The kinetics constants of the Ni (II) adsorption onto GNS/MnO2 composite.
Abstract
The increasing water demand and the worldwide shortage of clean water call for new technologies for wastewater treatment, of which sorption is recognized as simplest and efficient method for all major water pollutants, including heavy metal ions, organic dyes and organic solvents. In this context, graphene, an atomically thin two-dimensional hexagonal arrays of carbon atoms, and its analogs have been visualized as ultimate materials for the separation of pollutants from water due to properties such as superhydrophobicity, superoleophilicity, chemical-environmental-thermal stability, chemical manipulability, controllable morphology, texture, porosity and accessible surface area, facile processing, low density, biocompatibility and low-cost synthesis from a variety of abundant carbonaceous precursors. This chapter begins with an introduction of water purification, related processes and fundamentals of adsorption and absorption phenomenon. The next section emphasizes the importance and advantages of graphene as sorbent, brief about its synthesis, types of graphene-based composites/hybrid systems and their synthesis strategies. The last section throws light on the performance of graphene-based foams, aerogels and composites/hybrids for the separation of metal ions, organic dyes and various oils/organic solvents, supported by comprehensive literature account. Finally, the chapter concludes with the comments on the current status, major challenges and future scope in the direction.
Keywords
- sorption
- adsorption
- absorption
- graphene oxide (GO)
- reduced graphene oxide (RGO)
- superhydrophobicity
- superoleophilicity
1. Introduction
In the current scenario of global socioeconomic development, environmental conservation is a major concern and numerous initiatives have been undertaken to handle air, water, soil, noise and electromagnetic pollutions [1–13]. In particular, water pollution is recognized as a big threat for society, and enormous efforts are underway to prevent contamination of freshwater and to purify contaminated water. The water pollution is considered as an offshoot of scientific and technological growth, industrial revolutionization and ignorance/unavailability of efficient waste management strategies. The discharge of domestic and industrial effluents/wastewater into water bodies not only makes water sources unfit for drinking purpose but also adversely affects its utility for pharmaceutical, agricultural, chemical and industrial applications. In particular, dumping of untreated wastewater at domestic and industrial levels (e.g., by paper, textile, food, leather and chemical industries) introduces hazardous substances, for example, dyes, chromium compounds, heavy metals such as copper, arsenic, lead, cadmium, mercury, nickel, cobalt and certain toxic organic chemicals, into rivers, lakes and other freshwater bodies [10,14–18]. These contaminants affect the photosynthesis in aquatic systems and disturb the self-purification mechanism [19] of water with extinction of some aquatic species as one of its worst consequence. Their acute exposure poses serious health hazards for human, for example, organic dyes and heavy metal ions are known to exert harmful effects such as an increased heart rate, vomiting, shock, cyanosis, jaundice, tissue necrosis, bone defects, renal damage, paralysis and even death [20–22] in some cases.
The leakage and spilling of industrial chemicals and oils into water bodies also disturb the water quality and adversely affect the aquatic life. The large-scale oil spill accidents (occurring during onshore/offshore handling of oils) are identified as catastrophic and devastating situation for marine life. It also adversely affects the infrastructure (e.g., beaches), underwater ecosystem (fauna and flora) and badly affects the economies in terms of losses in tourism, fishing, seafood sectors and expenditures for the restoration of the same [23–31]. Therefore, in the past half-century, an extensive research was carried out across the globe to develop a number of efficient and smart materials/technologies for the effective treatment of wastewater containing various pollutant, especially metal ions, dyes, oils and solvents [32–42,17,43–45]. Among currently available mechanical, chemical and biological water purification processes such as coagulation, flocculation, ozone treatment, chemical oxidation, membrane filtration, ion exchange, photocatalysis and sorption [46–56], sorption (adsorption-absorption) practices emerged as most preferred commercially viable solution, owing to specific advantages in terms of simplicity of process, cost-effectiveness, environmental friendliness, applicability to diversified pollutants and low-energy consumption. In particular, adsorption practices are the sole most promising alternates in the isolation of metal ions that are otherwise very difficult to remove by means of photocatalysis and membrane filtration [57,58]. However, adsorption has also been demonstrated as viable solution for the removal of hazardous organic dyes from the wastewater streams of various industries. In contrast, absorption practices are prevalent in selective removal of nonpolar (hydrophobic) pollutants such as mineral or vegetable oils, crude oils and common organic solvents [28,59,60] from their aqueous emulsion or floating layers over water.
In the past, a number of adsorbing-absorbing materials have been exploited for wastewater treatment, including zeolite [61], silica gel [62], activated alumina [63], fly ash [64], polymeric and carbon-based materials [65–68]. Among them, carbon-based systems with environmental compatibility, large-scale availability, high porosity, large specific surface area and low cost are the most promising. Activated carbon derivatives with high degree of porosity and large specific surface area (600–2000) m2g−1 are used in adsorption-based water purification for many years [65,69–72]. However, essentiality of their surface activation to enhance adsorption capacity and release of secondary pollutants in the form of fine particles in water limited their utility. The new members of the carbon family fullerene, carbon nanotube (CNT) and graphene have truly revolutionalized the field with graphene, the latest member of the family, seems to be most promising alternate owing to its extraordinary mechanical, thermal & chemical properties coupled with very high specific surface area, inherent hydrophobicity, tunable chemical structure, cost-effective and scalable synthesis [10,73–78]. In this context, the quest for the development of highly efficient adsorbents and absorbents and advancements in graphene science and technology fuelled numerous efforts for designing/selecting highly efficient graphene-based sorbents, understanding their pollutant-capturing mechanism and assessing their actual purification performance [16,47,57,79–83,43].
It is worth mentioning that though sorption is a broad term, the underlying adsorption and absorption subprocesses are surface- and bulk-related phenomenon, respectively, and their governing factors are entirely different. For example, adsorption process depends on parameters such as nature of adsorbent-adsorbate pair, accessible surface area of adsorbent, concentration of pollutants, temperature, pH, etc [15,45,48,84]. In contrast, absorption is regulated by pore size/volume of the sorbent, its texture and wettability characteristics along with physical attributes of absorbate species and absorbent-absorbate interfacial properties [75,85,86]. Therefore, detailed understanding of adsorption and absorption phenomenon, related terminology, important parameters and governing empirical equations is necessary before identifying and designing a suitable graphene-based adsorbent or absorbent.
2. Adsorption
The term adsorption implies the presence of an excess concentration of molecular species (gas or liquid), known as adsorbate (Figure 1), at the surface of porous solid (i.e., at solid-fluid interface), known as adsorbent, compared to its concentration in bulk of the adsorbent.
Adsorption arises due to the fact that the surface particles of the adsorbent are not in the same environment as the particles inside the bulk. In solids, unsatisfactory valence forces of surface atoms, activate the surface. At these activated surfaces, other substances stick feasibly with a decrease in the entropy (
Therefore, adsorption is essentially an exothermic process and the magnitude of change in enthalpy (Δ
The term adsorption involves the capture of adsorbate exclusively over the surface of adsorbent. Therefore, on the basis of type interaction between adsorbent and adsorbate (i.e., physical or chemical), adsorption can be classified into two main categories, namely physisorption that involves van der Waals binding forces and chemisorption [87] wherein a strong chemical bond formation takes place between adsorbent and adsorbate. Adsorption is a complex phenomenon and requires systematic studies to understand completely its mechanism, kinetics and the thermodynamic parameters that influence adsorption capacity and rate. In particular, homogeneous and heterogeneous adsorption types have been identified with the involvement of single or multilayer adsorption of adsorbates [87]. To understand such processes and to account for the equilibrium adsorbate concentration over adsorbent and bulk of solution, several adsorption isotherms and related governing equations have been proposed, which are described in the following section.
2.1. Freundlich adsorption isotherm
Freundlich, in 1909, gave an empirical relationship between the quantity of a substance adsorbed by unit mass of solid adsorbent and the equilibrium concentration of adsorbate solution at a particular temperature for heterogeneous surfaces, which can be expressed by the following Eq. (2) [70]:
Plot of log(
2.2. Langmuir adsorption isotherm
Langmuir derived a quantitative expression for variation in the extent of adsorption with concentration, by assuming the equilibrium nature of adsorption and fixed number of equivalent energy adsorbing sites on adsorbent surface [70] .This model is applicable to homogeneous surfaces and assumes that only monolayer of adsorbate molecules formed on adsorbent surface and there is no interaction between the adsorbate species after adsorption. This isotherm represents the equilibrium distribution of a material in solid and liquid or gas phases and can be mathematically expressed as follows [70]:
By plotting 1/
This constant explains the characteristic features of Langmuir’s adsorption isotherm, as it indicates the shape of isotherm/energy of the adsorption. The magnitude of
2.3. Temkin adsorption isotherm
According to Temkin adsorption isotherm, energy of the adsorption is a linear function of adsorbent surface coverage by assuming the indirect interaction of adsorbent and adsorbate [18]. The heat of adsorption of adsorbate molecules decreases with increase in the surface coverage of adsorbent [18]. This model can be represented by the following mathematical equations:
A number of other adsorption isotherm models, namely BET isotherms [88], Dubinin-Radushkevich isotherm [89], Toth adsorption isotherms [90] are proposed to describe the adsorption phenomenon. Since precise mechanism of adsorption in solution phases is still not known to a greater extent; therefore, a single adsorption model is not applicable universally. The validity of these models generally changes from one adsorbent-adsorbate system to another and also with pH of solution, nature of solvent, ionic strength, etc. [15,91,18]. Freundlich and Langmuir adsorption isotherms are the two very common approaches generally used in the experimental practices. Since the use of adsorption isotherm equations essentially involves the ‘curve-fitting’ method, the model with higher value of regression coefficient is considered to be more valid than the one with lower regression coefficient value.
2.4. Thermodynamic treatment of adsorption isotherm
Since every spontaneous process proceeds by characteristic changes in thermodynamic parameters, thermodynamic parameters, such as Gibbs free energy change (Δ
The values of the Δ
2.5. Kinetics of adsorption
Thermodynamics deals with spontaneity of the processes, but it does not tell about rapidity (e.g., adsorption rates) of the adsorption process and its mechanistic details. Therefore, adsorption kinetic studies are employed for better understanding of adsorption mechanism and its rate. Since adsorption in solution phase involves more than two components viz. adsorbate, solvent and adsorbent, depending upon the adsorption system, several kinetic models have been proposed.
2.5.1. Pseudofirst-order kinetic model
In 1898, Lagergren proposed the pseudofirst-order kinetic model [15,92] for the adsorption of adsorbate particles from solution by a solid adsorbent and proposed the following governing mathematical Eq. (12):
2.5.2. Pseudosecond-order kinetic model
A more appropriate kinetic model for solution phase adsorption process is proposed by Ho and McKay [95] who showed that the rate of adsorption depends upon the adsorption capacity of adsorbate on solid adsorbent rather than its concentration in the solution phase. Eq. (13) was proposed to investigate the kinetics [96]:
For a better look into the mechanistic pathways, one should accounts the three basic steps by which adsorption proceeds viz. (i) the movement of adsorbate particles through bulk solution to the external surface of adsorbent, (ii) diffusion of adsorbate particles in the pores of adsorbent (interparticle diffusion) and (iii) adsorption of the adsorbate particles on the active sites of adsorbent. Any of the above steps can be rate-determining step.
For the identification of various steps involved in the adsorption process, interparticle diffusion model is used, which is expressed as follows [97]:
3. Absorption
Absorption is a phenomenon in which chemical substances, such as atoms, molecules and ions, enter into the bulk phase of absorbent and distributed throughout the bulk of absorbent. The process of absorption can be either physical [98] or chemical [98] depending upon the interaction between the absorbent and the absorbing species. Physical absorption is sometimes referred as a nonreactive process, for example, the absorption of air oxygen in water at air-water interface [99]. Such absorption phenomenon is highly temperature and pressure dependent. In practice, the absorbing capacity of the absorbent depends upon the interfacial surface area, contact time and the wettability characteristics of the both substances. For example, superhydrophilic materials preferentially absorb water molecules from a mixture of several substances, whereas superhydrophobic surfaces (e.g., lotus leaf) tend to exclude water. A reactive or chemical absorption process, which takes place by means of some chemical reactions, for example, the absorption of carbon dioxide by sodium hydroxide, occurs via the formation of sodium carbonate [99]. Since the absorption of adsorbate occurs through the surface of absorbent, surface properties of the solid absorbent are most critical in deciding their absorption capacity, absorption rate, etc. These properties include surface energy [100], surface wettability, [100] topological roughness [101] and contact angles [101]. For absolutely flat surfaces, surface wettability can be determined using Young’s equation that correlates the interfacial surface energies with contact angle value by the following equation:
According to Wenzel’s theory, no air bubbles are present between the liquid and solid surface. Hence, the liquid floods the roughness introduced channels (Figure 2b) leading to perfect wetting of the underlying surface, so that the contact angle of smooth (nontextured) and structured (rough) surfaces satisfy the following equation:
In Cassie’s model, due to the presence of air molecules present between the surfaces of two phases (i.e., within roughness introduced channels), solid surface is not perfectly wetted by liquid (Figure 2c). Hence, the contact angles of structured (rough) surface (
4. Synthesis of graphene-based hybrids and composites
A number of strategies have been used for the synthesis of variety of adsorbents and absorbents constituted by graphene-based hybrids and composites.
4.1. Dip-coating process
The dip coating is actually a two-step process (Figure 3) involving coating of graphene oxide (GO) over substrate (foam/particulate-solid) followed by chemical reduction of coating to reduced GO (RGO). In the typical coating process, sponge/foam substrate is immersed inside aqueous dispersion of GO for specified time and dried to form GO-coated foam. The concentration of GO solution and number of dip-dry cycles may be varied to change the coating thickness and uniformity and ultimately the GO loading. Once the desired coating/loading is achieved, the foam may be chemically reduced by exposure to chemical reducing agents such as hydrazine, ascorbic acid or other systems, resulting in the formation of RGO-coated foam. The formation of GO and RGO coatings are evident from the change in the shade of foam to brownish and blackish, respectively. The dip-coating process involved simple physical interactions between GO/RGO coating and foam and possess disadvantages in terms of coating uniformity and its poor adherence. In it modified version involving chemical grafting, suitable functionalized derivative of GO is chemically grafted over substrate (foam/particulate-solid) carrying complimentary functional groups. Such foams display better coating uniformity and adherence compared to dip-coating process.
4.2. Surface coating by in situ generation of graphene via thermal treatment
In such process, substrate material (e.g., sand) is treated with suitable (carbonizable) graphene precursor (e.g., sugar solution) leading to surface coating (Figure 4) with precursor (sugar with sand) upon drying. Further, high-temperature treatment leads to the carbonization of coated precursor and formation of graphene-/sand-type hybrids [106] (GSCs).
4.3. In situ incorporation process
In this process, the aqueous dispersion of GO (colloidal solution) is mixed with suitable secondary phase (CNTs, inorganic nanoparticles such as Fe23/Fe3O4) and subjected to further processing to form 3D self-assembled structures and cause reduction of GO phase to RGO.
For example, GO/CNTs mixed solution is subjected to freeze drying followed by chemical reduction to form RGO/CNTs hybrid-based aerogels (Figure 5). The presence of CNTs prevents the stacking of RGO phase and provides improved porosity and mechanical strength to the aerogel.
Similarly, GO/Fe3O4/glucose system is hydrothermally treated at high temperature to form the RGO/Fe3O4-based hybrids in a single step (Figure 6). Here, the Fe3O4 phase checks the RGO agglomeration, improves porosity and allows magnetic separation of the hybrids from the water (after the completion of uptake of pollutant).
4.4. Hydrothermal process in the presence of gelation-causing agent
This involves the hydrothermal treatment of GO dispersion in the presence of suitable gelation agent, for example, chitosan leading to the formation of hydrogel [107], which may lyophilized or supercritical dried to form the corresponding hybrid aerogel.
For example, mixed aqueous dispersion of GO and chitosan may be hydrothermally converted into 3D self-assembled macroscopic hydrogel (Figure 7), which consists of highly porous structure as evident from the scanning electron microscope (SEM) investigations of its lyophilized version.
5. The water purification performance of graphene-based hybrids and composites
As already discussed in previous section, due to its high specific surface area, tunable morphological features, controllable porosity, inherent hydrophobicity and oleophilicity, chemical manipulability, tunable surface functionality, facile processing via chemical route and good thermal/environmental/chemical stability, graphene has been widely used to design variety of sorbents to selectively remove the pollutants via adsorption (e.g., for metal ions or organic dyes) or absorption (e.g., for oils or organic solvents) processes [15,17,18,43,53,79,81,91,97,105,108–111]. The contaminant capture ability, including the affinity, toward particular type of contaminant, capturing mechanism and actual purification performance of synthesized graphene-based platforms depends upon the presence of specific set of above properties. This section provides comprehensive account of the purification performance of the graphene-based hybrids and composites for three major classes of pollutants viz. metal ions, organic dyes and oils/organic solvents, with emphasis on the role of above-mentioned specific properties and their correlation to observed performance [47,52,106,112].
5.1. Adsorption of metal ions
It has been well established that the presence of excessive amounts of heavy metals such as Hg (mercury), Pb (lead), As (Arsenic), Cr (chromium), Cu (copper), Ni (nickel), Cd (Cadmium), Se (selenium), etc. in water has a catastrophic effects on living systems and as they degrade the quality of water for other practices like in industries and agricultural sector. The main sources of these metal ions in water systems include effluents of various processes such as galvanization, batteries’ waste disposal, mining operations and paper/textile industries, tanneries, etc. [74,91]. Therefore, the removal of above metal ions from the wastewater streams is very important and several efforts in the direction are made using graphene-based adsorbents.
Chandra et al. synthesized magnetite (Fe3O4)/reduced graphene oxide (M-RGO) composites [17] and demonstrated their good binding affinity toward As(III) and As(V) ions. The presence of Fe3O4 phase enable easy removable of spent adsorbent from water after completion of adsorption of As ions. The composites displayed arsenic removal efficiency (>99.9%) with maximum adsorption capacity (Figure 8b) of 13.10 mg/g and 5.83 mg/g for As(V) and As(III), respectively.
The authors plotted the adsorption isotherm (Figure 8a) and fitted kinetic data (Figure 8c and 8d) into pseudosecond-order kinetic model and showed the applicability of the model on adsorption process. They also outlined the optimum temperature (Figure 8e) for maximum adsorption capacity. The difference in adsorption mechanism of As(V) and As(III) on M-RGO composites was observed by studying the effect of solution pH (Figure 8f) on adsorption capacity. An increase in the adsorption of As(III) (present as H3AsO4 arsenous acid) in basic conditions ruled out the electrostatic interactions between positively charged adsorbent and negatively charged arsenious acid. Rather, surface complexation of As(III) ions is responsible for very high adsorption capacity in alkaline conditions. On the other hand, As(V) ions present as [H2AsO3]− species) are electrostatically adsorbed by the adsorbent surfaces at low pH values. Wang et al. [74] exploited the surface area and charge density of graphene oxide sheets in the removal of cadmium and cobalt ions. They have studied the sorbing properties of graphene oxide nanosheets for the removal of Cd(II) and Co(II) ions from aqueous solutions at different pH values and showed that the adsorption of the Co(II) ions increases with increase in the pH of solution reaching maximum at pH>9. In case of Cd(II) ions, 98% adsorption of ions occurred at pH>9 mainly due to increase in negative surface charge density of graphene nanosheets (with an increase in the pH of solution) [74], which electrostatically adsorb the positively charged metal ions. Expanding the work in this area, Fan et al. [113] fused the acid resistant, magnetic cyclodextrin with GO nanosheets (MCGN) for enhancing the adsorption capacity of the composite for Cr(VI) ions (Figures 9 and 10).
The adsorbents work better under slightly acidic conditions with good recyclability, making it a good choice for heavy metal ions removal as shown in Figure 11.
The selectivity of adsorbent for a specific adsorbate is highly desirable. Hao et al. [114] synthesized a SiO2-graphene composite and specifically adsorb Pb(II) ions from solution. The authors observed that adsorption capacity is highly dependent on the ionic strength of solution and decrease with ionic strength due to completion between various ions for adsorbing sites. Luo et al. [82] highlighted the performance of heavy metal salts such as ZrO2 hybridized with graphene oxide for the removal of As(III) and As(V) ions. This composite showed ionic strength independent adsorption behavior with high adsorption capacities of 95.15 mg/g and 84.89 mg/g for As(III) and As(v) ions, respectively, with good recyclability. Ren et al. [81] outlined the role of temperature of solution in regulating adsorption. The graphene-MnO2 composite prepared by them for the removal of Ni(II) ions increase its adsorption capacity by a factor of 0.7 upon changing temperature from 298 K to 318 K. The kinetic parameters obtained from Table 1 suggested that the pseudosecond-order kinetic model is more appropriate than pseudofirst-order kinetic model. Langmuir adsorption isotherms parameters are given in Table 2 at various temperatures, which shows the increase in adsorption capacity at higher temperatures.
Adsorbents | ( |
Pseudofirst-order equation | Pseudosecond-order equation | ||||
---|---|---|---|---|---|---|---|
( |
( |
||||||
GNS/MnO2 | 42.855 | 28.372 | 0.00072 | 0.8672 | 46.447 | 0.00149 | 0.9993 |
Temperature ( |
GNS/MnO2 | ||
---|---|---|---|
298 | 46.55 | 0.333 | 0.995 |
308 | 60.31 | 0.310 | 0.991 |
318 | 66.01 | 0.558 | 0.999 |
A systematic study was done by Liu et al. [45] for the adsorption of Co(II) ions on magnetite-graphene composite (Figure 12).
The effect of ionic strength on adsorption capacity is negligible as shown in Figure 12a. But the presence of foreign ions significantly affected the adsorption behavior of the adsorbent. The pH of solution higher than 8.5 was favorable of maximum adsorption capacity. Zhou et al. [79] also reported the dependence of adsorption capacity of graphene composites on pH of solution. The material showed decreased affinity for Cr(IV) ions at higher pH as hydroxyl ion compete with the CrO42− ions for adsorbing sites [5]. Such studies are also reported by other groups to show how metal ion compete for adsorbing sites in the environment of excessive hydroxyl ions and hydronium ions [115]. It can be concluded from the discussion earlier that graphene-based materials are highly promising for the removal of heavy metal ions from wastewater systems.
5.2 Adsorption of dyes
Synthetic organic dyes that represent important color imparting ingredient of leather, paper, textile and rubber industries are also present in significant amount in their wastewater streams [22]. These dye stuffs have serious health hazards for both humans and aquatic systems [21,116]. In recent times, graphene analogs, including GO- or RGO-based sponges, composites and hybrids, have been successfully employed for the removal of toxic dyes from wastewater.
Liu et al. [47] used a centrifugal evaporator (Figure 13a) to synthesize GO-based sponge (Figure 13b) consisting of 3D interconnected network of graphene layers and demonstrated their potential for the removal of cationic dyes such as methylene blue (MB) and methyl violet (MV) with removal efficiency of 99.1 and 98.8%, respectively, with equilibrium reaching within 2 min. It has been highlighted that the microporous structure of GO sponge (Figure 13c), high negative charge density (due to rich oxygen functionalities) mediated cation-anion-type interactions, π-π stacking interactions between dye backbone and adsorbent and high specific surface area (|48.4 m2/g), collectively contribute toward the excellent dye adsorption capacity (Figure 13d), that is, 397 mg/g and 467 mg/g for MB and MV, respectively (Figure 13).
The effect of stirring (Figure 13e), temperature (Figure 13f) and pH (Figure 13g) on the adsorption rate and capacity have also been investigated, with the observation of increase in these parameters favoring adsorption rate and capacity. Once the adsorption is complete, spent adsorbent has to be removed from purified water by filtration process, which is not only bit cumbersome but also involve risks of recontamination. Gupta et al. [106] prepared sugar-derived graphene sand composite (GSC) consisting of graphene-coated sand particles (Figure 14a and b) via thermal processing. This cost-effective active adsorbent material-packed column (Figure 14c) showed good R6G dye removal efficiency with adsorption capacity of 50–55 mg/g. The time-dependent adsorption studies were also carried out to understand the system kinetics (Figure 14).
The authors highlighted the dependence of adsorption characteristics on GSC-heating temperature (Figure 14d) and adsorbent content (Figure 14e). The kinetic data were examined in terms of Lagergren pseudofirst-order (Section 2.5.1) and Ho’s pseudosecond-order (Section 2.5.2) kinetic models [95] and the fitted data (inset of Figure 14f) showed that a pseudosecond-order equation is more appropriate in describing the experimental data. Li et al. [84] synthesized a Mg(OH)2-RGO composite(GMC) to improve the adsorption capacity by increasing the porosity of the adsorbent. They pointed that surface charge density and π conjugation play an important role for high removal efficiency of GMC for cationic dyes such as MB. The presence of Mg(OH)2 ensured the formation of mesoporous structure (Figure 15 calculation of BET surface area and pore size distribution) and inhibit restacking of graphene sheets, thereby generating high accessible surface area (|104 m2/g) for adsorption (Figure 15).
These GMC readily desorbs the MB molecules in ethanol solution reflecting promising recyclability. It has been observed that despite their good adsorption capacity, the separation of these graphene-based powdered adsorbents is a difficult and cumbersome task. Therefore, they pose inherent disadvantages in terms of requirement of energy-intensive separation and regeneration techniques along with chances of recontamination of water with any leftover adsorbent particles. In order to overcome poor separation ability of powdered absorbents, Fan et al. [53] synthesized graphene-Fe3O4 with carbon (GFC)-type hybrid materials with coupled porosity and magnetic properties for MB removal (Figure 16).
This material exhibits good porosity and magnetic character (Figure 16a) resulting in good dye adsorption response (Figure 16b) with good capacity (73.26 mg/g) and fast adsorption rates (i.e. removal of 80% dye within 20 min). The superiority of such materials lies in the fact that they can be easily separated after adsorption of dye from water using an external magnetic field and can be regenerated by desorbing the dye in ethanol (Figure 16c). The good recyclability is evident from very low decrease in adsorption capacity after five cycles of regeneration and reuse. The adsorption mechanism of MB on GFCs was examined by applying Langmuir and Freundlich isotherm models and their parameters are reported in Table 3.
GFC190 | 73.26 | 0.58 | 0.96 | 31.74 | 3.66 | 0.92 |
On the basis of regression coefficient (
The authors also studied the role of dye solution pH (Figure 17b) on the adsorption mechanism of the composite. The adsorption capacity was found to increase with pH (from 3 to 5.5) mainly due to the fact that at low pH condition protonation of basic dye (amido groups) fuchsine occurs, which leads to increase solubility of dye in water and hence its relatively poor adsorption under slightly acidic conditions. The extensive research on development of such handy magnetic graphene materials is now of great interest as these materials have high dye removal efficiency, quick dye adsorption and facile removal of spent adsorbent from purified water after completion of pollutant adsorption. In this series, a very promising magnetic adsorbent Ni-RGO (NGC) composite is prepared by Li group [117], which almost completely removes rhodamine (RhB) and MB dyes from water within 4 h as evident from corresponding time-dependent UV-visible spectra (Figure 18) (Table 4).
0.376 | 0.302 | |
1.048 | 0.894 | |
0.99 | 0.99 |
The authors show that the Freundlich adsorption mode is applicable to NGC with regression coefficient value (
The authors showed that in case of MO, adsorption capacity decreases with pH of solution as the negatively charged MO molecules compete with hydroxide ions in alkaline conditions shown in Figure 19c. Also, zeta potential measurement Figure 19d showed that the MCGO nanocomposite attained isoelectric point at pH 10 and hence has poor affinity for anionic dye under high alkaline conditions. Because of high concentration gradient between adsorbate and adsorbent species, rapid dye adsorption takes place initially followed by a gradual decrease in adsorption rate (Figure 19f) as at this stage most of the adsorption sites are occupied by the dye molecules. The model fits of Langmuir and Freundlich isotherms for MO are shown in Figure 19e. It was found that the Langmuir isotherm better described the adsorption of MO with the higher regression coefficient
5.3. Absorption of oils/organic solvents
Addressing the severe water pollution arising from oil spillage and chemical leakage is a challenging task. In principle, materials with both superhydrophobic and superoleophilic properties are highly desired for solving the environmental issues because of their capacity of selective absorption of oils and organic solvents while repelling water completely. As a remediation of accidents, the cleanup of leaked chemicals or oil is a global environment issue. Generally, porous materials that have high porosity and high surface areas show great potential in oil/chemicals pickup; however, these materials usually show poor selectivity toward target oil, thus easily saturated with water. Recently, graphene-based 3D porous structures, possessing superhydrophobic and superoleophilic surfaces, attracted enormous attention owing to their high affinity for various oils and organic solvents and ability to selectively absorb them from their dispersion, emulsions or floating layered system with water. In particular, some work has been done in the direction of graphene-coated polymeric foams [105] type hybrids and graphene/composites based aerogels [118]. A number of polymeric foam substrates have been exploited for coating/decoration with graphene, including polyurethane (PU), polydimethoxysiloxane (PDMS) and melamine foams.
Liu et al. [105] fabricated reduced graphene oxide-coated polyurethane sponges (rGPU) via a two-step process involving dip coating with GO followed by its chemical reduction to RGO. In this system, porous structure of PU sponge-based substrate (SEM image Figure 20a) is coated with RGO layers (SEM image Figure 20b) without disturbance of macroporous cellular architecture of the sponge. However, due to its inherent hydrophobic nature, the uniformly coated of RGO impart high degree of hydrophobicity and oleophilicity to PU sponges, as confirmed from the contact angle measurements for water (Figure 20c) and oil (Figure 20d).
Such a combination of macroporosity, hydrophobicity and oleophilicity of these materials leads to efficient absorption of lubricating oil (Figure 20e–g), chloroform (Figure 20h–k) and variety of other oils and organic solvents with good specific absorption capacity.
In addition, these hybrid sponges also display high absorption rate (Figure 21a) with saturation attaining in 2 h, The authors also exploited the compressible nature of PU sponge for the reusability of these materials and shown that they can be reused number of times (Figure 21b) without much loss in absorption capacity.
Nguyen group prepared graphene-coated melamine sponges [86] and highlighted the role of graphene loading and solution pH on the water contact angle value of synthesized hybrid foams. The presence of graphene nanolayers on the surface of melamine sponge drastically changed its surface properties attributed by the fact that the water contact angle changed from 0° (for pristine melamine sponge) to 162° (for graphene-coated melamine sponge). Further, the stability of superhydrophibicity to aggressive environment is demonstrated by the fact that the WCA remained greater than 150 degree even after 12 h of floating over aqueous solutions of different pH values. The pure sink to the bottom (Figure 22c), whereas the graphene-coated sponge floats over water, retard forced immersion with no water uptake, which further demonstrates its superhydrophobic nature. The silver mirror-like appearance of the immersed part of the graphene-based sponge (the inset Figure 22c) is attributed to a uniform air layer trapped between the water and superhydrophobic surfaces, which are referred to nonwetting Cassie-Baxter surfaces (Section 3). Interestingly, the sponge also displays superoleophilicity such that water droplets (pointed arrows) display WCA of 162° (inset Figure 22d) and remained unabsorbed (Figure 22d), whereas motor oil droplet (encircled) was immediately absorbed. The coexistence of superhydrophobic and superoleophilic surfaces is attributed to the combination of the microporous structure (with trapped air pockets) of the melamine sponge substrate and the hydrophobicity of the graphene nanosheets, and the micro-/nanotextured structure of graphene nanosheets on sponge skeletons.
These hybrid sponges display good absorption capacities (ranging from 60 to 165 times of its own weight) for motor oil (Figure 23a), chloroform (Figure 23b) and several other solvents (Figure 23c), good recyclability, low density and chemical inertness.
The recyclability and reusability of the graphene-based sponge also plays an important role in oil/chemical clean up applications. In general, sponge regeneration and absorbed pollutant separation can be realized either by squeezing the sponges for high-boiling materials like oils or by distillation/squeezing for low-boiling oils/solvents. It is observed that the generalized recyclable absorption response is similar for all tested oils (Figure 23d) with large decrease in absorption capacity after first cycle due to the residual oils inside the sponges, which cannot be removed by manual squeezing. After the second cycle, the saturated absorption capacity decreases only slightly indicating good recyclability. However, in case of organic solvents, desorbed sponges (after distillation) display no obvious change in saturated absorption capacity (Figure 23e) reflecting complete pollutant (solvent) recovery and good sponge recyclability, which are requisite for practical utility. Despite their great promise for oil/chemical clean up, the poor adhesion between coated graphene and foam substrate, remained a problematic issue. An attempt has been made by Tajendra et al. to improve the adhesive forces between PU sponges and RGO via covalent bonding strategy [119] involving use of silane- or titanate-based coupling agents. The sponges exhibited absorption capacity of 30–50 g/g depending upon the nature of oil/solvent. Further, the authors reported that the covalent bonding between RGO and PU prevents the leaching problem of surface layers and hence increase the recyclability of the hybrid sponges.
Table 5 compares the oil/organic-solvent removal performance of various graphene-coated foams based hybrids. It can be seen that the achieved absorption capacities are still lower than theoretically possible values and there is large deviation between results of different works. Further, besides hydrophobicity of the hybrid sponges, the parameters like viscosity, densities, polarities, surface tensions/energies of spilled chemicals and pore size, porosity and surface texturing of the foamed substrates, plays an important role in governing absorption characteristics (absorption capacity, absorption rate, selectivity) and need to be looked into thoroughly to further understanding and improvements. The graphene coating’s adherence issues are sorted out to improve the reusability and to reduce the chances of cross contamination. In order to drastically improve the gravimetric absorption capacities, eliminate the adherence issues and improve the recyclability, all graphene-based 3D self-assembled networks such as graphene aerogel seems to be promising solution [16,75].
S. No. | Absorbate | Absorption capacities (g/g) of various materials | |||
---|---|---|---|---|---|
Graphene- coated melamine sponge |
GO-coated PU sponges |
RGO-coated PU sponges |
TTEAI-RGO sponge |
||
1 | Chloroform | 165 | 140 | 160 | 35 |
2 | DMF | 100 | 78 | 82 | – |
3 | Hexane | 60 | – | – | – |
4 | Acetone | 75 | 75 | 80 | 32 |
5 | Ethanol | 78 | – | – | – |
6 | Used pump oil |
90 | – | – | – |
7 | Methanol | 80 | – | – | – |
8 | Pump oil | 95 | 90 | 100 | 28 |
9 | Soya bean oil |
100 | 92 | 110 | – |
10 | Motor oil | 90 | – | – | – |
11 | Diesel oil | – | 75 | 90 | – |
12 | Olive oil | – | 85 | 100 | – |
13 | Lubricate oil |
– | 100 | 112 | – |
14 | Gasoline oil |
45 | |||
Ref. | [103] | [63] | [63] | [104] |
Nevertheless, huge efforts in the direction are needed for the realization of efficient, stable, cost-effective and commercially viable absorbents for large-scale oil/chemical clean up to be used at actual spill site especially under marine environment.
7. Conclusion
In summary, graphene-based composites/hybrids have a tremendous potential for water purification applications. The inherent properties of graphene in conjunction with other materials induce additional functionalities in the composites/hybrids reflected in terms of enhanced, surface areas, porosity, flexibility, induced magnetism, improved adsorption/absorption rates and capacities. As discussed in this chapter, these materials show extraordinary chemical stabilities with good recyclability and durability, which are some of the most crucial attributes of sorbing materials. Importantly, the generation of magnetism in graphene composites/hybrids with magnetic nanomaterials prevents to ease out the sorbent operationality and its recovery process. But issues, such as desorption of pollutants for the regeneration of the active materials, are still a major challenge and need to be thoroughly investigated.
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