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Coherent Current States in Two-Band Superconductors

By Alexander Omelyanchouk

Submitted: October 7th 2010Reviewed: February 5th 2011Published: July 18th 2011

DOI: 10.5772/16280

Downloaded: 2397

1. Introduction

To present day overwhelming majority works on theory of superconductivity were devoted to single gap superconductors. More than 50 years ago the possibility of superconductors with two superconducting order parameters were considered by V. Moskalenko

Figure 1.

a. The structure of MgB2 and the Fermi surface of MgB2 calculated by Kortus et al. (Kortus et al., 2001). b. The coexistence of two complex order parameters (in momentum space).

(Moskalenko, 1959) and H. Suhl, B.Matthias and L.Walker (Suhl et al., 1959). In the model of superconductor with the overlapping energy bands on Fermi surface V.Moskalenko has theoretically investigated the thermodynamic and electromagnetic properties of two-band superconductors. The real boom in investigation of multi-gap superconductivity started after the discovery of two gaps in MgB2(Nagamatsu et al., 2001) by the scanning tunneling (Giubileo et al., 2001; Iavarone et al., 2002 ) and point contact spectroscopy (Szabo et al., 2001; Schmidt et al., 2001; Yanson & Naidyuk, 2004). The structure of MgB2and the Fermi surface of MgB2calculated by Kortus et al. (Kortus et al, 2001) are presented at Fig.1.a. The compound MgB2has the highest critical temperature Tc=39K among superconductors with phonon mechanism of the pairing and two energy gaps Δ17meVand Δ22,5meVatT=0. At this time two-band superconductivity is studied also in another systems, e.g. in heavy fermion compounds (Jourdan et al., 2004; Seyfarth et al., 2005), high-Tc cuprates (Kresin & Wolf, 1990), borocarbides (Shulga et al., 1998), liquid metallic hydrogen (Ashcroft, 2000; Babaev, 2002; Babaev et. al, 2004). Recent discovery of high-temperature superconductivity in iron-based compounds (Kamihara et al., 2008) have expanded a range of multiband superconductors. Various thermodynamic and transport properties of MgB2and iron-based superconductors were studied in the framework of two-band BCS model (Golubov et al., 2002; Brinkman et al., 2002; Mazin et al., 2002; Nakai et al., 2002; Miranovic et al., 2003; Dahm & Schopohl, 2004; Dahm et al., 2004; Gurevich, 2003; Golubov & Koshelev, 2003). Ginzburg-Landau functional for two-gap superconductors was derived within the weak-coupling BCS theory in dirty (Koshelev & Golubov, 2003) and clean (Zhitomirsky & Dao, 2004) superconductors. Within the Ginzurg-Landau scheme the magnetic properties (Askerzade, 2003a; Askerzade, 2003b; Doh et al., 1999) and peculiar vortices (Mints et al., 2002; Babaev et al., 2002; Gurevich & Vinokur, 2003) were studied.

Two-band superconductivity proposes new interesting physics. The coexistence of two distinctive order parameters Ψ1=|Ψ1|exp(iϕ1)and Ψ2=|Ψ2|exp(iϕ2)(Fig.1.b.) renewed interest in phase coherent effects in superconductors. In the case of two order parameters we have the additional degree of freedom, and the question arises, what is the phase shift δϕ=ϕ1ϕ2between Ψ1andΨ2? How this phase shift manifested in the observable effects? From the minimization of the free energy it follows that in homogeneous equilibrium state this phase shift is fixed at 0 orπ, depending on the sign of interband coupling. It does not exclude the possibility of soliton-like states δϕ(x)in the ring geometry (Tanaka, 2002). In nonequilibrium state the phases ϕ1and ϕ2can be decoupled as small plasmon oscillations (Leggett mode) (Legett, 1966) or due to formation of phase slips textures in strong electric field (Gurevich & Vinokur, 2006).

In this chapter we are focusing on the implication of the δϕ-shift in the coherent superconducting current states in two-band superconductors. We use a simple (and, at the same time, quite general) approach of the Ginsburg–Landau theory, generalized on the case of two superconducting order parameters (Sec.2). In Sec.3 the coherent current states and depairing curves have been studied. It is shown the possibility of phase shift switching in homogeneous current state with increasing of the superfluid velocityvs. Such switching manifests itself in the dependence j(vs)and also in the Little-Parks effect (Sec.3). The Josephson effect in superconducting junctions is the probe for research of phase coherent effects. The stationary Josephson effect in tunnel S1-I-S2 junctions (I - dielectric) between two- and one- band superconductors have been studied recently in a number of articles (Agterberg et al., 2002; Ota et al., 2009; Ng & Nagaosa, 2009). Another basic type of Josephson junctions are the junctions with direct conductivity, S-C-S contacts (C – constriction). As was shown in (Kulik & Omelyanchouk, 1975; Kulik & Omelyanchouk, 1978; Artemenko et al., 1979) the Josephson behavior of S-C-S structures qualitatively differs from the properties of tunnel junctions. A simple theory (analog of Aslamazov-Larkin theory( Aslamazov & Larkin, 1968)) of stationary Josephson effect in S-C-S point contacts for the case of two-band superconductors is described in Sec.4).

2. Ginzburg-Landau equations for two-band superconductivity.

The phenomenological Ginzburg-Landau (GL) free energy density functional for two coupled superconducting order parameters ψ1and ψ2can be written as






The terms F1and F2are conventional contributions from ψ1andψ2, term F12describes without the loss of generality the interband coupling of order parameters. The coefficients γand ηdescribe the coupling of two order parameters (proximity effect) and their gradients (drag effect) (Askerzade, 2003a; Askerzade, 2003b; Doh et al., 1999), respectively. The microscopic theory for two-band superconductors (Koshelev & Golubov, 2003; Zhitomirsky & Dao, 2004; Gurevich, 2007) relates the phenomenological parameters to microscopic characteristics of superconducting state. Thus, in clean multiband systems the drag coupling term (η) is vanished. Also, on phenomenological level there is an important condition, that absolute minimum of free GL energy exist: |η|<12m1m2(see Yerin et al., 2008).

By minimization the free energy F=(F1+F2+F12+H28π)d3rwith respect toψ1, ψ2and Awe obtain the differential GL equations for two-band superconductor


and expression for the supercurrent


In the absence of currents and gradients the equilibrium values of order parameters ψ1,2=ψ1,2(0)eiχ1,2are determined by the set of coupled equations


For the case of two order parameters the question arises about the phase difference ϕ=χ1χ2between ψ1andψ2. In homogeneous zero current state, by analyzing the free energy term F12 (3), one can obtain that for γ>0phase shift ϕ=0and for γ<0ϕ=π. The statement, that ϕcan have only values 0 or πtakes place also in a current carrying state, but for coefficient η0the criterion for ϕequals 0 or πdepends now on the value of the current (see below).

If the interband interaction is ignored, the equations (7) are decoupled into two ordinary GL equations with two different critical temperaturesTc1andTc2. In general, independently of the sign ofγ, the superconducting phase transition results at a well-defined temperature exceeding both Tc1andTc2, which is determined from the equation:


Let the first order parameter is stronger then second one, i.e.Tc1>Tc2. Following (Zhitomirsky & Dao, 2004) we represent temperature dependent coefficients as


Phenomenological constants a1,2,a20and β1,2,γcan be related to microscopic parameters in two-band BCS model. From (8) and (9) we obtain for the critical temperatureTc:


For arbitrary value of the interband coupling γEq.(6) can be solved numerically. Forγ=0, Tc=Tc1and for temperature close to Tc(hence forTc2<TTc) equilibrium values of the order parameters areψ2(0)(T)=0,ψ1(0)(T)=a1(1T/Tc)/β1. Considering in the following weak interband coupling, we have from Eqs. (6-9) corrections γ2to these values:


Expanding expressions (11) over (1TTc)1we have conventional temperature dependence of equilibrium order parameters in weak interband coupling limit


Considered above case (expressions (10)-(12)) corresponds to different critical temperatures Tc1>Tc2in the absence of interband couplingγ. Order parameter in the second band ψ2(0)arises from the “proximity effect” of stronger ψ1(0)and is proportional to the value ofγ.

Consider now another situation, which we will use in the following as the model case. Suppose for simplicity that two condensates in current zero state are identical. In this case for arbitrary value of γwe have


3. Homogeneous current states and GL depairing current

In this section we will consider the homogeneous current states in thin wire or film with transverse dimensionsdξ1,2(T),λ1,2(T), where ξ1,2(T)and λ1,2(T)are coherence lengths and London penetration depths for each order parameter, respectively. This condition leads to a one-dimensional problem and permits us to neglect the self-magnetic field of the system. (see Fig.2). In the absence of external magnetic field we use the calibrationA=0.

Figure 2.

Geometry of the system.

The current density j and modules of the order parameters do not depend on the longitudinal direction x. Writing ψ1,2(x)as ψ1,2=|ψ1,2|exp(iχ1,2(x))and introducing the difference and weighted sum phases:


for the free energy density (2)-(4) we obtain




The current density j in terms of phases θand ϕhas the following form


Total current j includes the partial inputs j1,2and proportional to ηthe drag currentj12.

In contrast to the case of single order parameter (De Gennes, 1966), the condition divj=0does not fix the constancy of superfluid velocity. The Euler – Lagrange equations for θ(x)and ϕ(x)are complicated coupled nonlinear equations, which generally permit the soliton like solutions (in the case η=0they were considered in (Tanaka, 2002)). The possibility of states with inhomogeneous phase ϕ(x)is needed in separate investigation. Here, we restrict our consideration by the homogeneous phase difference between order parametersϕ=const. For ϕ=constfrom equations it follows that θ(x)=qx(q is total superfluid momentum) andcosϕ=0, i.e. ϕequals 0 orπ. Minimization of free energy for ϕgives


Note, that now the value ofϕ, in principle, depends on q, thus, on current density j. Finally, the expressions (16), (18) take the form:


We will parameterize the current states by the value of superfluid momentumq, which for given value of jis determined by equation (21). The dependence of the order parameter modules on qdetermines by GL equations:


The system of equations (21-23) describes the depairing curve j(q,T)and the dependences |ψ1|and |ψ2|on the current jand the temperature T. It can be solved numerically for given superconductor with concrete values of phenomenological parameters.

In order to study the specific effects produced by the interband coupling and dragging consider now the model case when order parameters coincide at j=0(Eqs. (13), (14)) but gradient terms in equations (4) are different. Eqs. (21)-(23) in this case take the form


Here we normalize ψ1,2on the value of the order parameters at j=0(14), jis measured in units of22e|γ|+|α|β|α|m1, qis measured in units of22m1|α|, γ˜=γ|α|, η˜=2ηm1,k=m1m2. If k=1order parameters coincides also in current-carrying state f1=f2=fand from eqs. (24, 25) we have the expressions


which for γ˜=η˜=0are conventional dependences for one-band superconductor (De Gennes, 1966) (see Fig. 3 a,b).

Figure 3.

Depairing current curve (a) and the graph of the order parameter modules versus current (b) for coincident order parameters. The unstable branches are shown as dashed lines.

For k1depairing curve j(q)can contain two increasing with q stable branches, which corresponds to possibility of bistable state. In Fig. 4 the numerically calculated from equations (24,25) curve j(q)is shown for k=5andγ˜=η˜=0.

The interband scattering (γ˜0) smears the second peak inj(q), see Fig.5.

If dragging effect (η˜0) is taking into account the depairing curve j(q)can contain the jump at definite value of q(for k=1see eq. 34), see Fig.6. This jump corresponds to the switching of relative phase difference from 0 toπ.

Figure 4.

Dependence of the current j on the superfluid momentum q for two band superconductor. For the value of the current j=j0 the stable (∘) and unstable (·) states are depicted. The ratio of effective massesk=5, andγ˜=η˜=0.

Figure 5.

Depairing current curves for different values of interband interaction: γ˜=0(solid line), γ˜=0.1(dotted line) and γ˜=1 (dashed line). The ratio of effective massesk=5, andη˜=0.

Figure 6.

Depairing current curves for different values of the effective masses ratio k=1 (solid line), k=1.5(dotted line) and k=5 (dashed line). The interband interaction coefficient γ˜=0.1 and drag effect coefficientη˜=0.5.

4. Little-Parks effect for two-band superconductors

In the present section we briefly consider the Little–Parks effect for two-band superconductors. The detailed rigorous theory can be found in the article (Yerin et al., 2008). It is pertinent to recall that the classical Little–Parks effect for single-band superconductors is well-known as one of the most striking demonstrations of the macroscopic phase coherence of the superconducting order parameter (De Gennes, 1966; Tinkham, 1996). It is observed in open thin-wall superconducting cylinders in the presence of a constant external magnetic field oriented along the axis of the cylinder. Under conditions where the field is essentially unscreened the superconducting transition temperature TcΦ(Φis the magnetic flux through the cylinder) undergoes strictly periodic oscillations (Little–Parks oscillations)


where TcΦTcΦ|Φ=0and Φ0=πc/eis the quantum of magnetic flux.

How the Little–Parks oscillations (28) will be modified in the case of two order parameters with taking into account the proximity (γ) and dragging (η) coupling? Let us consider a superconducting film in the form of a hollow thin cylinder in an external magnetic field H (see Fig.6).

We proceed with free energy density (20), but now the momentum qis not determined by the fixed current density j as in Sec.3. At given magnetic flux Adl=Hdσ=Φthe superfluid momentum qis related to the applied magnetic field


At fixed flux Φthe value of qtake on the infinite discrete set of values forn=0,±1,±2,.... The possible values of nare determined from the minimization of free energyF[|ψ1|,|ψ2|,q]. As a result the critical temperature of superconducting film depends on the magnetic field. The dependencies of the relative shift of the critical temperature Δtc(TcTcΦ)/Tcfor different values of parameters γ,β,Rwere calculated in (Yerin et al., 2008). The dependence of Δtc(Φ)as in the conventional case is strict periodic function of Φwith the period Φ0(contrary to the assertions made in Askerzade, 2006). The main qualitative difference from the classical case is the nonparabolic character of the flux dependence Δtc(Φ)in regions with the fixed optimal value ofn. More than that, the term (γη2q2)sign(γη2q2)in the free energy (19) engenders possibility of observable singularities in the functionΔtc(Φ), which are completely absent in the classical case (see Fig.8.).

Figure 7.

Geometry of the problem.

Figure 8.

Formula: Eqn199.wmf>for the case where the bands 1 and 2 have identical parameters and values of Δtc(Φ) are indicated.

5. Josephson effect in two-band superconducting microconstriction

In the Sec.3 GL-theory of two-band superconductors was applied for filament’s lengthη˜. Opposite case of the strongly inhomogeneous current state is the Josephson microbridge or point contact geometry (Superconductor-Constriction-Superconductor contact), which we model as narrow channel connecting two massive superconductors (banks). The length Land the diameterLof the channel (see Fig. 9) are assumed to be small as compared to the order parameters coherence lengthsd.

Figure 9.

Geometry of S-C-S contact as narrow superconducting channel in contact with bulk two-band superconductors. The values of the order parameters at the left (L) and right (R) banks are indicated

For ξ1,ξ2we can solve one-dimensional GL equations (5) inside the channel with the rigid boundary conditions for order parameters at the ends of the channel.

In the casedLwe can neglect in equations (5) all terms except the gradient ones and solve equations:


with the boundary conditions:


Calculating the current density ψ1(0)=ψ01exp(iχ1L),ψ2(0)=ψ02exp(iχ1R),ψ1(L)=ψ01exp(iχ2L),ψ2(L)=ψ02exp(iχ1R).in the channel we obtain:


The current density j21=η4eLψ02ψ01sin(χ2Rχ1L).(32) consists of four partials inputs produced by transitions from left bank to right bank between different bands. The relative directions of components jdepend on the intrinsic phase shifts in the banks jikand δϕL=χ1Lχ2L(Fig.10).

Figure 10.

Current directions in S-C-S contact between two-band superconductors. (a) – there is no shift between phases of order parameters in the left and right superconductors; (b) - there is the δϕR=χ1R−χ2R-shift of order parameters phases at the both banks ; (c) –π-shift is present in the right superconductor and is absent in the left superconductor; (d) –π-shift is present in the left superconductor and is absent in the right superconductor.

Introducing the phase difference on the contact πwe have the current-phase relation φ=χ1Rχ1Lfor different cases of phase shifts j(ϕ)in the banks:


The critical current jjcsinϕ=2eL(ψ012m1+ψ022m2)sin(ϕ)in cases a) and b) is positively defined quadratic form of jcand ψ01forψ02. In cases c) and d) the value of |η|<12m1m2can be negative. It corresponds to the so-called jcjunction (see e.g. (Golubov et. al, 2004)) (see illustration at Fig.11).

Figure 11.

Current-phase relations for different phase shifts in the banks.

This phenomenological theory, which is valid for temperatures near critical temperatureπ, is the generalization of Aslamazov-Larkin theory (Aslamazov & Larkin, 1968) for the case of two superconducting order parameters. The microscopic theory of Josephson effect in S-C-S junctions (KO theory) was developed in (Kulik & Omelyanchouk, 1975; Kulik & Omelyanchouk, 1978;) by solving the Usadel and Eilenberger equations (for dirty and clean limits). In papers (Omelyanchouk & Yerin, 2009; Yerin & Omelyanchouk, 2010) we generalized KO theory for the contact of two-band superconductors. Within the microscopic Usadel equations we calculate the Josephson current and study its dependence on the mixing of order parameters due to interband scattering and phase shifts in the contacting two-band superconductors. These results extend the phenomenological theory presented in this Section on the range of all temperaturesTc. The qualitative feature is the possibility of intermediate between 0<T<Tcand sinϕbehavior sinϕat low temperatures (Fig.12).

Figure 12.

The possible current-phase relations j(ϕ) for hetero-contact withj(ϕ).

6. Conclusion

In this chapter the current carrying states in two-band superconductors are described in the frame of phenomenological Ginzburg-Landau theory. The qualitative new feature, as compared with conventional superconductors, consists in coexistence of two distinct complex order parameters δϕR=0,δϕL=πandΨ1. It means the appearing of an additional internal degree of freedom, the phase shift between order parameters. We have studied the implications of the Ψ2-shift in homogeneous current state in long films or channels, Little-Parks oscillations in magnetic field, Josephson effect in microconstrictions. The observable effects are predicted. Along with fundamental problems, the application of two band superconductors with internal phase shift in SQUIDS represents significant interest (see review (Brinkman & Rowell, 2007).


The author highly appreciates S. Kuplevakhskii and Y.Yerin for fruitful collaborations and discussions. The research is partially supported by the Grant 04/10-N of NAS of Ukraine.

© 2011 The Author(s). Licensee IntechOpen. This chapter is distributed under the terms of the Creative Commons Attribution-NonCommercial-ShareAlike-3.0 License, which permits use, distribution and reproduction for non-commercial purposes, provided the original is properly cited and derivative works building on this content are distributed under the same license.

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Alexander Omelyanchouk (July 18th 2011). Coherent Current States in Two-Band Superconductors, Superconductivity - Theory and Applications, Adir Moyses Luiz, IntechOpen, DOI: 10.5772/16280. Available from:

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