Compositions of the different gases used in methanol synthesis.
Methanol is an important bulk chemical in the chemical industry. The global methanol demand was approximately 32 million metric tons in 2004 and is expected to grow . Methanol is used mainly for the production of formaldehyde, acetic acid, and application products including polymers and paints. Furthermore, methanol can be used as a clean and renewable energy carrier . Methanol is mainly produced from syngas, a mixture of H2, CO, and minor quantities of CO2 and CH4. Syngas is commonly produced from fossil resources like natural gas or coal. Biomass, however, can also be used as resource for syngas and allows the synthesis of green methanol. Green methanol not only has environmental benefits, but may also lead to considerable variable cost reductions if the biomass resource has a low or even negative value.
1.1. Renewable methanol
Methanol synthesis from biomass was already proposed during the first oil crisis in the 1970s . In the 1980s a comprehensive review was published on the production of methanol from syngas derived from wood. Different gasification technologies were proposed and demonstration projects of these technologies were discussed [2, 3]. In the mid 1990s several projects on methanol synthesis from biomass were initiated such as the Hynol project in the USA and the BLGMF (black liquor gasification with motor fuels production) process in Sweden [4-6]. Schwarze Pumpe, Germany developed a process to convert coal and waste, including sewage sludge, to methanol (capacity ± 150 ML/y) . Unfortunately no experimental data of these processes are available in open literature.
Several initiatives were started in the 2000s. At a scale of 4 t/d, Chemrec in Sweden produces methanol and dimethyl ether (DME) since 2011. Syngas is obtained by entrained flow gasification of black liquor . The production of methanol from glycerol is demonstrated on industrial scale by BioMCN in The Netherlands . At BioMCN, the natural gas reforming unit has been modified to enable steam reforming of glycerol. The syngas is converted to methanol in their conventional packed bed methanol synthesis reactors, with a capacity for methanol production of 250 ML/y .
The amount of published experimental results on the production of methanol from biomass is rather limited. Most publications on methanol production from biomass are desk-top studies and data comparison is difficult [5, 6, 9-13]. These studies often combine biomass gasification and conventional methanol synthesis with, in some cases, electricity production [5, 6, 11, 13]. Xu
An interesting concept of using biomass to produce methanol is the co-processing of biomass and fossil resources, e.g. co-gasification of biomass with coal or natural gas [9, 10, 12]. The advantage of co-feeding natural gas is that the syngas derived will become more suitable for methanol synthesis as syngas from biomass is deficient in H2 and syngas from natural gas in CO or CO2.
The concepts involved in the current processes for the synthesis of methanol from biomass generally involve an initial gasification step at elevated temperatures and pressures. The approach demonstrated in this chapter is syngas production through a hydrothermal process, viz. conversion of a wet biomass stream to syngas by reforming in supercritical water (RSCW), followed by high pressure methanol synthesis.
An interesting wet biomass resource is glycerol, the by-product from the biodiesel industry. In Europe, the share of transportation fuel to be derived from renewable resources in 2020 is targeted at 10% . It is expected that biodiesel and ethanol will make up the largest share and consequently Europe’s biodiesel production increased significantly in the 2000s (see Figure 1) . In the last few years, though, economics of biodiesel production deteriorated as the income from the sales of glycerol decreased, while the costs of feedstock increased.
As for the production of every (metric) ton of biodiesel, roughly 100 kg of methanol is required and a similar quantity of glycerol is produced, both methanol demand and glycerol production increased. An interesting option addressing the surplus of glycerol and the demand for methanol is to produce methanol from the glycerol. If this process is conducted by the biodiesel producer he will become less dependent on the methanol spot price, there is a (partial) security of supply of methanol, and by-products can be used as a green and sustainable feed product. However, the scale of traditional methanol synthesis (> 2000 t/d) is much larger than the scale of methanol synthesis explored in the Supermethanol project.
The Supermethanol initiative focuses on a small/medium scale biodiesel plant (30,000 – 100,000 t/y) and the aim of the project is to develop a methanol synthesis process using glycerol as feed at a capacity matching the biodiesel production. The glycerol intake for the production of syngas will be in the range of 3000 up to 10,000 t/y . The scope of the Supermethanol concept is schematically outlined in Figure 2.
The biodiesel factory is the core of the process in which vegetable oils react with methanol in the presence of a catalyst to produce biodiesel and by-product glycerol. The glycerol can be converted into methanol in the glycerol-to-methanol (GtM-) process. This process is an integration of two separate processes, viz. the reforming in supercritical water (RSCW) of glycerol to syngas, followed by the conversion of this syngas into methanol. Additional fuel gas is produced, which can be used to generate heat for the biodiesel production or in the GtM-process. A more detailed overview on the GtM-concept is given in the next section.
2. The glycerol-to-methanol concept
2.1. Theoretical considerations
The most attractive syngas for methanol synthesis has a stoichiometric number (
When glycerol decomposes solely into H2, CO, and CO2 the maximum
Application of the definition for
As a theoretical maximum, 2.33 mol carbon/mol glycerol end up in methanol (77.8% on carbon basis or 0.81 kg methanol/kg glycerol on weight basis). Actual yields, however, will be lower as both processes, glycerol reforming and methanol synthesis, involve equilibrium reactions and the occurrence of other reactions like the formation of higher hydrocarbons, higher alcohols (HA), and methanation.
2.2. Description of the continuous integrated GtM-bench scale unit
The integrated unit consists of a reformer section and a methanol synthesis section. A schematic flow sheet of the unit is given in Figure 3. An extensive description of the reformer section is published elsewhere . The reformer section was operated in continuous mode with a throughput of 1 L aqueous feed/h. Glycerol and water were introduced to the system from feed containers F1 or F2 through a pump and subsequently reformed in five reforming reactors (R1 – R5) in series. The temperature in each reactor can be adjusted individually.
The methanol section contains three tubular packed bed reactors (P1 – P3, each
The process pressure was the average of
The composition of the off-gas from the reforming section and methanol synthesis section was analyzed using an online dual-column gas chromatograph (GC 955, Syntech Spectras) equipped with thermal conductivity detectors. CO was analyzed and quantified using a molsieve 5 Å column (
The carbon conversion of glycerol (
The overall conversion of carbon in glycerol to carbon in methanol (
The methanol yield (
The conversion of gas component i (
The carbon selectivity towards product i (
2.5. Research strategy
The integration of syngas production in an RSCW-process and syngas conversion in methanol synthesis is the core of the GtM-process. In the RSCW of glycerol a high pressure syngas is produced. The use of this high pressure syngas has distinct advantages for methanol synthesis, which will be dealt with in Section 4. However, before successful integration both processes need to be optimized separately, which was done at the laboratories of the Biomass Technology Group (BTG) in The Netherlands. A unit was available to investigate both process separately before integraton. Results obtained for each process were used to optimize the overall process and maximize the overall carbon conversion (
3. Glycerol reforming in supercritical water
3.1. Introduction to reforming
Water becomes supercritical at conditions above its critical temperature (
Typical process conditions for three processes considered for wet biomass valorization are indicated here, viz. liquefaction, catalytic reforming, and high temperature reforming. Hydrothermal liquefaction is conducted at temperatures below and pressures above the critical point, where biomass is degraded to yield mainly bio-crude (a viscous water-insoluble liquid), char, water-soluble substances, and gas . RSCW of biomass is aimed at gas production and is carried out at conditions beyond the critical point. Here, water acts both as reaction medium and reactant. RSCW of biomass can be subdivided into catalytic reforming and noncatalytic reforming. Catalytic reforming is predominantly carried out at the lower temperature range, while noncatalytic or high temperature reforming is conducted at the higher temperatures (see Figure 4 ).
RSCW is characterized by the occurrence of many reactions, proceeding both in series and in parallel. The overall reaction of an actual (biomass) feed to liquid and gas phase products is shown in Eq. 10.
By-products (Cx’Hy’Oz’) are low molecular weight organic compounds, polymerized products, higher hydrocarbons (x’≥2, z’=0), or elemental carbon (y’=z’=0). Some of the low molecular weight organics can react further to gas phase components. Subsequent reactions of the gas phase components may also occur. The following gas phase reactions may occur, depending on process conditions :
The individual reaction rates depend on operating conditions and the presence of catalysts. A number of parameters affect the carbon conversion in RSCW, such as feedstock type, feed concentration, operating conditions, presence of catalysts or catalytic surfaces, and interaction between different components. The state of the art of RSCW in the 2000s has been reviewed extensively in several publications [19, 22-28].
3.2. Reforming of pure glycerol and crude glycerin
The reforming experiments were carried out using only the reforming section of the unit depicted in Figure 3. Typical conditions were temperatures of 723 – 923 K, residence times between 6 – 45 s, and feed concentrations of 3 – 20 wt%. The pressure was around 25 MPa. Two different types of glycerol were used, viz. pure glycerol and crude glycerin. Crude glycerin is glycerol derived from biodiesel production. The crude glycerin used in this research study contains approximately 5 wt% NaCl. The presence of alkali (in this case Na+) influences mainly the WGS reaction (see Eq. 11). The main gas products for pure glycerol and crude glycerin were: H2, CO, CO2, CH4, and C2H6. At complete conversion, roughly 2 mol of carbon in glycerol are converted to carbon oxides while 1 mol of carbon ends up as a hydrocarbon. The gas composition/yield appeared to be a function of the conversion and independent of the feed concentration. The conversion is a function of the process severity, a combination of the residence time and operating temperature. In Figure 5 the gas yields (mol gas/mol glycerol) of the two types of glycerol are depicted. The trend lines shown are fitted to experimental data points . The differences between pure glycerol and crude glycerin can be mainly attributed to the extent of the progress of the WGS reaction .
From reforming studies with methanol as model compound it was concluded that the hydrocarbons present in the gas mixture in case of glycerol reforming appear to be primary gas phase products. In the methanol reforming experiments in the same unit, gas mixtures with similar H2, CO, and CO2 ratios were obtained, but hydrocarbons were hardly observed. Thus, gas phase reactions producing hydrocarbons, e.g. methanation, hardly proceed in the system, which indicates that hydrocarbons are primary gas phase products formed upon glycerol decomposition and not or only to a small extent by gas phase reactions. In glycerol reforming the reactions depicted in Eqs. 10 and 11 proceed, while Eqs. 12 and 13 barely take place. Coke formation was not observed at all and most probably the reactions depicted in Eqs. 14-16 do not proceed.
Based on the experimental results, a simplified reaction scheme for the decomposition of glycerol with a focus on gas production was established and is given in Figure 6. More information on the selection of primary and secondary gas phase products can be found in literature .
In this scheme, CH4 is shown as a primary product, but can also be formed as a secondary product by methanation. Furthermore, water is produced and the WGS reaction and alkene hydrogenation are included. It is suggested that glycerol can either decompose into liquid soluble products that react further to gas products or that glycerol can directly decompose into gas products. In practice probably both reaction pathways occur. The overall mechanism at complete conversion of glycerol decomposition proceeds through the dehydration of 1 mol H2O/mol feed .
An important quality indicator for the gas composition is the
3.3. Catalytic reforming
Catalytic reforming was investigated to improve the quality of the syngas obtained in the noncatalytic reforming experiments for subsequent methanol synthesis. An extensive description of catalytic reforming using five different catalysts is given in literature . The catalytic experiments were conducted at temperatures between 648 to 973 K at pressures between 25.5 - 27.0 MPa. The feed concentration was 10 wt%, and the residence time varied from 8 to 87 s. The experiments were conducted using only three reactors (R2, R3, and R4 in Figure 3), with only the latter two reactors containing catalyst. The catalysts clearly promote the glycerol decomposition rate and higher conversion were measured compared to noncatalytic reforming. A typical figure with the gas concentration as a function of the temperature for a Ni based catalyst is given in Figure 8. The equilibrium curves were calculated using a model described in literature .
The gas composition is a function of the temperature and in this case equilibria are reached at temperatures exceeding 780 K. This catalyst strongly promotes methanation, as the CH4 concentration is much higher than in noncatalytic reforming. At the higher temperatures the CH4 concentration goes down according to thermodynamics. When a Ni based catalyst is used the WGS reaction (Eq. 11) is at equilibrium and almost all CO is converted into CO2. After the reforming experiments traces of coke were visually observed at the catalyst surface and the reactor wall.
The performance of this catalyst expressed in
3.4. Consequences of the reforming process for the integrated concept
The gas composition in noncatalytic reforming appeared to be not very attractive for methanol synthesis mainly due to the formation of hydrocarbons. Over a Ni based catalyst, CH4 was the only hydrocarbon present in the gas phase. Its maximum concentration was close to 40 vol% at 730 K. A temperature increase resulted in a decreasing CH4 concentration. A further decrease can be realized at higher temperatures and lower feed concentrations. Reduction of the hydrocarbon content has a positive effect on the
4. Methanol synthesis
4.1. Introduction to methanol synthesis
Methanol synthesis is conducted generally in catalytic gas-solid packed bed reactors. Three equilibrium reactions, taking place at the catalyst surface, are important: (i) the hydrogenation of CO (Eq. 17), (ii) the hydrogenation of CO2 (Eq. 18), and (iii) the WGS reaction (Eq. 11):
All reactions are exothermic. The conversion of CO+CO2 at chemical equilibrium is a function of pressure, temperature, and gas composition (see Figure 10).
Methanol synthesis at industrial scale was initiated by BASF in the 1920s. The operating temperatures were high (573 – 633 K) because of the low catalyst activity [30, 31]. High pressures (15 – 25 MPa) were needed to obtain reasonable conversions. When more active Cu based catalysts and better syngas purification techniques became available, the operating temperature and pressure could be reduced. This development led to the so-called low pressure methanol synthesis process (5 – 10 MPa, 490 – 570 K) which was developed by ICI in the 1960s. Since then, most high pressure units have been converted to low pressure systems [31, 32]. Both synthesis processes require large recycle streams of unconverted syngas due to the limited conversion per reactor pass as is shown in Figure 10 . The reactor temperatures can be lowered further (to 463 – 520 K) due to the recent development of more active catalysts.
In the research study described in this chapter, a combination of low temperatures (468 – 545 K) and high pressures (15 – 25 MPa) is investigated. At this combination of pressure and temperature the Equilibria conversions towards methanol are high (see Figure 10).
4.2. Methanol condensation
The methanol conversion in conventional methanol synthesis is restricted by the chemical equilibrium as shown in Figure 10. There are several opportunities to circumvent the limitations imposed by thermodynamic equilibria and they mainly involve
The liquid accumulated in the view cell upon prolonged reaction times. Part of the catalyst became immersed and even after complete immersion methanol synthesis from syngas bubbling through the liquid went on.
The liquid phase consists of mainly methanol and water. The exact composition is a function of conversion, process conditions, and syngas composition. Condensation may have positive effects on methanol synthesis as will be demonstrated later on in this chapter. Conversions higher than the chemical equilibrium are achieved and almost complete conversion of the limiting component(s) can be obtained at appropriate conditions. As a consequence, recycle and purge streams are not necessary, the limitations on the
4.3. Modelling simultaneous phase and chemical equilibria
A solution model to calculate equilibrium conversions in methanol synthesis including condensation was developed. The effects of process conditions (pressure, temperature, gas composition) can be assessed with the model. Dew points were calculated using Eq. 19 for a given pressure and temperature for each component [42, 43]. A modification of the Soave-Redlich-Kwong equation of state (for polar components) was used to calculate the fugacities of each phase.
A typical equilibrium diagram for H2/CO/CO2/CH4 = 70/5/20/5 vol% is given in Figure 12. The equilibrium diagram for this gas composition illustrates clearly the influence of condensation on the equilibrium conversion.
In the diagram, 4 curves are shown. Curve
4.4. High pressure methanol synthesis in a packed bed reactor
Methanol synthesis experiments were conducted in the packed bed reactor using 3 different syngases (see Table 1) and pressures of about 20 MPa. Gas 1 and 2 represent typical methanol synthesis gases (
To check the assumption of equilibrium at the reactor outlet and that the experiments were not conducted in the kinetic regime experiments with different flow rates were conducted for gas 1. For the experiments, methanation and the formation of higher hydrocarbons were negligible. For gas 1, the CO+CO2 conversion at 468 K and 20.7 MPa was 99.5%, which is 7.7% higher than the equilibrium conversion calculated at 7.5 MPa. For gas 2, the difference between methanol synthesis at 20 and 7.5 MPa is more pronounced. The CO+CO2 conversion at 484 K was 92.5% which is 46.9% higher than the equilibrium conversion predicted at 7.5 MPa.
|2||69.9||5.0||20.0||5.1||-||2.0||CO2 rich gas|
|3||54.2||28.9||10.9||4.0||2.0||1.1||Simulated RSCW gas|
The experimental and predicted equilibrium conversions for gas 1 and gas 2 are shown in Figure 13. At temperatures above 495 K for gas 1 and 507 K for gas 2 only a gas phase is present, while at lower temperatures condensation occurs. Methanol production continues in the two phase system until phase equilibrium and chemical equilibrium are reached. At the lowest temperatures in the range, the CO+CO2 conversion is nearly complete for gas 1 (Figure 13A). The conversion of CO+CO2 decreased with increasing temperature as dictated by thermodynamics. The experimental conversions coincide nicely with the conversion predicted by the model. The effect of condensation was more pronounced for gas 2 (Figure 13B). Here, the experimental conversion is even 12.7% higher than the extrapolated gas phase equilibrium curve (
In Figure 14, both the CO+CO2 conversion (Figure 14A) and the H2 conversion (Figure 14B) are depicted for gas 3. At the two lower temperatures, the equilibrium predictions coincide nicely with the experimental data for, but this changes at the higher temperatures most probably due to the formation of HA. This is a common phenomenon for systems at higher temperatures with high CO partial pressures [46, 47]. HA formation is not included in the equilibrium model and this explains the deviations at higher temperatures.
The concentration of the main HA is given in Figure 15. The methanol concentration clearly decreases over the temperature range in favor of the HA. Based on thermodynamics the formation of higher alcohols is expected as HA formation is favored over methanol . The main HA formed in the experiments were ethanol and 1-propanol followed by 1-butanol, 2-methyl-1-propanol, and 2-methyl-1-butanol.
4.5. Consequences of methanol synthesis for the integrated concept
The main result from high pressure methanol synthesis experiments is the observation that high conversions of the limiting component are attainable. These conversions are higher than calculated on the basis of chemical gas phase equilibria and are due to condensation. When the HA concentration was low, the experimental conversion corresponded nicely with the equilibria predicted. In conclusion, when a combination of high pressure and moderate temperature (463 ≤
5. Demonstration of the integrated concept
To demonstrate the integrated concept for methanol synthesis, experiments were conducted in the integrated continuous unit depicted in Figure 3 . Both, process conditions and recycle options of the reforming section were investigated to maximize methanol yields. This requires proper operating conditions for each reactor section (reforming, methanol synthesis) to limit by-product formation (e.g. CH4, higher hydrocarbons, and HA) and to allow operation at high equilibrium conversions in methanol synthesis. In this section, both the results for the overall integrated process will be discussed as well as the result for the reformer section in these experiments. Four different cases are considered with different feed concentrations and operating conditions. An overview of the experiments is presented in Table 2 and a short resume is given below.
The first case is considered the base case. The experiment of the base case was conducted using the LPS without recycling the effluent water (see Figure 3). Part of the gas produced is lost as it dissolves in the aqueous phase that leaves the process. In case 2, 3, and 4 the effluent water from the reformer is recycled after the HPS. Operating with a recycle stream at high pressure in RSCW is a unique feature. As a consequence of the recycle stream no gas is lost in the reformer section through the LPS and additionally, the water consumption of the process is reduced significantly. In these experiments the glycerol reforming is carried out catalytically by using the Ni based catalyst in combination with higher temperatures. All C2+ hydrocarbons are then reformed and the CH4 equilibrium concentration decreases (with higher temperatures) yielding a more attractive gas composition .
Finally, in case 4 an extra methanol synthesis packed bed (P1) was added to achieve equilibrium gas phase conditions at the outlet. The methanol synthesis section now consists of 3 packed bed reactors (P1 – P3) in series. The three packed beds were operated at different temperatures, viz. ± 518 K (P1), ± 503 K (P2), and 481 – 482 K (P3) by cooling the heating medium between the reactors. The reaction rate in methanol synthesis depends strongly on temperature. Higher temperatures lead to higher reaction rates. In the first reactor (P1) the reaction rate will be relatively high while the second (P2) and third (P3) are used to achieve equilibrium. Typical run times for the experiments were 6 – 10 h and steady state was reached in approximately 2 h. In case 4 the operating time exceeded 20 h of which 16 h in the integrated mode. This experiment is considered as the long duration experiment.
5.1. Reformer performance
Typical conditions for the reformer section (see Figure 3) for these experiments were pressures from 24 to 27 MPa and temperatures between 948 and 998 K. At these conditions the residence times of the reformer section (R1 – R5) were in the range of 30 – 35 s. The composition and quantity of the off-gas were analyzed to determine the carbon balance. The hydrocarbon concentration in the off-gas is the summation of the concentrations of CH4 and C2H6. The main results of the glycerol reformer section are summarized in Table 3.
Carbon balance closure for the reformer is very satisfactorily and was between 95 and 104%. The glycerol conversion was almost complete for all experiments, which is in line with previous work [18, 29]. The syngas produced had the following composition range: H2/CO/CO2/CxHy = 44 – 67/1 – 21/16 – 34/2 – 18 vol%, 0.7 ≤
5.1.1. Base case
The base case experiment was conducted with a glycerol feed concentration of 10 wt% at 27 MPa and 948 K. The unit was operated without a catalyst in the reformer section and in a once-through mode. Part of the gas (ca. 13%) dissolved in the effluent stream from the LPS (see Figure 3, D2) and is not used for the subsequent methanol synthesis. Due to the absence of catalysts, a significant amount of CO is present in the syngas. The product gas has a relatively low
5.1.2. Case 2 – 4
The intention for case 2 was to aim for higher
For case 3 the glycerol feed concentration was reduced to approximately 4 wt%. The H2 and CO2 concentration increased compared to the base case, whereas the CO and hydrocarbon concentration were lower, resulting in a slightly more attractive
5.2. Performance of the integrated process
The results for the integrated process, including methanol synthesis, are presented in Table 4. The equilibria in methanol synthesis were calculated with the data from Table 3 as input and the equilibrium model described in Section 4.3. If applicable, condensation of methanol and water was accounted for in the equilibrium calculations . The equilibrium data should be considered with some care, because the results are based on the assumption of constant gas composition and gas flow from the reformer section. As for the reforming experiments, all methanol synthesis experiments have good closures of the carbon balance (93 – 96%), particularly when regarding the complexity of the integrated process. A detailed summary of the experimental results of the integrated process is given below. As in section 5.1, case 1 is considered as base case and the results of the other experiments are compared to this experiment.
5.2.1. Base case
In the experiment in case 1, the methanol synthesis reactors were operated at 468 K. Hydrocarbons are inert in methanol synthesis and as a results their concentration increased strongly in the off-gas of the methanol synthesis reactor to over 50 vol%. The H2 and CO concentration in the outlet of the methanol reactor were 3 and 2 vol%, respectively. The CO2 concentration increased compared to the reforming gas, as mainly CO was converted to methanol. The gas composition and liquid yield at the exit of the methanol reactor were close to equilibrium, with the liquid yield slightly lower and experimental conversion slightly higher than predicted by equilibrium modelling. The overall carbon conversion was 26% which is equal to a methanol yield of 0.27 kg methanol/kg glycerol. The conversion of 26% is the highest conversion possible with such a syngas composition, because equilibrium was reached.
5.2.2. Case 2 – 3
In case 2, a different approach was followed. Due to the Ni based catalyst in the reforming section the hydrocarbon concentration decreased and almost all C2H6 was reformed. Furthermore, almost all CO was converted into CO2, which therefore became the main carbon source of methanol. The temperature of the methanol synthesis reactors was increased compared to the base case (from 468 – 498 K), because methanol synthesis from mainly CO2 proved to be slower than methanol synthesis from CO. The methanol yield was, with 0.29 kg methanol/kg glycerol, similar to the base case, but in case 2 equilibrium was not reached. Higher conversion are thus possible with longer residence times.
For case 3 the glycerol feed flow was reduced with a factor 3 to improve the gas composition, resulting in a reduction in feed gas flow. Therefore, to obtain higher conversion, the temperature of the methanol synthesis reactor was reduced to 483 K. Again, the carbon conversion and methanol yield (0.27 kg methanol/kg glycerol) were comparable to the base case, but remained far from equilibrium.
5.2.3. Case 4: Long duration experiment in the integrated unit
In case 4 (long duration run, 20 h) an extra methanol synthesis packed bed (P1) was filled with catalyst. The methanol synthesis reactors were operated at three different temperatures (± 518 K (P1), ± 503 K (P2), and 481 – 482 K (P3). The lowest hydrocarbon concentration in the gas phase after the reformer was observed due to the use of a fresh reforming catalyst. As a consequence the corresponding carbon conversion in the methanol synthesis unit increased to 60% (
Though some scattering in the methanol yield can be noted (due to some pressure fluctuation and uncontrolled release by the back pressure valve during the experiment), the integrated system was running steadily and the methanol yield was more or less constant. The selectivity (
5.3. Liquid composition after methanol synthesis reactor
The main constituents of the liquid products of the integrated experiments are given in Table 5. The liquid phase was analyzed on methanol, water, and the eight most common HA. In general, the concentration of HA was very low (< 0.23 wt% of the total and < 0.24 wt% of the organic fraction), probably due to the low temperatures of the methanol synthesis and the high CO2 content of the feed gas, leading to the formation of water . Ethanol was the most predominant among the HA, with a maximum concentration of 1.2 wt‰. Noticeably, when methanol was predominantly synthesized from CO2 (case 2 – 4) the concentrations of HA were negligible. This is in agreement with literature data which show that the concentrations of HA decrease at higher H2/CO ratios in the syngas feed [46, 47].
5.4. Process analysis
The experiments conducted in the integrated unit were aimed at obtaining high carbon conversions and methanol yields when reforming aqueous glycerol solutions to syngas followed by methanol synthesis. The gas composition after reforming appeared to be the most critical factor and has a major effect on the final methanol yield. Particularly the formation of hydrocarbons should be avoided in the reformer section as hydrocarbons are inert in the subsequent methanol synthesis. Therefore, hydrocarbon reduction was the main objective in the experimental reformer program and was pursued by the application of catalysts, higher reforming temperature, and reduction of the feed concentration. Application of a suitable catalyst (Ni based) indeed led to a considerable reduction in the amount of hydrocarbons in the reformer off-gas, though as a consequence almost all CO was converted into CO2. Further research will be required to identify reformer catalysts that promote glycerol decomposition rates and hydrocarbon reforming, but do not enhance the WGS reaction. In this respect, Ir-based catalysts are promising because of good performance in aqueous phase reforming .
The conversion of CO into CO2 in the reformer section, as observed when using the Ni based catalyst, is not detrimental for the subsequent methanol synthesis. With the commercial methanol synthesis catalyst used in this study, CO2 hydrogenation is possible, as was also proven here, though the overall reaction rates in methanol synthesis are lower than in case of CO hydrogenation . An advantage, however, of CO2 hydrogenation is the high purity of the organic fraction, as the formation of HA is suppressed by, most probably, the presence of water [46, 51].
In the demonstration of the integrated concept, pure glycerol was used as feedstock for the process. When crude glycerin is used salts are present and they have to be removed upfront. Continuous salt removal is possible and has been demonstrated in the literature .
A successful experimental demonstration of glycerol conversion to methanol was shown by the integration of two processes. Glycerol was reformed in supercritical water to syngas and the syngas was subsequently converted to methanol. Before integration of the two processes the processes were investigated individually. In glycerol reforming a gas containing mainly H2, CO, CO2, CH4, and C2H6 was produced. When a Ni based catalyst was used the higher hydrocarbons were reformed and CH4 approached its equilibrium concentration. In methanol synthesis
The methanol yields of the integrated process depended mainly on the gas composition obtained in the glycerol reforming process, which appeared to be the most attractive for methanol synthesis at high temperature and low feed concentration in combination with a Ni based catalyst. The continuous unit was modified during the experimental program to increase the methanol yields. The effluent water of the reformer section was recycled at high pressure, to reduce the water consumption of the process. The highest methanol yield of 0.62 kg methanol/kg glycerol was obtained using the Ni based catalyst in the reformer section and recycling of the effluent water. In this particular experiment glycerol was converted to mainly H2 and CO2 and smaller amounts of CH4 and CO. In this experiment, 60% of the carbon present in the glycerol ends up in methanol. These yields are close to the equilibrium yields. The integrated unit was operated smoothly for more than 16 h without catalyst deactivation.
The scope of the project is much broader than the production of methanol from glycerol for the reuse in biodiesel production. Due to the investigation of the individual processes more insights in reforming and methanol synthesis were obtained. Furthermore, the feedstock for the reforming process was glycerol in this case, but several types of biomass (preferably liquid) including aqueous phase fractions from pyrolysis oil upgrading, black liquor, etc. can be used for the reforming process. When these types of feedstocks are ‘green’ renewable methanol can be produced, which is a promising process for the (near) future.
The authors acknowledge the assistance given by the following companies and publishers in permitting the reproduction of figures, tables, and portions of the text (with minor adaptations) from their publications.
The authors would like to acknowledge the EU for funding the work through the 5th and the 7th Framework Program (Superhydrogen: ENK5-2001-00555 and Supermethanol: no. 212180) and Agentschap NL (EOSLT05020). The initial screening for Supermethanol was funded by Agentschap NL (no. 0268-05-04-02-011 and no. NEOT01008). We also would like to thank the partners of the Supermethanol project, and in particular D. Assink, K.P.J. Lemmens, S.D.G.B. Nieland from BTG, The Netherlands for building and operating the units, J. Vos from BTG for proofreading, and E. Wilbers, J.G.M. Winkelman and J. Bos from the University of Groningen, The Netherlands for their assistance in the work concerning the methanol synthesis and J. Bos for taking the pictures of the reactor. V.A. Kirillov from the Boreskov Institute of Catalysis, Russia is acknowledged for supplying the reforming catalyst.