Assumptions and methods applicable while complying with newly defined design basis requirements
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Barely three months into the new year and we are happy to announce a monumental milestone reached - 150 million downloads.
\n\nThis achievement solidifies IntechOpen’s place as a pioneer in Open Access publishing and the home to some of the most relevant scientific research available through Open Access.
\n\nWe are so proud to have worked with so many bright minds throughout the years who have helped us spread knowledge through the power of Open Access and we look forward to continuing to support some of the greatest thinkers of our day.
\n\nThank you for making IntechOpen your place of learning, sharing, and discovery, and here’s to 150 million more!
\n\n\n\n\n'}],latestNews:[{slug:"intechopen-supports-asapbio-s-new-initiative-publish-your-reviews-20220729",title:"IntechOpen Supports ASAPbio’s New Initiative Publish Your Reviews"},{slug:"webinar-introduction-to-open-science-wednesday-18-may-1-pm-cest-20220518",title:"Webinar: Introduction to Open Science | Wednesday 18 May, 1 PM CEST"},{slug:"step-in-the-right-direction-intechopen-launches-a-portfolio-of-open-science-journals-20220414",title:"Step in the Right Direction: IntechOpen Launches a Portfolio of Open Science Journals"},{slug:"let-s-meet-at-london-book-fair-5-7-april-2022-olympia-london-20220321",title:"Let’s meet at London Book Fair, 5-7 April 2022, Olympia London"},{slug:"50-books-published-as-part-of-intechopen-and-knowledge-unlatched-ku-collaboration-20220316",title:"50 Books published as part of IntechOpen and Knowledge Unlatched (KU) Collaboration"},{slug:"intechopen-joins-the-united-nations-sustainable-development-goals-publishers-compact-20221702",title:"IntechOpen joins the United Nations Sustainable Development Goals Publishers Compact"},{slug:"intechopen-signs-exclusive-representation-agreement-with-lsr-libros-servicios-y-representaciones-s-a-de-c-v-20211123",title:"IntechOpen Signs Exclusive Representation Agreement with LSR Libros Servicios y Representaciones S.A. de C.V"},{slug:"intechopen-expands-partnership-with-research4life-20211110",title:"IntechOpen Expands Partnership with Research4Life"}]},book:{item:{type:"book",id:"3765",leadTitle:null,fullTitle:"Computer Vision",title:"Computer Vision",subtitle:null,reviewType:"peer-reviewed",abstract:"This book presents research trends on computer vision, especially on application of robotics, and on advanced approachs for computer vision (such as omnidirectional vision). 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The seismic probabilistic safety assessments of several nuclear power plants also provided similar results. On the other hand, experiences show that plants survive much larger earthquakes than those considered in the design base, as it was the case of Kashiwazaki-Kariwa plant, where the safety classified structures, systems and components survived the Niigata-Chuetsu-Oki earthquake in 2007 without damage and loss of function (IAEA, 2007). In spite of the nuclear catastrophe of the Fukushima Daiichi plant caused by the tsunami after Great Tohoku earthquake 11th of March 2011, the behaviour of thirteen nuclear unit in the impacted area on the East-shore of the Honshu Island demonstrated high earthquake resistance. Consequently, proper understanding and assessment of the safety for the case earthquake (and generally for the external hazards) is very important for the operating nuclear power plants.
For the operating plants basic questions to be answered are, whether the nuclear power plant (NPP) is safe enough within the design basis and whether the operation can be continued safely if an earthquake hits the plant.
The designer and operators were mainly focusing on the first question, i.e. whether the reactor can be shut down, cooled-down, the residual heat can be removed from the core and spent-fuel stored at the plant, and the radioactive releases can be limited below the acceptable level in case of an earthquake. The second question became important especially after series of events when large nuclear capacities were shutdown for assessment of plant post-earthquake condition and justification of safety before their restart (Onagawa NPP in 2005, Shika NPP in 2007, Kashiwazaki-Kariwa NPP in 2007, Hamaoka NPP in 2009). Obviously, there is a need for reliable justification of plant safe status after felt earthquake for avoiding long shutdown time and consequent economic losses. Recently, the importance of the rapid assessment of the post-event plant status became very important from the point of view of the emergency management. This is one of the lessons learnt from the stress tests of nuclear operators following the Fukushima Dai-ichi accident.
Operators of nuclear power plants worldwide performed seismic re-evaluation and upgrading programmes of nuclear power plants during last three decades. A summary of international effort is given e.g. in (Campbell, et al, 1988; Gürpinar & Godoy, 1998) and in the special report issued by Nuclear Energy Agency, thereafter NEA, (NEA, 1998). The re-evaluation and upgrading of the seismic safety of the operating nuclear power plants were motivated mainly by the changing understanding of the seismic hazard at plant sites and/or recognition of inadequacy of design and/or qualification of certain safety related systems, structures and components relative to the seismic hazard or state-of-the-art of the technique and the requirements. In some countries, the existence of necessary margins with respect to the beyond design base earthquakes and avoidance of the cliff edge effects have to be demonstrated. The scope of the seismic re-qualification and upgrading programmes includes the definition of the pre-earthquake preparedness and post-earthquake actions at the plants.
All operating nuclear power plants in the United States are conducting an Individual Plant Examination of External Events, including earthquakes beyond the design basis, and about two-thirds of the operating plants are conducting parallel programs for verifying the seismic adequacy of equipment for the design basis earthquake; see (Campbell, et al, 1988). Western European countries also performed some re-evaluation of their older nuclear power plants for seismic events (NEA, 1998). Most extensive programmes have been performed in Eastern-European countries, where the operators implemented comprehensive programmes for evaluating and upgrading the seismic safety of their operating nuclear power plants (Gürpinar and Godoy, 1998; IAEA, 1995, 2000). Seismic re-qualification has been performed at following VVER plants:
NPP Paks, Hungary VVER 440-213, 4 units
NPP Mochovce, Slovakia VVER 440-213, 2 units
NPP V2 Bohunice, Slovakia VVER 440-213, 2 units
NPP Dukovany, Czech Republic VVER 440-213, 4 units
NPP Medzamor, Armenia, VVER 440(specific design) 1 unit
NPP Temelin, Czech Republic, VVER-1000, 2 units
NPP Kozloduy Unit 5 and 6, Bulgaria, VVER-1000, 2 units
The scope of seismic safety programmes at VVER-440/213 plants was the most extensive. It includes the re-evaluation of the hazard, reinforcement of structures and components, qualification of the active equipment, installation of seismic instrumentation and development of appropriate procedures. The seismic safety programme implemented at Paks NPP was one of the most complex one. The implementation of measures was completed in 2003. Therefore the peculiarities of the programme, its scope and the applied methodologies could not be properly addressed and interpreted in the referenced above review papers. Originally the Paks NPP has not been designed and qualified for the earthquake loads. The seismic safety programme at Paks NPP has therefore aimed at design basis reconstitution. The re-evaluation of site seismic hazard included all required geological, geophysical, seismological and geotechnical investigations. The seismic design basis had been newly defined. Formally the compliance with design basis requirements has to be ensured by design methods and standards. It was already recognised that a consequent and full scope re-design in line with design codes and standards and subsequent upgrading might be impossible at Paks NPP. It should be recognised that use of methodologies developed for the justification of the seismic safety of operating plants does not ensure the compliance with design basis requirements and cannot be directly applied for VVER plants. The qualification of the nuclear power plant have been executed for the newly defined design basis earthquake by applying procedures and criteria for the design, combined with the methods and techniques developed for seismic re-evaluation of operating nuclear power plants. The selection and use of methodologies has been graded in accordance with safety and seismic classification of the SSCs. After implementing the measures for design basis reconstitution, the achieved level of safety has been quantified via seismic PSA, which provides the core damage frequency.
The question of the safe continuation of operation became very important as the World largest Kashiwazaki-Kariwa plant was shutdown for long-term after Niigata-Chuetsu-Oki earthquake in 2007 that caused a 0.67g ground motion acceleration at the site (value measured at the Unit 1 base mat). The safety classified SSCs designed for PGA 0.27g survived the earthquake without damage and loss of function while the non-safety structures were heavily damaged. The justification of the safety took two years.
The decision on the continuation of the operation is rather simple if the earthquake does not exceed the operational base (OBE) level. The case becomes more difficult if the OBE-level is exceeded and there are obvious damages in place. The justification of operability is even more complex if the earthquake loads exceed the design base level and there are no obvious failures/damages as it happened at the Kashiwazaki-Kariwa plant. Obviously, the judgement on the continuation of operation should be based on the set of information regarding capability of SSCs to survive an earthquake and on the post-event inspections, tests and analyses. It would be very reasonable to have in advance an assessment method for the plant status to ensure the effectiveness of the post-earthquake walk-downs and other actions, and to limit the time of shutdown. The methods for judgement on the safe continuation of operation can be developed on the basis of the design information. The results of the seismic probabilistic safety analysis (seismic PSA) or margin assessment provide useful additional information regarding weak-links. The design provides deterministic type information that no failure or damage should be expected if the earthquake loads do not exceed the design base level. However, the probability of damage is not zero even if the loads are less than the design base one. The seismic PSA provides the core damage frequency as the output of the analysis, which is a measure of the seismic safety. The PSA is generally failure oriented. The seismic PSA shows the weak links. This knowledge can be very useful for the planning of the post-event inspections. Similar information is provided by the seismic margin analysis, which quantifies the capability of the plant to survive an event greater than the design basis one.
After the severe accident at Fukushima NPP the operators in European Union, U.S. and some other countries including Japan performed comprehensive safety and risk evaluation of operating nuclear power plants, see e.g. (European Commission, 2011). These tests/reviews will launch different re-evaluation and upgrading programmes with regard to seismic safety and for improvement of the capability to cope with the beyond design base earthquake and associated events (fire, flood) at the existing plants. This process includes at some sites the re-assessment of the site hazard motivated by recent events and/or new scientific evidences, for example in the U.S. (NRC, 2011). These lessons learned will also affect the projects under preparation and/or implementation. For the new plants, it has to be demonstrated that the plant has sufficient margins with respect to the design basis extension earthquake loads of and avoiding the cliff-edge effect. Consequently, the lessons learned from the former projects for evaluation of the seismic safety and upgrading of operating plants are still of great practical importance.
Objective of the recent Chapter is to provide practical insights to the re-evaluation and upgrading of seismic safety of operating plants.
Evaluation of seismic safety and re-qualification of operating plants require specific approach; the safety goals have to be ensured in reasonable manner, avoiding unnecessary conservatism, contrary to the design that is ab’ovo conservative. State-of-the-art methodologies have to be implemented in every aspect of the re-evaluation and upgrading process. The optimisation of the measures from logistics point of view is very important under the condition of an operating plant.
International Atomic Energy Agency developed a comprehensive Safety Guide on “Evaluation of Seismic Safety for Existing Nuclear Installations” (IAEA, 2009a). The supporting document of this Guide is the Safety Report Series No 28 on “Seismic Evaluation of Existing Nuclear Power Plants” (IAEA, 2003) that summarises the before 2003 experience in the seismic evaluation and upgrading of the operating plants. These documents focus mainly on the methodologies for seismic safety evaluation that do not involve a change in the design basis earthquake.
In this Chapter the case of seismic evaluation and upgrading methodologies and solutions are presented. The Chapter includes the case for upgrading of an operating nuclear power plant originally not designed for earthquake. Based on the graded approach, the feasibility of the application of seismic design methods combined with those developed for the re-evaluation of existing plants is demonstrated.
New areas of the seismic safety evaluation of operating plants are also addressed in the Chapter that were triggered by recent events, the Kashiwazaki-Kariwa plant and the Fukushima Dai-ichi plant, that are focusing on the assessment and assurance of the beyond design base capability of the nuclear power plants, periodic review of safety, etc.
Scope of the Chapter covers
the basic principles for ensuring the seismic safety of nuclear power plants,
typical cases of the re-evaluation and re-qualification programmes, including cases of design basis reconstitution and studies for restart after an earthquake as well as the evaluation of the beyond design base capabilities of the plants,
the applicable re-evaluation methodologies,
the most important aspects of the pre-earthquake preparedness and post-earthquake actions,
the full scope implementation example,
the aspects of maintaining the seismic qualification during operation and periodic safety review.
Section 2 of this Chapter defines the basic principles of seismic safety. Section 3 provides an overview of the methodologies applicable: Section 3.1 outlines the objective and scope of the seismic safety programmes. Section 3.2 provides an overview of applicable methodologies. Sections 3.3 address the issues of restart after earthquake. Section 3.4 outlines the questions of accident management. Sections 3.5 to 3.7 address the walk-down, design of upgrading and role of the peer-review. Section 4 is devoted to the pre-earthquake preparedness and post-earthquake actions. The practical and full scope example of seismic re-evaluation and upgrading is shown in Section 5. Section 6 and 7 are related to the maintenance of the seismic qualification during operation and periodic safety reviews. Extensive list of references is provided to the Chapter in Section 8.
The fundamental safety objective of design and operation of nuclear power plant is to protect human life and environment in case of any malfunctions, failures of the plant systems, structures and components which may occur during the plant lifetime including those caused by rarely occurring earthquakes. The generic approach for ensuring this safety objective is the application of the concept of the defence in depth. In accordance with this concept, the following requirements are applicable:
Inherent and/or engineered safety features, safety systems and procedures have to be in place for the case of earthquakes
for leading the plant to a safe shutdown state, i.e.
for the maintaining the sub-criticality in the reactor and spent fuel pool and,
for the cool down and heat removal from the core and spent fuel;
for maintaining at least one protection barrier to ensure that the radiological consequences would be below the required limits.
Means, plans and procedures have to be in place for on-site and off-site emergency response to mitigate the consequences of accidents that result from failure of safety features and accident management measures in case of severe earthquakes.
The seismic safety is ensured by the following complex activities:
Site investigations and evaluation of the site seismic hazard, including hazards caused by the earthquake, like soil liquefaction;
Definition of the characteristics of the design basis earthquake;
Adequate design;
Use of qualified components;
Installation of seismic instrumentation;
Development of accident-prevention and accident-management procedures;
Evaluation of safety;
Seismic housekeeping;
Periodic safety assessment and subsequent upgrading if needed.
The basic safety functions, i.e. shut down, cooling and containment, have to be maintained for the earthquakes within the design basis envelope and with some extent for the severe beyond design basis earthquakes.
Traditionally the design of the nuclear facilities adapted the two-level concept: design for safety, using a high-level seismic excitation for design basis and design for production, using a moderate level of seismic excitation for operational limit.
The design base earthquake has to be defined with quite low probability of exceedance during operating time. This earthquake is the Safe Shutdown Earthquake (SSE) as per U.S. terminology; see U.S. NRC 10CFR Part 50, Domestic Licensing of Production and Utilization Facilities (NRC, 1956). It is called
Operability of NPPs should be ensured after the moderately frequent and not severe earthquakes. The operational base earthquake (OBE or SL-1 level according to the IAEA terminology) level is defined as a design level for continuous operation. The OBE was usually defined as an event with frequency of 10-2/a, or a ground motion with maximum horizontal acceleration equal to a given fraction of the maximum acceleration value of the SSE. Through the years the concept of designing for two earthquakes has radically changed. Nowadays, the OBE is interpreted as an operational limit and inspection level rather than an obligatory design level. The definition of the OBE level is subject of design, operational, economic considerations; see the IAEA NS-G-3.3 Safety Guide (IAEA, 2002). Design for lower level is not required if the OBE PGA is equal or less than 1/3rd of the SSE PGA, see in Appendix S of the 10 CFR Part 50. Instead of OBE PGA, new criteria for the exceedance of operational limit/inspection level are introduced. The changes of the terminology in the German regulation demonstrate the changes in design concept: the former terms SSE
Major tasks of the seismic re-evaluation and upgrading projects are
identification of the objective and scope of the programme
selection of the methods for the re-evaluation, including definition of the seismic input for the analyses and performance of the analyses
design/development and implementation of modifications and re-qualification measures
evaluation of the achieved safety level, calculation of the core damage frequency due to earthquake.
The tasks are determined by the objective of the project as it has been shown above, i.e. resolution of qualification issues, ensuring the design basis compliance, etc.
Generic objective of the seismic safety programmes is to ensure the basic nuclear safety functions, i.e.
the control of the reactivity in the reactor and spent fuel pool, i.e. the ability to shutdown the reactor and maintain the sub-criticality after the earthquake,
to cool down and heat removal from the core and spent fuel,
to maintain the containment function for the reactor and spent fuel, i.e. limit the release of radioactive substances into the environment.
The functions have to be maintained for the earthquakes within the design basis envelope and with some extent for the earthquakes with parameters exceeding the design basis one.
The basic concept of the seismic safety re-evaluation and of the operating nuclear power plants, and the selection of the methods and criteria is different from that are required in case of the design of new power plants; see the
The graded approach is used while ensuring the seismic safety of NPPs, i.e. the safety importance of the SSCs is considered and according to this the SSCs are classified into seismic safety classes, which define the requirements assigned to the design, qualification and operation of the SSCs. Well-defined set of plant systems and structures and components are required to be functional during and after the earthquake for bringing the plant in-to stable shutdown condition. Some of those SSCs are passive, e.g. the pressure retaining boundaries or the containment. They shall sustain the vibratory load remaining leak-tight; however some plastic deformation, ductile behaviour might be allowed. In some cases the deformation has to be limited to the elastic for ensuring some active functions. Building structures and equipment supporting structures might be also loaded to plastic region up-to the level, which does not impair the intended safety functions. The active systems functionality requires qualification for the vibratory motion as well as availability of supporting functions, e.g. electrical power supply.
Practically, a conscious and careful evaluation and utilisation of the built-in margins provide the possibility for achieving the target safety level at operating plants by feasible amount of modifications and re-qualifications.
The scope and the methodology of the seismic safety programmes vary with the motivation of the particular project. Practically there have been three different objectives of the past seismic safety programmes:
to resolve the inadequacy of the design and qualification while the seismic design basis remains unchanged, i.e. to comply with the current licensing basis;
to comply with newly defined seismic design basis (modification of design basis either because of new scientific evidences regarding seismic hazard or because of changing regulations);
to evaluate and demonstrate the seismic margin.
The objective and scope of recent seismic safety re-evaluation programmes is to demonstrate the plant safety for the design base extension, to justify the re-start after strong earthquake, and to identify the plant vulnerability in case of severe event and develop adequate accident management provisions.
Example for the first type of seismic safety programme is the resolution of USI A-46 seismic issues of older, operating nuclear power plants in the U.S. (NRC, 1987). This programme was aimed to demonstrate the seismic adequacy of essential equipment at older operating plants by the use of available seismic experience data for similar equipment. The rules for the resolution of the USI A-46 issues are defined in the Generic Implementation Procedure, thereafter GIP, developed for Seismic Qualification Utility Group [SQUG] (SQUG, 1992). The scope of the programme was limited to the equipment needed for the safe shutdown of the reactor after a design basis earthquake and bringing the plant to a stable hot or cold shutdown condition for as minimum 72 hours of time. A single shutdown path and a backup for decay heat removal were defined. The seismic input used for the qualification was set to the SSE and the design floor response spectra. The core of the GIP is the empirical qualification method and database. The GIP was applied in several countries, e.g. U.K. and Belgium.
It is important to demonstrate on one hand that the nuclear power plant will remain safe in case of an earthquake that exceeds the design base level, whether the basic safety functions can be lost due to sudden failure (i.e. ‘cliff-edge’ effect). On the other hand it is important to know the contribution of the seismic hazard to the plant core damage frequency. Example for margin assessment and quantification of the seismic safety in terms of core damage frequency is the NRC initiated Individual Plant Examination of External Events, thereafter IPEEE in the U.S. (NRC, 1991). There are three methods for the margin assessment: the seismic PSA, and margin assessment using either the deterministic method developed by EPRI or the probabilistic method developed by the NRC. In this case of deterministic method a reference level earthquake is selected for which – under certain assumptions – the capacity has to be demonstrated. The scope of SSCs considered in the margin assessment depends on the method selected, e.g. in case of seismic PSA the scope of SSCs is identical to the Level 1 PSA plus the containment.
The most demanding programmes were those for ensuring the compliance with newly defined design basis.
These programmes include the following tasks:
Evaluation of the seismic hazard of the site that includes the associated with earthquake events, e.g. liquefaction;
Development of the design basis earthquake characteristics;
Identification of the structures, systems and equipment, which are needed for ensuring that basic safety functions;
Evaluation of the seismic capacity of SSCs and identification of the upgrading;
Design and implementation of the necessary corrective measures;
Installation of seismic instrumentation;
Development of pre-earthquake preparedness and post-earthquake measures;
Evaluation of the safety, i.e. quantification of the core damage frequency due to earthquake, quantification of the safety margins.
Depending on the case and the national regulation, the scope of the design base reconstitution programme can cover either all SSCs classified into seismic and safety classes as per new design, or the scope is limited to the SSCs required for safe shutdown and bringing the reactor into stable (hot or cold) shutdown condition. Those non-safety classified SSCs have to be also considered damage/failure of which can disable certain safety functions due to seismic interactions (falling down, flooding, fire).
The quantification of the margins has three aspects:
it is part of the design,
it is needed while evaluating the plant condition and justifying the restart after a strong earthquake hit the plant,
it is needed for the development of the severe accident management provisions.
According to the IAEA design requirements NS-R-1 (IAEA, 2000),
According to the novel requirements, the capability of the new plants to withstand the loads and conditions of the design basis extension has to be ensured by the design provisions. In case of new plants, a minimum configuration of SSCs for ensuring the shutdown and subcriticality of the reactor, heat removal to the ultimate heat sink and the containment have to remain functional for the accident management purposes. A margin type evaluation has to be performed for demonstration the beyond design base capabilities of the new plants (1.4 times the SSE loads as per EUR requirements and 1.67 times of the SSE loads in the U.S. practice). Best estimate methods can be used for the justification beyond design base capabilities.
The plant safety re-assessment after a strong earthquake requires an overall checking the post-event condition of all SSCs, even those non-safety classified SSCs, since both the safety and operability have to be demonstrated. The possible analysis and testing/inspection methods should be selected and applied in accordance with safety relevance and impact on the operation (Nomoto, 2000). According to (Kassawara, 2008), the probabilistic margin analysis can also be effective in this case.
Recently, the availability of severe accident management provisions become of great importance. The scope of stress tests covers review of compliance with design base requirements, demonstration of beyond design base capacity (avoidance of the cliff-edge effect) and identification of plant vulnerability/damage state and development of severe accident management measures and guidelines. Generally, some margin type analyses have been performed in the participating countries for the possible minimum configurations needed for shutdown and heat removal of the reactor and spent fuel and protection of the containment. Identification of seismic interactions (fires, flooding, logistical obstacles) became important since these can affect the function of the SSCs within the minimum configuration, inhibit the connections of provisory power and cooling lines, impeding the implementation of Severe Accident Management/mitigation measures as it is to see in the country reports at the European Nuclear Safety Regulators Group site (ENSREG, 2012).
The methodologies for the seismic re-evaluation and re-qualification are as follows:
Qualification by empirical methods
Quantification of margins:
Seismic Probabilistic Safety Assessment (NRC, 1983)
NRC Seismic Margins Method (Budnitz et al., 1985; Prassinos et al., 1986)
Electric Power Research Institute Seismic Margins Method (EPRI, 1988)
Design methods – justification by analysis
Empirical qualification of the plant equipment is a powerful tool for seismic re-qualification of operating NPPs. The empirical qualification methods have been recognised by IAEA in the Safety Guides NS-G-1.6 as well as NS-G-2.13.
The empirical qualification database developed for SQUG covers twenty classes of equipment, e.g. active equipment as well as cable raceways, tanks and heat exchangers (SQUG, 1992; Starck&Thomas, 1990), except of pipelines and structures. As an alternative solution, the U.S. Department of Energy [DoE] has developed the Seismic Evaluation Procedures, a procedure similar to GIP that also covers pipelines and ventilation ducts (DoE, 1997).
The steps of the Generic Implementation Procedure are as follows (SQUG, 1992):
Development of safe shutdown equipment list
Development of seismic demand (in-structure response)
Equipment walk-down and screening
Relay evaluation
Outlier resolution
Reporting
The methodology and the database (the so called SQUG-database) can be adapted to the needs of different programmes for the resolution of design/qualification inadequacy issues.
Generally the process has to be started with development of the list of SSCs requiring re-qualification for a given level of earthquake. The basis of the identification of the scope can be the list of SSCs for safe shutdown or the seismic and/or safety classification database as it was the case at Paks NPP.
Four criteria are used for the verification of seismic capacity: (1) Comparison of the seismic demand to the SQUG bounding spectrum; (2) Checking in the experience database (caveats and inclusion rules); (3) Checking the anchorage; (4) Evaluation of the seismic interactions.
The seismic demand can be defined either by design floor response spectra, or by scaling-up the design floor response spectra to the required level, or by completely new response calculation for the required input (e.g. at Paks NPP the floor response spectra have been calculated for the newly defined DBE).
In case of most of this equipment, the load-bearing capacity is verified by demonstrating that the equipment is adequately anchored. Operability is demonstrated by verifying that the equipment is similar to the equipment of the database created on the basis of experience and that it meets all of the prescriptions included in the GIP.
Important element of the procedure is the walk-down that provides the basis for screening out the obviously rugged items and for the consideration of the as built conditions, since in majority of cases, the load-bearing capacity is ensured, if the equipment is adequately anchored.
The applicability of the empirical qualification method should be carefully checked via reviewing the similarities between the features of the items in the database and item to be qualified at the plant. The empirical method and database were adapted for the qualification of the VVER equipment (Masopust, 2003) and used for the qualification of the VVER at Paks NPP Hungary, Bochunice and Mochovce NPP in Slovakia, though the objective and scope of the particular seismic safety programmes differed very much from those in the USI A-46.
The plant design shall ensure sufficient margins against seismic demand, as it is required by the IAEA design requirements NS-R-1 (IAEA, 2000).
In case of operating plants, the objective of the seismic margin assessment (SMA) is to evaluate, quantify the inbuilt seismic margin of those structures, systems and components of the power plant that fulfil their basic safety functions during and after the earthquake. The quantification of the margins is also recommended by the IAEA Safety Guides NS-G-1.6 and NS-G-2.13 (IAEA, 2003 and 2009). The goal of the analysis is to determine the seismic shaking level at which there is a high-confidence-of-low-probability-of-failure (HCLPF). This HCLPF is mathematically defined as 95% confidence of less than 5% probability of failure.
In SMA calculation the seismic capacity
Load combination has to consist of normal and SME loads. The ground response spectrum is median-shaped.
Conservative estimate of median damping have to be used.
Best estimate structural model has to be used and the uncertainty in frequencies has to be accounted.
Calculation of the soil-structure interaction has to be best estimate taking into account the parameter variation.
Code specific minimum strength or 95% non-exceedance probability values
Static capacity equations to be used have to be for code ultimate strength (ACI) for concrete, or maximum strength, (AISC) for steel structures, or Service level D (ASME) or functional limits in case of mechanical equipment.
Inelastic energy absorption values to be used for non-brittle failure modes and linear analysis can be taken e.g. from (IAEA, 2003a)
In-structure spectra have to be calculated by frequency shifting rather than peak broadening to account for uncertainty while median damping is used.
The capacity-demand ratio for elastic response
where
The seismic capability active equipment (electrical, electromechanical and I&C) is qualified by tests or empirical method (see Section 3.2.1 above). Based on the qualification or fragility test data or generic data, a bound of the test response spectra have to be defined at about the 99 per-cent exceedance probability level. The in-structure response spectra calculated for the reference level earthquake and the ratio of the bound of the test response spectra and in-structure/floor response spectra has to be calculated. Scaling up the reference level (PGA) with this ratio provides the HCLPF capacity of the equipment. The HCLPF capacity that has to be evaluated for all items needed for ensuring the basic safety function.
A systematic SMA procedure and methodology has been developed by EPRI in NP 6041 Rev 1 consisting of following main elements (EPRI, 1998):
Definition of the Review Level Earthquake (RLE)
Identification of success paths needed to bring the reactor into stable
Two independent functional paths to shutdown
Define components in the paths
Plant walk-down
Screening out the rugged components
Identify characteristics, vulnerability
Assures verification of as-installed properties and conditions
Identify interactions
Seismic capacity evaluation for unscreened components
The SMA seismic input is the Review Level Earthquake (RLE) that should exceed the SSE. The RLE is that screening level at which structures, systems and components, necessary for the shutdown of power plant and for keeping it in the stable shutdown condition and considered to be in the ‘success path’, should be examined. (According to the definition of given in EPRI NP-6041 report, SME is equivalent to RLE specified by NUREG-1407. There are three categories of sites according to the PGA: PGA≤0.3g, 0.3<PGA≤0.5g and PGA>0.5g with reference level PGA 0.3g, 0.5g and >0.5g respectively. For the analysis, the NUREG/CR-0098 median shape ground motion response spectral can be selected.)
In margin analysis, the success path selection must include a primary success path and an alternate success path utilizing to the greatest extent possible, different equipment. One of the paths must also have the capability to mitigate a small pipe break.
The rugged components have to be screened out during the plant walk-down. For those components that were not screened out during the walk-down phase, additional analyses shall be executed to determine the HCLPF. The weakest component in a shutdown path then defines the plant level HCLPF for that path.
For the new design, the margin beyond safe shutdown earthquake has to be demonstrated (HCLPF for at least 1.67 times of the SSE in the US design practice and 1.4 times of the SSE in the European design practice).
The seismic margin assessment procedure is experience and expert judgment driven. Therefore the selection of the team is a decisive precondition for success and adequacy of the result. The development of the safe shutdown equipment list and performance of the walk-downs require very experienced team consisting of systems engineer, structural/seismic engineers trained in design and empirical qualification as well.
One of the most complex cases for assessing the nuclear power plant (NPP) safety is the evaluation of the response of the plant to an earthquake load and the risk related with this. The objective of the seismic PSA is to define the contribution of the earthquakes to the core damage frequency of the reactor and finally to the overall risk of plant operation. Risk is expressed as triplets
In case of earthquake, the probability of damage/failure of a structure or component
where the
The basics of the seismic PSA were outlined in (Kennedy & Ravindra, 1984). Frequencies of core damage caused by an earthquake are calculated by modelling of the plant behaviour by event trees constructed to simulate the plant system response. Fault trees are needed for the development of the probability of failure of particular components taking into account all failure modes. The hazard is expressed as complementary probability: 1-cumulative probability function, i.e. probability that the peak ground acceleration exceeds a given value. The fragility is defined as the conditional probability of core damage as a function of
According to ASME/ANS RA-S-2008, for evaluation of core damage frequency the doublets
where
where
The HCLPF is related to the
where
The basic steps of seismic PSA are the followings:
Determination of seismic hazard by PSHA
Systems analysis
Fault trees and event trees
Define accident sequences, associated systems, components
Fragility analysis of SSCs – Conditional failure probability
Integration of hazard and fragility resulting in seismic core damage frequency.
Since the level of core damage probability to be assessed is very low, the assessment of seismic hazard has to be performed up to very low level of annual probability, e.g. up-to 10-7/a or less. The median hazard curve can be used which can be defined adapting the guidance in the IAEA Safety Guide SSG-9 (IAEA, 2010).
The consideration of uncertainty in both fragility and seismic hazard is important for adequate safety assessment. The above formulation uncouples the uncertainties in the load and resistance parameters, embodied in the in the fragility and load probability density functions respectively. These uncertainties are usually of different origins and it is convenient to be able to treat them separately.
The level 1+ seismic PSA gives estimation for the probability of seismic induced reactor core-melt. The level 1+ means the examination of containment that includes the evaluation of the safety of containment integrity and isolation as well as the development of bypass.
The experiences of the seismic probabilistic safety (risk) studies performed in the U.S. are summarised in (NRC, 2010). In comparison with core damage frequency (CDF) due to internal initiators, the seismic core damage frequencies seem to be dominating. Similar conclusion can be made regarding seismic PSA results obtained for the Paks NPP, where the contribution of the seismic events to the total CDF is approximately equal to 75 per-cent of the total CDF; see also (Riechner et al., 2008) on the Swiss experiences. Generally, the acceptable level of the annual probability of reactor core damage due to seismic events is of order of magnitude 10-5. It seems that the uncertainties dominate the seismic CDF caused by both uncertainty of the hazard definition, especially in the range below 10-5/a frequencies, and by the uncertainty of the fragilities.
An interval representation can be proposed for accounting the uncertainty of the fragility (Durga et al., 2009; Katona, 2010). The fragility is a doublet
The most trivial case for the use of p-box can be the screening according to ruggedness of the component. The rugged components might be described by p-box with lower and upper bounding value of the variable a, or any other damage indicator, i.e. cumulative absolute velocity. The probability bounds can be defined via expert elicitation.
It can also be convenient to express the uncertainty of fragility in form of a p-box, defined by a lower bound
As it was mentioned above, in the practice the lognormal distribution is applied for fragility of structures. If the bounds on mean,
The NRC seismic margins method (NUREG CR 5334) is a truncation of PSA, i.e. the plant systems are modelled by Boolean method, while the systems needed for ensuring the basic safety functions are considered, the seismic fragility curves are developed, and the plant level HCLPF is computed (Campbell, 1998). The procedure does not involve the use of a seismic hazard for the computation of the HCLPF and the core damage frequency is not calculated.
The NRC seismic margins method involves the following steps (Prassinos at al, 1986):
Selection of the review level earthquake
Development of systems models
Initial component ruggedness screening
Plant walk-down
Development of component and structural - fragilities
System analysis
Determination of plant level HCLPF
The systems models and fragility curves are used to determine the dominant accident sequences and the plant level HCLPF. The RLE selection and walk-down procedures are similar to those used in the EPRI margin method. The screening is conducted to eliminate many components from fragility computations.
The HCLPF capacities for components in each system included into the plant model have to be defined and combined according to the Boolean representation of the system via minimum-maximum procedure: minimum HCLPF of the elements connected by or-gate and maximum HCLPF of the elements connected by the and-gate. For example, if the Boolean representation of a system composed from elements A, B, C and D is equal to A*(B+C)*D then the HCLPF of the system is equal to Maximum of (A; Minimum of (B, C); D). The plant HCLPF can also been calculated via convolution procedure.
A consequent use of design methods and standards for the re-evaluation and upgrading is not practicable for the operating plants. However, in case if the plant was not designed for earthquakes or the hazard was very underestimated, the design methods and standards have to be used for achieving the compliance with design basis requirements as much as practicable.
The graded approach has to be applied for appropriate selection of evaluation methods. Deviation from design procedures can be accepted in case of qualification of outliers of Class 3 (seismic classification see e.g. IAEA Safety Guide NS-G-1.6 (IAEA, 2003b), safety classification principles are given e.g. in the IAEA NS-R-1 (IAEA, 2000b).
The possibility of differentiation at design is exposed by guideline NS-G-1.6:
Class 1:design ensuring the function and great safety margin are necessary
Class 2:items are classified because of seismic interactions; they ‘can be designed with smaller safety margin’
Class 3:these can be designed differentiated according to hazard
Class 4:general industrial standard can be used
The assumptions and methods applicable for each tasks of the seismic re-evaluation and upgrading of the operating plants with the aim of design basis reconstitution are given in the Table 1. Practical example is given in Section 5 below.
Evaluation of the seismic hazard of the site that includes the associated with earthquake events, e.g. liquefaction; Development of the design basis earthquake characteristics; | As for new design, preferable PSHA (see the IAEA NS-R-3, SSG-9 and NS-G-3.6) DBE as for new design – The Ground Motion Response Spectra have to be modified in accordance to ASCE/SEI 43-05 (ASCE, 2005) and Reg. Guide 1.208 (NRC, 2007) to be taken for design basis response spectra. |
Identification of the structures, systems and equipment, which are needed for ensuring that basic safety functions; | According to the safety and seismic classification plus interacting SSCs. Stable shutdown conditions have to be ensured as minimum for 72 hours. Single failure criterion has to be applied. |
Evaluation of the seismic capacity of SSCs and identification of the upgrading; | Graded approach: Class 1-3 evaluation by analysis according to design codes; Class 1 and 2 outliers has to be fixed; For Class 3 outliers justification via less conservative method (realistic damping, inelastic response) or upgrade; |
Design and implementation of the necessary corrective measures (fixes and qualifications); | Design of modification according to codes and standards. Qualification by tests or empirical method. |
Installation of seismic instrumentation; Development of pre-earthquake preparedness and post-earthquake measures; | According to the IAEA NS-G-1.6, NRC Regulatory Guide and 1.12, 1.166 and 1.167, (IAEA, 1995; NRC, 1997a, 1997b, 2000, EPRI, 1988, 1989, ANS 2002) |
Evaluation of the CDF due to earthquake, quantification of the safety margins. | Seismic PSA |
Assumptions and methods applicable while complying with newly defined design basis requirements
There are specific procedures developed for the evaluation of the plant safety after a strong earthquake that are part of the plant emergency procedures (EOPs) for the case of earthquake, e.g. (NRC, 1997a, 1997b), (EPRI, 1989), (ANS, 2002) and (IAEA 2011).
The post-earthquake evaluation is in principle eclectic. The practicable methods are e.g. the evaluation by analysis, margin assessment, checking the post-earthquake condition of equipment along empirical criteria, in-service inspections and testing. Selection of the method can be performed on the basis of walk-down and visual inspection’s experiences, safety classification, etc. Lessons learnt from the case of the Kashiwazaki-Kariwa plant after the 2007 earthquake are of great importance.
The justification of the continuation of the operation after a strong earthquake (even if it is below the SSE-level) is a rather complex issue.
The design is success oriented. Consequently, the comparison design versus experienced parameters provides basis for a deterministic statement, whether an SSC will fail or not.
The seismic PSA is failure oriented, it indicate the week links that have to be carefully checked. The margin studies quantify the built-in capacities/reserves that may cover the demand even beyond the design base, see (Kassawara, 2008).
Although it is the most time-consuming and expensive, the careful testing and the implementation of state-of-the-art analysis methods and removing the unnecessary conservatism of material parameters (mainly the damping) seems to be the most powerful tool for the evaluation of post-event situation.
There is an obvious need for a better damage indicator as the PGA and response spectra of the experienced earthquake and the comparison of these to the design base PGA and response spectra. The cumulative absolute velocity (CAV) is a good indicator for no damage according to the EPRI study (EPRI, 1988). Some recent studies show that the CAV can be used for damage indicator for assessing the post-event conditions, especially for the fatigue failure mode, since the CAV can be correlated to the product of the number of load cycles and the stress amplitudes, thus the fatigue lifetime limit can be written as a function of the CAV (Katona, 2011). Comparing of the Niigata-Chuetsu-Oki earthquake in 2007 and the Great Tohoku earthquake in 2011, the most significant difference is not in the PGA but in the overall energy of the ground motion that is properly characterised by the CAV value.
Recently, the severe accident management (SAM) studies with regard to extreme environmental conditions and hazards become great importance. For the planning of the accident management and mitigation measures and development of the severe accident management guidelines, the possible accident scenarios have to be known and the plant vulnerabilities and robust features have to be identified. For the design of technical means for the accident management/mitigation, the post-event conditions have to be forecasted.
For the adequate preparation for severe accident situations, simultaneous occurrence of extremities has to be assumed. Occurrence of additional earthquake induced events has to be expected, if the beyond design basis hits the plant. For example soil liquefaction can be the dominating issue and cause cliff-edge effect on soft soil sites if a strong beyond design base earthquake hits the site, while the liquefaction may not happen in design base case.
It has to be also assumed that extreme conditions, including logistical obstacles due to on-site and off-site damages will be in place while the accident management measures have to be implemented.
The seismic PSA and margin type analyses provide the basis for the definition of the possible damage sequences and identification of effective measures. According to the PSA experience, the most serious is the sequence of the total loss of power and possibility of the heat removal to the ultimate heat sink or even loss the ultimate heat sink while the containment isolation is lost with or without of containment isolation with or without significant structural damage of the containment.
Essential task of the studies related to severe accident management is the aseismic design of the connections of the provisional systems for cooling the reactor and spent fuel pool (pipelines for cooling and DC/AC power cabling and connections). The design basis of these provisions has to be defined well beyond the plant “usual” design basis. The seismic hazard curve should be available for this reason.
The concept and the main tasks of the severe accident management studies are as follows:
identification of possible minimum configurations needed for shutdown and heat removal of the reactor and spent fuel and protection of the containment
identification of provisional and mobile tools for ensuring the heat removal and containment protection
plant walk-down for
screening out the robust elements
identification of interactions affecting the SSCs within the minimum configuration and the inhibiting the connections of provisional power and cooling lines
identification of the logistical obstacles impeding the implementation of SAM measures
identification of the measures needed for SAM
assessment/quantification of the margins
As it has been shown in the Sections above, the walk-down of the power plant is a key element of the seismic re-evaluation and re-qualification of the operating NPPs. The walk-downs provide the opportunity to see what is difficult or impossible to recognise just looking, reviewing the documentation. The aim of the walk-down is as follows:
to check the as-is conditions, i.e.
the as-is lay-out conditions,
the adequacy of the anchorages,
to check the compliance with the conditions in the re-qualification database,
to identify those interactions, which can potentially affect the performance of the seismic safety related structures, systems and components during the occurrence of an earthquake and can render this equipment inoperable,
to check the feasibility of upgrading measures.
Examples for checking the interaction items during the walk-down are listed below:
unreinforced masonry walls adjacent to safety-related equipment may fall and impact safety-related equipment or cause loss of function of such equipment,
fire extinguishers may fall and impact or roll into safety-related equipment, or spurious actuation of the fire extinguish system may happen,
inadequately anchored or braced equipment as vessels, tanks, heat exchangers, cabinets etc. may overturn, slide and impact adjacent safety-related equipment,
equipment carts, chains, air bottles, welding equipment etc. may roll into, slide, overturn, or otherwise impact safety-related equipment,
storage cabinets, office cabinets, files, bookcases etc. located, for instance in control rooms, may fall and impact adjacent safety-related equipment,
break/damage of non-safety related piping, tanks, heating may cause spray, flood and loss of function of the safety related systems,
flexible piping, cable trays, conduits, and heating, ventilation and air-conditioning (HVAC) ducts may deflect and impact adjacent safety-related equipment,
anchor movement may cause breaks in nearby piping, cable trays, conduits, HVAC ducts etc. that may fall or deflect and impact adjacent safety-related equipment,
emergency lights and lower ceiling panels can fall down and damage safety-related equipment free crane hooks may bang safety-related equipment in their vicinity,
The plant walk-down is also required for the assessment of the severe earthquake vulnerabilities and design of accident management and mitigation measures, including the identification of the on-site and off-site logistical obstacles.
Design of the upgrading have to be performed according to the design codes and standards and for the design basis earthquake as defined by current licensing basis.
The seismic upgrading are design modifications requiring proper configuration management and regulatory approvals.
All methods presented above for the re-evaluation and re-qualification of the operating plants require specific knowledge and experience and decisively based on the expert judgement. Consequently, the re-evaluation, re-qualification and upgrading of operating plants have to be peer reviewed to provide an independent overview of its adequacy. The recommendations for the peer review are part of the descriptions of the procedures and also given in the (IAEA, 2003, 2009).
Operating basis earthquake level is understood as a limit for the continuation of the safe operation. If the plant is designed for two levels of earthquake, i.e. OBE and SSE, the limit of safe operation should be set equal to the OBE PGA measured at free-field, or to the response acceleration level at an appropriate location of the structure, e.g. at containment basement, calculated for the OBE. If the acceleration is crossing the set level the reactor protection system is actuated automatically. An automatic seismic trip system could be designed in accordance with the concept of the reactor protection system design with regard to the instrumentation, redundancy and the logic of the generation of actuating command. The system design should eliminate as much as possible the spurious trips. There are different concepts for selection of the trigger level. A "high level" trip could be set based on some per-cent of the SSE (usually chosen as greater than 60% of the SSE level) and could be designed to minimize spurious trips due to after-shock and low acceleration earthquakes. A "low level" trip would be set to activate on the compressional waves (P waves) when this first arrival caused displacement or acceleration greater than the calculated maximum allowable P wave for an OBE. The decision on the OBE exceedance per acceleration level crossing could be considered as traditional. Considerations have been made regarding advisability of the automated reactor shutdown in case of small earthquakes (Cummings, 1976, IAEA, 1995). There are plants and sites in low and moderate seismic activity regions where an automatic PGA or acceleration level triggered shutdown can be caused by practically harmless ground motions. There are plants that are practically not designed for two levels of earthquakes just upgraded to comply with the SSE related requirements. For these cases the U.S. NRC Regulatory Guide and 1.12, 1.166 and 1.167, and the IAEA as well as the NRC documents on the “Advisability of seismic scram“ provide guidance; see the also the (IAEA, 1995).
At the plant in the moderate seismicity regions the operational limit related to the OBE exceedance is formulated in terms of cumulative absolute velocity and spectral amplitude of the acceleration and velocity response spectra measured at the free field; see (NRC, 1997a, 1997b and 2000; EPRI, 1988; 1989, ANS 2002). According to U.S. NRC Regulatory Guide 1.166 the OBE exceedance criteria are as follows:
“The OBE response spectrum is exceeded if any one of the three components (two horizontal and one vertical) of the 5 percent of critical damping response spectra generated using the free-field ground motion is larger than:
The corresponding design response spectral acceleration (OBE spectrum if used in the design, otherwise 1/3 of the safe shutdown earthquake ground motion (SSE) spectrum) or 0.2g, whichever is greater, for frequencies between 2 to 10 Hz, or
The corresponding design response spectral velocity (OBE spectrum if used in the design, otherwise 1/3 of the SSE spectrum) or a spectral velocity of 6 inches per second (15.24 centimeters per second), whichever is greater, for frequencies between 1 and 2 Hz.”
The CAV is defined for each component of the free-field ground motion as
where a(t) is a component of the ground acceleration, T is the duration of the strong motion.
There are certain rules for the numerical calculation of the CAV: (1) the absolute acceleration (g units) time-history is divided into 1-second intervals, (2) each 1-second interval that has at least 1 exceedance of 0.025g is integrated over time, (3) all the integrated values are summed together to arrive at the CAV.
The CAV check is exceeded if any CAV calculation is greater than 0.16 g-seconds.
If the response spectrum check and the CAV check were exceeded, the OBE was exceeded and plant shutdown is required.
The seismic instrumentation has two important roles:
to provide information for the decision on OBE exceedance
to register the plant response for the post-event evaluation of the plant condition.
The instrumentation providing response records for the evaluation post-event condition of the plant should be installed at most important/significant location of the structures and main components.
The instrumentation for the judgement on the OBE exceedance has to be designed and fitted to the concept of limitation of the operation in case of earthquake. The instrumentation and voting logic for automatic scram should have the same structure, redundancy etc. as the reactor protection system.
For example the Soviet designed SIAZ (System of Industrial Antisesmic Protection) system initiating automatic reactor scram consists of nine tri-axial accelerometers in three independent systems with independent electric power supply and two sets of them. Contrary to this the tri-axial accelerometers for evaluation of OBE exceedance via CAV and response spectrum criteria should be installed at protected free-field locations.
Regarding design and installation of seismic instrumentation see (NRC, 1997c) and (IAEA, 2003b).
Activities that have to be executed during earthquake should be defined and adequate emergency operational procedures for accident prevention should be developed for the case of earthquake. The documents (NRC, 1997a, 1997b and 2000; EPRI, 1988; 1989, ANS 2002) and the (IAEA, 2011) provide guidelines for the development of the procedure.
The development of earthquake related severe accident management guidelines can be performed on the basis of severe accident oriented studies (Section 3.4) and IAEA documents (IAEA, 2009b).
The case of Paks NPP is significantly different from the cases of other nuclear power plants regarding the initial basis and objective of their seismic safety programmes. Ab’ovo, Paks NPP has not been designed and qualified for the earthquake loads. The reason was twofold: the site seismicity was underestimated and the design basis was set to the MSK-64 intesity 5 that was equal to the intensity of the historically credible earthquake plus one intensity ball. In mid eighties the safety deficiency had been recognised and a programme for the definition of the site seismic hazard had been launched, which had been extended to a comprehensive site evaluation programme, including geological, geophysical, seismological and geotechnical investigations as for design basis regarding the scope and the methodology. The probabilistic seismic hazard assessment had been completed in 1995 and the design basis earthquake had been defined on the 10-4/a non-exceedance level. The Hungarian Regulatory Authority had approved the new design basis, and requested to launch a programme for ensuring the compliance with newly defined design basis.
It was already recognised at the very beginning of the seismic safety programme that a consequent and full scope re-design in line with design codes and standards and subsequent upgrading might be impossible at Paks NPP. Therefore, acknowledging the international practice and IAEA recommendations, the Hungarian authorities allowed the use of methodologies for seismic re-evaluation and re-qualification of operating NPPs, less conservative than the design procedures. Admittedly, in early phase of the implementation of the seismic safety programme of Paks NPP, there was a bloodless hope that the issues at Paks NPP could be managed via application of SQUG/GIP, EPRI deterministic seismic margin method, Seismic Evaluation Procedures of the DoE (see Section 3.2 above).
Contrary to the relative alleviations regarding selection of the re-qualification methodologies, the scope of the seismic safety evaluation and upgrades was set by the regulation as for re-design, covering not only the seismic safety classified SSCs (including interacting items), but the whole scope of safety classified SSCs with three times full redundancy with application of the single failure criterion has been accounted instead of considering a success path and a backup only, etc. Also the process requirements were set as for new design, e.g. the heat removal after the design base earthquake shall be ensured unlimited in time, contrary to the 72 hours requirement applicable in usual margin-type assessment.
The real objective has been clearly understood after performing the first Periodic Safety Reviews in 1999, since the compliance with the just issued Nuclear Safety Regulations (Governmental Decree No 108/1997) requested to be achieved and demonstrated. It was recognised that the methodologies mentioned above does not provide the required for Paks NPP result regarding design base reconstitution, on the other hand they can’t be directly applied for VVER plants, certain adaptation was needed for accounting the VVER design features.
The qualification of the Paks NPP have been executed as for the newly defined design basis earthquake by applying procedures and criteria for the new design, combined with the methods and techniques developed for seismic re-evaluation of operating nuclear power plants. The seismic safety programme of the Paks NPP is presented below in Figure 1.
The description of the project as given below clearly indicates the similarities and differences between the programmes as understood in (Gürpinar & Godoy, 1998; Campbell at al, 1998) and programme at Paks NPP (Katona, 2001).
The selection and use of methodologies has been graded in accordance with safety relevance of the system, structure or component.
The Hungarian regulation requires performance of probabilistic safety analyses for internal and external events/initiators. Therefore, after implementing the seismic safety upgrading measures, the achieved level of safety has been quantified via seismic PSA, which provides the value of the CDF and also indicated certain week links to be avoided or accounted.
The implementation of the programme was broken into three phases:
Preparatory phase before 1995: The objective was to prepare the programme in a way that it could be executed within reasonable technical and economical limits (example see in Section 5.4). Learning and trial of the methods were going on simultaneously with the site evaluation. The conservatism had to be handled carefully during the seismic safety assessment. The easy to perform fixes had been designed for preliminary conservative seismic input and implemented. The easy-fix project covers 10184 items for 4 units. The volumes of the works are given in Table 2. Total amount of structural steel used for fixes is equal to 445 tons. Safety related batteries for all four units have been replaced and fixed in the frame of the easy-fix project.
Between 1996-1999: Selection of the methodology, evaluation of as-is seismic capacity and identification of the fixes had been performed.
Design and implementation of fixes 1999-2003: The amount of works is illustrated in Figure 2 and 3 and in Table 3.
The programme was broken down into manageable tasks and projects while the uniformity of the requirements and assumptions between these tasks had been ensured by appropriate quality assurance programme and methodological and criteria documents developed for each task.
Structure and tasks of seismic safety programme at Paks NPP
mechanical equipment | 202 | anchorages |
electrical equipment | 465 | anchorages |
cable trays | 2498 | anchorages |
I&C (cabinets, racks) | 2061 | anchorages and top bracing |
brick walls | 281 | steel frame fixes |
total number of easy-fix items | 5507 |
Tasks and work volumes of the easy-fix project
Viscous-dampers below the steam-generator
Steel-frame bridge between localisation towers for fixing the frames of the reactor hall (columns) in cross-wise direction
Electrical and I&C equipment | 1993-2002 | Qualifications, replacements |
High energy pipelines of primary circuit and equipment | 1997-1999 | 250 fixes (GERB viscous-dampers) |
Structure of the turbine and reactor hall | 1999-2000 | 1360 t of steel fixes |
Support bridge at localization towers | 2000-2001 | 300 t of steel fixes |
Other classified pipelines of primary circuit and the components | 1998-2000 | 760 fixes |
Classified piping and components of secondary circuit, fixes of supporting steel structures in the turbine building | 2000-2002 | 160 t of added steel structures 1500 fixes |
Other classified pipelines and equipment | 2001-2002 | 80 fixes |
Measures identified by seismic PSA | 2002- | Fixing the joints in the turbine building, relays qualification |
Tasks and work volumes of the easy-fix project
Full-scope site geological, geophysical, seismological and geotechnical investigation and evaluation has been performed with subsequent probabilistic seismic hazard assessment (PSHA). The methodology is described in (Tóth et al., 2009).
The design base earthquake is defined on the 10-4/a non-exceedance level, taken on the mean hazard curve. Recent Hungarian regulatory requirement is: the design base event has to be defined on the median hazard curve at 0.005 non-exceedance probability for the total lifetime of the plant, which means exactly a 10-4/a frequency for a 50 years operational lifetime (or approximately 10-5/a for a new built).
The horizontal and vertical peak ground accelerations (PGA) are equal to 0.25g and 0.2g respectively. (The PGA correlated to the original design basis seismicity was 0.025g.)
The uniform hazard response spectra were defined for the Pannonian surface (as for a virtual outcrop) below the site. The ground motion response spectra (GMRS) are calculated taking into account the nonlinear features of the soft soil layer covering the site.
The results are shown in Figure 4.
Accounting site mean spectral ratios and mean bedrock and surface UHRS at 5% damping for three different probability levels
The acceptability of the obtained ground motion response spectra for the design base was justified earlier (in 1995) by comparison with deterministically defined 84% response spectra (on the basis of US NRC Draft Guide 1032 issued later as Regulatory Guide 1.165) and recently per U.S. NRC Regulatory Guide 1.208 (NRC, 2005) and ASCE/SEI 43-05 procedure (ASCE, 2005). The latter ensure the avoidance of the cliff-edge effect with respect to the seismic input, since the increase in the amplitudes in ground motion response spectra due to relatively small increase (one order of magnitude) in the exceedance probability is accounted.
The parameters of a 10-2/a non-exceedance level earthquake have also been defined. The PGA is equal to 0.087g in this case. This information is used for certain fatigue type analyses. The response spectrum and cumulative absolute velocity criteria are used for the definition of OBE exceedance; see US NRC Regulatory Guide 1.166 (NRC, 1997a).
There is Pleistocene layer of 25-30 m covering the site, the upper 12-15 part of which originates from floods and consists of fine structure, well classified sand, while its lower part consist of sandy gravel and gravel. Under the Pleistocene layers, there are various upper Pannonian layers, which are irregularly divided by sandstone ridges. These ridges are cemented to various extents and can be regarded as semi-rock. The 25-30 m saturated young soft soil (~300m/s shear-wave velocity) covering the eroded Pannonian surface at the site is susceptible to liquefaction at the depth 10-15 m. The probabilistic liquefaction analysis performed in 1995 has shown that the best estimate return period of the occurrence of liquefaction exceeds 10000 years therefore the liquefaction was not considered as a design basis phenomenon.
For the seismic PSA purposes, the evaluation of the site effects was extended to very low probabilities (10−4÷10−6/a). According to the seismic PSA the building relative settlement due to the liquefaction is the dominating effect contributing to the CDF just below the design basis probability level. This experience triggered a state-of-the-art analysis of the liquefaction. It was also observed that the uncertainty of the analysis is essential due to uncertainty of soil parameters and the methods.
Liquefaction susceptibility can be expressed in terms of factor of safety FS
where CRR is the cyclic resistance ration and the CSR is cyclic stress ratio, see Regulatory Guide 1.198 (NRC, 2003). The cyclic stress generated by the given earthquake is as follows (Seed and Idriss 1971):
where
Depending on the method used the value of safety factor varies in rather wide range. The methodologies (Seed & Idriss, 1971, 1982; Tokimatsu & Yoshimi, 1983) used for Paks site resulted in a relative low margin, while the analysis via effective stress method provides much larger margins (Győri et al, 2002).
The building settlement caused by earthquake can affect the underground communications (service water piping and emergency power supply cables) due to relative displacements. This effect will be amplified if liquefaction occurs. The dominant failure mode in the acceleration ranges higher than the design basis is due to the relative building caused by the soil liquefaction. This makes it necessary to re-qualify the underground lines and connections jeopardized by the settlement of the main building or, if it is necessary, to modify them to make their relative movement unimpeded. An advanced probabilistic liquefaction and relative building settlement analysis is going on using an amended soil parameter database in relation to the investigation of beyond design base vulnerabilities performed for severe accident management reasons (Győri et al, 2011).
The procedure for the safe shutdown, cool-down and long-term heat removal of the reactors has been elaborated in two versions (Katona, 2003).
The first version was developed before 1995, when a very conservative guess of the DBE (with PGA 0.35g) was available. For this high demand, a safe shutdown technology was selected that could be realised by the upgrading of the minimum number of systems. It was advisable to select systems for the safe shutdown and cool-down, which are situated in the reinforced concrete containment part of the main building because only this part of the building seemed to sustain the loads. The upgraded and not upgraded systems or parts of systems should be separated in case of earthquake by fast closing valves. The control rods, and boron system would ensure shutdown of the reactor, and the stable subcritical conditions. The reactor should have been cooled-down by the secondary bleed and feed. The long-term heat removal would have been executed through the heat exchangers of the low-pressure emergency core cooling system that should have been modified for the execution of this function. This concept would require modifications in the safety systems and the installation of the great number of valves. Analysing the feasibility issues, it has to be recognised that the implementation of the concept is not only very expensive but it can reduce safety in all other cases than an earthquake because of the modification of the low pressure emergency core cooling system.
Performing the analyses for main building complex, it was recognised that the most critical structure is the gallery building that gives place to several vital systems and I&C equipment. This part of the main building should have been upgraded. Developing the possible technical solution for upgrading the longitudinal gallery building, it turned out that it can be best performed, if the steel frames of the turbine hall and the reactor hall are also fixed. This solution allows the application of structural upgrades that do not require fixes in the over-crowded by equipment and piping gallery building. If it the case, the systems for regular heat removal placed in the turbine hall would be available for heat removal after an earthquake, if their re-qualification is performed. Meantime, in 1995 the site seismic hazard evaluation has been completed which resulted in the DBE with 0.25g PGA. Response and stress calculations made for the newly defined DBE have shown that essential part of the mechanical equipment and pipelines can sustain the DBE demand and the reinforcement of the systems and structures necessary for seismic safety is feasible with reasonable effort.
Theoretical considerations have been made for the evaluation of upgrading effort required for fixing the pipelines and components required for heat removal via systems “as usual”, i.e. systems dedicated for emergency cases. It has been assumed that the “as is” seismic capacity of the pipe segments can be treated as a random variable; its value can be expressed by total design capacity multiplied by several factors representing the randomness of the actual design features, floor-response, etc. If it is the case, the calculated “as is” HCLPF values of pipe segments have to be lognormal distributed. If the distribution is known, the parameters of the distribution can be defined on the basis of HCLPF calculations for “as is” conditions and the number of pipe segments requiring fixes can be evaluated. The distributions of “as is” HCLPF values of pipe segments presented in Figure 5 justified the assumptions and made possible the evaluation of upgrading needs.
Distribution of “as is” HCLPF values of pipe segments (units 1-4 and units 3-4)
Based on the assessment of fixes of the piping and components, the cost of these fixes turned to be cheaper than the (automatic) isolation of the unreinforced parts of the systems by a great number (more than 100/unit) of fast closing valves.
Consequently, instead of a success path and backup for heat removal, the concept has been chosen that is based on the use of systems devoted for heat removal as per design, taking into account the design philosophy of the VVER-440/213 and widely using the synergy between structural and component fixes.
Meantime, the new nuclear regulation issued in 1997 required the upgrading and qualification of the SSCs enrolled into seismic classes. Moreover, the regulation requested to ensure the adequate capacity of the safety classified SSCs for hazards. Consequently, the scope of the seismic safety evaluation and upgrades was set as for re-design, covering not only the seismic safety classified SSCs (including interacting items), but the whole scope of safety classified SSCs with three times full redundancy, with application of the single failure criterion. The stable and unlimited in time cold shutdown condition have to be ensured after the design base earthquake.
According to the selected concept the sub-criticality is maintained by the shutdown and boron control systems. The cool-down is ensured by secondary-side bleed and feed. The continuous cooling is maintained by the heat removal system. In all redundant trains, the SSCs needed for ensuring these safety functions are fixed and qualified for DBE.
Certain modifications have been implemented for making possible the required functioning, e.g. modification of the venting of the tubes of control assemblies on the reactor pressure vessel head. The systems not required for the safety functions are isolated automatically from the seismically qualified one. The procedure was developed assuming that the plant is in normal operational condition; the outside energy supply (grid) and make-up water source is not available for 72 hours.
Loss of coolant accident is not assumed in consequence of the earthquake; hence, the primary system piping is fixed for DBE according to the design rules. Nevertheless, all redundant safety trains including emergency core cooling systems have been upgraded and qualified for DBE. Consequently the sequences with loss-of-coolant can also be managed, although these are already beyond design base sequences according to the safety philosophy.
On the other hand, the consequences of the small breaks (impulse pipes, drains, air vents) shall be examined from the aspect of the dose limits and containment integrity. The break of small-bore pipes shall be considered in connection with the passive single failures (see article 5.3 of NS-G-2.13). The degree of passive single failures is limited to the break of small-bore pipes (<DN50) and to the leakage of the sealing of pumps or valves.
Those non-safety-classified SSCs have to be also fixed for DBE, failure of which may endanger the integrity or functioning of the safety systems. The possibility of fires and flooding induced by earthquake is also avoided via modification and fixing of the relevant systems, and installing letdown systems for lubricant and Hydrogen.
The systems for the heat removal of the spent fuel and refuelling pools are also fixed and qualified for DBE.
The SSCs have been formally classified: Seismic Class 1 – active systems and components, Seismic Class 2 – passive structures and components (thereafter SCs) needed for ensuring the basic safety functions during and after DBE; Seismic Class 3 – SSCs are those, failure of which may inhibit the safety functions (interacting SCs, falling-on, casing fire or flooding, etc.). Seismic Class 4 – no safety functions and no interaction. Obviously, the scope of seismic safety programme at Paks NPP envelops the scope defined in the international practice for the operating nuclear power plants. Chapter 5 of NS-G-2.13 (IAEA, 2009) only prescribes the re-qualification of the minimal number of SSCs necessary for the implementation of safety functions during and after the earthquake. In case of Paks NPP this concept could not been applied since the design basis had to be reconstructed. Thus the requirements of the IAEA NS-R-1 and NS-G-1.6 were applied. The rational for seismic classification is rather questionable. If the safety related safety classified SSCs have to be designed for the design base external hazards, the basic safety functions would be ensured by these SSCs in case of earthquake too, i.e. no need of the seismic and safety classification.
Two approaches can be accepted for analysis of the soil-structure interaction:
flexible volume model, flexible volume frequency domain method
rigid boundary model, rigid boundary time domain method.
In case of the rigid boundary method, the modal damping was limited according to international standards (e.g. KTA 2201.3: 15% for horizontal, 30% for vertical motion). Although the uncertainty of the geotechnical data had been extensively studied, three values of the soil share modulus Gmin, Gav and Gmax, have to be considered for handling the uncertainty of soil parameters, where Gmin = 0.5 Gav and Gmax = 2.0 Gav (according to ASCE-4 (ASCE, 1998), 1.5 Gav is acceptable as minimum value).
The analysis of the structural response and capacity of the structures graded approach have been applied, i.e. the modelling and the analysis method have been selected according to the safety relevance of the structure.
The most important building complex is the VVER-440/V213 main reactor building that consists of the reinforced concrete confinement with the localization tower and the attached longitudinal and transversal gallery buildings, as well as the reactor and turbine hall. The most critical parts of the complex structure are the longitudinal and transversal gallery buildings. A method with solution of the equations of motion in frequency domain has been applied for analysis (Katona et al, 1995 a).
The secondary buildings are box-shaped structures composed of reinforced concrete prefabricated elements or structures composed of foundation and an upper steel structure. Because of the structural complexity of these buildings, an up-to-date 3D modelling was required. The soil-structure interaction was be modelled by frequency independent soil springs and dampers.
Unique blast tests have been performed for empirical modal analysis of the dynamic behaviour of the main building structures and for the verification of the models developed (Katona et al, 1992, 1993a; Halbritter at al, 1993a). These tests provide good information regarding soil-structure interaction under small-strain excitation.
For optimal modelling of primary system responses, a coupled mechanical and structural model has been developed (Halbritter et al, 1993b; Katona et al, 1993b, 1994, 1999).
The selection of upgrading concept for buildings has been made iteratively. For all options of upgrading, the response and resistance of modified structure has been made and the optimal solution selected via comparison of response and strength achieved. After selection of final upgrading solution the dynamic calculations have been repeated for the modified configuration for justification of the adequacy of the upgrades and development of the floor response spectra. Latter has little importance for the reinforced concrete containment part of the main building complex, but it was essential, e.g. in the gallery buildings. The same iterative procedure has been applied in case of Reactor Coolant System upgrade, and the fixed configuration has been re-calculated for the justification of code compliance of the integrity (Katona et al, 1999).
The methods for evaluation of as-built capacity of structures and components (passive SCs) have been selected in accordance of safety and seismic class, as follows:
Safety Class 1 and 2 mechanical components, piping, etc. and Safety Class 2 buildings – straightforward design procedure (codes and standards) have been used. For example, for the pressure retaining boundaries Class 1 and 2 German design code KTA, and for the Class 3 ASME; KTA-ASME comparative study also made, purely elastic approach) has been applied;
The Class 3 SCs failed to comply with design codes have been generally evaluated using realistic assumptions for damping and ductility similar to the (IAEA, 2003).
small bore, low-energy pipes – simplified code based method.
The floor response spectra used for the component capacity evaluation was defined according to the design codes (see e.g. ASCE-4-86). However, in case of Class 3 SCs that failed when conservative floor response was used, the calculation was performed for the best estimate floor response spectra (FRS). The best estimate FRS has been obtained either via probabilistic method, or taking into account the inelastic energy absorption, or accounting the equipment-structure mass ratio.
In those cases when the existing supports of pipelines are modified in order to provide adequate seismic capacity, e.g. when the number or type of the supports is changed, it shall be demonstrated on the basis of the relevant nuclear standards (ASME BPVC Section III (ANSI ANS N690) or KTA 3201, 3211, 3205) that the upgraded high energy pipelines and their supports comply with the following criteria:
The effect of restrained thermal expansion due to the modified pipeline’s supports complies with the requirements of the standard;
The requirements of the standard are met without using the ductility.
The pipeline’s supports comply with the requirements of ASME BPVC Section III NF or ANSI ANS N690 or equivalent nuclear standards (e.g. the German KTA) when they are affected by pipeline reaction due to normal operational conditions (including the restrained thermal expansion) + seismic inertia forces + seismic anchor motion loads related to DBE.
The qualification of active components has been made by several methods:
Some systems should be replaced or reconstructed for safety upgrading reasons, e.g. the reactor protection system (Siemens Teleperm XS). The new systems and equipment should be qualified and certified by the supplier for the conservatively defined floor response spectra.
Shaking table testing of sample items.
Qualification via empirical procedures (GIP, GIP-VVER).
For example, the relays have been qualified by replacing the not to be qualified by new one, shaking table testing of samples for in-rack response spectra (Katona et al, 1995b), experience based method, where it was applicable.
Since the GIP database does not specifically include all the equipment of Paks NPP (manufactured in the Soviet Union or Eastern European countries), it was necessary to apply GIP-VVER (Masopust, 2003) incorporating the knowledge and experience gained during the evaluation of VVER type power plants.
The comparison of 1.5 times bounding spectra (BS) to the floor response spectra is always recommended instead of the comparison of bounding spectra to the ground motion response spectra even below the 12 m level of the building.
The assumptions accepted for the re-evaluation are summarised in the Table 4. The applicable codes and methods are summarised in the Table 5.
The mixed use of the codes was excluded by careful definition of the evaluation packages. The assumptions, allowable stresses, etc. of the KTA and ASME have been compared.
The operability of active technological components should be qualified by empirical re-qualification procedures or test. The equipment classes and applied empirical qualification methods for active and certain passive components are summarised in the Table 6.
Damping, ductility | Code values or realistic for repeated checking of outliers | |
Structural models | Graded approach to the modelling: best estimate if applicable | |
Floor response spectra | Conservative design floor response spectra. In specific case best estimate | |
Material strength | Minimum values determined by standard | |
Capacity evaluation | Design type evaluation | KTA, primary system and vital mechanical equipment and pipelines inside the confinement area |
Margin type evaluation | CDFM+ASME | |
Simplified evaluation | Code based simplified procedures | |
Operability | GIP or GIP-VVER, if applicable, otherwise test |
Summary of applicable standards and methods
Passive equipment (tanks, pressure vessels, etc.) | Component body including internal parts | ASME BPVC Section III, Service level D KTA 3201/3211 |
Supports | ASME BPVC Section III Subsection NF KTA 3205; Subsection according to Classes. | |
Essential nozzles | ASME BPVC Section III, Service level D KTA 3201/3211 | |
Interactions | GIP, GIP-VVER | |
Active equipment | Operability | GIP-VVER |
Component body including internal parts | ASME BPVC Section III, Service level D KTA 3201/3211 | |
Supports | ASME BPVC Section III Subsection NF KTA 3205; | |
Essential nozzles | ASME BPVC Section III, Service level D KTA 3201/3211 | |
Interactions | GIP, GIP-VVER | |
Pipelines | Pipelines | ASME BPVC Section III, Service level D KTA 3201/3211 |
Supports | ASME BPVC Section III Subsection NF KTA 3205; | |
Interactions | GIP, GIP-VVER |
Summary of applicable standards and methods
A.The original twenty classes: | |
1.Motor Control Centres | GIP if applicable GIP-VVER, tests if the item does not fit to the database |
2.Low Voltage Switch-gears | |
3.Medium Voltage Switch-gears | |
4.Transformers | GIP-VVER experience data or tests |
5.Horizontal Pumps | |
6.Vertical Pumps | |
7.Fluid-Operated Valves | |
8.Motor-Operated Valves | |
9.Fans | |
10.Air Conditioning Devices | |
11.Cooling Devices | |
12.Air Compressors | |
13.Motor Generators | |
14.Distribution Panels | |
15.Batteries on Racks | |
Equipment classes | Recommended qualification procedure |
16.Battery Chargers and Inverters | |
17.Engine Generators | |
18.Instrument Racks | |
19.Sensor Racks | |
20.Control Panels and Cabinets | |
B.Additional classes: | |
21.Relays, Switches, Transmitters, Solenoids, Sensors | Test if the item does not fit to the database |
22.Electrical Penetration Assemblies | |
C.Additional VVER classes: | |
23.Vertical and Horizontal Tanks | Limited analysis, GIP-VVER |
24.Vertical and Horizontal Heat Exchangers | |
25.Ventilation Ducts | |
26.Cable Trays and Conduits | |
27.Small and Large Bore Cold Pipes |
Summary of qualification methods
The final evaluation of the effectiveness of upgrading measures and justification of the acceptable level of achieved safety in terms of CDF have been made via seismic PSA (Katona & Bareith, 1999; Bareith,2007; Elter, 2006). The seismic PSA demonstrated that the CDF ensured by the implementation of rather extensive upgrading programme is of order of magnitude 10-4/a. The PSA identified also several week links. For example, the capacity of the joints of the turbine hall structure was found insufficient. Eventual collapse of the turbine building may cause steam and feed-water header ruptures that result in total loss of main and auxiliary feed-water and disables closed loop heat removal through the secondary side. Repeated analysis for the case after implementing the additional measures resulted into CDF value of magnitude of 10-5/a, which is acceptable per Hungarian regulations.
The seismic PSA indicated also that the building settlement of the buildings due to the soil liquefaction jeopardizes the communications (pipes for diesel generator cooling and cables coming from the diesel generators) between the buildings. In the lower acceleration ranges the soil liquefaction that cause settlement of the main building plays dominant role in the occurrence probability of total loss of electric power supply. The studies indicated in Section 5.2.2 are focused on the liquefaction hazard.
The methodology of the seismic PSA applied at Paks NPP complies with the best international practice, see IPEEE NUREG-1407 (NRC, 1991) and (IAEA, 1993). The SPSA was developed on the basis of extensive PSA experience and existing PSA models for Paks NPP and information from newly performed response and strength analyses and qualification effort of the plant and plenty of walk-downs.
In case of an earthquake, the reactor is shutdown either by reactor protection system due to malfunctions, or manually by the operator based on the criteria of CAV and response spectrum criteria for OBE exceedance. The OBE-exceedance criteria is set CAV=0,16gs and response spectrum in the amplified range less than 0,2g. The seismic instrumentation and the pre-earthquake preparedness and post-earthquake actions are defined via adaptation of the IAEA NS-G-1.6, US NRC Regulatory Guide and 1.12, 1.166 and 1.167 respectively. Selection of the OBE exceedance criteria at Paks NPP was based on the analysis of the frequency of expected events, probability and consequences of spurious signals.
It has to be noted that the implementation of the concept and methodology for OBE-exceedance was not a simple copy-paste; it has been adapted to the conditions of Paks NPP. At Paks NPP, if the ggset measured at the base mat, the non-upgraded part of certain systems will be automatically isolated from the upgraded one by quick-closing valves. These system’s parts do not have function during and after an earthquake and the separation will not disturb the operation either. In the same time, there is also a signal for control room. If an earthquake happens, there are two possible cases:
The plant will be shutdown automatically due to disturbances, initiating event(s) caused by the earthquake and the sequence of actuations will depend on the initiating event. Further operator actions depend on the plant condition. The operator actions are defined by EOPs and trained on the simulator.
If the plant remains in operation after earthquake, the decision on OBE exceedance will be made by operator based on CAV and response spectrum criteria. The plant will continue to operate or will be shutdown if OBE exceeded. If the reactor scram initiated but the OBE hasn’t been exceeded, the restart has to be performed after predefined testing and walk-downs.
The seismic recording systems composed from tri-axial accelerometers that are installed at critical locations of structures and main components, provide information for the post-event evaluation of the plant condition.
The comparison of the seismic re-evaluation methods “as usual” and the methods applied at Paks NPP is shown in the Table 7.
Input | RLE | Hazard curve | Hazard curve; UHRS; Nonlinear soil for GM; Analysis of liquefaction; | |
Scope | Success + backup path | Event tree/ fault tree | ||
Structural response | Median structural response, frequency shifting | Probabilistic structural response | ||
Screening | Walk-down and screening per margins criteria, experience-based | Walk-down and screening per fragility estimations | ||
Evaluation, qualification | Analysis of selected SCs (CDFM) | Selected fragility calculations. Median capacities+ log standard deviations | Detailed information available + fragility development based on the results of the performed analyses; Containment + Liquefaction | |
Relay qualification | Screening; qualification of outliers | Screening + limited fragility | Qualification per screening Test or replacement | |
Modifications | Upgrades if needed | Risk informed upgrades | ||
Results | Plant level HCLPF | CDF |
The seismic re-evaluation methods as usual and the methods applied at Paks NPP
During modifications, replacements and reconstructions, design and procurement can be executed by complying with the seismic safety requirements corresponding to the seismic and safety classification. These processes are part of the configuration management and subject to authority approval. There is a database for seismic and safety SSCs. A procedure exists ensuring the adequacy of the design and procurement specifications.
Adequate maintenance and status monitoring programs are in place in order to maintain the required status of elements classified from the point of view of seismic safety and requiring maintenance, e.g. the anchorage of piping and components, damping devices. Maintenance of the qualification for earthquake is also part of the ageing management programmes.
The proper housekeeping is not irrelevant from the point of view of seismic safety. The following actions have to be required:
Restoring of fixing elements of cabinets and racks after maintenance
Restoring of the anchorages, fixing bolts, pipe hangers and the damping devices requiring maintenance and review,
Appropriate fixing of maintenance devices stored in the plant area.
According to the IAEA Safety Standard NS-G-2.10, the aim of the Periodic Safety Review (PSR) is “to determine by means of a comprehensive assessment of an existing nuclear power plant: the extent to which the plant conforms to current international safety standards and practices; the extent to which the licensing basis remains valid; the adequacy of the arrangements that are in place to maintain plant safety until the next PSR or the end of plant lifetime; and the safety improvements to be implemented to resolve the safety issues that have been identified.” Regarding external hazards the objective of the review of hazard analysis is to determine the adequacy of protection of the nuclear power plant against internal and external hazards with account taken of the actual plant design, actual site characteristics, the actual condition of SSCs and their predicted state at the end of the period covered by the PSR, and current analytical methods, safety standards and knowledge.
The period of the PSR is generally ten years. During ten years the knowledge and understanding of the site hazard may develop and a feedback from experiences of other plants may motivate review and upgrading programme. As it can be seen from the experiences of plenty of nuclear power plants, the seismic safety, just like the safety in general, is not a static thing and it covers the whole life cycle of the facility.
Entropy is an important physical parameter to reflect the disordered state of a certain system, which is mainly expressed by three different forms including Clausius entropy, Boltzmann entropy, and Shannon entropy. Among them, entropy measured by Boltzmann’s thermodynamic statistics principle is in the form of:
where
where Q is heat and T is temperature. The physical meaning of this expression is that the entropy of a system is equal to the amount of heat absorbed (or dissipated) by the system in a certain process divided by its absolute temperature. Different from Boltzmann entropy, Clausius entropy reflects the macroscopic quantity of thermodynamics. Probability is involved in the definition of Boltzmann entropy. The probability is not only used in physics but also in mathematics, information science, etc, which enables the application of entropy in other fields. Shannon entropy is one of the representatives, the expression is as follows:
Based on this, information entropy has been measured in the form of:
where
The concept of high entropy introduces a new path of developing advanced materials with unique properties, which cannot be achieved by the conventional micro-alloying approach based on only one dominant element. In contrast with traditional alloys composed of one principal element, HEAs generally have equimolar or near-equimolar atomic fractions of multiple constituents (generally more than 4 components), as shown in Figure 1a. As displayed in Figure 1b, the ternary or pseudo-ternary phase diagram can be roughly divided into the ordered alloys region (blue) near the corners and relatively disordered alloys region (dotted circle) near the center. The center of the phase diagram, relatively high-disordered region, often has few alloy systems available, especially for traditional alloy systems. In recent years, many new alloys with promising properties are likely to be discovered near the centers (as opposed to the corners) of phase diagrams, which no longer contain a single major component, but multiple major elements and form a concentrated solid-solution structure, namely high-entropy alloy systems. The development of HEAs has provided a novel design philosophy for alloy design and draw significant interest in designing its chemical disorder to bring different structural and physical characteristics.
Schematic diagram of traditional and high-entropy alloy systems. (a) atomic proportions of traditional alloys and high-entropy alloys; and (b) Ordered and disordered regions in a ternary phase diagram.
Here, we would like to discuss the definition of HEAs from the perspective of entropy. For a certain material system, the entropy mainly includes configuration entropy, vibration entropy, magnetic entropy, and thermal entropy. For HEAs with concentrated solid solution structures, the configuration entropy caused by the mixing of different atoms is the primary consideration. In order to simplify the calculation, the regular solution model is usually used to derive the mixed entropy of the HEAs in the state of random mutual dissolution [2]. The calculation formula is as follows:
where
Characteristics for the traditional alloys and two generations of HEAs [
With the development of HEAs, various HEAs with different forms have been reported. Here, the HEAs have been classified from different dimensions, as shown in Figure 3, mainly including three-dimensional (3-D) bulk materials, two-dimensional (2-D) film and sheet materials, one-dimensional (1-D) fiber materials, and zero-dimensional (0-D) powder materials [5].
Classification and general preparation methods of high-entropy alloys with different dimensions [
The 3-D HEAs, also referred to as bulk HEAs, are generally fabricated by alloy melting, additive manufacturing, and sintering methods, with a weight from several grams to tens of kilograms. Different cross-sectional shapes can also be obtained by casting, such as round rods and square rods. The 2-D HEAs are thinner than bulk alloys, and have several main types including thin films, coating, sheets, and thin strips. The high-entropy wire and fiber are the 1-D HEAs, which are generally obtained by drawing method and glass-covered spinning method. At present, micron-scale high-entropy wire can be obtained, and possess attractive mechanical properties. For the 0-D HEAs, mainly refers to high-entropy powders, which can be obtained through mechanical crushing and atomization. Currently, the high-entropy powder is used as raw materials for powder metallurgy and additive manufacturing, as well as a novel catalyst for functional applications.
As a novel complex emerging material, many unique characteristics of HEAs in dynamics, thermodynamics, and structure have aroused great interest. The ability of HEAs to be designed with unique properties in an unlimited space of alloy compositions is encouraging. At present, many outstanding works have been carried out and proved many attractive properties that break the trade-offs and limits of properties. Here, several representative performance advantages including overcoming the strength-ductility trade-off, outcoming low-temperature ductility, excellent thermal stability, good corrosion resistance, and irradiation resistance have been illustrated [6].
Overcoming the strength-ductility trade-off: In general, strength and plasticity are two opposing properties. In other words, the increase of strength is often accompanied by the loss of plasticity, and the increase of plasticity requires the sacrifice of strength. It is exciting to find that the HEAs show the potential to break through the strength-plastic trade-off. The high strength of HEAs can be mainly attributed to two strengthening mechanisms. One of the most key issues for breaking strength-ductility trade-off is tailoring the stability of the constituent phases in HEAs, such as designing phase transformation, twinning, and regulating the chemical short-order and nanoprecipitates.
Low-temperature ductility: Traditional materials tend to exhibit brittleness at low temperatures, which limits their application in extreme low-temperature conditions. Recent results prove that HEAs with fcc structure show excellent mechanical properties under low temperatures, such as CoCrFeMnNi alloy [7] (Cantor alloy), CoCrFeNi alloy [8], and Al0.3CoCrFeNi fiber [9]. This unique property is facilitated by the ability to form twin crystals, enabling defect storage and microstructural refinement at low temperatures.
Thermal stability: The diffusion rate is significantly slower than that in conventional materials. Severe lattice distortion directly is the key issue. Multiple components and complex interactions between the different atoms seriously affect the cooperative diffusion, and thereby slowing down the phase transition rate, hindering grain growth, and improving creep resistance.
Corrosion resistance: The synergistic effect of slow diffusion, easy to obtain amorphous, and nanocrystalline structure is the dominant reason for excellent corrosion resistance. At the same time, high content of doping elements also enables the formation of strong passivation layers.
Irradiation resistance: Recent results have proved that effective self-healing mechanisms can be designed in HEAs. The particle irradiation could cause atomic displacements, which induces the irradiation defects, such as vacancies and interstitials, and also is accompanied by thermal spikes. For HEAs, the possibility of vacancy-interstitial recombination is higher than in traditional alloys due to complex interactions between atoms. And also, high levels of atomic-level stress in HEAs destabilize the solid solution and facilitate atomic remake to eliminate defects. This part will be discussed in detail in subsequent chapters.
For the property of HEAs, besides the current efforts on breaking the trade-off between the strength and ductility, we would like to propose several trade-offs between the mechanical properties and the physical properties, such as the deformability and soft magnetic properties, conductivity, and strength. Generally, the functional properties are available from traditional materials. However, traditional materials usually fail to provide a well-service under extreme conditions due to the destabilization of mechanical properties. In this case, outstanding mechanical also is a major boost for developing functional HEAs. Hence, we predict that developing HEAs with unique physical properties is a key research topic for future development. There are also other attractive properties, such as irradiation resistance and self-sharping properties. In subsequent chapters, we will discuss these performances and related mechanisms in detail.
The performance of the soft magnetic material directly affects the transformer loss rate. Traditional soft magnetic materials, such as steel, Fe-Co alloys, and silicon steels, are often limited in their applications to the brittleness and poor deformability of the alloys. For soft-magnetic materials, it is very important to seek the balance between the magnetic properties and mechanical properties. However, this breakthrough is difficult to achieve in traditional materials, which generally have a relatively high degree of structural order, thereby showing poor deformability. In contrast, the excellent mechanical properties over a wide temperature range guarantee a well-service of HEAs under extreme environments. Moreover, high-entropy soft magnetic materials are expected to break the trade-off between power and frequency, as shown in Figure 4. For example, the conventional silicon steel is especially suitable for using in conditions of high power and low frequency. Once silicon steel is used at high frequencies, losses will increase dramatically. On the contrary, the amorphous alloys and ferrite generally possess low coercivity and exhibit lower losses at high frequencies, which give rise to the application of high-frequency transformers. Here, high-entropy soft-magnetic alloys show great advantages in filling the gap between high power/low frequency and low power/high frequency.
General relationship of power to frequent for common magnetic materials.
As we discussed in the previous chapter, HEAs have good mechanical properties, flexible deformability and excellent thermal stability, which is one of the most important properties for promising soft-magnetic materials. Many efforts have proved that HEAs also show acceptable soft magnetic properties. The promising soft-magnetic materials should have high-electrical resistivity, high-saturation magnetization, and low coercivity. As shown in Figure 5, the soft-magnetic HEAs are mainly located in the region of soft and semi-hard regions, and the properties of partial alloys are accepted by the soft-magnetic materials [10].
Saturation magnetization versus coercivity of HEAs compared with major conventional soft and semi-hard magnetic materials [
In addition, HEAs generally possess higher electrical resistivity in comparison with traditional alloys due to large lattice distortion. Chou et al. [11] have investigated the electrical resistivity of CoCrFeNiAlx alloy. Results showed that the resistivity of this series of HEAs is higher, second only to that of bulk amorphous alloys, and the resistivity increases with the increase of temperature, showing a linear relationship with temperature. Currently, many efforts have been conducted to improve the comprehensive soft-magnetic properties of HEAs. Zuo and co-workers [12] have designed a system of CoFeMnNi-X (X=Al, Cr, Ga, and Sn) magnetic alloys. The hysteresis loops of these HEAs are shown in Figure 6. Ordered phases form by adding Al/Ga/Sn to the FCC-structured CoFeMnNi alloy. This phase transition leads to the significant enhancement of the saturation magnetization. Especially for CoFeMnNiAl alloy, the alloy has Ms of 147.86 Am2/kg.
Hysteresis loops of (a) CoFeMnNiMn, (b) CoFeMnNiAl and CoFeMnNiGa, (c) CoFeMnNiSn, and (d) CoFeMnNiCr alloys at room temperature [
Moreover, Zuo and co-works have tried to optimize soft magnetic properties by changing the fabrication process [13]. They found that the HEAs fabricated by directional solidification process showed a lower coercivity. The coercivity value of FeCoNiAl0.2Si0.2 alloy manufactured by directionally solidified is reduced to 315 A/m, which is much lower than the as-cast alloy with 1400 A/m. Results prove that the chemical short-range order in HEAs significantly changes the local environment of atomic, which further reduces the average magnetic moment of magnetic atoms. Zhang and co-workers have also investigated the magnetic properties and mechanical properties of Fe-Co-Ni-Al-Si HEAs [14]. The alloy shows pretty good mechanical properties and deformability. As shown in Figure 7, the alloy was fabricated by vacuum magnetic suspension melting, and also can be conducted by cold-rolling to form the sheet. The alloy after annealing exhibits a tensile yield strength of 235 MPa, an ultimate tensile strength of 572 MPa, and an elongation of 38%. The superior ductility of HEAs provides the possibility of preparing thin plates, which can effectively reduce eddy current losses of magnetic devices.
The macroscopic appearance of (Fe0.3Co0.5Ni0.2)95(Al1/3Si2/3)5 cold-rolled sheet.
Generally, high-purity materials have high conductivity, and the higher the purity, the higher the electrical conductivity accordingly. Also, it is well known that the higher the purity of the material, the lower the strength. However, due to low strength of high-purity materials, they cannot meet the requirements of industrial applications. In this case, increasing the strength of alloy without significantly reducing the electrical conductivity is essential. There are many methods to strengthen materials, for example:
(i) Fine grain strengthening: Fine grains can be obtained through plastic deformation or other methods, which improves the strength but also hinders the electron transport; (ii) Solid solution strengthening: Solid solution treatment causes the crystal lattice distortion, which enhances the scattering of electrons, thus making the movement of electrons difficult; (iii) Second phase strengthening (precipitation strengthening): The second phase precipitated from the alloy matrix will hinder the movement of dislocations, which can improve the strength of the alloy, but at the same time, it will also block electrons, which will hinder the transmission of electrons; and (iv) Phase transformation strengthening: The lattice is strongly distorted, and the resistance increases sharply. Obviously, these strengthening methods reduce the conductivity. The current research work demonstrates the possibility of breaking the balance between conductivity and strength in the design of HEAs.
Excellent mechanical performance of HEAs is a basic guarantee for using as conductivity materials. Moreover, there have been HEA superconductors discovered to date, which seem to offer some interesting properties. Guo et al. [15] reported the observation of extraordinarily robust zero-resistance superconductivity in the pressurized (TaNb)0.67(HfZrTi)0.33 HEAs with a bcc phase structure. The transition to superconductivity (TC) increases from an initial temperature of 7.7 K at ambient pressure to 10 K at ∼60 GPa, and then slowly decreases to 9 K by 190.6 GPa, a pressure that falls within that of the outer core of the earth. High-pressure resistance measurements were performed for four samples that were cut from the material used as the standard for the superconductivity at ambient pressure. The electrical resistance measurements for these samples were performed between 4 and 300 K. They inferred that the continuous existence of the zero-resistance superconductivity from 1 atm up to such a high pressure requires a special combination of electronic and mechanical characteristics. The HEAs superconductor thus may have a bright future for applications under extreme conditions, and also poses a challenge for understanding the underlying quantum physics.
Vrtnik and co-workers [16] designed Ta-Nb-Hf-Zr-Ti HEAs with a structure varying between a homogeneous random solid solution and a partially ordered nanostructure in the form of a three-dimensional grid of short-range ordered atomic clusters enriched in Zr and Hf and investigated the superconducting behaviors. The superconducting transition temperatures TC of Ta-Nb-Hf-Zr-Ti HEAs are scattered in the range between 5.0 and 7.3 K and this scatter could be related to the degree of structural and chemical inhomogeneity of the samples. They demonstrated the important fact that the formation, stability, and structure of a regular (non-ideal) HEA mixture is determined by both, the minimization of the mixing enthalpy that favors local atomic ordering and the maximization of the mixing entropy that favors a random solid solution. The actual equilibrium state achieved during long-time thermal annealing via the atomic diffusion is generally partially ordered, and the resulting nanostructure is a sensitive function of the number of components constituting the HEA, their concentrations, and the differences in the atomic radii and the annealing temperature and time. This nanostructure essentially determines the electronic properties of HEA materials.
The unexpected stability of phase structure and mechanical performances in extreme environments makes HEAs attractive candidates for irradiation-resistant materials. It is well known that particle irradiation could cause atomic displacements, which induces the irradiation defects, such as vacancies and interstitials. In contrast with the traditional alloys, the integrated experiment and modeling work indicate that HEAs show a lower volume swelling rate and defect density, which may be attributed to the effective self-healing mechanisms of HEAs under irradiation conditions [6]. The possible self-healing mechanisms of HEAs can be concluded from three aspects, as shown in Figure 8 [6].
Schematic diagram for the self-healing mechanism of irradiation resistance HEAs [
Unlike interstitial atoms in conventional alloys, which migrate in the direction of the Burgers vector in a long-range one-dimensional mode, interstitial atoms and clusters in HEAs have short-range three-dimensional (3D) motion. The short-range 3D motion of interstitial clusters gives rise to the recombination of vacancy-interstitial, thereby reducing the defects in alloys, as shown in Figure 8-I. In other words, the chemical disorder and compositional complexity of HEAs promote the novel short-range 3D migration paths, which facilitate the disappearance of radiation damage, and improve the radiation tolerance. High atomic-level stresses caused by mixing of elements with different atomic sizes are the reason for self-healing mechanism in HEAs. Higher atomic-level stresses destabilize the solid solution, which will facilitate amorphization of alloys during irradiation process. In this case, the thermal spikes caused by particle irradiation will bring local melting and recrystallization, which promote the orderliness of the alloy, and further reduce the density of defects, as shown in Figure 8-II. Moreover, simulation results show that the electron mean free path decreases significantly with the increase of the number of component elements. In this case, the consumption efficiency in HEAs is lower than that in conventional alloys. This action can help to prolong thermal spike and significantly promote the defect recovery of HEAs.
Nagase and co-workers [17] have investigated the irradiation behavior of CoCrCuFeNi multicomponent nano-crystalline HEAs. A fine-grained fcc single phase was obtained in the sputtered specimens. The fcc solid solution showed high phase stability against irradiation over a wide temperature range from 298 to 773 K and remained as the main constituent phase even when the samples were irradiated up to 40 displacement per atom (dpa). Moreover, they found that the irradiation did not seem to induce grain coarsening. Jin et al. [18] have investigated the effects of compositional complexity on the ion-irradiation-induced swelling and hardening in Ni-containing HEAs. They designed four alloys with different component numbers, including Ni, NiCo, NiCoCr, and NiCoFeCrMn alloys. It is reported that the irradiation resistance at the temperature of 500 °C is improved by controlling the number and, especially, the type of alloying elements. Alloying with Fe and Mn has a stronger influence on swelling reduction than does alloying with Co and Cr. The quinary alloy NiCoFeCrMn, with known excellent mechanical properties, has shown 40 times higher swelling tolerance than nickel.
Briefly, the recent progress in HEAs demonstrates the possibility of obtaining high radiation tolerance through unique damage self-healing mechanisms. It is desirable to design high-performance HEAs for serving as irradiation resistance materials.
Serration behaviors in plastically deforming solids are related to avalanches of deformation processes. In the stress-strain curves, the serration characteristics are visible as stress drops or strain jumps. In fact, similar serration characteristics are ubiquitous in many structural and functional materials [19], such as amorphous materials, high-entropy alloys (HEAs), superalloys, ordered intermetallic, shape-memory alloys (SMAs), electrochemical noise, carbon steels, twinning-induced plasticity steels, phase transformation-induced plasticity steels, Al-Mg alloys, nanomaterials, magnetic functional materials, and so on.
The serration behaviors are produced by the material under the action of the external field present a disordered distribution in time and space, which is closely related to the rheological structural unit of the material. The zigzag rheological phenomenon of materials in the process of plastic deformation objectively reflects some characteristics of its deformation mechanism, such as the interaction of interstitial solute atoms or replacement solute atoms and dislocations, local shear instability, grain boundary migration, and twinning. At the same time, the rheological characteristics of sawtooth are affected by many factors (such as external factors including temperature, strain rate, and heat treatment process; and internal factors including composition, grain morphology, size, and phase composition of the material).
“Self-sharpening,” the capability of a material maintaining its acute head shape during penetration, is a highly required attribute of materials in armor piercing. Liu and co-workers [20] firstly reported the self-sharping behavior of HEAs in a composition of WFeNiCo. It was observed that the remnant of 93 W penetrator has suffered severe plastic deformation and exhibits an obvious mushroom-like head. In contrast, the remnant of WFeNiMo penetrator maintains an acute head shape, demonstrating a conspicuous self-sharpening ability, which is responsible for the improved penetration performance of WFeNiMo penetrators. In comparison with conventional single-principal-element tungsten alloys where precipitated phases are strictly suppressed, they found that the new tungsten HEA by chemical disordered design promotes precipitation of rhombohedral μ phase, which can trigger dynamic recrystallization softening mediated shear banding and give rise to the prominent self-sharpening behaviors. They proved that inhomogeneous deformation and relatively higher strain gradients caused by precipitates stimulate dynamic recrystallization and lead to shear band formation.
In this case, the inhomogeneous deformation is a key issue for self-sharping behaviors, and the serration is an important reflection of inhomogeneous deformation, as shown in Figure 9. Hence, we infer that there should be a correlation between serration behavior and self-sharpening behavior, which is expected to shed light on the origin of self-sharpening and might open new opportunities for developing high-performance penetrator materials.
Deformation diagram of conventional materials and self-sharping materials.
As an emerging material system, unique characteristics of HEAs in dynamics, thermodynamics, and structure have aroused great interest in potential structural materials. Considerate efforts have been focused on the mechanical properties and related mechanisms of HEAs. As we all know, most metallurgical mechanisms for increasing strength lead to ductility loss. One of the most exciting breakthroughs of HEAs is breaking the trade-off of strength and ductility. It can be attributed to several mechanisms as follows:
(1) Concentrated solid-solution structure: Causing significant solid solution strengthening effect. (2) Severe lattice distortion: A core effect in the design of HEAs, it has been proved that can effectively improve both yield stress and its sensitivity to grain size. In this case, fine grain strengthening effect plays a more positive role in HEAs, which improves the strength as well as optimizes the deformation stability. (3) Tailoring the stability of the constituent phases in HEAs in the wide compositional space: such as designing nanoprecipitates, phase transformation, twinning, and regulating the chemical short-order.
There are many salient works that have developed HEAs possess high strength, as well as good ductility, which show great application potential in new generation of structural materials. Li and co-workers [21] have reported that Fe80-xMnxCo10Cr10 (at. %) alloy systems successfully overcome the strength-ductility trade-off by regulating metastable phase. Transformation-induced plasticity and dual-phase strengthening are two key contributions to such a breakthrough. In the Fe80–xMnxCo10Cr10 HEA, two contributions lead to enhanced trans-grain and inter-grain slip resistance, and hence, increased strength. The increased strain hardening capacity that is enabled by dislocation hardening of the stable phase and transformation-induced hardening of the metastable phase produces increased ductility.
The high strength is a typical advantage of body-centered-cubic HEAs (BCC-HEAs). However, brittleness and weak strain-hardening ability are still their Achilles’ heel. Developing ultra-strong and ductile BCC-HEAs are highly desirable but extremely challenging. Yan and co-workers [22] have reported a (Zr0.5Ti0.35Nb0.15)100–xAlx (x=10 and 20 at. %) HEAs, which show extraordinary strength (∼1.2 to 1.8 GPa) together with good tensile ductility (∼8% to 25%) at room temperature. Ultrahigh strength and excellent tensile ductility are record-high values over existing BCC-HEAs, as shown in Figure 10. Remarkably, relatively low densities of less than 6 g/cm3 are exhibited in these alloys. They demonstrated that inducing nanoprecipitates and diversifying dislocation motion modes are the key factors to achieving such a remarkable breakthrough.
Comparison of the Zr-Ti-Nb-Al HEAs with existing HEAs and amorphous alloys. (a) Maps of yield strength versus tensile strain of HEAs reported previously at room temperature [Abbreviation: Yield strength (YS), Tensile strength (TS), Amorphous alloy (AM)]. (b) Maps of specific strength versus density of HEAs reported previously at room temperature [
The unique characteristics of HEAs in dynamics, thermodynamics, and structure have aroused great interest in the new generation of structural and functional materials. The ability of HEAs to be designed with unique properties in an unlimited space of alloy compositions is encouraging. In the past two decades, many salient efforts have been conducted to explore unique and useful properties of HEAs. Many attractive properties that break the limits of traditional materials are reported. It is desirable that the development of HEAs can shed light on the novel alloy design concept and open new opportunities for developing next-generation structural and functional materials.
Y. Z. acknowledges support from (1) Guangdong Basic and Applied Basic Research Foundation (2019B1515120020); and (2) Creative Research Groups of China (No. 51921001).
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There is a plethora of research carried out regarding professionalism in policing to meet the needs and challenges of the twenty-first century. Considering the recent developments in police education and training, this chapter mainly discusses three newly introduced routes for recruitment and education of police constables under the Policing Education Qualifications Framework (PEQF), namely Police Constable Degree Apprenticeship (PCDA), Degree Holder Entry Programme (DHEP), and Pre-Join Degree (PJD). Higher education institutions (HEIs), in partnership with the police forces, are providing professional qualifications for policing as a graduate level profession. Though they have made remarkable progress in developing police education programmes, they are facing various challenges in implementing the qualification framework. This chapter also explores pedagogical aspects of police education including the effectiveness and contrast between different forms of teaching and learning. While featuring the challenges and prospects of the new police education programmes, this chapter also outlines different aspects of partnership for delivering these professional qualification programmes.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"M. Mahruf C. Shohel, Gias Uddin, Julian Parker-McLeod and Daniel Silverstone",authors:[{id:"94099",title:"Dr.",name:"M. Mahruf C.",middleName:null,surname:"Shohel",slug:"m.-mahruf-c.-shohel",fullName:"M. Mahruf C. Shohel"},{id:"319810",title:"Mr.",name:"Gias",middleName:null,surname:"Uddin",slug:"gias-uddin",fullName:"Gias Uddin"},{id:"321004",title:"Dr.",name:"Julian",middleName:null,surname:"Parker-McLeod",slug:"julian-parker-mcleod",fullName:"Julian Parker-McLeod"},{id:"321005",title:"Dr.",name:"Daniel",middleName:null,surname:"Silverstone",slug:"daniel-silverstone",fullName:"Daniel Silverstone"}]},{id:"37643",doi:"10.5772/38861",title:"Globalization and Chagas Disease",slug:"globalization-and-chagas-disease",totalDownloads:1847,totalCrossrefCites:0,totalDimensionsCites:2,abstract:null,book:{id:"2205",slug:"globalization-and-responsibility",title:"Globalization and Responsibility",fullTitle:"Globalization and Responsibility"},signatures:"João Carlos Pinto Dias and José Rodrigues Coura",authors:[{id:"75739",title:"Prof.",name:"José Rodrigues",middleName:null,surname:"Coura",slug:"jose-rodrigues-coura",fullName:"José Rodrigues Coura"},{id:"120233",title:"Prof.",name:"Joao",middleName:null,surname:"Dias",slug:"joao-dias",fullName:"Joao Dias"}]},{id:"68932",doi:"10.5772/intechopen.86916",title:"Archaeological Sites, Cultural Heritage, and Sustainable Development in the Republic of Kazakhstan",slug:"archaeological-sites-cultural-heritage-and-sustainable-development-in-the-republic-of-kazakhstan",totalDownloads:681,totalCrossrefCites:1,totalDimensionsCites:2,abstract:"This paper addresses the problem of protecting and preserving archaeological sites from the Bronze Age through the Medieval Period (ca. 2500 BC–1500 CE) as part of sustainable development that includes such economic and social benefits as (1) promoting national status; (2) integrating archaeological sites into the Silk Route narrative; (3) developing tourism related to historic and cultural heritage; and (4) creating a citizenry that values its cultural and historic resources in the face of rapid economic development and changing natural and cultural landscapes. Two UNESCO World Heritage sites will be discussed briefly: Otrar and the surrounding oasis, a medieval complex of sites along the Great Silk Route, and Tamgaly, a petroglyph and archaeological reserve. These two UNESCO World Heritage archaeological sites or preserves will be contrasted with the Talgar Iron Age sites (400 BC–100 CE) situated in a rapidly changing landscape due to economic development and infrastructure (pipelines, railways, roads, and housing) about 12–15 km east of the major city of Almaty. The goal of this article is to discuss the complexity of the entangled sectors of cultural and historic preservation, economic development, tourism, and global transnational heritage within the framework of sustainability.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"Claudia Chang",authors:[{id:"296402",title:"Dr.",name:"Claudia",middleName:null,surname:"Chang",slug:"claudia-chang",fullName:"Claudia Chang"}]},{id:"71206",doi:"10.5772/intechopen.91053",title:"Uprising and Human Rights Abuses in Southern Cameroon-Ambazonia",slug:"uprising-and-human-rights-abuses-in-southern-cameroon-ambazonia",totalDownloads:949,totalCrossrefCites:1,totalDimensionsCites:2,abstract:"In 2016, lawyers, teachers and students in the two Anglophone regions initially led demonstrations and strikes, which eventually involved a wider section of the population. This mobilization was against their marginalization by the Francophone-dominated government in which they were chronically under-represented in all aspects of national life: political appointments and professional training and had been treated as second-class citizens since their reunification. They argued that their vibrant economic and political institutions had been completely erased, and their education and judicial systems had been undermined and degraded. Activists spread videos that show security forces abusing human rights (by suppressing peaceful gatherings, beating, harassing, arresting and killing protesters, burning their houses, schools and hospitals) in order to produce a counter-narrative to the ‘official story’ that main-stream media had been producing. We collected and analyzed 30 videos to better appreciate the human rights abuses. The videos provide information that cannot be provided by other types of data. They are used as ‘proofs of facts’ and they contain much more visual information on bodily movement and acoustic data. The videos show appalling images not just of how French-speaking soldiers tortured Anglophones but also their inability to communicate with them adequately although they share the same country.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"Nanche Billa Robert",authors:[{id:"285893",title:"Dr.",name:"Nanche Billa",middleName:null,surname:"Robert",slug:"nanche-billa-robert",fullName:"Nanche Billa Robert"}]}],mostDownloadedChaptersLast30Days:[{id:"68136",title:"Globalization of the Cruise Industry: A Tale of Ships Part II - Asia Post 1994",slug:"globalization-of-the-cruise-industry-a-tale-of-ships-part-ii-asia-post-1994",totalDownloads:926,totalCrossrefCites:1,totalDimensionsCites:1,abstract:"Cruising has grown over 7% a year since 1980. Sustained rapid expansion in North America, followed by local expansion in Europe and Asia, has made cruising a global industry, with 365 ships and estimated sales of $37.8 US billion (CIN, 2017). This global development has been fueled by innovation and introduction of market changing resident ships appealing to the mass traveler which were quickly matched by competitors, establishment of industry and port marketing organizations, awareness of cruising as a vacation option, and availability of suitable port and berthing facilities. When these four conditions coexisted the industry experienced rapid growth. Since 1966, the cruise industry has developed from a Miami-centered industry to a global industry centered in North America, Europe, Asia, and Australia/New Zealand. Given the high cost of state-of-the-art ships, their deployment is a good indication of industry’s confidence in market growth. This chapter chronicles the development of the Asian cruise industry from 1994 through 2017. Data from Cruise Industry News Annual Reports (CIN) and Berlitz Complete Guide to Cruising and Cruise Ships (Ward) are examined and conclusions are drawn.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"Andrew O. Coggins",authors:[{id:"229658",title:"Prof.",name:"Andrew",middleName:null,surname:"Coggins Jr",slug:"andrew-coggins-jr",fullName:"Andrew Coggins Jr"}]},{id:"72435",title:"Police Education in the United Kingdom: Challenges and Future Directions",slug:"police-education-in-the-united-kingdom-challenges-and-future-directions",totalDownloads:1132,totalCrossrefCites:2,totalDimensionsCites:2,abstract:"This chapter outlines the historical development of police education in the United Kingdom, more precisely in England and Wales, and highlights new strategies and planning for the professional development of the police. There is a plethora of research carried out regarding professionalism in policing to meet the needs and challenges of the twenty-first century. Considering the recent developments in police education and training, this chapter mainly discusses three newly introduced routes for recruitment and education of police constables under the Policing Education Qualifications Framework (PEQF), namely Police Constable Degree Apprenticeship (PCDA), Degree Holder Entry Programme (DHEP), and Pre-Join Degree (PJD). Higher education institutions (HEIs), in partnership with the police forces, are providing professional qualifications for policing as a graduate level profession. Though they have made remarkable progress in developing police education programmes, they are facing various challenges in implementing the qualification framework. This chapter also explores pedagogical aspects of police education including the effectiveness and contrast between different forms of teaching and learning. While featuring the challenges and prospects of the new police education programmes, this chapter also outlines different aspects of partnership for delivering these professional qualification programmes.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"M. Mahruf C. Shohel, Gias Uddin, Julian Parker-McLeod and Daniel Silverstone",authors:[{id:"94099",title:"Dr.",name:"M. Mahruf C.",middleName:null,surname:"Shohel",slug:"m.-mahruf-c.-shohel",fullName:"M. Mahruf C. Shohel"},{id:"319810",title:"Mr.",name:"Gias",middleName:null,surname:"Uddin",slug:"gias-uddin",fullName:"Gias Uddin"},{id:"321004",title:"Dr.",name:"Julian",middleName:null,surname:"Parker-McLeod",slug:"julian-parker-mcleod",fullName:"Julian Parker-McLeod"},{id:"321005",title:"Dr.",name:"Daniel",middleName:null,surname:"Silverstone",slug:"daniel-silverstone",fullName:"Daniel Silverstone"}]},{id:"73702",title:"Approaches to Analysis of Interstate Cooperation",slug:"approaches-to-analysis-of-interstate-cooperation",totalDownloads:643,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"At the present day cultural diplomacy plays a rather important role in the development of international relations and world politics. This concept is receiving increasing attention from various countries, international and non-governmental organizations and other actors. This trend exists due to a number of reasons, such as the desire of states to create a positive image of their country, the expansion of international cooperation, changes in the global and domestic political situation, the protection of national interests, the prevention of conflicts between states, etc. Cultural diplomacy, beyond historical precedents, consists of a relatively new practice of a country’s foreign policy, which has traditionally focused on trade and security and defense issues. It is true that in European countries there are institutions of cultural foreign relations since the beginning of the century, but in the last decade the issues, related to the projection of the international image of countries, have become more important.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"Alexander Rozanov, Maria Ivanchenko, Alexandra Baranova, Elena N. Antonova, Mikhail Smirnov, Olga Belyaeva, Maria Ilicheva, Ludmila Ilicheva, Maria Krotovskaya, Tatiana Grabovich, Zaru Utekova, Dmitry Medvedev, Natalya Ogneva, Furat Al-Mutairi, Elvira Shishlo, Amina Surpkelova, Irina Kopachevskaya, Irina Sokurova, Yulia Borisova, Fernando Joao, Artyom Pakulskikh, Polina Chernova, Alexandra Khramova, Oksana Gryuk, Jesus Yaniz Gonzalez, Valentina Komleva, Alina Papsheva and Arkadi Bessonov",authors:[{id:"233092",title:"Dr.",name:"Alexander",middleName:null,surname:"Rozanov",slug:"alexander-rozanov",fullName:"Alexander Rozanov"},{id:"312194",title:"Prof.",name:"Valentina",middleName:"Vycheslavovna",surname:"Komleva",slug:"valentina-komleva",fullName:"Valentina Komleva"},{id:"312195",title:"Ms.",name:"Alexandra",middleName:null,surname:"Baranova",slug:"alexandra-baranova",fullName:"Alexandra Baranova"},{id:"312196",title:"Dr.",name:"Furat",middleName:null,surname:"Al Mutairi",slug:"furat-al-mutairi",fullName:"Furat Al Mutairi"},{id:"312197",title:"Ms.",name:"Maria",middleName:null,surname:"Ivanchenko",slug:"maria-ivanchenko",fullName:"Maria Ivanchenko"},{id:"312198",title:"Associate Prof.",name:"Arkadi",middleName:null,surname:"Bessonov",slug:"arkadi-bessonov",fullName:"Arkadi Bessonov"},{id:"312199",title:"Ms.",name:"Alina",middleName:null,surname:"Papsheva",slug:"alina-papsheva",fullName:"Alina Papsheva"},{id:"312200",title:"Prof.",name:"Ludmila",middleName:null,surname:"Ilicheva",slug:"ludmila-ilicheva",fullName:"Ludmila Ilicheva"},{id:"312201",title:"Ph.D. Student",name:"Aleksandra",middleName:null,surname:"Khramova",slug:"aleksandra-khramova",fullName:"Aleksandra Khramova"},{id:"316768",title:"Dr.",name:"Maria",middleName:null,surname:"Ilicheva",slug:"maria-ilicheva",fullName:"Maria Ilicheva"},{id:"317753",title:"Dr.",name:"Oksana",middleName:null,surname:"Gryuk",slug:"oksana-gryuk",fullName:"Oksana Gryuk"}]},{id:"71206",title:"Uprising and Human Rights Abuses in Southern Cameroon-Ambazonia",slug:"uprising-and-human-rights-abuses-in-southern-cameroon-ambazonia",totalDownloads:951,totalCrossrefCites:1,totalDimensionsCites:2,abstract:"In 2016, lawyers, teachers and students in the two Anglophone regions initially led demonstrations and strikes, which eventually involved a wider section of the population. This mobilization was against their marginalization by the Francophone-dominated government in which they were chronically under-represented in all aspects of national life: political appointments and professional training and had been treated as second-class citizens since their reunification. They argued that their vibrant economic and political institutions had been completely erased, and their education and judicial systems had been undermined and degraded. Activists spread videos that show security forces abusing human rights (by suppressing peaceful gatherings, beating, harassing, arresting and killing protesters, burning their houses, schools and hospitals) in order to produce a counter-narrative to the ‘official story’ that main-stream media had been producing. We collected and analyzed 30 videos to better appreciate the human rights abuses. The videos provide information that cannot be provided by other types of data. They are used as ‘proofs of facts’ and they contain much more visual information on bodily movement and acoustic data. The videos show appalling images not just of how French-speaking soldiers tortured Anglophones but also their inability to communicate with them adequately although they share the same country.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"Nanche Billa Robert",authors:[{id:"285893",title:"Dr.",name:"Nanche Billa",middleName:null,surname:"Robert",slug:"nanche-billa-robert",fullName:"Nanche Billa Robert"}]},{id:"72097",title:"Towards Global Peace and Sustainability: Role of Education in Peace-Building in the Great Lakes Region of Sub-Saharan Africa",slug:"towards-global-peace-and-sustainability-role-of-education-in-peace-building-in-the-great-lakes-regio",totalDownloads:683,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"The Great Lakes Region of sub-Saharan Africa is well known for being volatile and turbulent in terms of peace and stability. For over 60 years, almost all countries in the region have experienced some kind of political and social turmoil such as civil war, coup de tat, and genocides. In 1960, the first democratically elected Congolese prime minister was assassinated. There were unprecedented social and political havoc in a nearby “other Congo” characterized by power struggle between various political and ethnic factions in the post-independence Congo Brazzaville. In Burundi and Rwanda, ethnic tensions between the Tutsi and Hutu engulfed the developmental dreams of nationalist freedom fighters until 2015. Though arguably stable, Tanzania has experienced its own share of socio-political messy including the 1998 Mwembechai and 2001 Pemba massacres. Efforts to build a sense of sustainable peace and development based on mutual understanding and socio-political harmony has brought limited success. In all these countries, the missing link in building sustainable peace and security has been a lack of education. The chapter intends to fill this gap by critically analyzing the potential role of basic education, especially pre-primary and early grades education, in sustainable peace-building in the sub-Saharan context.",book:{id:"6950",slug:"education-human-rights-and-peace-in-sustainable-development",title:"Education, Human Rights and Peace in Sustainable Development",fullTitle:"Education, Human Rights and Peace in Sustainable Development"},signatures:"Laurent Gabriel Ndijuye and Pambas Basil Tandika",authors:[{id:"301740",title:"Dr.",name:"Laurent Gabriel",middleName:null,surname:"Ndijuye",slug:"laurent-gabriel-ndijuye",fullName:"Laurent Gabriel Ndijuye"},{id:"319403",title:"Dr.",name:"Pambas Basilius",middleName:null,surname:"Tandika",slug:"pambas-basilius-tandika",fullName:"Pambas Basilius Tandika"}]}],onlineFirstChaptersFilter:{topicId:"476",limit:6,offset:0},onlineFirstChaptersCollection:[],onlineFirstChaptersTotal:0},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:8,limit:8,total:0},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:90,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:107,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:33,numberOfPublishedChapters:330,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:14,numberOfPublishedChapters:145,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:9,numberOfPublishedChapters:139,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:122,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:112,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:21,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:10,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:"2753-6580",doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}},{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}}]},series:{item:{id:"10",title:"Physiology",doi:"10.5772/intechopen.72796",issn:"2631-8261",scope:"Modern physiology requires a comprehensive understanding of the integration of tissues and organs throughout the mammalian body, including the cooperation between structure and function at the cellular and molecular levels governed by gene and protein expression. While a daunting task, learning is facilitated by identifying common and effective signaling pathways mediated by a variety of factors employed by nature to preserve and sustain homeostatic life. \r\nAs a leading example, the cellular interaction between intracellular concentration of Ca+2 increases, and changes in plasma membrane potential is integral for coordinating blood flow, governing the exocytosis of neurotransmitters, and modulating gene expression and cell effector secretory functions. Furthermore, in this manner, understanding the systemic interaction between the cardiovascular and nervous systems has become more important than ever as human populations' life prolongation, aging and mechanisms of cellular oxidative signaling are utilised for sustaining life. \r\nAltogether, physiological research enables our identification of distinct and precise points of transition from health to the development of multimorbidity throughout the inevitable aging disorders (e.g., diabetes, hypertension, chronic kidney disease, heart failure, peptic ulcer, inflammatory bowel disease, age-related macular degeneration, cancer). With consideration of all organ systems (e.g., brain, heart, lung, gut, skeletal and smooth muscle, liver, pancreas, kidney, eye) and the interactions thereof, this Physiology Series will address the goals of resolving (1) Aging physiology and chronic disease progression (2) Examination of key cellular pathways as they relate to calcium, oxidative stress, and electrical signaling, and (3) how changes in plasma membrane produced by lipid peroxidation products can affect aging physiology, covering new research in the area of cell, human, plant and animal physiology.",coverUrl:"https://cdn.intechopen.com/series/covers/10.jpg",latestPublicationDate:"July 20th, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:14,editor:{id:"35854",title:"Prof.",name:"Tomasz",middleName:null,surname:"Brzozowski",slug:"tomasz-brzozowski",fullName:"Tomasz Brzozowski",profilePictureURL:"https://mts.intechopen.com/storage/users/35854/images/system/35854.jpg",biography:"Prof. Dr. Thomas Brzozowski works as a professor of Human Physiology and is currently Chairman at the Department of Physiology and is V-Dean of the Medical Faculty at Jagiellonian University Medical College, Cracow, Poland. His primary area of interest is physiology and pathophysiology of the gastrointestinal (GI) tract, with the major focus on the mechanism of GI mucosal defense, protection, and ulcer healing. He was a postdoctoral NIH fellow at the University of California and the Gastroenterology VA Medical Center, Irvine, Long Beach, CA, USA, and at the Gastroenterology Clinics Erlangen-Nuremberg and Munster in Germany. He has published 290 original articles in some of the most prestigious scientific journals and seven book chapters on the pathophysiology of the GI tract, gastroprotection, ulcer healing, drug therapy of peptic ulcers, hormonal regulation of the gut, and inflammatory bowel disease.",institutionString:null,institution:{name:"Jagiellonian University",institutionURL:null,country:{name:"Poland"}}},editorTwo:null,editorThree:null},subseries:{paginationCount:4,paginationItems:[{id:"10",title:"Animal Physiology",coverUrl:"https://cdn.intechopen.com/series_topics/covers/10.jpg",isOpenForSubmission:!0,editor:{id:"202192",title:"Dr.",name:"Catrin",middleName:null,surname:"Rutland",slug:"catrin-rutland",fullName:"Catrin Rutland",profilePictureURL:"https://mts.intechopen.com/storage/users/202192/images/system/202192.png",biography:"Catrin Rutland is an Associate Professor of Anatomy and Developmental Genetics at the University of Nottingham, UK. She obtained a BSc from the University of Derby, England, a master’s degree from Technische Universität München, Germany, and a Ph.D. from the University of Nottingham. She undertook a post-doctoral research fellowship in the School of Medicine before accepting tenure in Veterinary Medicine and Science. Dr. Rutland also obtained an MMedSci (Medical Education) and a Postgraduate Certificate in Higher Education (PGCHE). She is the author of more than sixty peer-reviewed journal articles, twelve books/book chapters, and more than 100 research abstracts in cardiovascular biology and oncology. She is a board member of the European Association of Veterinary Anatomists, Fellow of the Anatomical Society, and Senior Fellow of the Higher Education Academy. Dr. Rutland has also written popular science books for the public. https://orcid.org/0000-0002-2009-4898. www.nottingham.ac.uk/vet/people/catrin.rutland",institutionString:null,institution:{name:"University of Nottingham",institutionURL:null,country:{name:"United Kingdom"}}},editorTwo:null,editorThree:null},{id:"11",title:"Cell Physiology",coverUrl:"https://cdn.intechopen.com/series_topics/covers/11.jpg",isOpenForSubmission:!0,editor:{id:"133493",title:"Prof.",name:"Angel",middleName:null,surname:"Catala",slug:"angel-catala",fullName:"Angel Catala",profilePictureURL:"https://mts.intechopen.com/storage/users/133493/images/3091_n.jpg",biography:"Prof. Dr. Angel Catalá \r\nShort Biography Angel Catalá was born in Rodeo (San Juan, Argentina). He studied \r\nchemistry at the Universidad Nacional de La Plata, Argentina, where received aPh.D. degree in chemistry (Biological Branch) in 1965. From\r\n1964 to 1974, he worked as Assistant in Biochemistry at the School of MedicineUniversidad Nacional de La Plata, Argentina. From 1974 to 1976, he was a Fellowof the National Institutes of Health (NIH) at the University of Connecticut, Health Center, USA. From 1985 to 2004, he served as a Full Professor oBiochemistry at the Universidad Nacional de La Plata, Argentina. He is Member ofthe National Research Council (CONICET), Argentina, and Argentine Society foBiochemistry and Molecular Biology (SAIB). His laboratory has been interested for manyears in the lipid peroxidation of biological membranes from various tissues and different species. Professor Catalá has directed twelve doctoral theses, publishedover 100 papers in peer reviewed journals, several chapters in books andtwelve edited books. Angel Catalá received awards at the 40th InternationaConference Biochemistry of Lipids 1999: Dijon (France). W inner of the Bimbo PanAmerican Nutrition, Food Science and Technology Award 2006 and 2012, South AmericaHuman Nutrition, Professional Category. 2006 award in pharmacology, Bernardo\r\nHoussay, in recognition of his meritorious works of research. Angel Catalá belongto the Editorial Board of Journal of lipids, International Review of Biophysical ChemistryFrontiers in Membrane Physiology and Biophysics, World Journal oExperimental Medicine and Biochemistry Research International, W orld Journal oBiological Chemistry, Oxidative Medicine and Cellular Longevity, Diabetes and thePancreas, International Journal of Chronic Diseases & Therapy, International Journal oNutrition, Co-Editor of The Open Biology Journal.",institutionString:null,institution:{name:"National University of La Plata",institutionURL:null,country:{name:"Argentina"}}},editorTwo:null,editorThree:null},{id:"12",title:"Human Physiology",coverUrl:"https://cdn.intechopen.com/series_topics/covers/12.jpg",isOpenForSubmission:!0,editor:{id:"195829",title:"Prof.",name:"Kunihiro",middleName:null,surname:"Sakuma",slug:"kunihiro-sakuma",fullName:"Kunihiro Sakuma",profilePictureURL:"https://mts.intechopen.com/storage/users/195829/images/system/195829.jpg",biography:"Professor Kunihiro Sakuma, Ph.D., currently works in the Institute for Liberal Arts at the Tokyo Institute of Technology. He is a physiologist working in the field of skeletal muscle. He was awarded his sports science diploma in 1995 by the University of Tsukuba and began his scientific work at the Department of Physiology, Aichi Human Service Center, focusing on the molecular mechanism of congenital muscular dystrophy and normal muscle regeneration. His interest later turned to the molecular mechanism and attenuating strategy of sarcopenia (age-related muscle atrophy). His opinion is to attenuate sarcopenia by improving autophagic defects using nutrient- and pharmaceutical-based treatments.",institutionString:null,institution:{name:"Tokyo Institute of Technology",institutionURL:null,country:{name:"Japan"}}},editorTwo:{id:"331519",title:"Dr.",name:"Kotomi",middleName:null,surname:"Sakai",slug:"kotomi-sakai",fullName:"Kotomi Sakai",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0033Y000031QtFXQA0/Profile_Picture_1637053227318",biography:"Senior researcher Kotomi Sakai, Ph.D., MPH, works at the Research Organization of Science and Technology in Ritsumeikan University. She is a researcher in the geriatric rehabilitation and public health field. She received Ph.D. from Nihon University and MPH from St.Luke’s International University. Her main research interest is sarcopenia in older adults, especially its association with nutritional status. Additionally, to understand how to maintain and improve physical function in older adults, to conduct studies about the mechanism of sarcopenia and determine when possible interventions are needed.",institutionString:null,institution:{name:"Ritsumeikan University",institutionURL:null,country:{name:"Japan"}}},editorThree:null},{id:"13",title:"Plant Physiology",coverUrl:"https://cdn.intechopen.com/series_topics/covers/13.jpg",isOpenForSubmission:!0,editor:{id:"332229",title:"Prof.",name:"Jen-Tsung",middleName:null,surname:"Chen",slug:"jen-tsung-chen",fullName:"Jen-Tsung Chen",profilePictureURL:"https://mts.intechopen.com/storage/users/332229/images/system/332229.png",biography:"Dr. Jen-Tsung Chen is currently a professor at the National University of Kaohsiung, Taiwan. He teaches cell biology, genomics, proteomics, medicinal plant biotechnology, and plant tissue culture. Dr. Chen\\'s research interests include bioactive compounds, chromatography techniques, in vitro culture, medicinal plants, phytochemicals, and plant biotechnology. He has published more than ninety scientific papers and serves as an editorial board member for Plant Methods, Biomolecules, and International Journal of Molecular Sciences.",institutionString:"National University of Kaohsiung",institution:{name:"National University of Kaohsiung",institutionURL:null,country:{name:"Taiwan"}}},editorTwo:null,editorThree:null}]},overviewPageOFChapters:{paginationCount:16,paginationItems:[{id:"82135",title:"Carotenoids in Cassava (Manihot esculenta Crantz)",doi:"10.5772/intechopen.105210",signatures:"Lovina I. Udoh, Josephine U. Agogbua, Eberechi R. Keyagha and Itorobong I. 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Buchholz and Erik J. Behringer",hash:"e373a3d1123dbd45fddf75d90e3e7c38",volumeInSeries:1,fullTitle:"Calcium and Signal Transduction",editors:[{id:"89438",title:"Dr.",name:"John N.",middleName:null,surname:"Buchholz",slug:"john-n.-buchholz",fullName:"John N. Buchholz",profilePictureURL:"https://mts.intechopen.com/storage/users/89438/images/6463_n.jpg",biography:"Full Professor and Vice Chair, Division of Pharmacology, Loma Linda University, School of Medicine. He received his B.S. Degree in Biology at La Sierra University, Riverside California (1980) and a PhD in Pharmacology from Loma Linda University School of Medicine (1988). Post-Doctoral Fellow at University of California, Irvine, College of Medicine 1989-1992 with a focus on autonomic nerve function in blood vessels and the impact of aging on the function of these nerves and overall blood vessel function. Twenty years of research funding and served on NIH R01 review panels, Editor-In-Chief of Edorium Journal of Aging Research. Serves as a peer reviewer for biomedical journals. Military Reserve Officer serving with the 100 Support Command, 100 Troop Command, 40 Infantry Division, CA National Guard.",institutionString:null,institution:{name:"Loma Linda University",institutionURL:null,country:{name:"United States of America"}}}]},{type:"book",id:"6925",title:"Endoplasmic Reticulum",subtitle:null,coverURL:"https://cdn.intechopen.com/books/images_new/6925.jpg",slug:"endoplasmic-reticulum",publishedDate:"April 17th 2019",editedByType:"Edited by",bookSignature:"Angel Català",hash:"a9e90d2dbdbc46128dfe7dac9f87c6b4",volumeInSeries:2,fullTitle:"Endoplasmic Reticulum",editors:[{id:"196544",title:"Prof.",name:"Angel",middleName:null,surname:"Catala",slug:"angel-catala",fullName:"Angel Catala",profilePictureURL:"https://mts.intechopen.com/storage/users/196544/images/system/196544.jpg",biography:"Angel Catalá studied chemistry at Universidad Nacional de La Plata, Argentina, where he received a Ph.D. in Chemistry (Biological Branch) in 1965. From 1964 to 1974, he worked as an Assistant in Biochemistry at the School of Medicine at the same university. From 1974 to 1976, he was a fellow of the National Institutes of Health (NIH) at the University of Connecticut, Health Center, USA. From 1985 to 2004, he served as a Full Professor of Biochemistry at the Universidad Nacional de La Plata. He is a member of the National Research Council (CONICET), Argentina, and the Argentine Society for Biochemistry and Molecular Biology (SAIB). His laboratory has been interested for many years in the lipid peroxidation of biological membranes from various tissues and different species. Dr. Catalá has directed twelve doctoral theses, published more than 100 papers in peer-reviewed journals, several chapters in books, and edited twelve books. He received awards at the 40th International Conference Biochemistry of Lipids 1999 in Dijon, France. He is the winner of the Bimbo Pan-American Nutrition, Food Science and Technology Award 2006 and 2012, South America, Human Nutrition, Professional Category. In 2006, he won the Bernardo Houssay award in pharmacology, in recognition of his meritorious works of research. Dr. Catalá belongs to the editorial board of several journals including Journal of Lipids; International Review of Biophysical Chemistry; Frontiers in Membrane Physiology and Biophysics; World Journal of Experimental Medicine and Biochemistry Research International; World Journal of Biological Chemistry, Diabetes, and the Pancreas; International Journal of Chronic Diseases & Therapy; and International Journal of Nutrition. He is the co-editor of The Open Biology Journal and associate editor for Oxidative Medicine and Cellular Longevity.",institutionString:"Universidad Nacional de La Plata",institution:{name:"National University of La Plata",institutionURL:null,country:{name:"Argentina"}}}]},{type:"book",id:"6924",title:"Adenosine Triphosphate in Health and Disease",subtitle:null,coverURL:"https://cdn.intechopen.com/books/images_new/6924.jpg",slug:"adenosine-triphosphate-in-health-and-disease",publishedDate:"April 24th 2019",editedByType:"Edited by",bookSignature:"Gyula Mozsik",hash:"04106c232a3c68fec07ba7cf00d2522d",volumeInSeries:3,fullTitle:"Adenosine Triphosphate in Health and Disease",editors:[{id:"58390",title:"Dr.",name:"Gyula",middleName:null,surname:"Mozsik",slug:"gyula-mozsik",fullName:"Gyula Mozsik",profilePictureURL:"https://mts.intechopen.com/storage/users/58390/images/system/58390.png",biography:"Gyula Mózsik MD, Ph.D., ScD (med), is an emeritus professor of Medicine at the First Department of Medicine, Univesity of Pécs, Hungary. He was head of this department from 1993 to 2003. His specializations are medicine, gastroenterology, clinical pharmacology, clinical nutrition, and dietetics. His research fields are biochemical pharmacological examinations in the human gastrointestinal (GI) mucosa, mechanisms of retinoids, drugs, capsaicin-sensitive afferent nerves, and innovative pharmacological, pharmaceutical, and nutritional (dietary) research in humans. He has published about 360 peer-reviewed papers, 197 book chapters, 692 abstracts, 19 monographs, and has edited 37 books. He has given about 1120 regular and review lectures. He has organized thirty-eight national and international congresses and symposia. He is the founder of the International Conference on Ulcer Research (ICUR); International Union of Pharmacology, Gastrointestinal Section (IUPHAR-GI); Brain-Gut Society symposiums, and gastrointestinal cytoprotective symposiums. He received the Andre Robert Award from IUPHAR-GI in 2014. Fifteen of his students have been appointed as full professors in Egypt, Cuba, and Hungary.",institutionString:"University of Pécs",institution:{name:"University of Pecs",institutionURL:null,country:{name:"Hungary"}}}]},{type:"book",id:"8008",title:"Antioxidants",subtitle:null,coverURL:"https://cdn.intechopen.com/books/images_new/8008.jpg",slug:"antioxidants",publishedDate:"November 6th 2019",editedByType:"Edited by",bookSignature:"Emad Shalaby",hash:"76361b4061e830906267933c1c670027",volumeInSeries:5,fullTitle:"Antioxidants",editors:[{id:"63600",title:"Prof.",name:"Emad",middleName:null,surname:"Shalaby",slug:"emad-shalaby",fullName:"Emad Shalaby",profilePictureURL:"https://mts.intechopen.com/storage/users/63600/images/system/63600.png",biography:"Dr. Emad Shalaby is a professor of biochemistry on the Biochemistry Department Faculty of Agriculture, Cairo University. He\nreceived a short-term scholarship to carry out his post-doctoral\nstudies abroad, from Japan International Cooperation Agency\n(JICA), in coordination with the Egyptian government. Dr.\nShalaby speaks fluent English and his native Arabic. He has 77\ninternationally published research papers, has attended 15 international conferences, and has contributed to 18 international books and chapters.\nDr. Shalaby works as a reviewer on over one hundred international journals and is\non the editorial board of more than twenty-five international journals. He is a member of seven international specialized scientific societies, besides his local one, and\nhe has won seven prizes.",institutionString:"Cairo University",institution:{name:"Cairo University",institutionURL:null,country:{name:"Egypt"}}}]}]},openForSubmissionBooks:{paginationCount:2,paginationItems:[{id:"11676",title:"Recent Advances in Homeostasis",coverURL:"https://cdn.intechopen.com/books/images_new/11676.jpg",hash:"63eb775115bf2d6d88530b234a1cc4c2",secondStepPassed:!0,currentStepOfPublishingProcess:3,submissionDeadline:"July 15th 2022",isOpenForSubmission:!0,editors:[{id:"203015",title:"Dr.",name:"Gaffar",surname:"Zaman",slug:"gaffar-zaman",fullName:"Gaffar Zaman"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null},{id:"12213",title:"New Advances in Photosynthesis",coverURL:"https://cdn.intechopen.com/books/images_new/12213.jpg",hash:"2eece9ed4f67de4eb73da424321fc455",secondStepPassed:!0,currentStepOfPublishingProcess:3,submissionDeadline:"July 15th 2022",isOpenForSubmission:!0,editors:[{id:"224171",title:"Prof.",name:"Josphert N.",surname:"Kimatu",slug:"josphert-n.-kimatu",fullName:"Josphert N. 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