Open access peer-reviewed chapter

# Applications of Combined Electrocoagulation and Electrooxidation Treatment to Industrial Wastewaters

By Baran Özyurt and Şule Camcıoğlu

Submitted: October 2nd 2017Reviewed: February 14th 2018Published: August 29th 2018

DOI: 10.5772/intechopen.75460

## Abstract

In recent years, it is aimed to reuse wastewater to form an economical input and to manage it sustainably without threatening human life and ecosystem. High pollutant removal yield from wastewaters was achieved using electrocoagulation method without adding any chemical coagulant or flocculants, thus reducing the amount of sludge. However, electrocoagulation (EC) is an inefficient method for the removal of stable and dissolved organic pollutants. Electrooxidation (EOx), which was evaluated as one of the most promising technologies for the treatment of wastewater containing soluble organic compounds, can directly and indirectly oxidize small organic pollutants. Although electrooxidation provides full mineralization of the organic matter, if suspended solids are present, energy consumption is increased. Since EC is a fast but incomplete process and EOx is a complete but slow process, combining the two processes offers a practical hybrid. In this chapter, mechanisms and applications of EC, EOx, and their combinations will be widely discussed.

### Keywords

• wastewater treatment
• electrocoagulation
• electrooxidation
• combined
• simultaneous
• sequential
• hybrid
• integrated

## 1. Introduction

Water pollution seriously affects the ecosystems and availability of healthy freshwater [1]. The preservation of water resources is one of the most important issues of the twenty-first century [2]. Nowadays, sources of safe drinking water are limited and under stress [3]. The main problems encountered are population growth, rapid decline of forest areas, urbanization, climate change due to global warming, and industrialization [1]. Large amounts of raw water were consumed by industrial processes for various purposes [4]. Consequently, wastewater is produced in large quantities [4]. Wastewaters are composed of a complex mixture of different organic and inorganic compounds, which may be toxic and difficult to degrade [4]. The most common inorganic water pollutants are heavy metals, nitrates, sulfates, phosphates, fluorides, and chlorides, which have serious hazardous effects [3]. The organic pollutants found in wastewaters may be generalized as insecticides, herbicides, fungicides, polycyclic aromatic hydrocarbons, phenols, biphenyls, halogenated aromatic hydrocarbons, formaldehyde, detergents, oils, greases, normal hydrocarbons, alcohols, aldehydes, ketones, proteins, lignin, and pharmaceuticals [3]. These pollutants remain either in dissolved, in colloidal, or in suspended form [3]. Mostly, wastewater treatment is carried out by conventional wastewater treatment processes [5]. Conventional wastewater treatment technologies could be categorized as physical processes including screening, flotation, filtration, and sedimentation [6]; chemical processes such as coagulation/flocculation, chlorination, adsorption, and ion exchange [6]; biological processes, i.e., activated sludge, aerated lagoons, and membrane bioreactors [2].

However, it is difficult to degrade the complex refractory organic pollutants in the wastewater by biological methods [7, 8]. In addition, physical–chemical methods are not always effective due to formation of additional pollution caused by the unreacted chemicals and difficulties of treatment of large amount of toxic sludge produced during conventional wastewater treatment [3, 4, 5, 9, 10]. With the strict environmental regulations on wastewater discharge, there is a need to develop efficient technologies and approaches at large scale for the treatment and management of industrial wastewater so that clean water quality can be maintained and amount increased while environmental protection and sustainability are achieved [1, 2, 3, 4, 5, 8, 11, 12, 13]. There has been an increasing interest in the use of electrochemical wastewater treatment technologies, such as electrodeposition [14], electrodisinfection [15], electro-Fenton [16], electrosorption [17], EOx [4] and EC [1] and their sequential [8, 18], and simultaneous [19, 20] combinations for the treatment of industrial wastewaters in recent years.

The foundations of electrochemical water treatment were laid in 1889 [11]. Electrocoagulation for drinking water was first carried out by Fred E. Stuart in 1946 [11, 21]. With the increasing interest in the second half of the twentieth century, many investigations were made on the topic [11]. Among others, EC and EOx methods are the electrochemical technologies that researchers are most interested in regarding water and wastewater treatment [2, 5, 11]. EC is based on the principle that coagulant species including hydroxide precipitates are produced in situ by electrolytic oxidation of the sacrificial anodic material, which is dissolved as ions by electric current applied through metal electrodes such as aluminum and iron [1, 22]. Thus, the EC method is more advantageous than the coagulation/flocculation method in which metal salts and polyelectrolytes are used as coagulants/flocculants in terms of sludge formation [23, 24]. EC aims to remove particles from the wastewater by destabilizing/neutralizing the repulsive forces that keep the particles suspended in the water [2]. When the repulsive forces are neutralized, suspended particles can be separated more easily from water by forming larger particles that can precipitate [2]. EC also provides the removal of pollutants by simultaneous cathodic reactions, either by deposition on the cathode or by flotation based on the formation of hydrogen gas at the cathode [1]. In recent years, EC was reported as an easy-to-operate, efficient, and economical method. Strengths of EC method can be summarized as follows; it requires simple equipment and operating conditions and does not require additional chemicals; treated water is colorless, odorless, and clear; the amount of the sludge formation is low which can be easily stabilized and dehydrated; compared with chemical coagulation, the effluent contains less total dissolved solids; and the gas bubbles produced in the cathode allow the pollutants to be separated easily by floating them to the surface. However, weaknesses of EC method can be listed as follows: sacrificial electrodes need to be replaced regularly, formation of an impermeable film layer on the cathode may reduce the efficiency of the process and it is inefficient for the removal of persistent dissolved organic pollutants.

With regard to the treatment of effluents polluted with organic compounds, biological oxidation is the most economical process, but the presence of toxic or biorefractive molecules may prevent this approach [25]. Despite chemical oxidation using chlorine, ozone or hydrogen peroxide is currently used for the oxidation of biorefractive contaminants to harmless or biodegradable products; in some reactions, the intermediate products remain in the solution and may cause similar or higher toxicity than the initial compounds [25]. EOx can completely degrade many harmful organic pollutants before they reach the receiving environment [4]. EOx is based on in situ production of oxidants either directly at the surface of the electrodes or indirectly from the chemical compounds in the treated water during treatment [4]. EOx may occur either through direct oxidation with hydroxyl radicals produced on the anode surface or indirectly through oxidants such as chlorine, hypochlorous acid, and hypochlorite or hydrogen peroxide/ozone formed at electrodes [13]. The hydroxyl radicals can oxidize substantially all of the organic compounds with an oxidation rate 109 times higher than that of ozone [26]. The oxidation power of chlorine and other anode-formed oxidants remains low compared to the hydroxyl radicals and as a result it does not allow many pollutants to be effectively oxidized to carbon dioxide and water [13]. Electrode material selection is very important because it affects process selectivity and efficiency [12]. Electrode material must have the properties such as resistance to erosion, corrosion and formation of passivation layers, high electrical conductivity, selectivity and catalytic activity, low cost, and durability. Noble metal electrodes; metal alloys electrodes; mixed metal oxide electrodes which are also referred as dimensionally stable anodes (DSAs) such as Ti/Ta2O5-IrO2, Ti/SnO2-IrO2, Ti/RuO2-IrO2, Ti/Sb-SnO2, Ti/SnO2-Sb2O5-RuO2, and Ti/TiO2-IrO2; carbon and graphite electrodes; and boron-doped diamond (BDD) electrodes are some examples of the electrode materials used in recent wastewater treatment studies [27]. Strengths of EOx method can be summarized as follows: it requires simple equipment and operating conditions, totally mineralizes persistent organic pollutants, has low electrode maintenance cost, and forms disinfecting compounds. However, EOx method has some weaknesses such as: it is inefficient for the removal of suspended solids, and formation of an impermeable film layer on the cathode may reduce the efficiency of the process.

Since EC is a fast but incomplete process and EOx is a complete but slow process, coupling the two processes offers a practical hybrid [26]. EC has the ability to remove pollutants quickly but not completely. EOx is able to remove pollutants slowly but consistently. Sequential and simultaneous operations are combining the best abilities of EC and EOx processes with fast and complete pollutant removal [26]. This chapter focuses on effects of operating parameters on EC and EOx, pollutant removal mechanisms, and recent applications of these methods and their sequential and simultaneous combinations.

## 2. Electrocoagulation mechanism and operation

### 2.1. Mechanism

In the EC process, coagulant species are produced in situ using the electrical dissolution of sacrificial anode, usually made of iron or aluminum by electric current applied between metal electrodes [1]. At the anode, metal is oxidized into cations as shown in Eqs. (1)(3).

AlsAlaq3++3eE1
FesFeaq2++2eE2
Feaq2++O2+2H2OFeaq3++4OHE3

In the case of high anode potential, following reactions may occur as shown in Eqs. (4) and (5).

2H2OO2g+4H++4eE4
2ClCl2g+2ein the presence ofClanionsE5

Chlorine formation may lead to the formation of hypochlorous acid, an oxidizing agent which may contribute to the oxidation of dissolved organic compounds as shown in Eq. (6) [1].

Cl2g+H2OHClO+H++ClE6

At the cathode, hydrogen gas and hydroxyl anions are formed by the reduction of water as shown in Eq.(7).

2H2O+2eH2g+2OHatalkaline conditionsE7

The amount of dissolved metal at the anode can be calculated using Faraday’s law as shown in Eq. (8).

m=ItMzFE8

where m is the mass of metal in g, t is the electrolysis time in s, I is the electric current in A, M is the atomic weight of the electrode material in g/mole, z is the number of electrons transferred, and F is Faraday’s constant (96486 C/mole). The most common phenomenon for metal cations released from the anode is the formation of non-soluble and easily precipitable metal hydroxide sweep flocs which have large surface areas beneficial for a rapid adsorption of soluble organic compounds and trapping of colloidal particles as shown in Eqs. (9)(13) [1].

Alaq3++3H2OAlOH3+3H+E9
AlOH3+H2OAlOH4+H+atpH>9E10
Feaq2++2OHFeOH2E11
4FeOH2+O2+H2O4FeOH3E12
FeOH3+OHFeOH4atpH>9E13

Removal mechanisms of various pollutants involve physical removal of dissolved pollutants during precipitation, adsorption, and complexation [1]; electrooxidation [28] or electroreduction [29] of the electro-active ion or molecules on the anode or the cathode; the direct adsorption of pollutants on the electrodes [30]; the compression of the double layer of a colloidal particle [31]; charge neutralization; and colloid entrapment [1].

### 2.2. Operating parameters

The parameters affecting the effectiveness of the EC process are operating conditions such as the current density, operating time, pH, conductivity, and electrode properties [22]. The bubble density affects system hydrodynamics, which determine the mass transfer between pollutants, coagulant, and gas microbubbles, and determines the collision rate of the coagulated particles resulting in flock formation [1].

The current density determines the coagulant dosage at the anode and the formation of hydrogen gas at the cathode. Unnecessarily high current values may negatively affect the EC efficiency as coagulant overdosage can reverse the charge of the colloids and redistribute them, reducing coagulation efficiency and also reducing electrode lifetime [1].

pH is an important factor affecting EC performance, particularly the coagulation mechanism, since it governs the hydrolyzed metal species formed in electrolyte media [32]. Adsorption and coagulation depend on pH in particular. The superficial charge of Al or Fe precipitates can be explained by the adsorption of charged soluble monomeric species on their own hydroxide precipitates [1]. For Al and Fe electrodes, the amount of insoluble aluminum hydroxide increases sharply with increasing pH from 4.5 to 7 [1]. For a pH above 10, amorphous metal hydroxide is absent. For acidic influent, effluent pH after EC treatment would increase but can decrease for alkaline influent, which is due to the buffering effect of EC [11].

Lower amounts of energy are consumed with decreasing the gap between electrodes. As the distance between electrodes becomes lower, the amount of generated gas bubbles increases, thus leading to a high mass transfer as well as to a high reaction rate between the coagulants and pollutants [1].

Applied potential difference of galvanostatic EC operation depends strongly on conductivity and ionic strength of the wastewater. Applied potential difference decreases with increasing electrolytic conductivity due to the decrease of ohmic resistance of wastewater [1]. Consequently, the energy consumption per unit volume of treated wastewater is reduced as shown in Eq. (14).

SEECkWh/m3=IVtVEE14

where SEEC is the specific electrical energy consumption, I is the electric current in A, V is the applied potential difference in V, t is the electrolysis time in h, and VE is the volume of treated wastewater in L.

### 2.3. Applications of electrocoagulation

In this section, recent studies on the application of EC method in the treatment of different wastewaters and pollutants such as chemical oxygen demand (COD), total organic carbon (TOC), total phosphate (TP), phenol, oil and grease (O&G), biochemical oxygen demand (BOD5), and total suspended solids (TSS) are presented. Ranges and optimum values of operating parameters, pollutant removal efficiencies, energy consumption, and operating cost values of previously published work are given in Table 1. It has been reported that EC treatment is an effective method in removing organic matter, turbidity, color, phenol, phosphate, heavy metals, pharmaceuticals, O&G from wastewater.

Ref.WastewaterElectrode materialParametersResearch ranges for parametersOptimum conditionsResults at optimum conditions
[33]Olive mill
(real)
AlElectrolysis time (min)3–2015Color removal:
91%
COD removal:
83%
Phenol removal:
87%
SEEC:
2.63 kWh/kg CODr
Operating cost:
0.27 €/kg CODr
Current density (A/m2)10–4000250
NaCl concentration (g/L)0.5–32
Initial pH2–104.2
[34]Textile
(synthetic)
AlCurrent density (A/m2)100–400300Turbidity removal:
90%
Color removal:
97%
SEEC:
19.5 kWh/kg dye removed
Inlet flow rate (L/h)15–6015
Initial concentration (mg/L)50–300< 300
Initial pH2.3–8.87.74
Residence time (min)5–5535
[35]Dairy
(real)
AlElectrolysis time (min)0–6030COD removal:
74.56%
BOD5 removal:
96.28%
Turbidity removal:
98.91%
SEEC:
3.36 kWh/m3
Initial pH2–127
Current density (mA/cm2)2.5–3514
NaCl concentration (g/L)0–21
[22]Pulp and paper
(real)
Al or FeElectrode materialAl-FeAlCOD removal:
65.33%
Color removal:
100%
Turbidity removal:
98.61%
TSS removal: 97.06%
SEEC:
8.82
kWh/kg COD
Electrical conductivity (mS/cm)2.3–4.22.72
pH3–125.82
Temperature (°C)10–5022.62
Electrolysis time (min)5–4510.83
Current intensity (A)0.5–1.81.22
[36]Car wash
(real)
Al or FeElectrode materialAl-FeFeCOD removal:
88%
O&G removal:
90%
Cl removal:
50%
Operating cost:
0.6 $/m3 Sludge: 2.1 kg/ m3 pH2–108 Current density (mA/cm2)0.1–53 Operating time (min)5–5030 [37]Industrial estate (real) FeCurrent density (mA/cm2)10–5030COD removal: 62.5% SEEC: 42.44 kWh/m3 Energy cost: 1.91 €/m3 Sludge: 1.91 g/g COD Na2SO4 concentration (mM)1–73 Initial pH3.12–8.836 ### Table 1. EC treatment results of various wastewaters for selected examples in the literature. ## 3. Electrooxidation mechanism and operation ### 3.1. Mechanism EOx may occur either by direct oxidation of pollutants using hydroxyl or hydroperoxyl radicals produced on anode surface or by an indirect process where oxidants like chlorine, hypochlorous acid, and hypochlorite or hydrogen peroxide/ozone are formed at electrodes. Direct anodic oxidation of pollutants and formation of indirect oxidizing agents occur according to the reactions given in Eqs. (15)(24) [26, 38, 39]. H2O+SSOH+H++eE15 R+SOHS+RO+H++eE16 H2O+S+ClSClOH+H++2eE17 R+SClOHS+RO+H++ClE18 H2O+SOHS+O2+3H++3eE19 H2O+SOHS+H2O2+H++eE20 SOH+H2O2S+HO2+H2OE21 O2+SOHS+O3+H++eE22 H2O+SClOH+ClCl2+S+O2+3H++4eE23 H2O+SClOH+Cl2S+ClO2+3H++2Cl+eE24 Indirect oxidation of pollutants occurs according to the reactions given in Eqs. (25)(29) [26]. 2ClCl2g+2eE25 Cl2+H2OHClO+H++ClE26 HClOH++ClOE27 H2O+R+ClO+H+RO+H3O++ClE28 6ClO+3H2O2ClO3+4Cl+6H++32O2+6eE29 Chlorate is usually an unwanted product in the effluent, and its formation could also prevent the use of EOx in various applications [25]. At the cathode, hydrogen gas and chloride anions are formed as shown in Eqs. (30)(32). 2H3O++2eH2+2H2Oatacidic conditionsE30 2H2O+2eH2+2OHatalkaline conditionsE31 ClO+H2O+2eCl+2OHE32 Here S symbolizes the active sites of the anode surface, and R represents the organic matter. To evaluate the selectivity of an anode material, competition between the oxidation of organic materials and the oxygen formation (the side reaction) at the anode (Eq. (4)) must be taken into account [12]. Oxygen formation is typically considered to be an undesirable side reaction in the electrochemical wastewater treatment because it affects the efficiency of the process and significantly increases the operating costs [25]. Removal mechanisms of various pollutants involve diffusion of pollutants from the bulk solution to the anode surface and direct oxidation at the anode surface either partially or completely [12] and generation of a strong oxidizing agent (i.e., chlorine) at the anode surface and indirect oxidation of pollutants in the bulk solution. ### 3.2. Operating parameters Among the variables that are usually studied in EOx treatment, the current density is one of the most frequently referenced terms since it affects the rate of reactions [12]. It should be noted that an increase in current density will not necessarily result in an increase in oxidation efficiency or oxidation rate [12]. The use of higher current densities usually leads to higher operating costs due to the increase in energy consumption. It should be noted that although there is no agreement on the effect of the conductivity on the overall oxidation efficiency, the cell voltage is reduced for a given current density as the conductivity of the electrolyte increases [12]. For this reason, the electrochemical oxidation process is more cost-effective if the treated wastewater already has a high conductivity [12]. When reactions are carried out in chloride-containing media, the pH value may affect the rate of oxidation because it determines the primary active chloro species present in the effluent [12]. During indirect oxidation, chlorine evolution occurs at the anode (Eq. (25)). At pH values lower than 3.3, the primary active chloro species is Cl2, while at higher pH values, it forms HClO at pH <7.5 (Eq. (26)) and ClO at pH >7.5 (Eq. (27)). Operation at strongly acidic conditions is favorable since chlorine is the strongest oxidant followed by HClO and ClO, respectively [12]. Depending on the electrolytic cell design, desorption of chlorine from reaction medium may prevent its action as an oxidizing agent. Thus, neutral or mildly alkali medium may be preferred since HClO and ClO species remain almost unaffected by desorption of gases and they can act as oxidizing reagents in the whole volume of wastewater [40]. ### 3.3. Applications of electrooxidation This section briefly describes the treatment of different wastewater types by EOx method in the last few years. Table 2 shows a general insight on minimum, maximum, and optimum values of operating parameters, pollutant reduction, energy consumption, and operating cost of EOx treatment. By evaluating the previously published studies, it has been concluded that EOx is a remarkable treatment method in terms of organic matter, turbidity, color, phenol, total Kjeldahl nitrogen (TKN), and O&G removal efficiencies. Ref.WastewaterElectrode materialParametersResearch ranges for parametersOptimum conditionsResults at optimum conditions [41]Pulp and paper industry (real) Anode: Catalytic oxide coated titanium Cathode: Stainless steel Current density (A/dm2)2.5–52.5COD removal: 67.99% SEEC: 37.67 kWh/kg COD NaCl concentration (g/L)1–53 [42]Textile (real) GraphiteInitial pH4–104COD removal: 90.78% Color removal: 96.27% SEEC: 23.58 kWh/kg COD Current density (A/m2)27.78–138.8927.78 NaCl concentration (g/L)0–22 Electrolysis time (min)10–130110 [43]Olive mill (real) Anode: Ti/Pt mesh Cathode: Ti mesh Electrolysis time (h)1–245COD removal: 100% TOC removal: 78% Phenol removal: 100% SEEC: 451.25 kWh/m3 Energy cost: 6.02$/kg COD
Mixing rate (rpm)0–6000
Dilution ratio1/5–5/51/5
pH2–84.5–4.7
Type of support electrolyteNa2SO4, KCl, NaClNaCl
Concentration of support electrolyte (mM)0.25–1.250.25
Current density (mA/cm2)2.5–157.69
Temperature (°C)10–5010
[44]Pharmaceutical
(synthetic)
Anode:
BDD
Cathode:
Stainless steel
Current density (mA/cm2)1.56–6.256.25TOC removal:
80%
SEEC:
2.34 kWh/g TOC
[45]Industrial park sewage
(real)
Anode:
Mesh-structure plate
Cathode:
Mesh-structure Ti plate
Anode materialTi/PbO2,
Ti/RuO2, Ti/RuO2-IrO2
Ti/PbO2COD:
60 mg/L
Color:
20 CU
SEEC:
4.12 kWh/ton
Operating cost:
0.57 $/ton Current density (mA/cm2)2–155 ### Table 2. EOx treatment results of various wastewaters for selected examples in the literature. ## 4. Combined electrocoagulation and electrooxidation mechanism and applications ### 4.1. Mechanism As stated in Section 1, EC is a fast but incomplete process, while EOx is a complete but slow process; coupling the two processes proposes a functional hybrid. COD removal mechanism of a combined EC and EOx process can be summarized as follows: production of metal ions; hydrolysis of metal ions to generate metal hydroxides and/or polyhydroxides in appropriate pH; generation of bubbles of oxygen and hydrogen gases at the anode and the cathode, respectively, which provides the flotation of coagulated pollutants; destabilization of colloidal pollutants and trapping of destabilized colloidal particles to form flocks; removal of pollutants by precipitation [46]; formation of adsorbed hydroxyl radicals on anode surface [39]; degradation of organic pollutants by direct oxidation of adsorbed hydroxyl radicals; generation of indirect oxidizing agents such as chlorine, hypochlorite, and hydrogen peroxide near the anode; and electrochemical combustion of organic pollutants by indirect oxidizing agents [26]. ### 4.2. Applications of combined electrocoagulation and electrooxidation In the recent years, application of combined treatment has been successfully achieved in the removal of different kinds of pollutants either by sequential EOx treatment of the electrocoagulated effluent or simultaneous EC and EOx treatment with an appropriate electrode configuration. The aim of sequential EC-EOx is to propose a new approach that combines the synergistic effects of the two methods [47]. Simultaneous EC-EOx offers a hybrid system integrating monopolar (MP) EOx and bipolar (BP) EC in a single reactor that also provides all the advantages of sequential EC-EOx [19]. Recent studies on combined EC-EOx treatment of different kinds of wastewater are presented in Tables 3 and 4. Ref.WastewaterElectrode materialParametersResearch ranges for parametersOptimum conditionsResults at optimum conditions [48]Dairy (synthetic) Anode: Al Cathode: Ti/Pt Current density (A/m2)0–7550COD removal: 54.16% TP removal: 42.9% Turbidity removal: 37% Electrolysis time (min)0–52 Initial pH4–116.6 NaCl concentration (g/L)0–21.5 [49]Anaerobic reactor effluent (real) Anode: MP RuO2/Ti Cathode: MP stainless steel Sacrificial electrode: BP Al pH5–107Ammonia removal: 98% TP removal: 98% COD removal: 72% Current intensity (A)1–33 Detention time (min)10–6060 [50]Pharmaceutical (synthetic) Anode: MP stainless steel Cathode: MP stainless steel pH4.5–10.910.9Diclofenac sodium removal: 84% COD removal: 80% [20]Olive mill (real) Anode: RuO2/Ti Cathode: Stainless steel Sacrificial electrodes: BP Al pH3–94COD removal: 96% BOD5 removal: 93.6% Phenol removal: 94.4% Color removal: 91.4% Turbidity removal: 88.7% TSS removal: 97% O&G removal: 97.1% BOD5/COD: 0.46 Current density (mA/cm2)5–4040 NaCl concentration (g/L)0.5–31 H2O2 concentration (mg/L)0–20001000 Detention time (min)5–3030 [19]Textile (real) Anode: MP Ti/IrO2 Cathode: MP Ti Sacrificial electrode: BP Al or Fe Sacrificial electrode materialAl-FeAlCOD removal: 93.5% TSS removal: 97% Color removal: 97.5% BOD5 removal: 90% Turbidity removal: 96% Phenol removal: 99% TP removal: 97% Operating cost: 1.69 US$/m3
Electrolysis time (min)20–9090
Current intensity (A)0.2–10.6
pH5–106
Interelectrode distance (cm)0.5–1.51
Stirring speed (rpm)250–750500
[26]Pulp and paper mill
(real)
Anode:
MP graphite
Cathode:
MP graphite
Sacrificial electrode:
BP Al or Fe
Electrode materialAl-FeAlCOD removal:
87%
Color removal:
100%
Turbidity removal:
100%
SEEC:
31.6 kWh/kg COD
Operating cost:
1.33 \$/m3
Initial pH3–96
Electrical conductivity (mS/cm)3–75
Temperature (°C)10–3020
Current intensity (A)0.5–1.51

### Table 3.

Simultaneous EC-EOx treatment results of various wastewaters for selected examples in the literature.

Ref.WastewaterElectrode materialParametersOptimum conditionsResults at optimum conditions
[18]Textile
(synthetic)
EC:
Al
Current density (mA/cm2)30COD removal:
~94%
SEEC:
0.02 kWh/g
Treatment time (min)5
EOx:
Graphite
Current density (mA/cm2)0.91
Treatment time (min)425
[8]Industrial park (real)EC:
Fe
pH8Color removal:
100%
Turbidity removal:
100%
COD removal:
100%
BOD5 removal:
100%
Current density (A/m2)800
Treatment time (min)30
EOx:
Anode:
BDD
Cathode:
Fe
pH8
Current density (A/m2)800
Treatment time (min)150
[51]Car wash
(real)
EC:
Anode:
Fe
Cathode:
Stainless steel
Electrolysis time (min)6COD removal:
> 97%
SEEC:
12 kWh/m3
Current density (mA/cm2)2
EOx:
Anode:
BDD
Cathode:
Stainless steel
Electrolysis time (min)90
Current density (mA/cm2)10
[47]Dairy
(real)
EC:
Al
Current density (A/dm2)0.6Turbidity removal:
100%
Color removal:
90.4%
COD removal:
66.4%
Operating time (min)6
EOx:
platinized titanium
Current density (A/dm2)1.4
Operating time (min)15
[52]Cardboard (real)EC:
Al
Current density (mA/cm2)7.5Turbidity removal:
98.7%
TOC removal:
86.4%
COD removal:
85.3%
Operating time (min)60
Initial pH7
EOx:
Anode:
BDD
Cathode:
Stainless steel
Current density (mA/cm2)100
Operating time (min)180
Initial pH7.2
Na2SO4 concentration (g/L)5
[53]Soft drink
(real)
EC:
Copper
Current density (mA/cm2)51COD removal:
85%
TOC removal:
75%
TP removal:
89%
Total nitrogen:
84%
Color removal:
100%
Initial pH8
Time (min)20
EOx:
Anode:
Niobium substrate BDD
Cathode:
Copper
Current density (A/m2)30
pH6
Time (h)6
[54]Soluble coffee industrial plant
(real)
EC:
Anode:
Al
Cathode:
Graphite
Current density (A/m2)149.2Color removal:
100%
COD removal:
89%
TOC removal:
72%
SEEC:
45.28 kWh/m3
BOD5/COD:
0.6
Initial pH7.98
Treatment time (min)62
EOx:
Anode:
Graphite
Cathode:
Al
Current density (A/m2)500
Treatment time (min)53

### Table 4.

Sequential EC-EOx treatment results of various wastewaters for selected examples in the literature.

## 5. Conclusion

Due to the increasing need for freshwater resources and the large number of pollutants produced by the industries, it becomes more and more important to treat and reuse wastewater. For this purpose, effective, economical, and easy-to-operate wastewater treatment technologies need to be developed. Because of the fact that electrochemical treatment methods have various advantages, they are still investigated extensively. Besides being simple and effective, they are able to remove almost all kinds of pollutants at the same time. They are also eco-friendly and clean due to in situ generation of metal hydroxides and hydroxyl radicals. Many EC and EOx studies have been published on the treatment of industrial wastewaters such as olive mill, textile, dairy, pulp and paper, tannery, pharmaceutical, bilge, refinery, slaughterhouse, food processing, potato chips manufacturing, and leather. It is reported that EC and EOx methods have been successfully applied for removing COD, BOD, oil, phenol, lignin, phosphate, arsenic, color, turbidity, chromium, sulfate, total coliforms, boron, nickel, copper, and pharmaceuticals from wastewaters. Recent studies were briefly presented in this chapter, and it is observed that a minimum of 54.16% COD, 90.4% color, 90% BOD, 37% turbidity, 94.4% phenol, 42.9% phosphate, 72% TOC, and 97% TSS removal efficiencies and a maximum of 45.28 kWh/m3 SEEC were achieved by applying combined treatment. Since EC is a fast and efficient method for wastewaters containing suspended solids but also an inefficient method for the removal of persistent dissolved organic pollutants and EOx is able to mineralize persistent organic pollutants completely but also a slow and energy-consuming method for the removal of suspended solids, combining these two processes offers a practical hybrid by taking advantage of the synergistic effects. According to the results, it can be concluded that combined EC-EOx process is an efficient alternative for industrial wastewater treatment in terms of pollutant removal and more research on applications to the industrial wastewaters are required.

## Acknowledgments

This research was supported by Ankara University Scientific Research Projects Coordination Unit [grant numbers 16B0443001 and 14 L0443005].

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Baran Özyurt and Şule Camcıoğlu (August 29th 2018). Applications of Combined Electrocoagulation and Electrooxidation Treatment to Industrial Wastewaters, Wastewater and Water Quality, Taner Yonar, IntechOpen, DOI: 10.5772/intechopen.75460. Available from:

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