1. Introduction
Flash memory has been leading player in the nonvolatile memories in recent ten years because of a small cell size and a high scalability. A gate length of a flash memory has reached to 20 nm. A number of charges also have been getting smaller. a several hundred in the 20 nm device. However, a flash memory needs high operating voltage for short write time. The high operating voltage causes low durability [1, 2], and a signal due to capacitance coupling between neighbor cells becomes larger with further miniaturization [1, 2]. Therefore, lower operating voltage and stronger capacitive coupling between a gate electrode and a charge storage compare to neighbor cells are desired.
A single walled carbon nanotube (SWNT) is a cylindrical structure with a diameter of about 1 nm [3-8]. A SWNT with a semiconductor property is very sensitive to the charge around the SWNT, because whole SWNT channel can be easily modulated by the arounded charge because of the small diameter of a SWNT. This high sensitivity can sense even a single-charge [9-14]. Therefore, many sensor applications of SWNT have been reported, e.g. bio- and gas-sensors [15-31]. Moreover, a cylindrical type memory can achieve higher electric field concentration compare to a planer type memory because of higher capacitive coupling between charge storage and a gate electrode. Therefore, the signal noise attributed to the parasitic capacitances between a neighbor cells can be reduced by this higher capacitive coupling.
In this study, we succeeded in fabricating a multifunctional quantum transistor using the particle nature and wave nature of holes in SWNT. This transistor can operate as anresonant tunneling transistor (RTT) and also as an single-hole transistor (SHT). An RTT is a device that uses the wave nature of hole and an SHT uses the particle nature of hole in the SWNT. Both devices need tunneling barriers at both sides of the quantum island. The RTT needs strong coupling while the SHT needs weak coupling between the quantum island and the electrodes. Usually, these tunneling barriers are made from thin oxide layers, etc. Therefore, the thickness of the tunneling barriers and the coupling strength cannot normally be controlled in a given device. In the present device, however, the Schottky barriers act as the tunneling barriers between the SWNT quantum island and electrodes. Therefore, the thickness of the tunneling barriers and the coupling strength between the SWNT and electrodes can be controlled by the applied gate voltage
SWNT electron devices show hysteresis characteristics in gate voltage-drain current characteristics. The hysteresis characteristics are caused by gate-voltage-dependent charge fluctuation, e.g., adsorption of water molecules around a SWNT [32], charging into insulator layer around a SWNT [33], and charging into amorphous carbon around a SWNT [34] By eliminating these origins of the hysteresis characteristics, the number of fluctuating charges becomes small and a single-charge fluctuating around the SWNT channel can be distinguished by a SWNT multi-functional quantum transistor.
Moreover, a SWNT transistor surrounded by SiNx /Al2O3 double gate insulator layers with quantum dot in the insulator layers was fabricated, demonstrating discrete threshold voltage shift resulting in discrete drain current modulation at room temperature.
2. Detection of single-charge around SWNT channel
2.1. Method
We have eliminated the three origins of the hysteresis characteristics of a SWNT field effect transistor mainly pointed out in current reports [32-35]. To burn out amorphous carbon, we annealed a SWNT at low temperature in oxidizable atmosphere [33]. To reduce the number of adsorbed atmosphere molecules, we covered the channel with a silicon dioxide layer. To reduce the number of trap sites in the insulator, we reduced channel length to 73 nm. The SWNT multi-functional quantum transistor fabricated by the process mentioned above shows almost no hysteresis characteristics in the gate voltage rage from -40 to 40 V. Moreover, an abrupt discrete switching of the source-drain current is observed in the electrical measurements of the SWNT multi-functional quantum transistor at 7.3 K. These random telegraph signals (RTS) are attributed to charge fluctuating charge traps near the SWNT multi-functional quantum transistor conduction channel. The current-switching behavior associated with the occupation of individual electron traps is demonstrated and analyzed statistically.
2.2. Sample preparations
A schematic of the sample structure is shown in Fig. 1. SWNT was prepared as follows. An n+-Si wafer with a thermally grown 300 nm thick oxide was used as a substrate. Layered Fe/Mo/Si (2 nm/20 nm/40 nm) catalysts were evaporated using an electron-beam evaporator under a vacuum of 10-6 Pa. These layered catalysts were patterned on the substrate using the conventional photo-lithography process. SWNT was grown by thermal chemical vapor deposition (CVD) using the mixed gases of hydrogen and argon-bubbled ethanol. After the growth of the SWNT, it was purified by burning out the amorphous carbon around the SWNT in an air atmosphere at a temperature of several hundred degrees Celsius [31]. Ti (30 nm) electrodes were deposited on the patterned catalysts as the source and drain, and on the back side of the n+-Si substrate for the gate, using the electron-beam evaporator under a vacuum of 10-6 Pa. The distance (
2.3. Results and discussions
2.3.1. Single charge sensitivity of SWNT multi-functional quantum transistor
Figure 2 (a) shows the time dependence of the conductance of the SWNT multi-functional quantum transistor at 7.3 K with a gate bias of
The applied gate voltage was under the Fabry-Perot interference region. The SWNT multi-functional quantum transistor shows RTS, as shown in Fig. 2(a), The RTS showed three levels, n, n+1 and n+2, of the conductance shown in Fig. 2(a). At a lower applied gate voltage, current levels higher than n+2 such as n+3 and n+4 appeared. The multiple levels of RTS are attributed to charge fluctuating charge storages near the conduction channels of the SWNT multi-functional quantum transistor. Moreover, because there was a single-charge storage including multiple energy levels or were some charge storages being at almost the same distances from the conductance channel of the SWNT multi-functional quantum transistor, the RTS appeared. Figures 2(b) and (c) show histograms of the conductance levels of RTS at
The gate voltage dependences of the natural log of the ratio between the
The charge transition is modeled, as shown in Fig. 4(a), in which the energy barrier is between the SWNT and the charge storage.Figures 3(b)-3(e) are enlargement plots of each
where
Equation (2) is the transformed Arrhenius equation, in which
From the dependence of
2.4. Conclusion
In summary, we succeeded in fabricating and demonstrating a multi-functional quantum transistor using the particle nature and wave nature of holes in SWNT. This transistor can operate in the wave nature mode as an RTT and in the particle nature mode as an SHT. We were able to reveal that the principle of the characteristic transition from an SHT to an RTT is the modulation of the coupling strength between the SWNT quantum island and the electrodes by the applied
3. Control of single-hole transition at room temperature
3.1. Method
A SWNT transistor surrounded by SiNx /Al2O3 double gate insulator layers with quantum dot in the insulator layers was fabricated, demonstrating discrete threshold voltage shift resulting in discrete drain current modulation by single-hole transfer at room temperature.
3.2. Sample preparation
The fabrication process of the SWNT transistor surrounded by SiNx /Al2O3 double gate insulator layers with quantum dot in the insulator layers is shown in Fig. 1. The fabrication process of the single-charge memory is shown in Fig. 5. A SWNT was grown by the chemical vapor deposition process on the SiO2 substrate, and the source and drain electrodes were formed on the SWNT, where a distance between the electrodes was 70 nm. The SiO2 under the SWNTwas etched off by chemical wet process and the SWNT bridge was formed between source and drain electrodes as shown in Fig. 5 (a). Then, the SWNT was surrounded by double-layers of SiNx of 27 nm over Al2O3 of 3 nm using atomic layer deposition (ALD) process (FlexAL, Oxford Inst.) using tris(dimethylamino)silane for SiNx and trimethylaluminum for Al2O3 as a precursor as shown in Fig. 1(b).Figure 5 (c) – (g) shows scanning electron microscope (SEM) images of a device after an ALD process. Owing to thin insulator layers and highacceleration energy of SEM, the insulator layers can be seen through and the difference of the materials are recognized because of the difference of the contrast as shown in Fig. 5(c)-(g). Fig. 5(c) and (d) shows the top view and bird’s eye view of the device near the gap. The gap of 10 nm length is realized between the source and drain electrode. Fig. 5(e) shows the cross sectional view around the drain electrode indicated by dashed square in Fig. 5(b). The drain electrode is fully covered by the insulator layers, and the space under the channel can be seen. Fig. 5(f)-(g) shows the side view and cross sectional view of the SWNT surrounded by the insulator layer of 30 nm thick in which the SWNT is seen as a light gray line at the center of the insulator. Fig. 5(h) and (i)are the schematic cross sectional view and 3D image of the device after the formation of the top gate electrode.
Using an isotropic deposition of the ALD process 10 nm length of top gate electrode is realized self-assembly as shown in Fig. 5(h). The 30 nm thick insulator layer was deposited from the source and drain electrode which narrowed a gap between the electrodes from 70 nm to 10 nm by the isotropic ALD deposition. Ti and Au were deposited through this gap to form a top gate electrode. Thus, the 10 nm long top gate electrode was self-assembly formed at a center of the source and drain electrode which is covered by the ALD insulator layers. The SiNx deposition by ALD was carried out with low deposition rate of 0.31 Å/ cycle. The low deposition rate enables to form the composite of nano particles of Si, N and C at the beginning of the deposition because of the low uniformity and the incomplete reaction. The composite of nano particles may act as a dot for the charge storage.
3.3. Results and discussions
Figure 6(a) shows drain current characteristic as a function of the applied top gate voltage at room temperature. The source and drain voltage were set at -25 mV and 25 mV, respectively.
The drain current showed the repeated threshold shift characteristic indicated by right-arrows,where the drain current repeatedly showed the drastic increases indicated by up-arrows and the gradual decreases indicated by tangential lines with increase of the applied top gate voltage as shown in Fig. 6(a).The threshold shift was observed in period of 0.22 V with increasing applied top gate voltage. The holes had been accumulated in the charge storage dot by negative gate voltage at the beginning of the measurement. By increasing the applied top gate voltage, the hole started to transfer to the SWNT channel. At this moment, the potential of the charge storage dot decreased and blocked the transfer of other holes i.e., Coulomb blockade effect. Therefore, the hole could transfer one by one, where each transfer was separated by Coulomb blockade effect. The decreased potential of the charge storage dot also impacted the SWNT channel and the drain current drastically increased because of p type channel. Therefore, the drastic increases of the drain current in Fig. 6(a) are attributed to a single-hole transfer from the accumulated charge storage dot to the SWNT channel. The gradual decreases of the drain current are attributed to the channel modulation by the applied top gate voltage as well as a conventional MOS-FET device. The charge storage dot density of
Moreover, the threshold voltage shift caused by single charge transition was given by Δ
Figure 7(a) – (c) shows the time
The drain currents were plotted in the same time scale, however, time lengths of the measurement were different. The drain current increased with elapsed time and also showed five steps indicated by dotted lines as shown in Fig. 7(a) – (c). The increases of the drain current at each step were the same among Fig. 7(a) – (c). However, the time width of each steps showed the variety even if the steps were at the same drain current levels in Fig. 7(a) – (c). From the plots, average of the drain current width was
4. Summary
In conclusion, control of single transition in carbon nanotube transistor with quantum dot in gate insulator at room temperature was demonstrated. To obtain the narrow top gate electrode of 10 nm, the isotropic deposition by ALD process for the insulators formation was used. At the same time, the concentric circle structure of insulators was formed around the SWNT channel which was on the center. The defective deposition of SiNx on Al2O3 may formnano size particles at the beginning of the deposition process, which worked as charge storage dots. Because of the narrow top gate electrode, only single-dot was just under the top gate electrode which stored single-hole. Though top gate electrode could surround only the upper half of insulators that realized electric field concentration all-around the SWNT channel and caused Fowler-Nordheim tunneling which make the hole transfer to the charge storage dot. The drain current affected by the stored charge showed the threshold voltage shift as a function of the applied top gate voltage at room temperature. This threshold voltage shift is attributed to the abrupt potential energy change by the transfer of single-holes from the dot to the SWNT channel. The time dependence of the drain current after changing the top gate voltage showed the step like characteristics. The time widths of the steps corresponded to the interval of stochastic transfer of single-holes, and the number of the steps corresponded to the variation of single-holes in the dot. By observing the steps, the individual transfers of single-holes could be counted in real-time at room temperature. The SWNT property with high sensitivity for the charges is suitable to the application of the single-charge memory. And the SWNT must be one of the leading candidates for the single-charge applications.
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