## 1. Introduction

The quantum theory of matter does not describe real matter until electromagnetic theory is used to account for such diverse radiative phenomena as spontaneous emission and the shift of quantum energy levels. Classical electrodynamics fails to account quantitatively for these radiative effects in the structure of matter. Quantum electrodynamics (QED) does successfully account for radiative effects in the structure of matter once an infinite contribution to the energy, which diverges linearly with electromagnetic-wave frequency, is subtracted from the theory based on physical argument that such contribution is already included, to zeroth order in perturbation theory, in the description of a radiative as opposed to a nonradiative or bare electron. This mathematical procedure is known as mass renormalization and introduces the concept that total mass comprises both material and electromagnetic contributions, neither of which is observable by itself.

In Section II of this paper a theory is presented which describes both the material and radiative properties of matter in a single, inseparable form. We show that the time-domain relativistic-wave equation of Paul Dirac can be inferred from the Lorentz invariant obtained from the scalar product of the electron’s four-momentum and an electromagnetic four-potential, once an electromagnetic carrier-wave frequency is formally identified with the rest-mass energy of the electron divided by

In Section III we provide an analytic proof that Dirac’s temporally harmonic solution of his equationis equivalent to solving temporally coupled equations by adiabatic elimination, which is a widely-used approximation method to solve temporally coupled equations in the optical-physics literature. In a wordDirac’s temporally harmonic solution is approximate, but his solution ofthe resulting time-independent or energy-domain equation, which is astaple of the relativistic quantum mechanics literature, is exact.The current interpretation of Dirac’s theory as describing only the material properties of matter derives from Dirac’s solution of his time-domain equation using the harmonic substitution,

In Section IV numerical results are presented for the general solution of Dirac’s time-dependent equation. Fourier analysis of the generaltime-dependent solution shows that the spectrum of quantum states for the Coulomb problem comprises coupled positive- and negative-energy states. The wave function is a mixture of bound and continuum states, with an unbound component propagating away from the atom in a manner which satisfies the Lorentz-invariant relationship or causality between position and time, r**2 - (ct)**2 = 0. The unbound behavior has long been known as Zitterbewegung for a free electron, and here we show its counterpart for the Coulomb problem. In view of the Dirac-Maxwell relationship elucidated in Section II we postulate that the physical interpretation of Zitterbewegung is the emission of a photon with energy of order 2mc**2 due to the presence of empty negative-energy states in the general time-dependent solution. Dirac's artifice of filling up the negative-energy levels with electrons to stabilize the atom is not available in the general time-dependent solution.

In Section V equations of motion for the photon are given. In Section VI subatomic bound solutions are discovered which are expected due to the temporally second-order nature of the time-domain Dirac equation. Subatomic bound solutions do not exist for Dirac’s time-independent equation (hereafter called standard Dirac theory) due to his use of the single-frequency temporally harmonic form discussed in Section III. Thus the existence of a complex neutron cannot be ruled out in the case of the general time-dependent solution as it was earlier in the case of standard Dirac theory [6]. These solutions resemble known Dirac energy-domain functions for Z > 137. The spectral content of these solutions comprises a spectral peak at -mc**2 for an electron and a spectral peak at +mc**2 for a positron - yes this state exists for a positive Coulomb potential. An electron can thus make an upward transition into the positive-energy continuum with transition energy 2mc**2, as in standard Dirac theory, while a positron can make a downward transition into the negative-energy continuum with transition energy -2mc**2. The upward transition is considered to be a matter transition, while the downward transition is considered to be an anti-matter transition.

## 2. Maxwell-Dirac equivalency

There exists a physical equivalency between Dirac and Maxwell theories which can be stated as follows. It is well known that Lorentz’ equation is the Lorentz invariant formed by taking the scalar product of the four-gradient and the electromagnetic four-potential,

Recall that the scalar product of four-vectors is always a Lorentz Invariant. One may postulate that a four-potential exists for the electron, such that an electron equation of motion can be written as the Lorentz invariant formed by taking the scalar product of the electron's four-momentum and the electron's four-potential,

The electron scalar and vector potentials can be written in the form of carrier-wave expansions,

from which on substituting Eqs. (3) into Eq. (2) and separately setting the coefficients of the exponential factors equal to zero, we obtain,

On setting

Identically if the carrier-wave energy is equal to the rest-mass energy

where

An electromagnetic contribution to the mass of the electron due to the quantum radiation field associated with its motion is a well known concept in QED. Indeed the carrier-wave frequency of the electron's four-potential [Eqs. (3)] is equal to mc**2/hbar, which is the high-frequency cut off for the quantum radiation field assumed in QED atomic structure calculations. The present derivation of Dirac’s equation suggests thatthe total mass of the electron is electromagnetic in nature. This result is consistent with a previous result in which the charge of the electron was derived from Maxwell’s equations [7].

## 3. Adiabatic nature of Dirac’s solution of his equation

Although the time-dependent Dirac equation can be written in the Schroedinger form,

where HD is the Dirac Hamiltonian and

equation can be written in the Schroedinger form,

unless one requires that all components of

Eqs. (5) are rewritten in the standard Dirac form,

where

where we have specialized to an electromagnetic field free problem by setting

where we have used the identity,

Dirac’s harmonic ansatz for his time-dependent equation gives him aenergy-domain equation which is exactly solvable for the free-electron and Coulomb problems. The Schroedinger form of the temporal solution, which is exact for Schroedinger’s scalar wave equation but not for Dirac’s vector wave equation, is in effect a form of calibration of Dirac theory to Schroedinger theory and has cast Dirac theory in the limited role of “correcting” Schroedinger theory primarily for relativistic effects in atomic structure. Probably as a result of its restricted use in electron physics, time-domain Dirac theory until recently had not been used to discover the a priori physical basis for Fermi-Dirac statistics [8], which is a spin-dependent phenomenon. The history of quantum mechanics instead followed a path of ensuring that Schroedinger wave functions satisfy Fermi-Dirac statistics on the basis of experimental observation and not a priori theory by using the Slater determinantal wave function to solve Schroedinger’s wave equation for many electrons, even though Schroedinger theory, in which particle spin is absent, contains no physical basis for Fermi-Dirac statistics. One must instead turn to time-domain Dirac theory and the Dirac current to discover the physical basis for Fermi-Dirac statistics, which is elucidated using spin-dependent quantum trajectories [8]. Richard Feynman [9] once asked if spin is a relativistic requirement and then answered in the negative because the Klein-Gordon equation is a valid relativistic equation for a spin-0 particle. The correct answer is thatspin is a relativistic requirement to insure Lorentz invariance in a vector-wave theory such as the Dirac or Maxwell theories. In the sense that Fermi-Dirac statistics depends critically on spin and yet is a phenomenonof order (Zc)^{0}, where c is the speed of light and Z is the atomic number, it would appear that authors [10] are misguided who present the quantum theory of matter as fundamentally based on Schroedinger theory as augmented by Dirac theory for “relativistic corrections” of order Z^{4}c^{-2} due to the acceleration of an electron moving near a nucleus with atomic number Z.

## 4. Genera solution of Dirac’s time-domain wave equation

In this section the general time-dependent solution is presented free of any harmonic bias. Solving the Coulomb problem (

follows from the well-known substitutions,

where the angular functions are Dirac’s two-component spinors.Eq. (11) is solved numerically in the variables r and ct for the hydrogen-like ground state (

At the point t=t’ the Crank-Nicolson implicit integration procedure is used in order to insure that the time integration of the equation itself is unconditionally stable. Fig. 1 shows the spectrum of states calculated from the inverse temporal Fourier transform of the wave function [11-12]. The spectrum has a strong peak in the positive-energy regime and a weak peak in the negative-energy regime, which lies in the negative-energy continuum and thus accounts for the unbound tail (Fig. 2). This temporally expanding tail appears to be the Coulomb counterpart of the Zitterbewegung solution calculated by Schroedinger [13] using the time-dependent Dirac equation for a free electron.

Fig. 2 shows the real part of radial wave function times r. Notice that the wave function is unusual in that it behaves like a bound state close to the nucleus but yet is unbound with a small-amplitude tail along the r axis whose length is equal to ct. In other words the tail propagates away from the nucleus at the speed of light. Nevertheless I have normalized the wave function for unit probability of finding the electron within a sphere of radius r_{max}. The amplitude of the interior portion flows with time between the real part (Fig. 2) and imaginary part of the wave function such that the probability density is steady within the radius of the atom. (ct)_{max} is chosen to be three-fourths of r_{max} in order that the propagating piece of the wave function stays well away from the grid boundary at r_{max}. Calculations show that the results are Insensitive to r_{max} and therefore to (ct)_{max} as long as r_{max} is well outside the region represented by the bound piece of the wave function, that is well outside of the radius of the atom as represented by standard Dirac theory. Notice that if the dynamical calculation were extended to very large times, then the wave function would fill a verylarge volume. In principle after a sufficient time the wave function could fill a volume the size of the universe although its interior part would remain the size of an atom.

What is the physical interpretation of Zitterbewegung? In view of theMaxwell-Dirac equivalency elucidated in Section II, we postulate here thatit is a photonic energy of order 2mc**2, which is the energy gap betweenthe positive- and negative-energy electron continua and which was identified in Section II as an electromagnetic carrier-wave energy equal to

In the general time-domain solution presented here it appears that theatom is self-stabilizing due to the mixed material-electromagnetic natureof the electron. Recall that in Section II we postulated that the electron’sequation of motion should be the scalar product of its material four-momentum and its electromagnetic four potential. The solution of the equation of motion shows that the electron can share two ground-state material energy levels with energy conservation and without temporal decay of its quantum state as long as the energy difference between the two ground-state levels is converted to the energy of a continuously-emitted photon.

## 5. Photon equations of motion

In this section equations of motion for the photon are given and used to calculate a divergence-free Lamb shift [14-15]. As in the case of the electron in Section II we assume that a complex four-potential exists for the photon such that a photon EOM can be written as the Lorentz invariant formed by taking the scalar product of the photon's four-momentum and the photon's four-potential,

for either electric or magnetic fields

The electron scalar and vector potentials can be written in the form of carrier-wave expansions,

from which on substituting Eqs. (14) into Eq. (13) and separately setting the coefficients of the exponential factors equal to zero, we obtain,

On setting

Writing

where we have used the identity,

## 6. Subatomic bound states

Dirac’s time-domain equation can be cast in the form of an equationsecond order in space and time; thus we should expect a second spatial-temporal solution to exist which is independent of the first spatial-temporal solution which we have elucidated in Section IV. I show that a regime exists in which an adiabatic solution to the time-dependent Dirac equation is not justified even in an approximate sense. The existence of the regime is easily recognized by writing Dirac equations in the form given by Eq. (11) for the large component with a reversal of charge and for the small component with no reversal of charge and then seeking solutions for which the phase in the exponential factor vanishes for all times. These equations are,

Eqs. (20) are solved numerically for Z=1 and

Although the wave function is pulled inward toward the origin, its extent is still large compared to the radius of the proton r_{p}=1.3x10^{-13} cm = 2.46x10^{-5} au.

The spectral energies are those which cancel the terms ^{2}-|V| = 0. For the unit-strength Coulomb potential the radius at which the stationary-phases occur is given by

The bound behavior of the positronic-electronic wave function shown in Fig. 4 can be understood as follows. Recognizing that the first and third terms on the left side of Eq. (20) cancel from the spectral values

A solution to Eq. (20) is sought in the form

Figs. 5-6 show plots of the real part of f and of the real and imaginary parts of g respectively for r=ct and

## Acknowledgments

The author is grateful to T. Scott Carman for supporting this work. This work was performed under the auspices of the Lawrence Livermore National Security, LLC, (LLNS) under Contract No. DE-AC52-07NA27344.

## References

- 1.
J. D. Bjorken and Sidney D. Drell, Relativistic Quantum Mechanics (McGraw Hill, New York, .1964 ), Chapter 2 - 2.
118 657 ([2] C. G. Darwin Proc. Roy Soc. 1928 ). - 3.
371380 1380 ([3] O. Laporte Uhlenbeck G. Phys Rev. 1931 ). - 4.
34815 815 ([4] R. Armour Jr Found. Phys 2004 ) and references therein. - 5.
262 229 ([5] B. Ritchie Optics. Communications 2006 ). - 6.
46107 107 ([6] H. Margenau Phys. Rev 1934 ). - 7.
552903 2903 ([7] B. Ritchie J. Mod Optics. 2008 ). - 8.
111 1 ([8] R. Ritchie Int. J. Quantum Chem. 2011 ). - 9.
[9] Richard Feynman, Quantum Electrodynamics (Benjamin, New York, 1962 37 - 10.
[10] For example Op. Cit. 1 p. - 11.
47412 412 ([11] M. D. Feit J. A. Fleck Jr Steiger A. Comput J. Phys 1982 ). - 12.
75. Ritchie, Phys. Rev. B 75, 052101 ([12] B. Ritchie Phys. Rev 2007 ). - 13.
24 24, 418 ([13] E. Schroedinger Sitzungb. Preuss Akad. Wiss Ohys. Math 1930 ). - 14.
Communications Optics. 280 126 (Ritchie B. 2007 ). - 15.
Communications Optics. 282 3286 (Ritchie B. 2009 ). - 16.
Communications Optics. 281 3492 (Ritchie B. 2008 ).