minority to the tannin-furanic mix. We also address the applicability of these foams to isocyanate-based polyurethane foam factories. Synthetic isocyanate-based polyurethane foams, even those using biopolyols, are not generally fire resistant unless some fire-retardant is used. Although the foams presented here are intrinsically fire resistant, like phenolic foams, but without their pollution characteristics.
Pure furanic foams are prepared by polycondensation of furfuryl alcohol under acid conditions [1, 2, 3]. Furanic foams are commonly used in foundries, because of their high resistance to heat and their relatively low cost, to bind the sand of molds or cores for casting engine heads or other kinds of steel tools [4, 5]. A study on the formation of pure furanic foams and the conservation and modification of their structure after carbonization is described in [6]. Ambient temperature catalysis of furfuryl alcohol with para-toluen sulphonic acid (pTSA) is the method used to prepare pure furanic foams. This research shows that the furfuryl group is the main repeating unit/motive from which derive the whole variety of structures observed in the polymer network formed (Figures 1 and 2), with structures shown in Figure 2 been present.
Structure of the linear furanic oligomers formed by the self-condensation of furfuryl alcohol.
Methylene and methylene ether bridges linking furanic nuclei in furanic oligomer structures found in linear oligomers from the self-condensation of furfuryl alcohol (FA). Top: reaction of the –CH2OH of FA with the furanic ring of a second FA molecule. Bottom: reaction of the –CH2OH of FA with the –CH2OH of another molecule of FA. Both reactions are obtained by elimination of water.
The same work [6] studied the type of structures that remain in a furanic foam after carbonization at 900°C. The research shows that many polynuclear aromatic hydrocarbons are present after carbonization (Figure 3). The average molecular weight of the fragments increases during carbonization because of the rearrangement of the furanic structures. Gasification during carbonization makes the signal of the pTSA catalyst derivates disappear by degrading to toluene and SO2 not surviving carbonization. However, certain furanic oligomers survive carbonization; these are mostly cyclic compounds with 4–6 or more furan rings. Thus, even if most of the constituents are transformed to more stable aromatic structures, some of the starting chemical species survive intact or partly transformed to carbonization even if most structures are converted to more stable aromatic structures (Figure 3). This shows the stability of some furanic oligomers that are not degraded or rearranged by carbonization. Molecular mechanics calculation of their relative energies appeared to confirm that these structures are cyclic furanic oligomers.
Example of rearranged structures formed during carbonization of furanic foams [
Tannin-furanic foams were mentioned for the first time in the literature in the early 1970s when Grey, Roux, Pizzi, and Ryder developed a foam formulation in South Africa [7]. This formulation had some severe problems and its performance was unacceptable. Moreover, industry did not appear to have any interest in the foam, as there was more focus on the dominant synthetic oil-derived foams at the time. In addition, the public opinion of the relative cost structure/performance relationship of these foams and of the biomaterials used also appeared to be unfavorable. The first tannin-furanic biofoam formulation that appeared to work well was published in the literature in 1994 by Meikleham and Pizzi [8]. Nonetheless, even then there was no interest in these materials; interest in them materialized only in the late 2000s [9].
Ambient temperature, self-blowing tannin-furanic foams were the first researched for a relatively long period, these being chemically foamed and set by the exothermic acid self-condensation of furfuryl alcohol (Figure 4). In earlier times, diethyl ether was used as a blowing agent [8]. The foams prepared with this early research were either catalyzed by an acid or a base but showed characteristics and performance comparable to synthetic phenolic foams. The liquid polymer phase was a tannin-formaldehyde resin. Foaming occurred by the forced evaporation of a physical blowing agent, while cross-linking rendered the foams dimensionally stable and with the goal target density. Acid-catalyzed foams expanded by evaporating the blowing agent due to the heat-surge agent produced by the self-condensation of furfuryl alcohol. Tannin-furan copolymers were so obtained. No toxic gasses on these foams’ carbonization were detected [9, 10]. This formulation worked, but when this research was again started up in the late 2000s several problems remained that needed to be solved. These were (1) the elimination of formaldehyde, used up to then to improve cross-linking and (2) the elimination of diethyl ether by substituting it with a less volatile and less dangerous blowing agent. In-depth characterization of these foams ensued. Different condensed tannins, namely, mimosa tannin bark extract, pine bark tannin, and quebracho tannin wood extract, were coupled to furfuryl alcohol as foam building blocks. Hydroxymethylated lignin up to a level of 20% by weight, and even smaller proportions of polyurethane, isocyanate [11], and industrial surfactant [9], were added successfully to modify these foams. Physical tests such as water absorption, compression resistance, direct flame behavior, and measure of foam cells’ dimensions were carried out [9]. These foams were chemically characterized by 13C-NMR analysis.
An example of a tannin-furanic rigid foam (left) and of its structure as observed at the scanning electron microscope (right).
Equally, these tannin-furanic foams’ resistance to fire and chemicals (e.g., resistance up to 1200°C and higher), absorption of and resistance to various liquids (e.g., ethanol, 33% sulphuric acid, and organic and mineral acids), permeability, thermal conductivity (e.g., between 0.024 and 0.044 W/m K), and mechanical (compressive and tensile) strength were tested. Boric acid and/or phosphoric acid were added to modify the foams’ structure while improving substantially their fire resistance (Figure 3). Rigid foams resisting well to strong acid, bases, and solvents were prepared with these early formulations [12]. High affinity for water, but limited affinity for organic solvents, was also put into evidence. Slightly anisotropic mechanical properties were measured. These foams were brittle in tension and compression, but their thermal conductivity and mechanical performance fully compared with those of synthetic phenolic foams. X-ray microtomography was also used to examine these early foams [13, 14, 15, 16]. This provided additional and useful information regarding their physical characteristics such as porosity, pore size distribution, proportion of open and closed cells, connectivity, and tortuosity.
These foams garnered considerable interest for their phenomenal fire resistance and hence their heat insulation potential [16]. Even when exposed to a flame 1200°C or higher, they do not burn for whatever length of time. The red color induced on the area where the flame is applied is automatically and immediately self-extinguishing on subtracting the flame. These tannin-furanic foams only begin to decompose at 3000°C. We will discuss the multiple uses for which they were tested later in the chapter. These include, for example, thermal insulating materials, fire-resistant filling for hollow doors and wood sandwich structures [17], green acoustic absorption materials [18], support for cut flowers [19] and hydroponic cultures [19], and flexible and rigid polyurethane-tannin-furanic mixed foams [20, 21].
The substitution of diethyl ether as a blowing agent with a much safer solvent was the first modification introduced in these tannin-furanic foams. The blowing agent chosen was n-pentane in synthetic phenolic foams. A necessary formulation rebalancing ensued, as pentane boils at a temperature higher than diethyl ether.
The first necessity was to eliminate formaldehyde from the formulation, formaldehyde having been declared unsuitable for sanitary reasons [22, 23]. With the elimination of formaldehyde, the new foams that were obtained presented lower density, thermal conductivity, hydrophilicity, and brittleness, and thus greater flexibility than the first generation of tannin-furanic foams. Formaldehyde was replaced with more furfuryl alcohol and a greater proportion of blowing agent, significantly improving the characteristics previously described [24, 25]. Table 1 shows the characteristics of these foams regarding their range of compressive strength and thermal conductivity as a function of their apparent density. Table 1 shows that as the apparent foam density increases the compressive strength sharply improves; however, the thermal conductivity increases, which is less acceptable as regards insulation.
Apparent density (g/cm3) | Compressive strength (MPa) | Thermal conductivity (W m−1 K−1) |
---|---|---|
0.016 | 0.03 | 0.024–0.030 |
0.040–0.080 | 0.12–0.45 | 0.040–0.050 |
0.10–1.30 | 0.65–1.10 | 0.050–0.060 |
Next, both formaldehyde and solvent (pentane) were eliminated, rendering the foams 98% “green.” Comparison of kinetic curves describing the simultaneously measured foams’ expansion, hardening, temperature, and pressure variation as a function of time illustrated the differences in process and foaming parameters as a function of time by the differences in formulation between the experimental and control foams and optimization of the foaming and hardening parameters involved [26, 27].
A first encouraging attempt to prepare elastic tannin-furanic foams occurred at this time [28]. In this first successful approach, flexible tannin-furanic foams, rather than the rigid ones prepared up to then, were obtained by the addition of glycerol as an external (unreacted) plasticizer. The choice of glycerol was dictated by its high boiling temperature, lack of evaporation, and lack of toxicity. Flexibility and spring-back of these experimental foams when subjected to a cyclic compression force followed by spring-back and compression again was quantified by both thermomechanical analysis at different temperatures as well as by compression/spring-back hysteresis cycle tests in a universal testing machine. Tannin-furanic foams with formaldehyde and no glycerol reached a stress plateau indicative of structure crushing. Tannin-furanic foams without both formaldehyde and glycerol become very fragile, brittle, and rigid just two months after their preparation. They also show structure crushing with ageing. Tannin-furanic foams with no formaldehyde but with glycerol remain instead equally and truly flexible in time [27, 28].
Furthermore, open cell foams obtained by the simultaneous co-reaction of condensed flavonoid tannins with an alkoxylated fatty amine and polymeric diphenylmethane isocyanate yielded highly flexible/elastic polyurethane foams [28]. Copolymerized amine/isocyanate/tannin oligomers were identified by 13C NMR and MALDI-TOF spectroscopy. In general, between 30% and 50% of natural tannins is added to the components used to polymerize the polyurethane. The characteristic of these new, partially biosourced polyurethanes is that the presence of the tannin slows down burning; some of them can be made flame self-extinguishing and if burning they neither flow nor sprinkle flaming material around, contrary to what occurs with normal polyurethanes. This limits transmitting the fire to other materials in the same environment. Cyclic compression tests were carried out showing that after 50 cycles foam recovery was more than 80%.
Hyperbranched poly (acylamide-ester) polyol synthesized reacting in one step succinic anhydride with diethanol amine was also used to modify tannin-furanic foams [29]. Glutaraldehyde was reacted with the hyperbranched poly (acylamide-ester) polyol to acetalize it, and the dendrimer so prepared was used to modify the tannin-based foams. It was found that the compression strength of the tannin-furanic foam improved by 36.6% with the addition of 3.5 wt% of acetalized poly (acylamide-ester) polyol without affecting the other foam properties.
Pine bark tannins are much more reactive than mimosa and quebracho tannins experimented with up to 2012. Pine bark tannin-furanic foams were prepared for the first time in 2013 [30, 31, 32, 33]. The tannin-furanic foam formulations underwent fundamental changes due to the greater pine tannin reactivity. This had to be implemented to coordinate foam hardening, reaction exotherm, and solvent blowing to obtain a rigid foam. This work was achieved using the FOAMAT, an equipment able to simultaneously monitor during foaming the variation of temperature, pressure, velocity, and dielectric polarization. This allowed for determining the function of the surfactant (castor oil ethoxylate) and the plasticizer (polyethylene glycol) during foam formation and thus to monitor their polymerization, expansion, hardening, and shrinkage. Foam density and its physical properties were found to be either surfactant- or plasticizer-controlled in this research work. Foams presenting a homogeneous microstructure were obtained with castor oil ethoxylate and polyethylene glycol. However, polyethylene glycol made the foams more elastic but with lower shrinkage. Pine tannin-furanic foams both with and without formaldehyde were also prepared and tested to determine their stress–strain curves, thermal conductivity, Young’s modulus, compression strength, densification, densification rate, and energy absorbed under compression. These pine tannin-furanic foams with formaldehyde had properties similar to mimosa tannin-furanic foams. At very low densities, mimosa foams are more mechanically resistant than pine foams. Mimosa foams with formaldehyde have a greater Young’s modulus less than 0.10 g cm−3 and a greater compressive strength less than 0.14 g cm−3 than pine tannin foams. Pine tannin-furanic foams without formaldehyde were more elastic and had lesser mechanical strength. However, on a comparative test, pine tannin foams are a better insulation material with an average thermal conductivity of 0.030 W/m/K for pine foam without formaldehyde, 0.034 W/m/K for pine foam with formaldehyde, and 0.037 W/m/K for mimosa tannin foam with formaldehyde at a density of 0.031 g cm−3.
The reformulation undertaken for these pine tannin-furanic foams allowed to develop such foams for the whole class of very reactive procyanidin tannins and not only different species of pine tannins [30, 31, 32, 33] such as spruce tannins [34, 35, 36, 37], and others. Pine tannin-furanic foams free of any aldehyde, and of formaldehyde, have also been developed, but their main drawback is their lower resistance to compression. Consequently, formaldehyde-free pine tannin-furanic rigid foams were successfully obtained by using non-volatile aldehydes [22, 23], namely glyoxal or glutaraldehyde, as alternative non-toxic hardeners [30, 31, 32]. All the open-cell pine tannin-furanic foams and mimosa−/quebracho-type tannin-furanic foams have also yielded medium and high frequencies (1000–4000 Hz) and good sound absorption/acoustic insulation with acoustic absorption coefficients of 0.85–0.97 [17]. They were better than polyurethane foams, melamine foams, fiberglass, and mineral wool acoustic insulations within this frequency range [17]. Their acoustic absorption coefficient decreased to 0.40–0.60 at lower frequencies of 250–500 Hz.
Tannin-furanic foams have shown typical characteristics comparable to synthetic commercial foams as light porous materials. Open-cell foams result in better sound absorption with thicker samples performing better in the medium frequency range.
Surface friability of tannin-furanic foams was a drawback for such potential applications, but this problem was also solved. A second main drawback is absorption of water within the foam itself. Both these drawbacks have been eliminated or at least minimized by adding to the formulation a small percentage of an oil-grafted tannin. The fatty chains introduced in the foam markedly decreased foam friability and increased water repellency in the foam’s body [38]. Also, adding small amounts of soy protein hydrolysate decreased surface friability of these foams [18].
Lightweight sandwich panels with a tannin-furanic foam core and wood veneers or hardboard thin panels as surfaces bonded on to the foam core were also prepared (Figure 5) [39, 40].
Foam cores sandwiched from top left to bottom right between surfaces formed of wood veneers, thick solid wood boards, thin plywood surfaces, thick and thin hardboard surfaces, and not sandwiched (just foam core).
As procyanidin tannins are the world’s predominant potential source of condensed tannins the development outlined for pine tannins-furanic foams are of considerable importance as they allow any future diffuse utilization of tannin foams anywhere.
The determinant parameters when designing new tannin-furanic foams have been clearly identified and codified [41]. Further progress in this field can be achieved by anyone who would care to follow these parameter guidelines.
Tannin-based carbon aerogel foams innovatively based on the ionic and radical autocondensation of tannins under alkaline conditions promoted by their reaction with silica and silicates [42, 43, 44, 45, 46] have also been prepared [47]. Upscaling to pilot plant level of the preparation of these types of foams has also been reported [48].
Recently, some more progress on the chemical analysis of this foam has also been made using Raman spectroscopy and attenuated total reflection–Fourier transform infrared spectroscopy (ATR–FTIR) approaches [49, 50]. Research groups have also been active in the preparation processes of these tannin-furanic foams [51, 52, 53] as well on the range of different applications possible, the most notable being in the medical field [21]. For example, tannin-furanic foams can be used in medicine to form a tannin-hydoxyapatite scaffold of stem cells for bone reconstruction without using any synthetic materials [21].
While phenolic foams can be clearly substituted to good effect with tannin-furanic foams, the market is particularly interested in the use of biobased polyurethane foams. This interesting situation came to the fore with an industrial plant trial for a plant where isocyanate had to be compulsorily used, otherwise the plant could not run. This was furthermore quite a sizeable polyurethane foam panels line (approx. 18 thousand tons/year). Mixed phenolic–polyurethane-type rigid foams were developed using tannin-furfuryl alcohol natural materials co-reacted with polymeric isocyanate in the proportions imposed by the limitations inherent to the continuous industrial plants for polyurethane foams and used in the plant trial [54]. Chemical analysis of the final foams identified several different copolymerization oligomers having been generated. Urethane linkages were generated by reaction of the isocyanate with two flavonoid tannin reactive sites, mainly at the flavonoid aliphatic hydroxygroup at C3, and less so on the phenolic hydroxygroups of the tannin flavonoid units. Urethane linkages also formed by isocyanate reaction with (1) glyoxal both alone or pre-reacted with the tannin, (2) the phenolsulfonic acid catalyst, and (3) with furfural. This latter reagent does react preferentially through formation of a methylene bridge with the A-ring of the flavonoid units of the tannin rather than reacting with the isocyanate to form urethanes [54]. All the materials appeared to have co-reacted to form a mix of urethane linkages and methylene bridges between all the main components used. Thus, the tannin, furfuryl alcohol, isocyanate, glyoxal, and even the phenolsulfonic acid catalyst formed a variety of mixed species linked by the two bridge types. Several mixed species constituted of 2, 3, and even 4 co-reacted different components were observed.
The more interesting result here, however, was that this approach was unusually different from the approach of oxypropylating tannins to render them more apt polyols for reaction with isocyanates [55, 56], hence using an additional reaction step. The unusual results [54] were especially interesting because they were obtained on an industrial plant line trial. Effectively, what occurred was that the glyoxal easily reacted with the tannin during the trial producing –OH groups much more easily approached by the isocyanate, thus forming a glyoxalated tannin polyurethane in a single step, which is a remarkably useful outcome [54]. Thus, species of the type shown in Figure 6 were present.
Example of mixed tannin polyurethanes obtained by the reaction of the isocyanate group on the glyoxal groups pre-reacted with flavonoid tannin units. The reaction can be carried out simultaneously as well, as used under industrial conditions.
The reaction of glyoxal with the tannin and then with isocyanates to form urethanes closely repeat the same reaction already used for wood adhesives but using the –CH2OH groups formed by the reaction of formaldehyde with tannins and with synthetic phenolic and amino resins [57, 58, 59]. As regards the fire resistance of these foams the preponderance of the tannin phenolic groups and furanic nuclei gives a certain level of fire resistance due to the inclusion of tannins in standard polyurethane formulations [20], but fire resistance is expected to be lower than the standard tannin-furanic foams described earlier in the chapter.
The potential of using tannin-furfuryl alcohol resin for biobased composites using vegetal fiber reinforcement has also been investigated [60, 61, 62]. Results showed that a mix of 54% furfuryl alcohol, 45% modified quebracho tannin extract, and 0.9% pTSA as a catalyst yields a resin with which one can prepare lightweight composites by working as bonding and solidifying matrix of a nonwoven flax fiber. The composite panels so prepared, once tested for tensile and flexural modulus and strength, water resistance, and thermo-degradation, presented good mechanical properties and a very short curing time in a hot press.
Tannin-furfuryl alcohol resins reacting under alkaline conditions to minimize self-condensation of furfuryl alcohol and force its reaction with tannins have proved to be another alternative for formaldehyde-free, environmentally friendly adhesives from renewable materials [63]. An indication of the reactivity of tannin with furfuryl alcohol to harden an adhesive composed of these two materials is given in Figures 7 and 8 where it is shown that the mixture of the two materials gels at pH levels of less than 2–2.5 and greater than 8–9 according to the reactivity of the tannin itself, with pine tannin being more reactive than mimosa tannin. At the acid pH, the reaction is both reaction of tannin with furfuryl alcohol as well as self-condensation of furfuryl alcohol, whereas under rather alkaline conditions furfuryl alcohol cannot really self-condense and thus is forced to react with the tannin. It must be pointed out that the reactivity of the tannin even with aldehydes progressively increases from pH 4 (minimum reactivity) towards a more acidic pH, with the tannin being progressively more reactive as the pH become progressively lower. The same is true under alkaline conditions where the reactivity of the tannin increases and gel time decreases as one progresses to higher pH. The resins were prepared by mixing 100 parts of tannin with 100 parts of water and reacting this with 50 and 75 parts of furfuryl alcohol. The results were monitored by gel time measurements and thermomechanical analysis (TMA). The laboratory particleboard bonded with this resin under standard laboratory conditions and the dry internal bond (IB) strength was tested according to European Norm EN 312, 1995. The results confirmed that tannin extracts and furfuryl alcohol react with each other and do cross-link in the total absence of formaldehyde (Table 2).
Gel time of mimosa tannin reacted with furfuryl alcohol at pH ranging from 1 to 11. The gel time at pH 3, 4, 5, and 8 cannot be attained [
Gel time of pine tannin reacted with furfuryl alcohol at pH ranging from 1 to 9. The gel time at pH 3, 4, and 5 cannot be attained [
Gel time (s) | TMA max MOE (MPa) | Board density (kg/m3) | IB strength (MPa) | |
---|---|---|---|---|
Mimosa tan + 100%FA, pH 11 | 260 | 1929 ± 81 | — | — |
Mimosa tan + 50%FA, pH 11 | 500 | 2177 ± 82 | — | — |
Mimosa tan + 100%FA, pH 10 | 400 | 2332 ± 112 | — | — |
Mimosa tan + 50%FA, pH 10 | 600 | 2401 ± 97 | 716 | 0.34 ± 0.02 |
Pine tannin + 50% FA, pH 8 | 150 | 2430 ± 100 | 697 | 0.35 ± 0.02 |
Pine tannin + 75%FA, pH 8 | 110 | 3034 ± 130 | 715 | 0.40 ± 0.02 |
Results for wood particleboard panels bonded with furanic-tannin-based wood adhesives.
MOE = modulus of elasticity; IB = internal bond.
For the mimosa tannin-furfuryl alcohol particleboards, the dry IB strength satisfies only marginally the requirements of the relevant European norm. However, for the pine tannin-furfuryl alcohol particleboards the dry IB strength satisfies the relevant EN 312 requirements.
Ten-ply and twenty-ply high continuous-type pressure paper laminates were prepared by impregnating filter paper with a mimosa-tannin solution mixed with furfuryl alcohol and a formurea concentrate [64]. Crosscut, abrasion resistance, and water vapor resistance measurements were done. The effect of bonding 10-ply paper laminates on plywood shear strength was also determined. The 10-ply paper laminates with mimosa tannin-furfuryl alcohol resin appeared to increase the plywood dry shear strength while reducing its absorption of water. When pressed at 140°C temperature at 120 kg cm2 pressure for 600 s, the 10-ply paper laminates gave the best appearance compared to other laminates.
The syntheses of difurfuryl diisocyanates [e.g., ethylidenebis (2,5-furandiylmethylene) diisocyanate (EDFI)] with formula shown in Figure 9 have been reported in the literature [65].
Structural formula of difurfuryl diisocyanate.
Difurfuryl diisocyanates (Figure 9) are structurally similar to diphenylmethane diisocyanate (MDI), hence they can be equally good adhesives for bonding wood composites. The EDFI adhesive is synthesized from biomass-derived chemicals, contrary to the petroleum-derived MDI. The mechanical performances of MDI- and EDFI-bonded aspen flakeboards were compared. Flakeboards bonded with MDI showed results only marginally better than those bonded with EDFI. The difference has been ascribed to EDFI having greater viscosity than MDI. This has been thought to have caused a less optimal distribution of EDFI during spraying on the wood flakes, causing the slight difference in strength properties. The dry IB strength values of EDFI-bonded flakeboards showed dry IB strengths of 0.97 MPa, hence a value significantly greater than the 0.41 MPa required by the American National Standards Institute for type-2 medium-density particleboard when compared to MDI yielding 1.13 MPa.
Furfuryl alcohol, a biosourced material, is widely used in the foundry industry and in adhesives as additives or modifiers. However, furanic resins have not been reported as being used alone as wood panel adhesives. Furfuryl alcohol-aldehyde resins were nonetheless recently prepared for wood panel adhesives by reacting furfuryl alcohol with three different aldehydes: formaldehyde, glyoxal, and glutaraldehyde [66]. p-Toluene sulfonic acid coupled with an acid self-neutralizing system to minimize any damage to the wood substrate was used as a resin hardener to prepare plywood panels and to determine their bonding performances. In this adhesive system, formaldehyde and glyoxal reacted with furfuryl alcohol and the resin so prepared had excellent performance. The reaction of glutaraldehyde with furfuryl alcohol instead seemed difficult, the furfuryl alcohol autocondensation predominating instead. The curing agent acidity greatly influences the resin bonding performance. The furfuryl alcohol-glyoxal resin showed a good bonding strength and water resistance greater than the standard requirements (≥0.7 MPa), even when using an acid self-neutralizing system as a hardener. This resin performed particularly well, considering that no formaldehyde was used.
Furfural and more recently hydroxymethyl furfural (HMF) are well-known upgraders of formaldehyde-based synthetic resins. An excellent review on this exists and the reader is addressed to it [67]. Even early literature and patents are known on this subject. The use of hydroxymethyl furfural is less known in synthetic resins where formaldehyde has been totally eliminated. Recent examples of the increased interest in HMF are the resins based on the coupling of glyoxal with HMF. Glyoxal is an aldehyde that is both nonvolatile and nontoxic. It can be used to substitute formaldehyde to prepare melamine-glyoxal (MG) resins for the wood industry. Due to the lower reactivity of glyoxal compared to formaldehyde, the MG resins performance is not as good as could be expected. Thus, 5-hydroxymethyl furfural (HMF) was used as a modifier to improve the properties of MG resins to prepare a hydroxymethyl furfural modified melamine-glyoxal (HMFMG) adhesive for bonding plywood [68]. The structure of the oligomers formed was determined along with the thermomechanical properties of the resins. The HMFMG resin presented a lower curing activation energy than the MG resin, yielding a much better bonded and water-resistant plywood.
Some fully biobased carbohydrate extracts from African trees have shown to release both hydroxymethyl furfural and furan 2,5-dialdehyde as hardeners [69, 70] during hot-pressing. Figure 10 shows an example of the reactions involved.
Schematic representation of the formation of the reactive species hydroxymethyl furfural and furan 2,5-dialdehyde from carbohydrate exudates of several African trees and their reaction to cross-link tannins.
This approach also fits with the adhesives based on the reaction of the reactive procyanidins of pine bark tannin with hydroxymethyl furfural [69] also yielding encouraging wood bonding results.
A 100% biosourced thermoset material based on condensed tannin-furfuryl alcohol thermoset resins has been used as the resin matrix of solid abrasive wheels by using pTSA as a catalyst [62, 71, 72, 73]. The system is based on two reactions: the reaction of furfuryl alcohol with the tannin and the acid-induced self-condensation of the furfuryl alcohol (Figure 11). The co-polymerization reactions were studied by 13C NMR and MALDI-ToF mass spectrometry; they are shown in Figure 11.
Schematic representation of the reaction of furfuryl alcohol with tannin to form hard thermoset plastics.
The 100% renewable bioresourced tannin–furanic thermosetting resin was found to have a glass transition temperature as high as 211°C, and a 95% weight loss temperature of 244°C and 240°C in nitrogen and in air atmosphere, respectively. The char yield is as high as 52%. Moreover, this new thermoset material showed excellent mechanical properties: a Brinell hardness of 23 HBS, which is higher than commercial acrylic, polyvinyl chloride and a little lower than that of solid (not foamed) polystyrene. The compressive break strength was found to be as high as 194.4 MPa, thus higher than that of filled phenolic resins and much higher than that of solid polystyrene and acetal resins (Table 3). Figure 12 shows its appearance and the repetition of the resin stress vs. strain curves.
Resin name | Breaking strength (MPa) | Young’s modulus (GPa) |
---|---|---|
Tannin–furanic plastic | 194.4 + 2.3 | 2.16 + 0.09 |
Solid Polystyrene | 106 | 3.88 |
Acetal resin | 100 | 3.28 |
Filled phenolic resin | 158 | 6.82 |
Breaking strength and Young’s modulus of tannin–furanic resin under compression.a
Note: the values of the other resins are cited from ASTM_D695-10.
Top: examples of rigid plastic specimens prepared by the reaction of tannin and furfuryl alcohol. Bottom: plot of the stress/strain curves of the tannin-furfuryl rigid plastic, the two curves showing its behavior repeatability.
This hard thermoset resin was produced by a simple process that is easily industrialized. Abrasive wheels held together with this resin bonding different mineral and organic abrasive powders were developed and characterized. The main abrasive powder used was aluminum trioxide Al2O3 of different grit levels (Figure 13). Hard nutshell powders were also tried but did not give sufficiently good results. These abrasive wheels showed excellent abrasiveness properties when compared to commercial abrasive wheels [71].
Left: example of angle grinder disc formed by a tannin-furfuryl rigid plastic matrix and aluminium oxide abrasive. Right, example of a steel tube cut with the same type of disc but with different abrasive grits [
Angle-grinder’s cutting and grinding discs based on this green resin were also used for bonding abrasive particles of aluminium trioxide of different sizes and of different grits level (Figure 13). These discs were characterized and showed excellent abrasiveness and cutting properties. Their mechanical resistance was found to be comparable to that of commercial grinding discs bonded with synthetic phenolic resins. They tolerated well the severe stresses induced on them at 11,000 revolutions per minute (rpm) by operation in an angle grinder when grinding or cutting steel [72].
The same hard resin was used as a resin matrix for automotive brake pads. These experimental automotive brake pads based on this green resin showed excellent braking properties and wear resistance when used in a real car under full-scale test conditions. Their mechanical resistance was found to be comparable to that of commercial automotive brake pads bonded with synthetic phenolic resins. They tolerated well the severe stresses induced by strong braking, such as emergency braking at 50 km/h (31 mph) until complete standstill and showed braking distances comparable or even shorter than commercial brake pads [73].
The same technology led to the preparation of both highly flexible films and strongly adhering non-scratch surface finishes by reacting partially aminated polyflavonoid tannins with furfuryl alcohol in the presence of plasticizers such as glycerol or polyethyleneimine. Chemical analysis showed partial amination of the tannin under the conditions used and even the formation of some –N〓 bridges between flavonoid units, although these were shown to be rare. Oligomers formed by the reaction of furfuryl alcohol with the flavonoid units and the simultaneous self-condensation of furfuryl alcohol were detected. Linear methylene–furanic chains were also found to be linked to flavonoid reactive sites. Side condensation reactions of furfuryl alcohol led to the formation of methylene ether bridges between furanic nuclei, followed by rearrangement to methylene bridges with liberation of formaldehyde. The latter reacted with both the flavonoid units and furan ring reactive sites to yield –CH2OH, –CH2+ groups and methylene bridges [74].
Furanic resins either alone or in combination with other renewable biosourced materials have come of age in fields where they were never considered before, either because of their dark color or high cost. Their biosourced, renewable materials-derived label has changed this perception in a world looking for materials that are not oil-derived. Thus, from their traditional industrial applications, namely, in foundry sand shell molds for metal casting, they are starting to be used other areas such as fire-resistant, thermally insulating, and sound absorbent foams, as wood panel adhesives, hard rigid plastics, resistant matrix resins for abrasive aggregates, and even for the formation of flexible films and non-scratch surface finishes. These biomaterials are attracting the interest of researchers to develop new uses for them. Thus, their future expansion to a variety of products appears now to be assured.
The LERMAB is supported by a grant of France’s Agence Nationale de la Recherche (ANR) in the ambit of the laboratory of excellence (LABEX) ARBRE.
The authors declare no conflict of interests.
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\\n\\nEditors can also have Conflicts of Interest. Editors are expected to maintain the highest standards of conduct, which are outlined in our Best Practice Guidelines (templates for Best Practice Guidelines). Among other obligations, it is essential that Editors make transparent declarations of any possible Conflicts of Interest that they might have.
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\\n\\nCONFLICT OF INTEREST - REVIEWER
\\n\\nAll Reviewers are required to declare possible Conflicts of Interest at the beginning of the evaluation process. If a Reviewer feels he or she might have any material, financial or any other conflict of interest with regards to the manuscript being reviewed, he or she is required to declare such concern and, if necessary, request exclusion from any further involvement in the evaluation process. A Reviewer's potential Conflicts of Interest are declared in the review report and presented to the Academic Editor, who then assesses whether or not the declared potential or actual Conflicts of Interest had, or could be perceived to have had, any significant impact on the review itself.
\\n\\nEXAMPLES OF CONFLICTS OF INTEREST:
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\\n\\nNON-FINANCIAL
\\n\\nAuthors are required to declare all potentially relevant non-financial, financial and material Conflicts of Interest that may have had an influence on their scientific work.
\\n\\nAcademic Editors and Reviewers are required to declare any non-financial, financial and material Conflicts of Interest that could influence their fair and balanced evaluation of manuscripts. If such conflict exists with regards to a submitted manuscript, Academic Editors and Reviewers should exclude themselves from handling it.
\\n\\nAll Authors, Academic Editors, and Reviewers are required to declare all possible financial and material Conflicts of Interest in the last five years, although it is advisable to declare less recent Conflicts of Interest as well.
\\n\\nEXAMPLES:
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\\n\\nAuthors should declare if they are board members of an organization that could benefit financially or materially from the publication of their work.
\\n\\nAcademic Editors should declare if they were coauthors or they have worked on the research project with the Author who has submitted a manuscript.
\\n\\nAcademic Editors should declare if the Author of a submitted manuscript is affiliated with the same department, faculty, institute, or company as they are.
\\n\\nPolicy last updated: 2016-06-09
\\n"}]'},components:[{type:"htmlEditorComponent",content:"In each instance of a possible Conflict of Interest, IntechOpen aims to disclose the situation in as transparent a way as possible in order to allow readers to judge whether a particular potential Conflict of Interest has influenced the Work of any individual Author, Editor, or Reviewer. IntechOpen takes all possible Conflicts of Interest into account during the review process and ensures maximum transparency in implementing its policies.
\n\nA Conflict of Interest is a situation in which a person's professional judgment may be influenced by a range of factors, including financial gain, material interest, or some other personal or professional interest. For IntechOpen as a publisher, it is essential that all possible Conflicts of Interest are avoided. Each contributor, whether an Author, Editor, or Reviewer, who suspects they may have a Conflict of Interest, is obliged to declare that concern in order to make the publisher and the readership aware of any potential influence on the work being undertaken.
\n\nA Conflict of Interest can be identified at different phases of the publishing process.
\n\nIntechOpen requires:
\n\nCONFLICT OF INTEREST - AUTHOR
\n\nAll Authors are obliged to declare every existing or potential Conflict of Interest, including financial or personal factors, as well as any relationship which could influence their scientific work. Authors must declare Conflicts of Interest at the time of manuscript submission, although they may exceptionally do so at any point during manuscript review. For jointly prepared manuscripts, the corresponding Author is obliged to declare potential Conflicts of Interest of any other Authors who have contributed to the manuscript.
\n\nCONFLICT OF INTEREST – ACADEMIC EDITOR
\n\nEditors can also have Conflicts of Interest. Editors are expected to maintain the highest standards of conduct, which are outlined in our Best Practice Guidelines (templates for Best Practice Guidelines). Among other obligations, it is essential that Editors make transparent declarations of any possible Conflicts of Interest that they might have.
\n\nAvoidance Measures for Academic Editors of Conflicts of Interest:
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\n\nIf a manuscript is submitted by an Author who is a member of an Academic Editor's family or is personally or professionally related to the Academic Editor in any way, either as a friend, colleague, student or mentor, the work will be handled by a different Academic Editor who is not in any way connected to the Author.
\n\nCONFLICT OF INTEREST - REVIEWER
\n\nAll Reviewers are required to declare possible Conflicts of Interest at the beginning of the evaluation process. If a Reviewer feels he or she might have any material, financial or any other conflict of interest with regards to the manuscript being reviewed, he or she is required to declare such concern and, if necessary, request exclusion from any further involvement in the evaluation process. A Reviewer's potential Conflicts of Interest are declared in the review report and presented to the Academic Editor, who then assesses whether or not the declared potential or actual Conflicts of Interest had, or could be perceived to have had, any significant impact on the review itself.
\n\nEXAMPLES OF CONFLICTS OF INTEREST:
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\n\nNON-FINANCIAL
\n\nAuthors are required to declare all potentially relevant non-financial, financial and material Conflicts of Interest that may have had an influence on their scientific work.
\n\nAcademic Editors and Reviewers are required to declare any non-financial, financial and material Conflicts of Interest that could influence their fair and balanced evaluation of manuscripts. If such conflict exists with regards to a submitted manuscript, Academic Editors and Reviewers should exclude themselves from handling it.
\n\nAll Authors, Academic Editors, and Reviewers are required to declare all possible financial and material Conflicts of Interest in the last five years, although it is advisable to declare less recent Conflicts of Interest as well.
\n\nEXAMPLES:
\n\nAuthors should declare if they were or they still are Academic Editors of the publications in which they wish to publish their work.
\n\nAuthors should declare if they are board members of an organization that could benefit financially or materially from the publication of their work.
\n\nAcademic Editors should declare if they were coauthors or they have worked on the research project with the Author who has submitted a manuscript.
\n\nAcademic Editors should declare if the Author of a submitted manuscript is affiliated with the same department, faculty, institute, or company as they are.
\n\nPolicy last updated: 2016-06-09
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Finally, this chapter would be helpful in the basic understanding of clinical PET radiopharmaceuticals for physicians or technologists.",book:{id:"7373",slug:"nuclear-medicine-physics",title:"Nuclear Medicine Physics",fullTitle:"Nuclear Medicine Physics"},signatures:"Ya-Yao Huang",authors:[{id:"247754",title:"Prof.",name:"Ya-Yao",middleName:null,surname:"Huang",slug:"ya-yao-huang",fullName:"Ya-Yao Huang"}]},{id:"48894",doi:"10.5772/60435",title:"Gamma Radiation as a Recycling Tool for Waste Materials Used in Concrete",slug:"gamma-radiation-as-a-recycling-tool-for-waste-materials-used-in-concrete",totalDownloads:2292,totalCrossrefCites:4,totalDimensionsCites:8,abstract:"Over the course of the last 50 years, a large number of major technological advances have contributed to the development of higher-strength, high-performance materials that provide excellent benefits. Nevertheless, in most cases, after a very short useful life, these products become waste material and contribute to environmental degradation. This situation has created an environmental crisis that has reached global proportions. In efforts to combat this issue and to promote sustainable development and reduce environmental pollution, some investigations have focused on recycling using innovative and clean technologies, such as gamma radiation, as an alternative to conventional mechanical and chemical recycling procedures. In this context, the reuse and recycling of waste materials and the use of gamma radiation are useful tools for improving the mechanical properties of concrete; for example, the compressive strength and modulus of elasticity are improved by the addition of waste particles and application of gamma radiation. In this chapter, we propose the use of gamma radiation as a method for modifying waste materials; for instance, polyethylene terephthalate plastic bottles, automotive tire rubber, and the cellulose in Tetra Pak containers, and their reuse to enhance the properties of concrete.",book:{id:"4604",slug:"evolution-of-ionizing-radiation-research",title:"Evolution of Ionizing Radiation Research",fullTitle:"Evolution of Ionizing Radiation Research"},signatures:"Gonzalo Martínez-Barrera, Liliana Ivette Ávila-Córdoba, Miguel\nMartínez-López, Eduardo Sadot Herrera-Sosa, Enrique Vigueras-\nSantiago, Carlos Eduardo Barrera-Díaz, Fernando Ureña-Nuñez and\nNelly González-Rivas",authors:[{id:"102080",title:"Dr.",name:"Gonzalo",middleName:null,surname:"Martínez-Barrera",slug:"gonzalo-martinez-barrera",fullName:"Gonzalo Martínez-Barrera"},{id:"110214",title:"Dr.",name:"Fernando",middleName:null,surname:"Ureña-Nuñez",slug:"fernando-urena-nunez",fullName:"Fernando Ureña-Nuñez"},{id:"177864",title:"Dr.",name:"Liliana Ivette",middleName:null,surname:"Ávila-Córdoba",slug:"liliana-ivette-avila-cordoba",fullName:"Liliana Ivette Ávila-Córdoba"},{id:"177865",title:"Dr.",name:"Miguel",middleName:null,surname:"Martínez-López",slug:"miguel-martinez-lopez",fullName:"Miguel Martínez-López"},{id:"177866",title:"Dr.",name:"Eduardo",middleName:null,surname:"Sadot Herrera-Sosa",slug:"eduardo-sadot-herrera-sosa",fullName:"Eduardo Sadot Herrera-Sosa"},{id:"177867",title:"Dr.",name:"Enrique",middleName:null,surname:"Vigueras-Santiago",slug:"enrique-vigueras-santiago",fullName:"Enrique Vigueras-Santiago"},{id:"177868",title:"Dr.",name:"Carlos Eduardo",middleName:null,surname:"Barrera-Díaz",slug:"carlos-eduardo-barrera-diaz",fullName:"Carlos Eduardo Barrera-Díaz"},{id:"177869",title:"Dr.",name:"Nelly",middleName:null,surname:"González-Rivas",slug:"nelly-gonzalez-rivas",fullName:"Nelly González-Rivas"}]},{id:"49039",doi:"10.5772/60846",title:"Physical and Radiobiological Evaluation of Radiotherapy Treatment Plan",slug:"physical-and-radiobiological-evaluation-of-radiotherapy-treatment-plan",totalDownloads:4389,totalCrossrefCites:5,totalDimensionsCites:8,abstract:"Radiation treatment planning plays an important role in modern radiation therapy; it could simulate to plan the geometric, radiobiological, and dosimetric aspects of the therapy using radiation transport simulations and optimization. In this chapter, we have reviewed several quantitative methods used for evaluating radiation treatment plans and discussed some important considering points. For the purpose of quantitative plan evaluation, we reviewed dosimetrical indexes like PITV, CI, TCI, HI, MHI, CN, COSI, and QF. Furthermore, radiobiological indexes like Niemierko’s EUD-based TCP and NTCP were included for the purpose of radiobiological outcome modeling. Additionally, we have reviewed dose tolerance for critical organs including RTOG clinical trial results, QUENTEC data, Emami data, and Milano clinical trial results. For the purpose of clinical evaluation of radiation-induced organ toxicity, we have reviewed RTOG and EORTC toxicity criteria. Several programs could help for the easy calculation and analysis of dosimetrical plan indexes and biological results. We have reviewed the recent trend in this field and proposed further clinical use of such programs. Along this line, we have proposed clinically optimized plan comparison protocols and indicated further directions of such studies.",book:{id:"4604",slug:"evolution-of-ionizing-radiation-research",title:"Evolution of Ionizing Radiation Research",fullTitle:"Evolution of Ionizing Radiation Research"},signatures:"Suk Lee, Yuan Jie Cao and Chul Yong Kim",authors:[{id:"96630",title:"Prof.",name:"Suk",middleName:null,surname:"Lee",slug:"suk-lee",fullName:"Suk Lee"},{id:"175104",title:"Prof.",name:"Chul Yong",middleName:null,surname:"Kim",slug:"chul-yong-kim",fullName:"Chul Yong Kim"},{id:"175234",title:"Dr.",name:"Yuan Jie",middleName:null,surname:"Cao",slug:"yuan-jie-cao",fullName:"Yuan Jie Cao"}]}],mostDownloadedChaptersLast30Days:[{id:"48796",title:"Ionizing Radiation Detectors",slug:"ionizing-radiation-detectors",totalDownloads:3890,totalCrossrefCites:1,totalDimensionsCites:4,abstract:"Ionizing radiation has always been present in the natural environment. However, this radiation is not easily detected and since it also possesses high ionizing power and penetration strength, it constitutes a risk to human health when it is found outside of its acceptable limits. The adverse effects of ionizing radiation on human health need to be systematically monitored in order to prevent damage, overexposure, or even death. The detection of the radiation depends on its particular interaction with a sensitive material, and different types of detectors, in different physical states (solid, liquid or gas), are used to measure selective types of ionizing radiation. New materials such as organic semiconductors, for instance, are being targeted for research and as potential candidates for new perspectives on ionizing radiation sensing.",book:{id:"4604",slug:"evolution-of-ionizing-radiation-research",title:"Evolution of Ionizing Radiation Research",fullTitle:"Evolution of Ionizing Radiation Research"},signatures:"Marcia Dutra R. 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PET and SPECT are developing scanning techniques that provides effective diagnostic tool to identify pathophysiology of diseased cells. In this chapter, we are exploring and explaining different mechanisms of radiopharmaceutical localization for imaging and therapeutic processes. 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In this chapter, we have reviewed several quantitative methods used for evaluating radiation treatment plans and discussed some important considering points. For the purpose of quantitative plan evaluation, we reviewed dosimetrical indexes like PITV, CI, TCI, HI, MHI, CN, COSI, and QF. Furthermore, radiobiological indexes like Niemierko’s EUD-based TCP and NTCP were included for the purpose of radiobiological outcome modeling. Additionally, we have reviewed dose tolerance for critical organs including RTOG clinical trial results, QUENTEC data, Emami data, and Milano clinical trial results. For the purpose of clinical evaluation of radiation-induced organ toxicity, we have reviewed RTOG and EORTC toxicity criteria. Several programs could help for the easy calculation and analysis of dosimetrical plan indexes and biological results. We have reviewed the recent trend in this field and proposed further clinical use of such programs. 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Noninvasive parathyroid imaging studies include 99mTc-sestamibi scintigraphy, ultrasonography, computed tomography scanning, magnetic resonance imaging, and positron emission tomography. There is a general consensus that the most sensitive and specific imaging modality, especially when it is combined with single-photon emission CT is the scintigraphy with 99mTc-sestamibi or 99mTc-tetrofosmin. 99mTc-sestamibi scintigraphy significantly increases the role of preoperative scintigraphy in patients with hyperparathyroidism and allows unilateral surgical approach with minimally invasive parathyroidectomy to be used. Generally, three protocols with the use of two radiopharmaceuticals, 99mTc-sestamibi or 99mTc-tetrofosmin, are most widely applied: single-phase dual-isotope subtraction, dual-phase single-isotope and combination of both. Each one of them has specific advantages and disadvantages. While single parathyroid adenomas are localized with greater precision, hyperfunctioning parathyroid hyperplastic cells represent a real challenge to the imaging modalities. Several factors can influence the radionuclide uptake in pathologically changed parathyroid cells, like the size, the level of their functional activity, the quantity of oxyphilic cells, mitochondria, P glycoprotein and other MDR gene products.",book:{id:"7769",slug:"medical-isotopes",title:"Medical Isotopes",fullTitle:"Medical Isotopes"},signatures:"Albena Dimitrova Botushanova and Nikolay Petrov Botushanov",authors:null},{id:"70578",title:"Gallium-68: Radiolabeling of Radiopharmaceuticals for PET Imaging - A Lot to Consider",slug:"gallium-68-radiolabeling-of-radiopharmaceuticals-for-pet-imaging-a-lot-to-consider",totalDownloads:1684,totalCrossrefCites:4,totalDimensionsCites:5,abstract:"Gallium-68 was applied for positron emission tomography (PET) imaging already in the early beginnings of PET imaging. Today, with the introduction of PSMA-targeting tracers (e.g. PSMA-11, PSMA-617, and PSMA-I&T), the number of clinical applications of 68Ga-radiopharmaceuticals for diagnostic imaging has grown considerably. This development was initiated and supported already in the mid-2000s by the commercial availability of 68Ge/68Ga generators designed for clinical usage. This progression was accompanied by the development of several purification methods to generator eluate as well as sophisticated 68Ga-radiopharmaceuticals. Due to the 68Ga-rush, the need for implementation of gallium-68 (depending on production route) and its certain tracers into the pharmacopeia increased. 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He has both an MS and Ph.D. in Biomedical Engineering. He was previously a research scientist at the University of California Los Angeles (UCLA) and visiting professor and researcher at the University of North Dakota. He is currently working in artificial intelligence and its applications in medical signal processing. In addition, he is using digital signal processing in medical imaging and speech processing. Dr. Asadpour has developed brain-computer interfacing algorithms and has published books, book chapters, and several journal and conference papers in this field and other areas of intelligent signal processing. He has also designed medical devices, including a laser Doppler monitoring system.",institutionString:"Kaiser Permanente Southern California",institution:null},{id:"169608",title:"Prof.",name:"Marian",middleName:null,surname:"Găiceanu",slug:"marian-gaiceanu",fullName:"Marian Găiceanu",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/169608/images/system/169608.png",biography:"Prof. Dr. Marian Gaiceanu graduated from the Naval and Electrical Engineering Faculty, Dunarea de Jos University of Galati, Romania, in 1997. He received a Ph.D. (Magna Cum Laude) in Electrical Engineering in 2002. Since 2017, Dr. Gaiceanu has been a Ph.D. supervisor for students in Electrical Engineering. He has been employed at Dunarea de Jos University of Galati since 1996, where he is currently a professor. Dr. Gaiceanu is a member of the National Council for Attesting Titles, Diplomas and Certificates, an expert of the Executive Agency for Higher Education, Research Funding, and a member of the Senate of the Dunarea de Jos University of Galati. He has been the head of the Integrated Energy Conversion Systems and Advanced Control of Complex Processes Research Center, Romania, since 2016. He has conducted several projects in power converter systems for electrical drives, power quality, PEM and SOFC fuel cell power converters for utilities, electric vehicles, and marine applications with the Department of Regulation and Control, SIEI S.pA. (2002–2004) and the Polytechnic University of Turin, Italy (2002–2004, 2006–2007). He is a member of the Institute of Electrical and Electronics Engineers (IEEE) and cofounder-member of the IEEE Power Electronics Romanian Chapter. He is a guest editor at Energies and an academic book editor for IntechOpen. He is also a member of the editorial boards of the Journal of Electrical Engineering, Electronics, Control and Computer Science and Sustainability. Dr. Gaiceanu has been General Chairman of the IEEE International Symposium on Electrical and Electronics Engineering in the last six editions.",institutionString:'"Dunarea de Jos" University of Galati',institution:{name:'"Dunarea de Jos" University of Galati',country:{name:"Romania"}}},{id:"4519",title:"Prof.",name:"Jaydip",middleName:null,surname:"Sen",slug:"jaydip-sen",fullName:"Jaydip Sen",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/4519/images/system/4519.jpeg",biography:"Jaydip Sen is associated with Praxis Business School, Kolkata, India, as a professor in the Department of Data Science. His research areas include security and privacy issues in computing and communication, intrusion detection systems, machine learning, deep learning, and artificial intelligence in the financial domain. He has more than 200 publications in reputed international journals, refereed conference proceedings, and 20 book chapters in books published by internationally renowned publishing houses, such as Springer, CRC press, IGI Global, etc. Currently, he is serving on the editorial board of the prestigious journal Frontiers in Communications and Networks and in the technical program committees of a number of high-ranked international conferences organized by the IEEE, USA, and the ACM, USA. He has been listed among the top 2% of scientists in the world for the last three consecutive years, 2019 to 2021 as per studies conducted by the Stanford University, USA.",institutionString:"Praxis Business School",institution:null},{id:"320071",title:"Dr.",name:"Sidra",middleName:null,surname:"Mehtab",slug:"sidra-mehtab",fullName:"Sidra Mehtab",position:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y00002v6KHoQAM/Profile_Picture_1584512086360",biography:"Sidra Mehtab has completed her BS with honors in Physics from Calcutta University, India in 2018. She has done MS in Data Science and Analytics from Maulana Abul Kalam Azad University of Technology (MAKAUT), Kolkata, India in 2020. Her research areas include Econometrics, Time Series Analysis, Machine Learning, Deep Learning, Artificial Intelligence, and Computer and Network Security with a particular focus on Cyber Security Analytics. Ms. Mehtab has published seven papers in international conferences and one of her papers has been accepted for publication in a reputable international journal. She has won the best paper awards in two prestigious international conferences – BAICONF 2019, and ICADCML 2021, organized in the Indian Institute of Management, Bangalore, India in December 2019, and SOA University, Bhubaneswar, India in January 2021. Besides, Ms. Mehtab has also published two book chapters in two books. Seven of her book chapters will be published in a volume shortly in 2021 by Cambridge Scholars’ Press, UK. Currently, she is working as the joint editor of two edited volumes on Time Series Analysis and Forecasting to be published in the first half of 2021 by an international house. Currently, she is working as a Data Scientist with an MNC in Delhi, India.",institutionString:"NSHM College of Management and Technology",institution:null},{id:"226240",title:"Dr.",name:"Andri Irfan",middleName:null,surname:"Rifai",slug:"andri-irfan-rifai",fullName:"Andri Irfan Rifai",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/226240/images/7412_n.jpg",biography:"Andri IRFAN is a Senior Lecturer of Civil Engineering and Planning. He completed the PhD at the Universitas Indonesia & Universidade do Minho with Sandwich Program Scholarship from the Directorate General of Higher Education and LPDP scholarship. He has been teaching for more than 19 years and much active to applied his knowledge in the project construction in Indonesia. His research interest ranges from pavement management system to advanced data mining techniques for transportation engineering. He has published more than 50 papers in journals and 2 books.",institutionString:null,institution:{name:"Universitas Internasional Batam",country:{name:"Indonesia"}}},{id:"314576",title:"Dr.",name:"Ibai",middleName:null,surname:"Laña",slug:"ibai-lana",fullName:"Ibai Laña",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/314576/images/system/314576.jpg",biography:"Dr. Ibai Laña works at TECNALIA as a data analyst. He received his Ph.D. in Artificial Intelligence from the University of the Basque Country (UPV/EHU), Spain, in 2018. He is currently a senior researcher at TECNALIA. His research interests fall within the intersection of intelligent transportation systems, machine learning, traffic data analysis, and data science. He has dealt with urban traffic forecasting problems, applying machine learning models and evolutionary algorithms. He has experience in origin-destination matrix estimation or point of interest and trajectory detection. Working with large volumes of data has given him a good command of big data processing tools and NoSQL databases. He has also been a visiting scholar at the Knowledge Engineering and Discovery Research Institute, Auckland University of Technology.",institutionString:"TECNALIA Research & Innovation",institution:{name:"Tecnalia",country:{name:"Spain"}}},{id:"314575",title:"Dr.",name:"Jesus",middleName:null,surname:"L. Lobo",slug:"jesus-l.-lobo",fullName:"Jesus L. Lobo",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/314575/images/system/314575.png",biography:"Dr. Jesús López is currently based in Bilbao (Spain) working at TECNALIA as Artificial Intelligence Research Scientist. In most cases, a project idea or a new research line needs to be investigated to see if it is good enough to take into production or to focus on it. That is exactly what he does, diving into Machine Learning algorithms and technologies to help TECNALIA to decide whether something is great in theory or will actually impact on the product or processes of its projects. So, he is expert at framing experiments, developing hypotheses, and proving whether they’re true or not, in order to investigate fundamental problems with a longer time horizon. He is also able to design and develop PoCs and system prototypes in simulation. He has participated in several national and internacional R&D projects.\n\nAs another relevant part of his everyday research work, he usually publishes his findings in reputed scientific refereed journals and international conferences, occasionally acting as reviewer and Programme Commitee member. Concretely, since 2018 he has published 9 JCR (8 Q1) journal papers, 9 conference papers (e.g. ECML PKDD 2021), and he has co-edited a book. He is also active in popular science writing data science stories for reputed blogs (KDNuggets, TowardsDataScience, Naukas). Besides, he has recently embarked on mentoring programmes as mentor, and has also worked as data science trainer.",institutionString:"TECNALIA Research & Innovation",institution:{name:"Tecnalia",country:{name:"Spain"}}},{id:"103779",title:"Prof.",name:"Yalcin",middleName:null,surname:"Isler",slug:"yalcin-isler",fullName:"Yalcin Isler",position:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRyQ8QAK/Profile_Picture_1628834958734",biography:"Yalcin Isler (1971 - Burdur / Turkey) received the B.Sc. degree in the Department of Electrical and Electronics Engineering from Anadolu University, Eskisehir, Turkey, in 1993, the M.Sc. degree from the Department of Electronics and Communication Engineering, Suleyman Demirel University, Isparta, Turkey, in 1996, the Ph.D. degree from the Department of Electrical and Electronics Engineering, Dokuz Eylul University, Izmir, Turkey, in 2009, and the Competence of Associate Professorship from the Turkish Interuniversity Council in 2019.\n\nHe was Lecturer at Burdur Vocational School in Suleyman Demirel University (1993-2000, Burdur / Turkey), Software Engineer (2000-2002, Izmir / Turkey), Research Assistant in Bulent Ecevit University (2002-2003, Zonguldak / Turkey), Research Assistant in Dokuz Eylul University (2003-2010, Izmir / Turkey), Assistant Professor at the Department of Electrical and Electronics Engineering in Bulent Ecevit University (2010-2012, Zonguldak / Turkey), Assistant Professor at the Department of Biomedical Engineering in Izmir Katip Celebi University (2012-2019, Izmir / Turkey). He is an Associate Professor at the Department of Biomedical Engineering at Izmir Katip Celebi University, Izmir / Turkey, since 2019. In addition to academics, he has also founded Islerya Medical and Information Technologies Company, Izmir / Turkey, since 2017.\n\nHis main research interests cover biomedical signal processing, pattern recognition, medical device design, programming, and embedded systems. He has many scientific papers and participated in several projects in these study fields. He was an IEEE Student Member (2009-2011) and IEEE Member (2011-2014) and has been IEEE Senior Member since 2014.",institutionString:null,institution:{name:"Izmir Kâtip Çelebi University",country:{name:"Turkey"}}},{id:"339677",title:"Dr.",name:"Mrinmoy",middleName:null,surname:"Roy",slug:"mrinmoy-roy",fullName:"Mrinmoy Roy",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/339677/images/16768_n.jpg",biography:"An accomplished Sales & Marketing professional with 12 years of cross-functional experience in well-known organisations such as CIPLA, LUPIN, GLENMARK, ASTRAZENECA across different segment of Sales & Marketing, International Business, Institutional Business, Product Management, Strategic Marketing of HIV, Oncology, Derma, Respiratory, Anti-Diabetic, Nutraceutical & Stomatological Product Portfolio and Generic as well as Chronic Critical Care Portfolio. A First Class MBA in International Business & Strategic Marketing, B.Pharm, D.Pharm, Google Certified Digital Marketing Professional. Qualified PhD Candidate in Operations and Management with special focus on Artificial Intelligence and Machine Learning adoption, analysis and use in Healthcare, Hospital & Pharma Domain. Seasoned with diverse therapy area of Pharmaceutical Sales & Marketing ranging from generating revenue through generating prescriptions, launching new products, and making them big brands with continuous strategy execution at the Physician and Patients level. Moved from Sales to Marketing and Business Development for 3.5 years in South East Asian Market operating from Manila, Philippines. Came back to India and handled and developed Brands such as Gluconorm, Lupisulin, Supracal, Absolut Woman, Hemozink, Fabiflu (For COVID 19), and many more. In my previous assignment I used to develop and execute strategies on Sales & Marketing, Commercialization & Business Development for Institution and Corporate Hospital Business portfolio of Oncology Therapy Area for AstraZeneca Pharma India Ltd. Being a Research Scholar and Student of ‘Operations Research & Management: Artificial Intelligence’ I published several pioneer research papers and book chapters on the same in Internationally reputed journals and Books indexed in Scopus, Springer and Ei Compendex, Google Scholar etc. Currently, I am launching PGDM Pharmaceutical Management Program in IIHMR Bangalore and spearheading the course curriculum and structure of the same. I am interested in Collaboration for Healthcare Innovation, Pharma AI Innovation, Future trend in Marketing and Management with incubation on Healthcare, Healthcare IT startups, AI-ML Modelling and Healthcare Algorithm based training module development. I am also an affiliated member of the Institute of Management Consultant of India, looking forward to Healthcare, Healthcare IT and Innovation, Pharma and Hospital Management Consulting works.",institutionString:null,institution:{name:"Lovely Professional University",country:{name:"India"}}},{id:"1063",title:"Prof.",name:"Constantin",middleName:null,surname:"Volosencu",slug:"constantin-volosencu",fullName:"Constantin Volosencu",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/1063/images/system/1063.png",biography:"Prof. Dr. Constantin Voloşencu graduated as an engineer from\nPolitehnica University of Timișoara, Romania, where he also\nobtained a doctorate degree. He is currently a full professor in\nthe Department of Automation and Applied Informatics at the\nsame university. Dr. Voloşencu is the author of ten books, seven\nbook chapters, and more than 160 papers published in journals\nand conference proceedings. He has also edited twelve books and\nhas twenty-seven patents to his name. He is a manager of research grants, editor in\nchief and member of international journal editorial boards, a former plenary speaker, a member of scientific committees, and chair at international conferences. His\nresearch is in the fields of control systems, control of electric drives, fuzzy control\nsystems, neural network applications, fault detection and diagnosis, sensor network\napplications, monitoring of distributed parameter systems, and power ultrasound\napplications. He has developed automation equipment for machine tools, spooling\nmachines, high-power ultrasound processes, and more.",institutionString:"Polytechnic University of Timişoara",institution:{name:"Polytechnic University of Timişoara",country:{name:"Romania"}}},{id:"221364",title:"Dr.",name:"Eneko",middleName:null,surname:"Osaba",slug:"eneko-osaba",fullName:"Eneko Osaba",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/221364/images/system/221364.jpg",biography:"Dr. Eneko Osaba works at TECNALIA as a senior researcher. He obtained his Ph.D. in Artificial Intelligence in 2015. He has participated in more than twenty-five local and European research projects, and in the publication of more than 130 papers. He has performed several stays at universities in the United Kingdom, Italy, and Malta. Dr. Osaba has served as a program committee member in more than forty international conferences and participated in organizing activities in more than ten international conferences. He is a member of the editorial board of the International Journal of Artificial Intelligence, Data in Brief, and Journal of Advanced Transportation. He is also a guest editor for the Journal of Computational Science, Neurocomputing, Swarm, and Evolutionary Computation and IEEE ITS Magazine.",institutionString:"TECNALIA Research & Innovation",institution:{name:"Tecnalia",country:{name:"Spain"}}},{id:"275829",title:"Dr.",name:"Esther",middleName:null,surname:"Villar-Rodriguez",slug:"esther-villar-rodriguez",fullName:"Esther Villar-Rodriguez",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/275829/images/system/275829.jpg",biography:"Dr. Esther Villar obtained a Ph.D. in Information and Communication Technologies from the University of Alcalá, Spain, in 2015. She obtained a degree in Computer Science from the University of Deusto, Spain, in 2010, and an MSc in Computer Languages and Systems from the National University of Distance Education, Spain, in 2012. Her areas of interest and knowledge include natural language processing (NLP), detection of impersonation in social networks, semantic web, and machine learning. Dr. Esther Villar made several contributions at conferences and publishing in various journals in those fields. Currently, she is working within the OPTIMA (Optimization Modeling & Analytics) business of TECNALIA’s ICT Division as a data scientist in projects related to the prediction and optimization of management and industrial processes (resource planning, energy efficiency, etc).",institutionString:"TECNALIA Research & Innovation",institution:{name:"Tecnalia",country:{name:"Spain"}}},{id:"49813",title:"Dr.",name:"Javier",middleName:null,surname:"Del Ser",slug:"javier-del-ser",fullName:"Javier Del Ser",position:null,profilePictureURL:"https://mts.intechopen.com/storage/users/49813/images/system/49813.png",biography:"Prof. Dr. Javier Del Ser received his first PhD in Telecommunication Engineering (Cum Laude) from the University of Navarra, Spain, in 2006, and a second PhD in Computational Intelligence (Summa Cum Laude) from the University of Alcala, Spain, in 2013. He is currently a principal researcher in data analytics and optimisation at TECNALIA (Spain), a visiting fellow at the Basque Center for Applied Mathematics (BCAM) and a part-time lecturer at the University of the Basque Country (UPV/EHU). His research interests gravitate on the use of descriptive, prescriptive and predictive algorithms for data mining and optimization in a diverse range of application fields such as Energy, Transport, Telecommunications, Health and Industry, among others. In these fields he has published more than 240 articles, co-supervised 8 Ph.D. theses, edited 6 books, coauthored 7 patents and participated/led more than 40 research projects. He is a Senior Member of the IEEE, and a recipient of the Biscay Talent prize for his academic career.",institutionString:"Tecnalia Research & Innovation",institution:null},{id:"278948",title:"Dr.",name:"Carlos Pedro",middleName:null,surname:"Gonçalves",slug:"carlos-pedro-goncalves",fullName:"Carlos Pedro Gonçalves",position:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRcmyQAC/Profile_Picture_1564224512145",biography:'Carlos Pedro Gonçalves (PhD) is an Associate Professor at Lusophone University of Humanities and Technologies and a researcher on Complexity Sciences, Quantum Technologies, Artificial Intelligence, Strategic Studies, Studies in Intelligence and Security, FinTech and Financial Risk Modeling. 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Currently working as an Assistant Professor in the Department of Mathematics, Institute of Applied Science, Mangalayatan University, Aligarh. She taught so many courses of Mathematics of UG and PG level. Her research Area of Expertise is Functional Analysis & Sequence Spaces. She has been working on Ideal Convergence of double sequence. She has published 17 research papers in National and International Journals including Cogent Mathematics, Filomat, Journal of Intelligent and Fuzzy Systems, Advances in Difference Equations, Journal of Mathematical Analysis, Journal of Mathematical & Computer Science etc. She has also reviewed few research papers for the and international journals. 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