",isbn:"978-1-83881-111-2",printIsbn:"978-1-83880-992-8",pdfIsbn:"978-1-83881-112-9",doi:null,price:0,priceEur:0,priceUsd:0,slug:null,numberOfPages:0,isOpenForSubmission:!0,isSalesforceBook:!1,isNomenclature:!1,hash:"acb2875b3bfc189c9881a9b44b6a5184",bookSignature:"Dr. Abdo Abou Jaoudé",publishedDate:null,coverURL:"https://cdn.intechopen.com/books/images_new/11865.jpg",keywords:"Linear Operators, Normal Operators, Spectral Theorem, Applications, Differential Operators, Integral Operators, Functional Calculus, Complex Variables, Complex Analysis, Theory, Recent Advances, Latest Trends",numberOfDownloads:null,numberOfWosCitations:0,numberOfCrossrefCitations:null,numberOfDimensionsCitations:null,numberOfTotalCitations:null,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"April 13th 2022",dateEndSecondStepPublish:"June 21st 2022",dateEndThirdStepPublish:"August 20th 2022",dateEndFourthStepPublish:"November 8th 2022",dateEndFifthStepPublish:"January 7th 2023",dateConfirmationOfParticipation:null,remainingDaysToSecondStep:"2 months",secondStepPassed:!0,areRegistrationsClosed:!1,currentStepOfPublishingProcess:3,editedByType:null,kuFlag:!1,biosketch:"Abdo Abou Jaoudé is a pioneering Associate Professor of Mathematics and Statistics at Notre Dame University-Louaizé. 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1. Introduction
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Recently, semiconductor and circuits have been developed to make many high technologies of processing be easier to be introduced. By using this technology, there has been considerable amount of research effort directed towards applied information and communications technology (ICT) to medical services [1, 2]. Body area networks (BANs) have emerged as an important subject in personal wireless communications. The standardization task group IEEE 802.15.6 determines the standardization of PHY and MAC layers for BANs. WBAN are networks composed of in vivo and in vitro wireless communication. Communication between devices located outside of a human body is named wearable WBAN, and similarly, Communication between devices located inside of a human body is called implanted WBAN.
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Wearable WBAN is expected to have numerous applications [3]. For example, each sensor device, which consists of wearable WBAN, can continuously measure and transmit vital parameters data via wearable WBAN. Based on the information sent by a wearable WBAN worn by a particular patient, the hypo-thetical Healthcare Central System of the hospital can be continuously aware of the patient vital functions and is able to take the appropriate countermeasures in case of medical alert. And wearable WBAN is also taken non-medical use (entertainment: video game, music, etc) into consideration. The potential mass market includes medical and non-medical applications. In wearable WBAN, devices treat vital signs of a human body and, therefore, more secure communications are needed. Furthermore, medical ICT has needed data rates of about 10 kbps. Considering practical purposes and non-medical use, however, it is necessary to achieve higher data rates [4, 5]. Most cases of non-medical applications do not require strong error controlling but less complexity and power consumption, and in the special case of video transmission a large throughput and low latency are needed to keep their battery life longer. On the contrary, medical applications require high reliability and relative low data rate transmission as well high data rate transmission. Hence, strong error controlling is expected while relatively larger complexity is allowed. As they require different quality of service (QoS) in terms of reliability and performance, a fixed error controlling mechanism like forward error correction (FEC) is not appropriate.
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In order to reconcile medical and non-medical applications requirements, we propose an adaptive error controlling mechanism in the form of hybrid ARQ (H-ARQ). Such error-controlling system adapts to the channel conditions which can optimize the throughput, latency and reliability according to the application specification and channel conditions.
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The proposed scheme can be used for both narrowband and wideband PHYs. Although, in the current status of the task group IEEE 802.15.6, non-medical applications are envisioned for the wideband PHY proposal only, i.e., UWB-PHY. On the other hand, medical applications use the narrowband and wideband PHYs. Therefore, we focus on the UWB-PHY for designing and showing the coexistence of medical and non-medical applications for BANs through the proposed H-ARQ.
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UWB systems have emerged as a potential candidate for on-body communications in BANs. Indeed, UWB radios allow [1]:
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Low implementation complexity, which is critical for low power consumption.
The signal power levels are in the order of those used in the MICS band. That is, UWB provides safe power levels for the human body, besides low interference to other devices.
Finally, impulse radio based UWB systems allows bit rate scalability.
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In this section, we propose a simple and practical binary pulse position modulation (2PPM) scheme with energy detection at the receiver. This makes it feasible to implement and analogue front-end at the receiver (with low power consumption) in the high band of UWB, where UWB-BANs are proposed to operate, globally.
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In this research, it is assumed that there are interference among coexisting piconets BANs, because a coordinator in each piconet BAN of IEEE802.15.6 can control the whole device access within its coordinating piconet so as to avoid contention among accesses of all the devices although interference among coexisting piconet BANs due to asynchronous access among the coexisting piconets. Since high band of UWB regulation such as 7.25-10.25GHz has suppressed interference enough low for coexistence with other radio communication systems. However, non-coherent transceivers have poorer performance than coherent architectures. Therefore, it is necessary to introduce an error controlling mechanism that can guarantee QoS and performance depending on the application and channel condition, while relying on a simple UWB-PHY.
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We show that the good performance in UWB-BAN channels can be achieved. Therefore, a robust scheme is possible for the medical applications of BANs. The advantage of this scheme is its less complex and consequently less power consumption plus it achieves higher throughput compared to using the FEC alone, which are important for BAN applications. Furthermore, from comparing the performance of without our proposed scheme, the proposed schemes obtain up to 2dB of gain at the uncorrected erroneous packet rate and its throughput efficiency improves at a maximum 40 percent while the bit rate for non-medical communications is not changed. Moreover, this error-controlling scheme is proposed at IEEE 802.15.6 committee and that standardization makes agreement to oblige employing this scheme for UWB based medical applications.
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2. System model and the definition of WBAN
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In this section, we briefly describe the definition of wireless body area network (WBAN)[1, 2], and the description of ultra wideband (UWB) signal and transmission system [4, 5].
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2.1. Aim of WBAN
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WBAN is for short range, wireless communication in the vicinity of, or inside, a human body (but not limited to humans). It uses existing ISM bands as well as frequency bands approved by national medical and/or regulatory authorities such as UWB(Ultra Wide Band). Quality of service (QoS), extremely low power, and data rates up to 10 Mbps are required while satisfying a strict non-interference guideline. IEEE 802.15.6 standardization considers effects on portable antennas due to the presence of a person (varying with male, female, skinny, heavy, etc.), radiation pattern shaping to minimize Specific Absorption Rate(SAR) into the body, and changes in characteristics as a result of the user motions.
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The purpose of WBAN is to provide an international standard for a short range (ie about human body range), low power and highly reliable wireless communication for use in close proximity to, or inside, a human body. Data rates can be offered to satisfy an evolutionary set of entertainment and healthcare services. Current Personal area networks (PANs) do not meet the medical (proximity to human tissue) and relevant communication regulations for some application environments. They also do not support the combination of reliability, QoS, low power, data rate and non-interference required to broadly address the breadth of body area network applications.
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2.2. General framework elements
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This section provides the basic framework required for all nodes and hubs. It covers the following fundamental aspects: the network topology used for medium access, the reference model used for functional partitioning, the time base used for access scheduling, the state diagram used for frame exchange, and the security paradigm used for message protection.
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2.2.1. Network topology
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All nodes and hubs will be organized into logical sets, referred to BANs in this specification, and coordinated by their respective hubs for medium access and power management as illustrated in figure 1. There should be one and only one hub in a BAN. In a one-hop star BAN, frame exchanges may occur directly only between nodes and the hub of the BAN. In a two-hop extended star BAN, the hub and a node may optionally exchange frames via a relay capable node.
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Figure 1.
Network topology
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2.2.2. MAC frame formats
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All nodes and hubs should establish a time reference base, if their medium access must be scheduled in time, where the time axis is divided into beacon periods (superframes) of equal length and each beacon period is composed of allocation slots of equal length and numbered from 0, 1,.... An allocation interval may be referenced in terms of the numbered allocation slots comprising it, and a point of time may be referenced in terms of the numbered allocation slot preceding or following it as well.
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If time reference is needed for access scheduling in its BAN, the hub will choose the boundaries of beacon periods (superframes) and hence the allocation slots therein. In beacon mode operation for which beacons are transmitted, the hub shall communicate such boundaries by transmitting beacons at the start or other specified locations of beacon periods (superframes), and optionally time frames (T-Poll frames) containing their transmit time relative to the start time of current beacon period (superframe). In non-beacon mode operation for which beacons are not transmitted but time reference is needed, the hub will communicate such boundaries by transmitting time frames (T-Poll frames) also containing their transmitted time relative to the start time of current superframe.
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A node requiring a time reference in the BAN will derive and recalibrate the boundaries of beacon periods (superframes) and allocation slots from reception of beacons or/and time frames (T-Poll frames). A frame transmission may span more than one allocation slot, starting or ending not necessarily on an allocation slot boundary.
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2.3. UWB PHY description
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The UWB PHY specification is designed to provide robust performance for BANs. UWB transceivers allow low implementation complexity (critical for low power consumption). Moreover, the signal power levels are in the order of those used in the MICS (Medical Implant Communication Services) band, for example, safety power levels for the human body and low interference to other devices.
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2.3.1. Signal model
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The paper assumes UWB impulse radio and non-coherent modulation in the form of 2PPM, energy detection. This is the most promising candidate as mandatory mode for the wideband PHY of the IEEE 802.15.6 TG on BANs.
where g\n\t\t\t\t\t\tm∈{0,1} is the mth component of a given codeword, T\n\t\t\t\t\t\tBPM is the slot time for 2PPM, and T\n\t\t\t\t\t\tsym is the symbol time. The basis function w(t) is a burst of short pulses p(t), where d\n\t\t\t\t\t\tm,n is a scrambling sequence and N\n\t\t\t\t\t\tcpb is a sequence length. This is only to control data rate and legacy to IEEE 802.15.4a systems.
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For the sake of illustration and without loss of generality, it is assumed that N\n\t\t\t\t\t\tcpb=1 and d\n\t\t\t\t\t\tm,0 =1,for all m. Moreover, p(t) is a modulated square root raised cosine pulse waveform with duration T\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tp\n\t\t\t\t\t\t=2nsec, roll-off factor of 0.5 and truncated to 8 pulse times. The central frequency f\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tc\n\t\t\t\t\t\t is 7.9872 GHz (corresponding to the 9th band of the IEEEE 802.15.4a band plan) and the bandwidth is 499.2 MHz.
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3. Proposed error-controlling scheme for WBAN
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This section explains our proposed error controlling scheme for WBAN. First, proposed scheme and system model description are described. Next, we derive the theoretical performance of our proposed scheme.
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3.1. Error-controlling scheme necessity
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Medical and non-medical applications need to coexist in BANs. In particular, the communication link for medical applications requires higher reliability or QoS in contrast to non-medical applications. Most cases of non-medical applications do not require strong error controlling but less complexity and power consumption, and in the special case of video transmission a large throughput and low latency are needed. On the contrary, medical applications require high reliability and relative low data rate transmission. Hence, strong error controlling is expected while relatively larger complexity is allowed. Consequently, the higher QoS BAN needs, the more complexity and higher power consumption are required.
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3.1.1. Our idea for error-controlling scheme
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As they require different QoS in terms of reliability and performance, a fixed error controlling mechanism like FEC is not appropriate. Thus, in order to reconcile between medical and non-medical applications requirements, we propose an adaptive error controlling mechanism in the form of H-ARQ. Such error system adapts to the channel conditions which can optimize the throughput, latency and reliability according to the application specification and channel conditions.
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As H-ARQ combines FEC and retransmission, the main purpose is to design the FEC such that it corrects the error patterns that appear frequently in the channel. The FEC is maintained with low complexity as much as possible. On the other hand, when error patterns appear less frequently like time-varying behaviour and/or deep fades, a retransmission is requested. Hence, a fine balance between throughput and error correction is achieved, which makes the system much more reliable.
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3.1.2. H-ARQ scheme of our proposed system
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The compliant UWB PHY in cases of medical and non-medical should support a mandatory FEC [1] : (63, 51) BCH codes. Since it is not our research, we refer the draft of IEEE 802.15.6 WBAN standard. In order to harmonize medical a non-medical applications, the first transmission packet should be encoded by (63, 51) BCH code. H-ARQ is only required for high QoS medical applications. Thus, we propose that non-medical devices employ only (63, 51) BCH code and medical devices are H-ARQ enabled.
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As WBAN devices should be as less complex as possible, when the retransmitted packet is received, it would be better to minimize the buffering size of the receiver.
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In general, the two main types of H-ARQ are Chase combining (CC) and incremental redundancy (IR) [6, 7, 8]. With CC schemes, the same encoded packet is sent for transmission and retransmission. On retransmission, the packets are combined based on either the weighted SNR\'s (signal to noise ratio) of individual bits or soft energy values. Thus, the receiver must utilize soft decision, and buffer soft output. Its buffering size is three times higher than without using H-ARQ; i.e., ‘111’represents ‘1’.
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With IR schemes, transmission and retransmission differ. However, if a half-rate code is used in this scheme, the buffering size is same or double than without using H-ARQ. In this scheme, retransmission packets consist only of parity bits. The receiver combines additional parity bits from retransmission, and decodes in an efficient manner. The retransmissions are alternate repetitions of the parity bits and first transmission bits.
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Thus, we employ the notion of IR scheme. At the first transmission of both medical and non-medical, the transmission packets consist only of (63, 51) BCH codewords. For a retransmission, the transmitter encodes the first transmission packets based on a half-rate systematic codes and obtains retransmission packets of parity bits only. Therefore, the buffering size of our proposed scheme is same or double than without using H-ARQ. Additionally, decoding (63, 51) BCH codes and a half-rate systematic codes makes its performance more effective than the basic IR scheme since double coding and decoding.
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This error-controlling scheme is proposed at IEEE 802.15.6 committee by Prof.Kohno in March and May 2009. That standardization makes agreement to oblige employing this scheme for UWB based medical applications.
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3.2. Proposed system description
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As mentioned above, the proposed system is H-ARQ with IR scheme. In such scheme, only parity bits are sent with some retransmissions. Erroneous packets are not discarded and the decoder can employ the previous received packets. The main requirement for the error controlling scheme are low coding overhead and are suitable for bursty (time-varying) channels.
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\n\t\t\t\t\tFigures 2 and 3 show the flowchart and our proposed system model, respectively. Where, û and u’ represent demodulated and decoding bits
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In our proposed system, both of the medical and non-medical applications use the same modulation and demodulation schemes. But only the medical application has a H-ARQ function. Hence, when the lack of the reliability has detected, the medical devices can request a retransmission.
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First transmissions packet (we call data packet) shown in figure 3(a) consists of (n=63, k=51) BCH codewords c0=(m,p0) where
Date packets occur in both case of medical and non-medical and decoding based on (63, 51) BCH codes is processed. If medical receiver detects erroneous bits by computing its syndrome, the packet consists only of half-rate systematic parity bits c1 (we call parity packet) is required by sending NAK. Figure 3(b) shows the parity packet transmission. Upon receiving the second NAK, the transmitter re-sends the data packet or the parity packet alternately. The parity bits c1=(p1)
After receiving the data (or parity) packet or parity packet, previous data (or parity) packet is discarded and combined with previous parity (or data) packet. And the receivers decode based on (63, 51) BCH codes and a half-rate systematic codes. Thus, the data and parity packet are buffered at the receiver.
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The retransmissions continue until the error bits are not detected in information bits m\' or the number of retransmission reaches the limited number.
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Figure 3.
The proposed system model
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3.2.1. Packet construction of our proposed system
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From above mentioned, figure 4 shows packet construction of our proposed system.
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Figure 4.
Packet construction of our proposed system
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The data packets c0=(m, p0) comprise of (n=63, k=51) BCH codewords. And the parity packets c1=(p1) consist of only parity bits of a half-rate systematic (n\n\t\t\t\t\t\t1, k\n\t\t\t\t\t\t1) codewords.
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After receiving the parity packets, the receivers combine the data packets c0 and the parity packets c1 and obtain a half-rate systematic (n\n\t\t\t\t\t\t1, k\n\t\t\t\t\t\t1) codewords.
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First, the receivers decode based on a half-rate systematic (n\n\t\t\t\t\t\t1, k\n\t\t\t\t\t\t1) codes, and then decode based on (n=63, k=51) BCH codes.
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3.3. Derived theoretical performance
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In this section, we derive the theoretical performance of our proposed scheme. For comparison, we also consider the case of ARQ system. In this case, the retransmission is occurred by collision.
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3.3.1. Assumed MAC layer configuration
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\n\t\t\t\t\t\tFigure 5 shows the diagram of transmission protocol.
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The message is divided into the packets and then transmitted. The length of the packet is less the length of the slot. If the number of retransmission is limited, there is a possibility of accepting the erroneous packet. The quality of the message is deteriorated by accepting the erroneous packet. We evaluate this performance after.
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Considering the message of other devices, it is necessary to think about not only PHY but also MAC. Hence, the network coordinator defines the start and end of a superframe by transmitting a periodic beacon. The superframe may consist of both an active and inactive period. The active portion of the superframe is composed of three parts: a beacon, a contention access period (CAP), and a contention free period (CFP). In this research, only CAP or CFP case is assumed. Therefore, we evaluated the proposed scheme in each network algorithm of Slotted ALOHA or Polling.
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Figure 5.
Transmission protocol
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The message transmission delay $D$ is assumed to be a passing number of slots between the message #A arrive at sending node and all $N$ packets that belong to #A are accepted at receiving node. Then we can calculate the throughput efficiencyη.
Thus,when the maximum number of transmission equals M, received bit error rate p\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tARQ\n\t\t\t\t\t\t and the message transmission delay D\n\t\t\t\t\t\tARQ are calculated by these equations.
\n\t\t\t\t\t\tp\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tb1\n\t\t\t\t\t\t, p\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tb2\n\t\t\t\t\t\t,..., p\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tbi\n\t\t\t\t\t\t,... : Channel bit error rate for each number of transmission (i=1,2,...)
\n\t\t\t\t\t
\n\t\t\t\t\t\tp\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tf1\n\t\t\t\t\t\t, p\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tf2\n\t\t\t\t\t\t,..., p\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tfi\n\t\t\t\t\t\t,... : Channel packet error rate for each number of transmission (i=1,2,...)
\n\t\t\t\t\t
\n\t\t\t\t\t\tR\n\t\t\t\t\t\te : Passing number of slots until the following transmission (or retransmission) when erroneous packet is detected.
Thus,when the maximum number of transmission equals M, received bit error rate p\n\t\t\t\t\t\tprop and the message transmission delay D\n\t\t\t\t\t\tprop are described by the equations below.
4. Code selection for proposed error-controlling scheme
\n\t\t\t
First, we explain the description of a mandatory FEC for WBAN. And the bit error rate performance of our proposed scheme in cases of using other codes is showed. Moreover, we derive the effect of FEC of Hybrid ARQ on the bit error rate performance at each number of retransmission.
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Finally, we determine which code employed for proposed scheme. Moreover, since our proposed scheme is employed the IEEE802.15.6 standardization, code selection is important research.
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4.1. Requirements for codes of our proposed H-ARQ scheme
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In order to ensure interoperability, a mandatory mode is required. A compliant FEC for UWB PHY should support systematic (63, 51) BCH code [1].
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From the construction of packet for our proposed system in section 3, candidate codes must have the following features:
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The code is a half-rate and systematic. For decreasing the buffer usage as far as possible, it is desired that the length of candidate codeword is double as long as first transmission codeword.
The information length of the code is 63 or it is a divisor of 63. Since a compliant FEC for UWB PHY should support systematic (63, 51) BCH code.
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If a compliant FEC for UWB PHY is different, requirement of the code is a half-rate and systematic is same.
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4.2. Candidate codes for proposed error-controlling scheme
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The above mentioned are qualified as a candidate FEC for H-ARQ of our proposed system.
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Since it is satisfied the above mentioned requirements for codes of our proposed H-ARQ scheme, we use shortened BCH codes and systematic convolutional codes to make the code rate 1/2. The decoding methods are the bounded distance decoding and the viterbi decoding. For employment viterbi decoding, constraint length must be less of 10 [8].
\n\t\t\t\t
Parameters and its generator polynomial are noted in table 1 and 2.
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Although, (30, 15) BCH code is not satisfied for our proposed H-ARQ scheme, we consider to compare.
Parameters of systematic convolutional code with code rate 1/2.
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4.3. Performance evaluation for code selection
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In this section, the performances of the above-mentioned candidate codes are evaluated for code selection.
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4.3.1. Decoded bit error performance of candidate codes
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The decoded bit error performances of the above-mentioned candidate codes are evaluated by the Monte-Carlo simulations.
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The simulation parameters are summarized in the table 3 [1, 5, 8].
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Channel
\n\t\t\t\t\t\t\t\t
IEEE802.15.6 CM3
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\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
Pulse shape
\n\t\t\t\t\t\t\t\t
Modulated RRC
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\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
Bandwidth
\n\t\t\t\t\t\t\t\t
500MHz
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
Bit rate
\n\t\t\t\t\t\t\t\t
2Mbps
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
Coding
\n\t\t\t\t\t\t\t\t
Data packet : (63,51) BCH codes Parity packet : above-mentioned
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ARQ protocol
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Selective Repeat ARQ
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\n\t\t\t\t\t\t
Table 3.
Simulation Parameters for code selection
\n\t\t\t\t\t
In the case of using the candidate BCH codes, the improvement of the data packet retransmission is larger than the parity packet retransmission. This performance declares the block code is affected by erroneous data bits. On the other hand, using convolutional codes, the improvement of each retransmission is same. It denotes that the encoding and decoding processes are influenced previous bits.
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Figure 6.
SNR (signal to ratio) at BER (bit error rate)=10-3 with each codes
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Figure 7.
SNR (signal to ratio) at BER (bit error rate)=10-6 with each codes
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4.3.2. Decoding complexity of candidate codes
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In bounded distance decoding with euclid algorithm, the decoding complexity is O(t\n\t\t\t\t\t\t2), where t represents error correcting capability and it is calculated by this equation.
The decoding complexity O(t\n\t\t\t\t\t\t\t\t2) of bounded distance decoding
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Meanwhile, the complexity of viterbi decoding increases as O(2\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tK\n\t\t\t\t\t\t), with the constraint length K.
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\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\tK\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\t3\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\t7\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\t9\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\tO(2K)\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\tO(8)\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\tO(128)\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t\t\tO(512)\n\t\t\t\t\t\t\t\t
\n\t\t\t\t\t\t\t
\n\t\t\t\t\t\t
Table 5.
The decoding complexity O(2\n\t\t\t\t\t\t\t\t\n\t\t\t\t\t\t\t\t\tK\n\t\t\t\t\t\t\t\t) of viterbi decoding
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\n\t\t\t\t\t\tTable 5.4 and 5.5 show O(t\n\t\t\t\t\t\t2) and O(2\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tK\n\t\t\t\t\t\t) of the candidate codes, respectively.
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The complexity of (126, 63) BCH code is smaller than K=7 convolutional code. Also, (126, 63) BCH code has good bit error rate performance. Moreover, lower code rate of block codes makes low undetected erroneous bit. It is good for retransmission to determine.
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From these performances, we select (126, 63) BCH code.
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5. Performance evaluation
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In this section, the above-mentioned proposed system considering PHY and MAC is evaluated by the Monte-Carlo simulations. Then, we evaluate the performance of our proposed scheme, and we show that our proposed scheme makes low erroneous frame rate. Moreover, message throughput efficiency becomes more efficient than using FEC only.
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5.1. Simulation parameters and definitions
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The simulation parameters are summarized in the table 6. We refer the standardization of IEEE 802.15.6 [1, 5, 8].
Using Slotted ALOHA algorithm, if the average probability of frame arrival is equal toλ, the probability P(K) that the K frames arrive at the sending node in the interval time τ is
Then, offered traffic G=λτ is fixed; 0.01, 0.5, 1.00 and the probability of occurring collision are calculated [22]. Besides, using Polling algorithm, the number of users U is fixed; 2, 4, and the performance are derived.
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For comparing, we also derive the performance of without using H-ARQ scheme. In this case, the receiver can detect erroneous bits by calculating the syndrome of (63,51) BCH codes. However, an only data packet is retransmitted.
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5.2. Numerical results and theoretical value
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The maximum number of transmissions M is bounded 1~10.
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We show our proposed scheme effectively from evaluating the performances of uncorrected erroneous packet rate and throughput efficiency. And, since the drawback is increasing of buffer usage, also we derive this performance.
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5.2.1. Uncorrected erroneous packet rate
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Erroneous packet is received when the number of transmission is reached the maximum number of transmission M. Figures 7 shows the performances of uncorrected erroneous packet rate of simulation and theoretical results using S-ALOHA algorithm when G=0.01.
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In case of polling algorithm, the performance is not influenced from the number of other users U. We show only the performance of uncorrected erroneous packet rate of simulation and theoretical results using polling algorithm when U =2 at figures 8.
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For deriving the performance by Monte-Carlo simulations, the large number of trials requires a lot of time. Thus, at low value of uncorrected erroneous packet rate cannot be shown these figures.
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Figure 8.
Uncorrected erroneous packet rate using S-ALOHA algorithm (G=0.01)
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Figure 9.
Uncorrected erroneous packet rate using polling algorithm (U=2)
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5.2.2. Buffer usage
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\n\t\t\t\t\t\tFigure 10 shows the average buffering usage [packets] per one message with S-ALOHA and polling algorithms. When the $N$ packets are accepted, they are sent to the user and deleted in buffer.
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To compare without using proposed scheme, figure 11 and 12 show the performance of G=1.0 and U=2 respectively.
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Figure 10.
The average number of buffering packets per one message
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Figure 11.
The average number of buffering packets per one message using S-ALOHA algorithm (G=1.0)
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Figure 12.
The average number of buffering packets per one message using Polling algorithm (U=2)
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5.2.3. Throughput efficiency
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The message throughput efficiency η with S-ALOHA and polling algorithm shows in figures 13 and 14. We want to make the performance more visible, these figures shows at SNR=11.5 and 12.5dB respectively (each marker denotes: ○:S-ALOHA, G=0.01., □:S-ALOHA, G =0.5., ◇:S-ALOHA, G =1., +:polling, U=2., ×:polling, U =4.)
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Figure 13.
Message throughput efficiency using S-ALOHA and polling algorithms at SNR=11.5 dB(medical case)
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Figure 14.
Message throughput efficiency using S-ALOHA and polling algorithms at SNR=12.5 dB(medical case)
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In figure 14, the message throughput efficiency ηof without or using our proposed scheme with S-ALOHA algorithm (G=0.01).
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Figure 15.
Message throughput efficiency using S-ALOHA algorithms (medical case)
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Furthermore, figures 15 and 16 shows the throughput efficiency of medical and non-medical communication cases. For comparing medical and non-medical usage, the throughput efficiency is redefined the following equations.
Medical cases: ε\' denotes received erroneous packet rate.
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Non-medical cases: ε\' denotes received bit error rate.
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In the case of non-medical communications, the receiver does not check the erroneous packet and accepts any packet. On the other hand, in medical cases, the receiver checks. Furthermore, the erroneous packet is discarding.
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Since the performances of first transmission of proposed scheme overlap the unapplied one, the first transmission performance of proposed scheme is not shown in figures 15 and 16.
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Figure 16.
Throughput efficiency of simulation and theoretical results using S-ALOHA algorithm (medical and non-medical)
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Figure 17.
Throughput efficiency of simulation and theoretical results using polling algorithm (medical and non-medical)
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5.3. Performance evaluation
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From figure7, since the collision is a lot of occurred and the same data or parity packet are retransmitted, the improvement by H-ARQ is limited. On the other hand, using polling algorithm, there is no collision. Thus, our proposed scheme performances of each number of transmissions improve as shown figure 8. Both of S-ALOHA and polling algorithm, our proposed schemes achieve up to 2dB of gain from comparing the unapplied proposed scheme. So the proposed scheme provides the high reliability of the medical communications.
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\n\t\t\t\t\tFigure 9 shows the average number of buffering packets per one message. If SNR is low, they are not accepted easily. Therefore the buffering usage increases. However, when a lot of the collision makes the number of the transmission reaches M, the receiver accepts the packet and deletes in buffer. So the buffering usage is decreases. Therefore, at SNR < 9.5-11 dB, as G is larger, the buffer usage is lower. Meanwhile, since N packets are accepted successfully by improvement of receiving both of data and parity packets, a lot of deleted packet is arisen. Hence, the buffering usage decreases.
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For comparing the unapplied proposed scheme, figures 10 and 11 bring out our proposed scheme drawback. When SNR is low, a lot of data and parity packets are transmitted. Therefore, the proposed scheme is less inferior to the unapplied. However, if the channel condition becomes good, packets are accepted successfully by improvement of H-ARQ and a lot of deleted packet is arisen.
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In figures 12 and 13, the performance of our proposed scheme has large efficient at SNR=11.5dB. It shows the effectiveness of H-ARQ on the poor channel conditions. And, the performance of using S-ALOHA algorithm G=0.50 at SNR=11.5dB is larger than using polling U=4 at M> 6. This reason is that the using polling algorithm makes a lot of message delay when the maximum number of retransmission is large. Furthermore, figure 14 shows the adequate number of transmission is determine at each SNR (i.e. at SNR=12.5dB, the adequate number of transmission is 3).
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From figures 15 and 16, the throughput performance of non-medical case exceed medical cases at SNR < 10dB. The reason of performance is receivers of non-medical applications do not check erroneous packets. It makes high bit rate for non-medical communications. Also figures show throughput efficiency of proposed scheme improves at a maximum 40 percent.
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Therefore, the medical communications can satisfy its QoS by using proposed scheme while the bit rate for non-medical communications is not changed. Our proposed scheme achieves to reconcile medical and non-medical applications requirements.
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To summarize, using polling algorithm achieves good performance of received erroneous packet rate and buffering usage. However, it is not same for the throughput efficiency. When there are many other communication devices, the performance using polling algorithm is low efficiency as shown figures 12 and 13. Thus, we are going to propose the system which can decide retransmission by consideration of both PHY and MAC.
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6. Conclusion
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We show using our proposed error-controlling scheme can be achieved robustness for medical applications without ruining efficiency of data rate for non-medical applications in UWB-BAN channels.
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This research work explored H-ARQ techniques for BANs. The signalling scheme was IR-UWB in the high band of UWB with 2PPM and energy detection. The investigated H-ARQs were based on IR scheme combined with two linear codes. We employed (126, 63) BCH codes based H-ARQ to achieve both of high data rate of the non-medical application and low bit error rate of the medical one. This error-controlling scheme is proposed at IEEE 802.15.6 committee and that standardization makes agreement to oblige employing this scheme for UWB based medical applications.
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Simulations results show that good performance in UWB-BAN channels can be achieved. Hence, a robust scheme is possible for the medical applications of BANs. The advantage of this scheme is less complex and consequently less power consumption plus it achieves higher throughput than when only the FEC was used, which are important for BAN applications. Furthermore, from comparing the performance of without our proposed scheme, the proposed schemes obtain up to 2dB of gain at the uncorrected erroneous packet rat and its throughput efficiency improves at a maximum 40 percent while the bit rate for non-medical communications is not changed. Finally, the proposed schemes showed a practical form of coexistence between the medical and the non-medical applications in BANs.
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According to the performance evaluation, it is obvious not only channel condition but also the probability of collision effect the performance. It is considered that if the waiting time for packet transmission exceeds the tolerable quantity or transmission delay $D$ much increases, using more complexity decoding at the receiver makes the number of waiting packet decreases. However, the drawback is the improvement of the error rate cannot exceed when the retransmission is received. In the future, we are going to construct the system which can decide retransmission by consideration of both PHY and MAC.
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\n\t\n',keywords:null,chapterPDFUrl:"https://cdn.intechopen.com/pdfs/16744.pdf",chapterXML:"https://mts.intechopen.com/source/xml/16744.xml",downloadPdfUrl:"/chapter/pdf-download/16744",previewPdfUrl:"/chapter/pdf-preview/16744",totalDownloads:2443,totalViews:124,totalCrossrefCites:0,totalDimensionsCites:0,totalAltmetricsMentions:0,introChapter:null,impactScore:0,impactScorePercentile:26,impactScoreQuartile:2,hasAltmetrics:0,dateSubmitted:"October 21st 2010",dateReviewed:"April 28th 2011",datePrePublished:null,datePublished:"July 27th 2011",dateFinished:null,readingETA:"0",abstract:null,reviewType:"peer-reviewed",bibtexUrl:"/chapter/bibtex/16744",risUrl:"/chapter/ris/16744",book:{id:"439",slug:"ultra-wideband-communications-novel-trends-system-architecture-and-implementation"},signatures:"Ryuji Kohno and Haruka Suzuki",authors:[{id:"28516",title:"Prof.",name:"Ryuji",middleName:null,surname:"Kohno",fullName:"Ryuji Kohno",slug:"ryuji-kohno",email:"kohno@ynu.ac.jp",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institution:{name:"Yokohama National University",institutionURL:null,country:{name:"Japan"}}},{id:"28520",title:"Ms",name:"Haruka",middleName:null,surname:"Suzuki",fullName:"Haruka Suzuki",slug:"haruka-suzuki",email:"jam_011@live.jp",position:null,profilePictureURL:"//cdnintech.com/web/frontend/www/assets/author.svg",institution:null}],sections:[{id:"sec_1",title:"1. Introduction",level:"1"},{id:"sec_2",title:"2. System model and the definition of WBAN",level:"1"},{id:"sec_2_2",title:"2.1. Aim of WBAN",level:"2"},{id:"sec_3_2",title:"2.2. General framework elements",level:"2"},{id:"sec_3_3",title:"2.2.1. Network topology",level:"3"},{id:"sec_4_3",title:"2.2.2. MAC frame formats",level:"3"},{id:"sec_6_2",title:"2.3. UWB PHY description",level:"2"},{id:"sec_6_3",title:"2.3.1. Signal model",level:"3"},{id:"sec_9",title:"3. Proposed error-controlling scheme for WBAN",level:"1"},{id:"sec_9_2",title:"3.1. Error-controlling scheme necessity",level:"2"},{id:"sec_9_3",title:"3.1.1. Our idea for error-controlling scheme",level:"3"},{id:"sec_10_3",title:"3.1.2. H-ARQ scheme of our proposed system",level:"3"},{id:"sec_12_2",title:"3.2. Proposed system description",level:"2"},{id:"sec_12_3",title:"3.2.1. Packet construction of our proposed system",level:"3"},{id:"sec_14_2",title:"3.3. Derived theoretical performance",level:"2"},{id:"sec_14_3",title:"3.3.1. Assumed MAC layer configuration",level:"3"},{id:"sec_15_3",title:"3.3.2. ARQ system",level:"3"},{id:"sec_16_3",title:"3.3.3. Our proposed system",level:"3"},{id:"sec_19",title:"4. Code selection for proposed error-controlling scheme",level:"1"},{id:"sec_19_2",title:"4.1. Requirements for codes of our proposed H-ARQ scheme",level:"2"},{id:"sec_20_2",title:"4.2. Candidate codes for proposed error-controlling scheme",level:"2"},{id:"sec_21_2",title:"4.3. Performance evaluation for code selection",level:"2"},{id:"sec_21_3",title:"Table 3.",level:"3"},{id:"sec_22_3",title:"Table 4.",level:"3"},{id:"sec_25",title:"5. Performance evaluation",level:"1"},{id:"sec_25_2",title:"5.1. Simulation parameters and definitions",level:"2"},{id:"sec_26_2",title:"5.2. Numerical results and theoretical value",level:"2"},{id:"sec_26_3",title:"5.2.1. Uncorrected erroneous packet rate",level:"3"},{id:"sec_27_3",title:"5.2.2. Buffer usage",level:"3"},{id:"sec_28_3",title:"5.2.3. Throughput efficiency",level:"3"},{id:"sec_30_2",title:"5.3. Performance evaluation",level:"2"},{id:"sec_32",title:"6. Conclusion",level:"1"}],chapterReferences:[{id:"B1",body:'\n\t\t\t\t\n\t\t\t\t\tIEEE P802.15 Working Group for Wireless Personal Area Networks(WPANs).TG6 Body Area Networks (BAN) draft standard, IEEE 802Online]\n\t\t\t'},{id:"B2",body:'\n\t\t\t\t\n\t\t\t\t\tW.ASTRIN, Huan-Bang LI, Ryuji KOHNO.Standardization for Body Area Networks, IEEE Transactions on Communications,\n\t\t\t\t\tE92-B\n\t\t\t\t\t2February 2009\n\t\t\t\t\n\t\t\t'},{id:"B3",body:'\n\t\t\t\t\n\t\t\t\t\tIEEE P802.15 Working Group for Wireless Personal Area Networks(WPANs).Channel Model for Body Area Network (BAN), IEEE 802Online]\n\t\t\t'},{id:"B4",body:'\n\t\t\t\t\n\t\t\t\t\tIgor Dotlic, Ryuji Kohno.\n\t\t\t\t\t2009NICT Phy Solution:Part1 Chirp Pulse Based IR UWB Physical Layer, IEEE 802Online]\n\t\t\t'},{id:"B5",body:'\n\t\t\t\t\n\t\t\t\t\tMarco Hernandez, Ryuji Kohno.\n\t\t\t\t\t2009NICT’s Wideband PHY Proposal Part2: MB-IR-UWB, IEEE 802Online]\n\t\t\t'},{id:"B6",body:'S. Lin, P. Yu. A Hybrid ARQ with Parity Retransmission for Error Control of Satellite Channels, IEEE Transactions on Communications, vol.30, No 7, pp.1701-1719, July 1982.'},{id:"B7",body:'\n\t\t\t\t\n\t\t\t\t\tDavid Chase. Code Combining--A Maximum-Likelihood Decoding Approach for Combining an Arbitrary Number of Noisy Packets, IEEE Transactions on Communications, vol.COM-33, 5\n\t\t\t\t\t385\n\t\t\t\t\t393May 1985\n\t\t\t\t\n\t\t\t'},{id:"B8",body:'\n\t\t\t\t\n\t\t\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tLin\n\t\t\t\t\t\t\tS.\n\t\t\t\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tCostello\n\t\t\t\t\t\t\tD. J.\n\t\t\t\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\t\tJr \n\t\t\t\t\t\t\t\n\t\t\t\t\t\t\n\t\t\t\t\t\n\t\t\t\t\t1983ErrorControl Coding: Fundamental and Applications, Prentice-Hall, Englewood Cliffs NJ\n\t\t\t'}],footnotes:[],contributors:[{corresp:"yes",contributorFullName:"Haruka Suzuki",address:"",affiliation:'
Division of Physics, Electrical & Computer EngineeringGraduate School of Engineering, Yokohama National University, Japan
Division of Physics, Electrical & Computer EngineeringGraduate School of Engineering, Yokohama National University, Japan
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1. Introduction
Climate change in the 21st century influences the water resources and food which pattern disease and impact greatly the mankind livelihood. Thus, an efficient mechanism is mandatory to control the emission of hazardous gases. The reduction in carbon emission will also help greatly for the environment, most of the nations are seriously working to mitigate this problem. The utilization of available low Carbon energy resources such as solar and wind will be a milestone to cater to the energy necessities of the globe without harming the environment. After the oil crisis in the year 1973, the alternative sources for energy harvesting are derived by many scientists and still, research is going on [1]. The rising population and higher living standards are influencing climate change significantly. Industrialization, the technologically driven changing landscape of cities have increased the energy demand hugely. The resources of energy are commercial and non-commercial where the commercial resources mainly include fossil fuels like coal or natural gas whereas the non-commercial resources include wood and animal and agriculture wastes as well. Fossil fuel resources are non-renewable, limited in stocks, and creates pollution in the environment, as well as these, are fastly depleting. Therefore, research on the development of new energy resources is extremely needed to cater to the energy demand of the revolutionized world. Renewable energy resources are eco-friendly, abundant, and practically inexhaustible. Sun is one of the renewable resources for green and free energy which provides a tremendous amount of energy without any expenditure. The sun irradiates more energy per hour vis-à-vis the total energy consumed globally during one year. Solar energy is non-depletable, pollution-free, and available in abundance on the surface of Earth planet throughout the year. The Bloomberg New Energy Finance (BNEF) research organization made research on the current scenario of energy consumption and production and concluded that 50 percent of the world’s energy would come from solar cells and wind by the end of 2050 [2]. Therefore, the use of solar energy could increase the economic growth of any country without affecting the environment.
The solar cell is a device that transforms solar or light into electrical energy, it is just a p-n junction or a diode. The Silicon-based solar cells were firstly used to convert sunlight into electricity, therefore, these solar cells are also recognized as traditional or conventional solar cells. The solar cells are classified into three generations. The first generation or crystalline Silicon solar cells are widely used as these have been shown higher power conversion efficiency (ɳ) about 26% [3, 4] and dominated the solar cell market ever since its invention, but fabrication of crystalline Silicon solar cells suffers from high module cost and a significant amount of by-products. The second generation comprises thin-film-based solar cells which reduced materials consumption and consequently cost of the device. This generation includes amorphous silicon solar cells, cadmium telluride (CdTe) thin-film solar cells, and copper indium gallium diselenide (CIGS) thin-film solar cells [5, 6, 7]. The materials to the second generation solar cells are rare elements (e.g. Tellurium) and hazardous (e.g. Cadmium). Due to the high cost of first-generation solar cells, and toxicity, and limited availability of materials for second-generation solar cells, a new generation of solar cells emerges as third generation [8]. The third-generation solar cells comprise a variety of new materials besides the evergreen and champion Silicon which include nanomaterials and Silicon wires. The third-generation solar cells are designed to trim down the cost and are based on the simple, cheap, and easy fabrication process. This generation includes dye-sensitized, polymer, quantum dot, perovskite solar cells. Given cost-effectiveness, efficiency, and easy fabrication process, the dye-sensitized solar cells (DSSC) could be one of the best promising alternatives to the Silicon solar cells [9].
The configuration of dye-sensitized solar cells (DSSCs) comprises a glass substrate (conductive substrate), nanostructure semiconductor (photo-anode), sensitizer (dye), electrolyte, and catalyst counter electrode [10]. Nowadays, the DSSC devices are developed to have such a photo-anode that could efficiently harvest the energy, increase the dye pickup, light scattering ability, reduce recombination reaction and improve charge transferability [11]. The prototype DSSC was reported by Michael Gratzel in 1991. The DSSCs are one of the most efficient photo-to-electron conversion devices under indoor and low-level outdoor lighting for integrating green buildings. For a DSSC device, the highest achieved efficiency is 14.30% (practically) to the date where the Co (II/III) based electrolyte was used with the co-sensitization of organic dyes [12]. The theoretically predicted maximum efficiency for DSSC is 32% which is estimated and limited by the Shockley-Queisser limit based upon the principle of detailed balance [13]. In the architecture of dye-sensitized solar cells, usually, TiO2 (titanium dioxide) is preferred because of its photoactive, low cost, and abundant availability [14]. The most used dye for DSSC is N719 (Cis-Di-(thiocyanato) bis (2,2′-bipyridyl)-4,4′-dicarboxylate) ruthenium (II)) owing to its good light absorber and charge transfer properties vis-à-vis to any other dyes [15]. A volatile electrolyte such as iodide/triiodide is commonly used which has a highly corrosive nature and good reaction with Platinum (Pt) based counter electrode [16, 17]. The photo-anode of DSSC is usually coated employing chemical route-based techniques like doctor blade and spin coating followed by high-temperature heat treatment [18, 19, 20].
DSSC can be useful for portable electronic devices, iPods, and solar lamps that work on the outdoor light source. The outdoor performance of the DSSC device was observed by many scientists in terms of the commercialization of DSSC. But the main factor that affects solar efficiency is a temperature that decreases the long-term stability of the device. To increases the stability of DSSC it was covered by plastic but appropriate results are not obtained. DSSC can easily work in a low-light condition or cloudy condition so these cells are a good option for building integrated photovoltaic cells (BIPV). However, DSSC also exhibits photoresponse/EQE concerning dye and electrolyte. Higher the EQE/IPCE means the photon absorbed by dye molecule is high therefore regeneration of electrolyte takes place and high efficiency of the respected device is observed. This chapter comprises a basic introduction to solar cells viz. principle of solar cells, and description of dye-sensitized solar cells as well the outdoor performance and stability along with photoresponse external quantum efficiency of the solar cell (EQE).
A solar cell directly converts solar energy into electrical energy by a physical process termed as “photovoltaic effect”. The conversion of energy occurs without any intermediate process in certain semiconductor materials. In the photovoltaic effect, a semiconducting material generates charge carriers (electrons in conduction band and corresponding holes in valence band) when it is exposed by light where the light or solar energy and optical energy band gap of the exposed material are the important parameters. In the photoelectric effect, charge carriers are electrons while in the photovoltaic effect, charge carriers are both the electrons and holes. The photovoltaic effect was firstly discovered in 1839 by French Physicist Edmond Becquerel. During experimentation with wet cells, Becquerel noted that the voltage of the cell increased when its silver plates were exposed to the sunlight [21]. The solar cells are composed of different types of semiconductors where p-type and n-type layers are joined together to form a p-n junction (Figure 1). The junction between two types of semiconductors promotes an electrical field which is formed in the region of the junction as electrons move towards the positive p-side and holes towards the negative n-side. This generated field causes negatively charged carriers to move in one direction and positively charged carriers in opposite direction. On connecting it with the load, an electric current is produced in the circuit.
Figure 1.
A systematic presentation of the photovoltaic effect [22].
The sunlight is composed of photons which are the smallest energy bundles of electromagnetic radiation or energy. These photons can be absorbed by the absorber layer of the photovoltaic cell if the photons have energy (hυ) equal or greater than Eg and less than 2 Eg where Eg is the band gap of the layer concerned. When the light of a suitable wavelength is incident on these cells, energy from the photon is transferred to an atom of the semiconducting material in the p-n junction. Specifically, energy is transferred to the electrons in the material. This causes the electrons to jump to a higher energy level which is known as the conduction band. This leaves behind a “hole” in the valance band from which an electron is jumped up. This movement of the electron as a result of added energy creates two charge carriers viz. electrons in the conduction band and holes in the valence band. The asymmetric junction of different natures of semiconducting materials in the solar cell leads to the separation of these charge carriers (electron and holes) and establishes the built-in potential which impels these charge carriers towards the respective electrodes to contribute to electric current in the circuit.
2. Dye-sensitized solar cells
As stated in the introduction part that the energy demand has increased the depletion of fossil fuels, therefore, the development of new skills which are based on renewable energy resources are spurred by world-leading scientists so that the upcoming new generation does not face any crisis related to the energy. Photovoltaic technology is eco-friendly and attractive among all renewable energy technologies. It directly converts sunlight into electrical energy, thus, it is broadly used for harvesting solar energy. The conventional Silicon-based solar cells are quite restricted because of their high cost, hence inexpensive, environmentally friendly, and simple fabrication process-based solar cells such as dye-sensitized solar cells (DSSCs) are used [23]. The dye-sensitized solar cells are comprised of a semiconducting material photo-anode, a counter electrode, an electrolyte, and a sensitizer (dye). DSSC can work in dark and cloudy conditions so it is an excellent candidate for indoor applications. O’Regan and Gratzel developed the first dye-sensitized solar in 1991 by colloidal nanoparticles of TiO2 thin films which had an efficiency of 7.1%. The main aim of the present chapter is to introduce DSSC therefore, it is discussed in detail.
2.1 Device structure and working principle of dye-sensitized solar cell
A typical dye-sensitized solar cell is assembled in a sandwich-type structure. Generally, transparent conductive glass is used as a substrate for the deposition of nanocrystalline thin films of metal oxide. The metal oxide films are sensitized by absorbing dye molecules where dye is covalently attached to the surface of the photo-anode for generating the photoelectrons. An organic electrolyte solution that contains redox couple is used for collecting electrons at the surface of the counter electrode and regenerating dye molecules. A catalyst deposited on a conductive substrate is used as a counter electrode for the development of dye-sensitized solar cells [24]. The schematic representation of the device structure to a typical DSSC is shown in Figure 2.
Figure 2.
Schematic device structure of a typical dye-sensitized solar cell (DSSC).
The absorption of irradiance and charge separation is quite different in the dye-sensitized solar cell as compared to the classical p-n junction solar cell [25]. An electron transfer process of sandwich-type dye-sensitized solar cells is systematically represented in Figure 3. The whole working process of the dye-sensitized solar cell is explained in three steps (1) Photo-excitation, (2) Transportation, and (3) Regeneration.
Figure 3.
A pictorial view of the operational principle of a typical dye-sensitized solar cell [26].
When the sunlight falls on a dye-sensitized solar cell device, then the present dye molecules on the surface of the TiO2 layer (behaves like electron transport layer) absorb the incident photons and consequently excite the electrons. The excited electrons of dye which present above the conduction band of TiO2 are immediately injected into the conduction band of TiO2 and dye molecules get oxidized. At this stage, an electrochemical potential difference is generated between semiconductor oxide and electrolyte, and the electron density of TiO2 also is increased due to charge carrier transfer from dye molecules to metal oxide.
Now, these electrons transfer from metal oxide to counter electrode through the external load where these electrons further transfer to the electrolyte. Herein, reduction of the electrolyte takes place by converting tri-iodide (I3−) into iodide (I−). Regeneration of dye molecules is occurred by receiving electrons from iodide and simultaneous oxidation of iodide to tri-iodide happens. Regeneration of I− is taken place by counter electrode so the whole cycle is regenerated. The flow of electrons through the external circuit generates electrical energy [27, 28, 29].
The chemical reactions that took place in the mechanism are given as below [30, 31, 32, 33]:
2.1.1 The chemical reaction of dye-sensitized solar cell
Dye+hv→Dye∗PhotoexcitationE1
Dye∗+TiO2→Dye++eCB−TiO2ElectroninjectionE2
2Dye++3I−→2Dye+I3−DyeregenerationE3
I3−+2e−catalyst→3I−ElectrolyteregenerationE4
Dye++eCB−TiO2→Dye+TiO2RecombinationE5
I3−+2e−CBTiO2→3I−+TiO2BackreactionE6
Dye∗→DyeE7
2.2 Components of dye-sensitized solar cell
Substrate: Generally, a transparent conductive glass substrate is used for the fabrication of thin-film layers which could be employed as transparent conducting oxide substrates to develop a device. The transparent conducting oxide can be either Fluorine doped Tin oxide (FTO) or Indium doped Tin oxide (ITO) [34]. FTO substrate is usually applied for DSSC owing to good conduction property, stability, durability, and low toxicity. Besides the conductive glass substrates, the plastic materials, metal sheets, Ti foils are also useful substrates for DSSCs and according to the device, architecture may be designed.
Photo-anode: In DSSC, the photo-anode is a wide bandgap semiconducting material e.g. TiO2, ZnO, SnO2, ZrO2, Nb2O5, Al2O3 are used as photo-anode for device development [35, 36, 37, 38, 39, 40, 41]. The main goal of these semiconductor materials is to absorb dye molecules and collection of the photo-excited electrons. Photo-anode materials should have a high surface area so absorption of dye molecules could be increased which eventually enhanced the power conversion efficiency of the solar cell device concerned. The crystallite size, porosity, microstructure, etc. play an important role to develop an efficient device for maximum harvesting of the incident irradiance. Typically, the DSSC photo-anode is prepared by conventional technique i.e. doctor blade but nowadays, many techniques are available which could be applied as per need and device architecture [42, 43, 44, 45, 46]. Doping of semiconductor material with suitable cation or anion also alters its optical energy bandgap, and post-deposition treatments like annealing affect the electrical, structural, and other relevant properties [47, 48, 49].
Counter electrode: The counter electrode (cathode) plays an important role in the regeneration of electrolytes by transporting electrons to the electrolyte which arrived externally from the circuit. Thus, the counter electrode should have good conductivity and catalytic activity. Platinum (Pt) is normally preferred to choose as a counter electrode for dye-sensitized solar cells [50]. The high cost and corrosion of Platinum limit its use and therefore, alternative options could be undertaken for counter electrodes. Carbon and conducting polymers (PEDOT) are also suitable materials due to their low cost, abundance, and adequate conductivity but their catalytic activity is lower as compared to the Platinum [51, 52]. Besides these, NiS/rGO, polypyrrole (PPy), Co0.5Ni0.5Se/GN, and WO2 are utilized as counter electrodes for dye-sensitized solar cells [53, 54, 55, 56].
Electrolyte: The function of electrolyte is to regenerate dye molecules and to work as conducting medium. Electrolyte plays important role in achieving higher efficiency of a solar cell. Based on the physical state, the electrolytes are classified into three main categories as a liquid electrolyte, quasi-solid electrolyte, and solid electrolyte [57]. As a liquid, triiodide/iodide (I3−/I−) is mostly used as a redox couple because of the fast regeneration of the dye and slow recombination process in the dye-sensitized solar cell. Other electrolytes are also available like Br−/Br3−, SeCN−/(SeCN)2, SCN−/(SCN)2, Co (II)/(III), Cu (I/II) etc. [58, 59, 60]. To overcome the problem of volatilization and leakage of liquid electrolytes, the quasi-solid and solid electrolytes are explored. Quasi solid electrolytes are organic liquid polymers that are converted into gel form by chemical and physical reactions that have cohesive nature and diffusive transport properties [61]. As solid electrolytes, mainly hole-transporting materials (HTM) are used viz. spiro-OMeTAD, CuSCN, CuI, P3HT, PEDOT, CsSnI3 which can overcome the issue of leakage, corrosion, and salvation for DSSCs [62]. In HTM or semiconductors, charge transportation takes place via electrons or holes while in electrolytes, it takes place through ions.
Sensitizer: Dyes play the important role of photo-sensitizer in DSSCs where a self-assembled layer of dye is anchored on the surface of the photo-anode. When sunlight strikes on dye molecules then these dye molecules absorb photons and consequently, the photoexcitation of electrons occurs which injects electrons into the conduction band of the photo-anode. Based on the composition used in dye, it is classified into three main categories viz. metal complex, metal-free organic complex, and natural sensitizer [63]. Ruthenium-based sensitizers are remarkable for achieving higher efficiency in dye-sensitized solar cells [64, 65].
3. Outdoor performance and stability of dye-sensitized solar cell
In outdoor conditions the main factor that affects efficiency is temperature. In this section different solar radiation illumination was discussed. The stability of dye-sensitized solar cell is mainly influenced by electrolyte, liquid electrolyte exhibit higher efficiency but the volatile nature of liquid electrolyte degrades solar cell and therefore stability of the cell reduces.
Yuan et al. [66] tested outdoor application of DSSC for Building Integrated Photovoltaics (BIPV) application where a time duration of four years was taken into consideration. Here dye Z991 and Z907 were used for cell fabrication where the first one harnesses 15% more electricity over the later one for two years. Given the stability of the device, the efficiency of dye Z991 based solar cell decreases to 17% for the initial two years thereafter efficiency remains stable for the remaining two years. Moreover, the Z907 based DSSC device is out of the use or degrade after four years in outdoor application. The stability of Z991 over Z907 is due to the presence of thiophene moieties in Z991 i.e. responsible for better energy harvesting and thermal stability. When the solar irradiance increase there is no linearly incremented in electricity generation for irradiance of lower than 20 Wh.
Kato et al. [67] synthesized dye-sensitized solar cells with N719 dye, TiO2, and carbon counter electrode and tested durability test in the outdoor working condition for a time duration of 2.5 years. The DSSC modules were developed monolithically series interconnected on the TCO substrate and covered by a waterproof cover. Before the exposure to sunlight, the device reveals 0.32 and 0.71 suns from the current–voltage curve and power-voltage curve. During the stability test voltage was approximately kept around 1.6 V. The solar parameters such as JSC fall for 5 months thereafter it remains constant for left years and efficiency decreases/degrades subsequently decrement in VOC and FF. Additionally, EIS reveals exposure of cell in outdoor increases the Nernst impedance of triiodide and Raman spectra also reveals increment in luminescent ingredients of electrolyte, therefore, VOC and FF decreases in outdoor condition. Berginc et al. [68] outdoor exposed ionic liquid-based dye-sensitized solar cell for 7 months in solar radiation of 906kWh/m2. In the summers maximum VOC is obtained in the early morning and on an autumn day when days are shorter and temperature is lower that time JSC of cell increases. Park et al. [69] observed the change in film thickness effects J-V curve (Figure 4) of TiO2 based solar cell under 1 sunlight intensity. On increasing the thickness, the JSC of the cell increases from 6.6 to 10.7 mA/cm2 i.e. about 62% whereas the fall down in VOC is 759 to 727 mV due to increases in surface area that accounts for more dye molecule absorbing.
Figure 4.
The effect of film thickness on the J-V curve of DSSC. Reprinted with permission from ref. [69] copyright (2000) American Chemical Society.
Asghar et al. [70] developed dye-sensitized solar cell and tested in outdoor condition as well comparison with silicon cell was carried out. Here the lower irradiance and higher temperature are suitable for DSSC, at these parameter DSSC harvest more energy instead of silicon solar cell. The efficiency of DSSC decreases as time duration increases. Moreover, the device that was fabricated by employing MPN as an electrolyte degrades fast whereas ionic liquid-based devices are more stable and constant efficiency was observed for two months then degradation initiates. The thermal influence of dye-sensitized solar cells was studied by Matsui et al. [71] where the current collecting study was done. When the temperature was maintained at around 85° C leakage of ionic liquid does not occur but the long-term stability of the device is strongly affected by moisture. Therefore double-sealed package for the device was invented and a test on substrate size of 50 mm × 50 mm was used where 85° C temperature was maintained for 1000 hours and stability was observed. Bella et al. [72] designed fluoropolymer and rare elements-free light shifting coating systems for dye-sensitized solar cell devices. The introduction of fluorescent species in DSSC downshifts UV photons into visible light that significantly improves PV efficiency by 60%. The improvement in efficiency is accountable for improvement in photon flux i.e. caused by the introduction of luminescent agent that results from nanometric light shifting in organic dyes. Now the outdoor long-term stability was measured for 3 months where the introduction of a light shifting agent preserves the power conversion efficiency of the solar cell.
Freitag et al. [74] demonstrated dye-sensitized solar cells with dye D35 and XY1 were copper-based redox electrolyte is used. At the AM of 1.5 G, the observed PCE is 11.3% and under 1000 lux indoor condition it achieves 28.9%. The obtained results point out DSSC are suitable for ambient light condition. Mehmood et al. [75] constructed DSSC with an organic photosensitizer. The PCE of the cell was 2.58% at 25°C in air mass of 1.5 G and illumination of 100 mW/cm2. The increment in temperature falls down the efficiency of this solar cell it is stable up to 35°C. Wu et al. [73] demonstrated dye-sensitized solar cells with an area of 100 cm2 and lightweight based on Ti substrates. Here PEDOT counter electrode is used which is having good transparency and electrocatalytic activity. The J-V curve (Figure 5) reveals the current density (ISC) of PEDOT-Pt/Ti is higher. The photoconversion efficiency was achieved about 6.69% and in an outdoor condition of solar radiation of 55 mW cm−2 0.368 W power output was observed.
Figure 5.
The J-V curve for DSSC with the different counter electrodes. Reprinted with permission from ref. [73] copyright (2012) John Wiley and Sons.
Generally, dye-sensitized solar cell photoresponse for a given incident wavelength of light and the result is depicted in form of varying wavelength and percentage of IPCE. When the current is generated through the response of photon that time characteristics peak appears at a particular wavelength. It is the ratio of generated electrons to the incident photons. Moreover, IPCE depends upon the yield of electron transfer and light-harvesting efficiency that causes quantum charge injection and electron quantum efficiency in the present external circuit of the device. In the case of DSSC, the measurement of IPCE clears that dye is well linked to photoanode and electrolyte. When incident photons are exposed on DSSC that time dye uptake electrons from photoanode and create electron–hole pair and holes are transmitted to the electrolyte.
The generation of photocurrent i.e. dependent on wavelength is known as external quantum efficiency (EQE) where AC and DC mode is used for the generation of the beam. In the case of DC mode irradiation of monochromatic beam on a sample is continuously carried out for 3 sec so electrons reach to steady-state. In AC mode monochromatic light is chopped by shutter and illumination of bias light on a sample is carried out. Jeong et al. [76] measured EQE of DSSC and tandem cell (DSSC/CIGS) in DC mode. The EQE spectra reveal in the wavelength range of 300–800 nm EQE of DSSC was observed and for tandem cells, EQE spectra are almost similar to DSSC. When Berginc et al. [68] DSSC was exposed to outdoor conditions for seven months, the EQE of the solar cell was measured. The peak at 360 nm is accountable for absorption in the TiO2 layer, 380 nm for change in I3- and at 450 nm for dye molecules degradation.
Kubo et al. [77] developed a tandem structure-based solar cell that improves the photocurrent of dye-sensitized solar cells. The IPCE of tandem solar cells is relatively outstanding to single cells. Tandem solar cell has elevated solar response (good external quantum efficiency), photocurrent and conversion efficiency from single-cell as well lower VOC and higher FF was also observed. Park et al. [69] prepared homogeneous, crack-free, and rod-shaped rutile TiO2 thin films with having a thickness of 12 μm. The measurement of IPCE (incident photon-to-current efficiency) till 600 nm wavelength indicated that a significant amount of light was absorbed very fast in few microns but at higher wavelength, the increment in IPCE was directly proportional to the film thickness see Figure 6. Rutile and anatase films were compared having similar thickness where photocurrent of rutile based solar cell was 30% lower vis-a-vis to the anatase phase owing to the less amount of absorbed dye, small surface area, and transportation of electrons was also slow for rutile thin film-based solar cells. Lepikko et al. [78] tested outdoor performance of DSSC for 1000 h in 1 sun. The efficiency and fill factor of cell rise in outdoor condition i.e. just double of indoor condition well-remaining of solar irradiance. The IPCE decreases about 30% during testing of the cell this is due to photodegradation of electrolyte see Figure 7.
Figure 6.
The effect of a film thickness of TiO2 on IPCE value of a solar cell. Reprinted with permission from ref. [69] copyright (2000) American Chemical Society.
Figure 7.
The IPCE curve of DSSC in harsh northern outdoor conditions. Reprinted with permission from ref. [78] copyright (2018) John Wiley and Sons.
Roy et al. [79] studied the annealing of TiO2 nanotubes at 450°C for 30 minutes where the amorphous phase was converted into anatase. Post annealing and the TiCl4 treatments were carried in a closed vessel at 70°C for 30 min. SEM image of TiO2 nanotubes treated with TiCl4 confirmed uniform decoration with TiO2 nanoparticles and IPCE of the decorated samples was found 66% with a conversion efficiency of 3.8%. The ultrathin nanosheets of SnO2 were introduced as photo-anode in dye-sensitized solar cells for improvement in photoconversion efficiency by Xing et al. [80] The nanosheets were developed by hydrothermal method and screen printed over FTO substrates, then a coating of TiO2 on SnO2 was performed to solve the problem of lower open-circuit voltage. The diffraction peak in XRD patterns revealed to the tetragonal rutile like SnO2 and FESEM images displayed a 3D flowerlike structure. HRTEM images of nanosheets showed lattice fringes over the entire surface. The efficiency of the devices using SnO2 NSs-TiO2 was 1.79% and IPCE was 35% which was much higher vis-a-vis the devices made up of SnO2 nanoparticles i.e. revealed by Figure 8.
Figure 8.
IPCE curve of DSSC with different photoelectrode. Reprinted with permission from ref. [80] copyright (2012) American Chemical Society.
Kumara et al. [81] employed natural dyes obtained from Ixora sp. (IX) and Canarium odontophyllum (CMB) which mainly contained anthocyanin that was used to improve the performance of DSSCs. The layered co-sensitization of dyes was carried out by firstly immersing TiO2 electrode in CMB extract followed by de-adsorption and then again immersed in second sensitizer IX for adsorption. The absorption spectrum of the co-sensitized electrode was increased as compared to the individual and mixture sensitized and similar results were obtained in IPCE measurement. The photovoltaic properties of the co-sensitized electrode were obtained under irradiance of 1000 W/m2 with a short circuit current density of 9.80 mA/cm2, VOC of 343 mV, fill factor of 0.46, and photoconversion efficiency of 1.55%. Gupta et al. [82] developed Cu/S co-doped TiO2 as a photoanode for dye-sensitized solar cells. Here undoped TiO2 exhibits about 70.02% of IPCE whereas it increases further on codoping with Cu/S. 0.1% Cu/S exhibits 73.65% of IPCE and on increment, the 0.3% Cu/S exhibits 82.98% of IPCE at a wavelength of 530 nm. The improvement in IPCE is accountable due to the small size of particles and enhancement in short circuit current density (JSC).
Patni et al. [83] fabricated dye-sensitized solar cells with natural dyes. The natural dyes were used are anthocyanin, betalain, and chlorophyll obtained from the extracts of Roselle spinach beetroot respectively. At the wavelength of 430 nm 6.21% IPCE was observed for anthocyanin dye and at 530 nm 9.9% of IPCE was measured for betalain and 6.1% IPCE was observed for chlorophyll-based dye at a wavelength of 660 nm. The blending or mixing of dye improves the IPCE. Wood et al. [84] reported the IPCE for different dye i.e. The cationic 1-hexyl-2,3,3-3H indolium acceptor dye (CAD3) dye exhibit IPCE of 50% and bodipy dye, it is 53% and for P1 54% was observed where the p-type dye-sensitized solar cell was fabricated. This chapter comprised literature on the solar response of DSSC on exposure of induced photons. Different dyes exhibit a variation in photon-to-current conversion efficiency. The higher the IPCE means the efficiency of the cell is a good and better amount of energy can be harvested by solar cell.
5. Conclusion
The dye-sensitized solar cell technology has an impact on the PV market owing to easy fabrication, cost, chemical stability, availability of chemicals, and good power conversion efficiency. In this chapter, we discussed the introduction of solar cells with working principles, complete elaboration of dye-sensitized solar cells, and outdoor performance and stability in different solar irradiations. Outdoor performance is affected by the temperature because on exposure to sunlight the temperature raise degrades the electrolyte and therefore stability and performance of the device decreases. Moreover, on rainy days the chances of degradation are increasing due to water or moisture, therefore, coating/layer of a suitable material is carried out over the solar cell this also increases the long-term stability of the device. The IPCE of solar cells initially is higher but with time duration it falls due to cell degradation or leaking and for a long time it stabilizes without so many changes. This chapter emphasizes the efficiency of DSSC when it exposes the outdoor and solar response of DSSC.
Acknowledgments
The authors thank Mohanlal Sukhadia University, Udaipur. Reema Agarwal greatly acknowledges CSIR, New Delhi for financial support through Senior Research Fellowship (File No.: 09/172(0090)/2019-EMR-I).
Conflict of interest
The authors declare no conflict of interest.
\n',keywords:"DSSC, Solar energy, Outdoor, Stability, IPCE",chapterPDFUrl:"https://cdn.intechopen.com/pdfs/77273.pdf",chapterXML:"https://mts.intechopen.com/source/xml/77273.xml",downloadPdfUrl:"/chapter/pdf-download/77273",previewPdfUrl:"/chapter/pdf-preview/77273",totalDownloads:159,totalViews:0,totalCrossrefCites:0,dateSubmitted:"January 15th 2021",dateReviewed:"May 28th 2021",datePrePublished:"December 21st 2021",datePublished:null,dateFinished:"June 23rd 2021",readingETA:"0",abstract:"In this era the requirement for energy is enhancing, therefore, many energy resources are developed among them the emerging third-generation dye-sensitized solar cell is one of the environment-friendly solar cell-based technology. Generally, dye-sensitized solar cells consist of a nanomaterial-based photoanode, dye molecules as an absorber, electrolyte, and counter electrode. In the case of indoor application, this solar cell works easily so this is the characteristics of a dye-sensitized solar cell. Moreover, the outdoor performance of DSSC degrades on exposure to sunlight. Exposure to sunlight increases the temperature of the internal component of DSSC and consequently degradation in device performance. Long-term stability is obtained by the choice of such material where degradation takes place slowly and plastic covers are also coated over DSSC to prevent degradation. The solar response of DSSC towards dye was also mentioned, the higher the percentage of EQE higher the efficiency of the device. In this chapter, the authors discuss the introduction of a solar cell, the working principle of DSSC, and the available research background for outdoor performance and long-term stability with a solar response of device i.e. EQE or IPCE.",reviewType:"peer-reviewed",bibtexUrl:"/chapter/bibtex/77273",risUrl:"/chapter/ris/77273",signatures:"Reema Agarwal, Yogeshwari Vyas, Priyanka Chundawat, Dharmendra and Chetna Ameta",book:{id:"9862",type:"book",title:"Solar Radiation - Measurements, Modeling and Forecasting for Photovoltaic Solar Energy Applications",subtitle:null,fullTitle:"Solar Radiation - Measurements, Modeling and Forecasting for Photovoltaic Solar Energy Applications",slug:null,publishedDate:null,bookSignature:"Dr. Mohammadreza Aghaei",coverURL:"https://cdn.intechopen.com/books/images_new/9862.jpg",licenceType:"CC BY 3.0",editedByType:null,isbn:"978-1-83968-859-1",printIsbn:"978-1-83968-858-4",pdfIsbn:"978-1-83968-860-7",isAvailableForWebshopOrdering:!0,editors:[{id:"317230",title:"Dr.",name:"Mohammadreza",middleName:null,surname:"Aghaei",slug:"mohammadreza-aghaei",fullName:"Mohammadreza Aghaei"}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"}},authors:null,sections:[{id:"sec_1",title:"1. Introduction",level:"1"},{id:"sec_2",title:"2. Dye-sensitized solar cells",level:"1"},{id:"sec_2_2",title:"2.1 Device structure and working principle of dye-sensitized solar cell",level:"2"},{id:"sec_2_3",title:"2.1.1 The chemical reaction of dye-sensitized solar cell",level:"3"},{id:"sec_4_2",title:"2.2 Components of dye-sensitized solar cell",level:"2"},{id:"sec_6",title:"3. Outdoor performance and stability of dye-sensitized solar cell",level:"1"},{id:"sec_7",title:"4. Spectral response/external quantum efficiency (EQE) response/incident photon-to-current conversion efficiency (IPCE)",level:"1"},{id:"sec_8",title:"5. Conclusion",level:"1"},{id:"sec_9",title:"Acknowledgments",level:"1"},{id:"sec_12",title:"Conflict of interest",level:"1"}],chapterReferences:[{id:"B1",body:'Painter DS. Oil and geopolitics: The oil crises of the 1970s and the cold war. Historical Social Research. 2014;39:186-208. 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DOI: 10.1016/j.matlet.2014.03.041'},{id:"B51",body:'Wang W, Liu Y, Zhong YJ, Wang L, Zhou W, Wang S, Tadé MO, Shao Z. Mint: Rational design of LaNiO3/Carbon composites as outstanding platinum-free photocathodes in dye-sensitized solar cells with enhanced catalysis for the triiodide reduction reaction. Solar RRL. 2017;1:1700074. DOI: 10.1002/solr.201700074'},{id:"B52",body:'Sudhagar P, Nagarajan S, Lee Y-G, Song D, Son T, Cho W, Heo M, Lee K, Won J, Kang YS. Mint: Synergistic catalytic effect of a composite (CoS/PEDOT:PSS) counter electrode on triiodide reduction in dye-sensitized solar cells. ACS Applied Materials & Interfaces. 2011;3:1838-1843. DOI: 10.1021/am2003735'},{id:"B53",body:'Sarkar A, Chakraborty AK, Bera S. Mint: NiS/rGO nanohybrid: An excellent counter electrode for dye sensitized solar cell. Solar Energy Materials and Solar Cells. 2018;182:314-320. DOI: 10.1016/j.solmat.2018.03.026'},{id:"B54",body:'Bu C, Tai Q, Liu Y, Guo S, Zhao X. Mint: A transparent and stable polypyrrole counter electrode for dye-sensitized solar cell. Journal of Power Sources. 2013;221:78-83. DOI: 10.1016/j.jpowsour.2012.07.117'},{id:"B55",body:'Murugadoss V, Panneerselvam P, Yan C, Guo Z, Angaiah S. Mint: A simple one-step hydrothermal synthesis of cobalt-nickel selenide/graphene nanohybrid as an advanced platinum free counter electrode for dye sensitized solar cell. Electrochimica Acta. 2019;312:157-167. DOI: 10.1016/j.electacta.2019.04.142'},{id:"B56",body:'Wu M, Lin X, Hagfeldt A Ma T. Mint: A novel catalyst of WO2 nanorod for the counter electrode of dye-sensitized solar cells. Chemical Communications. 2011;47:4535-4537. DOI: 10.1039/C1CC10638D'},{id:"B57",body:'Wu J, Lan Z, Lin J, Huang M, Huang Y, Fan L, Luo G. Mint: Electrolytes in dye-sensitized solar cells. Chemical Reviews. 2015;115:2136-2173. DOI: 10.1021/cr400675m'},{id:"B58",body:'Kakiage K, Tokutome T, Iwamoto S, Kyomen T Hanaya M. Mint: Fabrication of a dye-sensitized solar cell containing a Mg-doped TiO2 electrode and a Br3−/Br− redox mediator with a high open-circuit photovoltage of 1.21 V. Chemical Communications. 2013;49:179-180. DOI: 10.1039/C2CC36873K'},{id:"B59",body:'Powar S, Daeneke T, Ma MT, Fu D, Duffy NW, Götz G, Weidelener M, Mishra A, Bäuerle P, Spiccia L, Bach U. Mint: Highly efficient p-type dye-sensitized solar cells based on Tris (1,2-diaminoethane) Cobalt (II)/(III) electrolytes. Angewandte Chemie. 2012;52:602-605. DOI: 10.1002/anie.201206219'},{id:"B60",body:'Freitag M, Giordano F, Yang W, Pazoki M, Hao Y, Zietz B, Grätzel M, Hagfeldt A, Boschloo G. Mint: Copper phenanthroline as a fast and high-performance redox mediator for dye-sensitized solar cells. The Journal of Physical Chemistry C. 2016;120:9595-9603. DOI: 10.1021/acs.jpcc.6b01658'},{id:"B61",body:'Vinoth S, Kanimozhi G, Narsimulu D, Kumar H, Srinadhu ES, Satyanarayana N. 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DOI: 10.1016/j.ccr.2017.12.012'},{id:"B65",body:'Hug H, Bader M, Mair P, Glatzel T. Mint: Biophotovoltaics: Natural pigments in dye-sensitized solar cells. Applied Energy. 2014;115:216-225. DOI: 10.1016/j.apenergy.2013.10.055'},{id:"B66",body:'Yuan H, Wang W, Xu D, Xu Q, Xie J, Chen X, Zhang T, Xiong C, He Y, Zhang Y, Liu Y, Shen H. Mint: Outdoor testing and ageing of dye-sensitized solar cells for building integrated photovoltaics. Solar Energy 2018;165:233-239. DOI: https://doi.org/10.1016/j.solener.2018.03.017'},{id:"B67",body:'Kato N, Takeda Y, Higuchi K, Takeichi A, Sudo E, Tanaka H, Motohiroa T, Sano T, Toyoda T. Mint: Degradation analysis of dye-sensitized solar cell module after long-term stability test under outdoor working condition. Solar Energy Materials & Solar Cells 2009;93:893-897. DOI: https://doi.org/10.1016/j.solmat.2008.10.022'},{id:"B68",body:'Berginc M, Krašovec UO, Topič M. Mint: Outdoor ageing of the dye-sensitized solar cell under different operation regimes. Solar Energy Materials & Solar Cells 2014;120:491-499. DOI: http://dx.doi.org/10.1016/j.solmat.2013.09.029'},{id:"B69",body:'Park N-G, Lagemaat J, Frank AJ. Mint: Comparison of dye-sensitized rutile- and anatase-based TiO2 solar cells. Journal of Physical Chemistry B 2000;104:8989-8994. DOI: https://doi.org/10.1021/jp994365l'},{id:"B70",body:'Asghar A, Emziane M, Pak HK, Oh SY. Mint: Outdoor testing and degradation of dye-sensitized solar cells in Abu Dhabi. Solar Energy Materials & Solar Cells 2014;128:335-342. DOI: http://dx.doi.org/10.1016/j.solmat.2014.05.048'},{id:"B71",body:'Matsui H, Okada K, Kitamura T, Tanabe N. Mint: Thermal stability of dye-sensitized solar cells with current collecting grid. Solar Energy Materials & Solar Cells 2009;93:1110-1115. DOI: 10.1016/j.solmat.2009.01.008'},{id:"B72",body:'Bella F, Griffini G, Gerosa M, Turri S, Bongiovanni R. Mint: Performance and stability improvements for dye-sensitized solar cells in the presence of luminescent coatings. Journal of Power Sources 2015;283:195-203. DOI: http://dx.doi.org/10.1016/j.jpowsour.2015.02.105'},{id:"B73",body:'Wu J, Xiao Y, Tang Q, Yue G, Lin J, Huang M, Huang Y, Fan L, Lan Z, Yin S, Sato T. Mint: A large-area light-weight dye-sensitized solar cell based on all titanium substrates with an efficiency of 6.69% outdoors. Advanced Materials 2012;24:1884-1888. DOI: 10.1002/adma.201200003'},{id:"B74",body:'Freitag M, Teuscher J, Saygili Y, Zhang X, Giordano F, Liska P, Hua J, Zakeeruddin SM, Moser JE, Grätzel M, Hagfeldt A. Mint: Dye-sensitized solar cells for efficient power generation under ambient lighting. Nature Photonics 2017;11:372-378. DOI: 10.1038/NPHOTON.2017.60'},{id:"B75",body:'Mehmood U, Malik MI, Khan AU, Hussein IA, Harrabi K, Al-Ahmed A. Mint: Effect of outdoor temperature on the power-conversion efficiency of newly synthesized organic photosensitizer based dye-sensitized solar cells. Materials Letters 2018;220:222-225. 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This chapter focuses on the design and implementation process of a low-cost real-time flight simulator for the training of armed force pilots using mathematical models of flight physics. To address such concern, the mathematical models of a Cessna type aircraft have been developed. This has been followed by a flight simulator, which operated with a new construction using a Stewart scale platform and operated by a joystick. Specifically, the simulator has been developed using an approximation of a physical cyber-system and a mechatronic design methodology that consists of mechanical, electrical and electronic elements that control the Stewart platform with three degrees of freedom. Based on software engineering, the algorithms of mathematical and physical models have been developed. These have been used to create an interactive flight simulator of an aircraft based on the Unity 3D game engine platform. The performance of the algorithms has been evaluated, using threads and processes to handle the communication and data transmission of the flight simulator to the Stewart platform. The evaluation of the developed simulator has been validated with professional pilots drilled with the Microsoft Flight Simulator. The results demonstrated that this flight simulator stimulates the development of skills and abilities for the maneuver and control of an aircraft.",book:{id:"8588",slug:"military-engineering",title:"Military Engineering",fullTitle:"Military Engineering"},signatures:"César Villacís, Walter Fuertes, Luis Escobar, Fabián Romero and Santiago Chamorro",authors:null}],mostDownloadedChaptersLast30Days:[{id:"67881",title:"Military Aviation Principles",slug:"military-aviation-principles",totalDownloads:1368,totalCrossrefCites:1,totalDimensionsCites:1,abstract:"Military all over the world uses military aircraft in both offensive and defensive purposes. In offensive role, these aircraft are used in destroying enemy’s vital installations, air strips, ordnance depots and supplies. In defensive role, it provides close air support to land-based army and also deters the threats of enemy air strike. In naval warfare, military aircraft plays a significant role to detect and neutralize submarines and warships to keep the seacoast free from enemy attack. Military aircraft also provides logistic supply to forward bases, conducting airlift (cargo and troops), and participates in rescue operations during national disaster. Military aviation includes both transport and warcraft and consisting of fixed wing aircraft, rotary-wing aircraft (RWA) and unmanned aerial vehicle (UAV). From the early days of world war, it has been realized that air power supremacy is vital for winning a war as well as maintaining the sovereignty of any country. This chapter discusses basic flight mechanics, types and roles of aircraft, safety considerations and design and certification procedures.",book:{id:"8588",slug:"military-engineering",title:"Military Engineering",fullTitle:"Military Engineering"},signatures:"Kanchan Biswas",authors:null},{id:"67505",title:"A New Real-Time Flight Simulator for Military Training Using Mechatronics and Cyber-Physical System Methods",slug:"a-new-real-time-flight-simulator-for-military-training-using-mechatronics-and-cyber-physical-system-",totalDownloads:1228,totalCrossrefCites:3,totalDimensionsCites:3,abstract:"So far, the aeronautical industry has developed flight simulators and space disorientation with high costs. This chapter focuses on the design and implementation process of a low-cost real-time flight simulator for the training of armed force pilots using mathematical models of flight physics. To address such concern, the mathematical models of a Cessna type aircraft have been developed. This has been followed by a flight simulator, which operated with a new construction using a Stewart scale platform and operated by a joystick. Specifically, the simulator has been developed using an approximation of a physical cyber-system and a mechatronic design methodology that consists of mechanical, electrical and electronic elements that control the Stewart platform with three degrees of freedom. Based on software engineering, the algorithms of mathematical and physical models have been developed. These have been used to create an interactive flight simulator of an aircraft based on the Unity 3D game engine platform. The performance of the algorithms has been evaluated, using threads and processes to handle the communication and data transmission of the flight simulator to the Stewart platform. The evaluation of the developed simulator has been validated with professional pilots drilled with the Microsoft Flight Simulator. The results demonstrated that this flight simulator stimulates the development of skills and abilities for the maneuver and control of an aircraft.",book:{id:"8588",slug:"military-engineering",title:"Military Engineering",fullTitle:"Military Engineering"},signatures:"César Villacís, Walter Fuertes, Luis Escobar, Fabián Romero and Santiago Chamorro",authors:null},{id:"55272",title:"Ground‐Penetrating Radar for Close‐in Mine Detection",slug:"ground-penetrating-radar-for-close-in-mine-detection",totalDownloads:2897,totalCrossrefCites:3,totalDimensionsCites:5,abstract:"In this chapter, two of the major challenges in the application of ground‐penetrating radar in humanitarian demining operations are addressed: (i) development and testing of affordable and practical ground penetrating radar (GPR)‐based systems, which can be used off‐ground and (ii) development of robust signal processing techniques for landmines detection and identification. Different approaches developed at the Royal Military Academy in order to demonstrate the possibility of enhancing close‐range landmine detection and identification using ground‐penetrating radar under laboratory and outdoor conditions are summarized here. Data acquired using different affordable and practical GPR‐based systems are used to validate a number of promising developments in signal processing techniques for target detection and identification. The proposed approaches have been validated with success in laboratory and outdoor conditions and for different scenarios, including antipersonnel, low‐metal content landmines, improvised explosive devices and real mine‐affected soils.",book:{id:"4818",slug:"mine-action-the-research-experience-of-the-royal-military-academy-of-belgium",title:"Mine Action",fullTitle:"Mine Action - The Research Experience of the Royal Military Academy of Belgium"},signatures:"Olga Lucia Lopera Tellez and Bart Scheers",authors:[{id:"176830",title:"Dr.",name:"Olga",middleName:"Lucia",surname:"Lopera Tellez",slug:"olga-lopera-tellez",fullName:"Olga Lopera Tellez"}]},{id:"67714",title:"Scientific Knowledge of Spanish Military Engineers in the Seventeenth Century",slug:"scientific-knowledge-of-spanish-military-engineers-in-the-seventeenth-century",totalDownloads:915,totalCrossrefCites:0,totalDimensionsCites:0,abstract:"The catenary arches were used in Spanish Art Nouveau architecture by Antoni Gaudí (1852–1926). The theory of the chain, in the shape of a hanging collar, was proposed by Robert Hooke (1676) and used by Christopher Wren in Saint Paul’s dome (1675). British school modern mechanic theory was introduced in Spain by Spanish Bourbonic military engineers and also by the Catholic Scottish and Irish families during the eighteenth century. The assessment of some drawings of gunpowder warehouses, found in the collection of Mapas planos y Dibujos (MPD) of the General Archive of Simancas (Archivo General de Simancas, AGS) (AGS 2014), has revealed the use of the chain theory in Miguel Marín’s projects for Barcelona (1731) and Tortosa (1733) and Juan de la Feriére ones in A Coruña (1736). A built evidence has also been found: the Carlón wine cellars in Benicarló, built by the O’Connors family from Ireland (1757). The analysis of these examples proved the theory of the chain arrival to Spain during the first half of the eighteenth century.",book:{id:"8588",slug:"military-engineering",title:"Military Engineering",fullTitle:"Military Engineering"},signatures:"Josep Lluis i Ginovart",authors:null},{id:"55688",title:"The Special Case of Sea Mines",slug:"the-special-case-of-sea-mines",totalDownloads:2251,totalCrossrefCites:1,totalDimensionsCites:4,abstract:"In this chapter, work carried out at the Royal Military Academy regarding sea mines and mine countermeasures is summarized. Three sensors used for the detection and identification of sea mines are studied here: sonar, gradiometer and infrared camera. These sensors can be applied to detect different types of sea mines. Some signal and image processing techniques developed to extract relevant information for the detection of underwater objects are presented in this chapter. These techniques are validated using data collected in the frame of different European and NATO projects.",book:{id:"4818",slug:"mine-action-the-research-experience-of-the-royal-military-academy-of-belgium",title:"Mine Action",fullTitle:"Mine Action - The Research Experience of the Royal Military Academy of Belgium"},signatures:"Olga Lucia Lopera Tellez, Alexander Borghgraef and Eric Mersch",authors:[{id:"176830",title:"Dr.",name:"Olga",middleName:"Lucia",surname:"Lopera Tellez",slug:"olga-lopera-tellez",fullName:"Olga Lopera Tellez"}]}],onlineFirstChaptersFilter:{topicId:"293",limit:6,offset:0},onlineFirstChaptersCollection:[],onlineFirstChaptersTotal:0},preDownload:{success:null,errors:{}},subscriptionForm:{success:null,errors:{}},aboutIntechopen:{},privacyPolicy:{},peerReviewing:{},howOpenAccessPublishingWithIntechopenWorks:{},sponsorshipBooks:{sponsorshipBooks:[],offset:0,limit:8,total:null},allSeries:{pteSeriesList:[{id:"14",title:"Artificial Intelligence",numberOfPublishedBooks:9,numberOfPublishedChapters:90,numberOfOpenTopics:6,numberOfUpcomingTopics:0,issn:"2633-1403",doi:"10.5772/intechopen.79920",isOpenForSubmission:!0},{id:"7",title:"Biomedical Engineering",numberOfPublishedBooks:12,numberOfPublishedChapters:108,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2631-5343",doi:"10.5772/intechopen.71985",isOpenForSubmission:!0}],lsSeriesList:[{id:"11",title:"Biochemistry",numberOfPublishedBooks:33,numberOfPublishedChapters:330,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2632-0983",doi:"10.5772/intechopen.72877",isOpenForSubmission:!0},{id:"25",title:"Environmental Sciences",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2754-6713",doi:"10.5772/intechopen.100362",isOpenForSubmission:!0},{id:"10",title:"Physiology",numberOfPublishedBooks:14,numberOfPublishedChapters:145,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-8261",doi:"10.5772/intechopen.72796",isOpenForSubmission:!0}],hsSeriesList:[{id:"3",title:"Dentistry",numberOfPublishedBooks:9,numberOfPublishedChapters:141,numberOfOpenTopics:2,numberOfUpcomingTopics:0,issn:"2631-6218",doi:"10.5772/intechopen.71199",isOpenForSubmission:!0},{id:"6",title:"Infectious Diseases",numberOfPublishedBooks:13,numberOfPublishedChapters:123,numberOfOpenTopics:4,numberOfUpcomingTopics:0,issn:"2631-6188",doi:"10.5772/intechopen.71852",isOpenForSubmission:!0},{id:"13",title:"Veterinary Medicine and Science",numberOfPublishedBooks:11,numberOfPublishedChapters:112,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2632-0517",doi:"10.5772/intechopen.73681",isOpenForSubmission:!0}],sshSeriesList:[{id:"22",title:"Business, Management and Economics",numberOfPublishedBooks:1,numberOfPublishedChapters:22,numberOfOpenTopics:3,numberOfUpcomingTopics:0,issn:"2753-894X",doi:"10.5772/intechopen.100359",isOpenForSubmission:!0},{id:"23",title:"Education and Human Development",numberOfPublishedBooks:0,numberOfPublishedChapters:11,numberOfOpenTopics:1,numberOfUpcomingTopics:1,issn:null,doi:"10.5772/intechopen.100360",isOpenForSubmission:!0},{id:"24",title:"Sustainable Development",numberOfPublishedBooks:1,numberOfPublishedChapters:19,numberOfOpenTopics:5,numberOfUpcomingTopics:0,issn:"2753-6580",doi:"10.5772/intechopen.100361",isOpenForSubmission:!0}],testimonialsList:[{id:"6",text:"It is great to work with the IntechOpen to produce a worthwhile collection of research that also becomes a great educational resource and guide for future research endeavors.",author:{id:"259298",name:"Edward",surname:"Narayan",institutionString:null,profilePictureURL:"https://mts.intechopen.com/storage/users/259298/images/system/259298.jpeg",slug:"edward-narayan",institution:{id:"3",name:"University of Queensland",country:{id:null,name:"Australia"}}}},{id:"13",text:"The collaboration with and support of the technical staff of IntechOpen is fantastic. The whole process of submitting an article and editing of the submitted article goes extremely smooth and fast, the number of reads and downloads of chapters is high, and the contributions are also frequently cited.",author:{id:"55578",name:"Antonio",surname:"Jurado-Navas",institutionString:null,profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRisIQAS/Profile_Picture_1626166543950",slug:"antonio-jurado-navas",institution:{id:"720",name:"University of Malaga",country:{id:null,name:"Spain"}}}}]},series:{item:{id:"24",title:"Sustainable Development",doi:"10.5772/intechopen.100361",issn:"2753-6580",scope:"
\r\n\tTransforming our World: the 2030 Agenda for Sustainable Development endorsed by United Nations and 193 Member States, came into effect on Jan 1, 2016, to guide decision making and actions to the year 2030 and beyond. Central to this Agenda are 17 Goals, 169 associated targets and over 230 indicators that are reviewed annually. The vision envisaged in the implementation of the SDGs is centered on the five Ps: People, Planet, Prosperity, Peace and Partnership. This call for renewed focused efforts ensure we have a safe and healthy planet for current and future generations.
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\r\n\tThis Series focuses on covering research and applied research involving the five Ps through the following topics:
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\r\n\t1. Sustainable Economy and Fair Society that relates to SDG 1 on No Poverty, SDG 2 on Zero Hunger, SDG 8 on Decent Work and Economic Growth, SDG 10 on Reduced Inequalities, SDG 12 on Responsible Consumption and Production, and SDG 17 Partnership for the Goals
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\r\n\t2. Health and Wellbeing focusing on SDG 3 on Good Health and Wellbeing and SDG 6 on Clean Water and Sanitation
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\r\n\t3. Inclusivity and Social Equality involving SDG 4 on Quality Education, SDG 5 on Gender Equality, and SDG 16 on Peace, Justice and Strong Institutions
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\r\n\t4. Climate Change and Environmental Sustainability comprising SDG 13 on Climate Action, SDG 14 on Life Below Water, and SDG 15 on Life on Land
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\r\n\t5. Urban Planning and Environmental Management embracing SDG 7 on Affordable Clean Energy, SDG 9 on Industry, Innovation and Infrastructure, and SDG 11 on Sustainable Cities and Communities.
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\r\n\tThe series also seeks to support the use of cross cutting SDGs, as many of the goals listed above, targets and indicators are all interconnected to impact our lives and the decisions we make on a daily basis, making them impossible to tie to a single topic.
",coverUrl:"https://cdn.intechopen.com/series/covers/24.jpg",latestPublicationDate:"August 2nd, 2022",hasOnlineFirst:!0,numberOfPublishedBooks:1,editor:{id:"262440",title:"Prof.",name:"Usha",middleName:null,surname:"Iyer-Raniga",slug:"usha-iyer-raniga",fullName:"Usha Iyer-Raniga",profilePictureURL:"https://s3.us-east-1.amazonaws.com/intech-files/0030O00002bRYSXQA4/Profile_Picture_2022-02-28T13:55:36.jpeg",biography:"Usha Iyer-Raniga is a professor in the School of Property and Construction Management at RMIT University. Usha co-leads the One Planet Network’s Sustainable Buildings and Construction Programme (SBC), a United Nations 10 Year Framework of Programmes on Sustainable Consumption and Production (UN 10FYP SCP) aligned with Sustainable Development Goal 12. The work also directly impacts SDG 11 on Sustainable Cities and Communities. She completed her undergraduate degree as an architect before obtaining her Masters degree from Canada and her Doctorate in Australia. Usha has been a keynote speaker as well as an invited speaker at national and international conferences, seminars and workshops. Her teaching experience includes teaching in Asian countries. She has advised Austrade, APEC, national, state and local governments. She serves as a reviewer and a member of the scientific committee for national and international refereed journals and refereed conferences. She is on the editorial board for refereed journals and has worked on Special Issues. Usha has served and continues to serve on the Boards of several not-for-profit organisations and she has also served as panel judge for a number of awards including the Premiers Sustainability Award in Victoria and the International Green Gown Awards. Usha has published over 100 publications, including research and consulting reports. Her publications cover a wide range of scientific and technical research publications that include edited books, book chapters, refereed journals, refereed conference papers and reports for local, state and federal government clients. She has also produced podcasts for various organisations and participated in media interviews. She has received state, national and international funding worth over USD $25 million. Usha has been awarded the Quarterly Franklin Membership by London Journals Press (UK). Her biography has been included in the Marquis Who's Who in the World® 2018, 2016 (33rd Edition), along with approximately 55,000 of the most accomplished men and women from around the world, including luminaries as U.N. Secretary-General Ban Ki-moon. 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Her focus is on quality, innovation, leadership, and personalised learning. She works primarily at the strategic and policy levels, both nationally and internationally, and with key international organisations. She is committed to promoting and improving OFDL in the context of SDG4 and the future of education. Ossiannilsson has more than 20 years of experience in her current field, but more than 40 years in the education sector. She works as a reviewer and expert for the European Commission and collaborates with the Joint Research Centre for Quality in Open Education. Ossiannilsson also collaborates with ITCILO and ICoBC (International Council on Badges and Credentials). She is a member of the ICDE Board of Directors and has previously served on the boards of EDEN and EUCEN. Ossiannilsson is a quality expert and reviewer for ICDE, EDEN and the EADTU. She chairs the ICDE OER Advocacy Committee and is a member of the ICDE Quality Network. 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\r\n\tIf we aim to prosper as a society and as a species, there is no alternative to sustainability-oriented development and growth. Sustainable development is no longer a choice but a necessity for us all. Ecosystems and preserving ecosystem services and inclusive urban development present promising solutions to environmental problems. Contextually, the emphasis on studying these fields will enable us to identify and define the critical factors for territorial success in the upcoming decades to be considered by the main-actors, decision and policy makers, technicians, and public in general.
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