Summary of PRO experiments performed with the TFC2 membrane and variable cross-flow velocities.
Pressure retarded osmosis (PRO) can be used to exploit the mixing energy e.g. between river water and sea water. A PRO membrane must be highly permeable for water, whereas salt ions should be retained. Furthermore, the structure parameter of the membrane support and backing structure must be low. This paper summarises an assessment of the pressure dependency of the structure parameter for flat sheet membranes, and a transport model for PRO and procedures for determination of the pressure dependency of the structure parameter are presented. The results from laboratory experiments show that that the structure parameter increases significantly with increasing trans-membrane pressure. The increase in the structure parameter was observed to depend on both characteristics of the membrane and the fresh water spacer. Using a finely textured tricot spacer reduced the pressure dependency on the structure parameter, compared to a coarser spacer. Applying a non-woven backing material between the membrane and the fresh water spacer also reduced the impact of pressure. The results show that membranes suitable for river water/sea water PRO must have a sufficiently low structure parameter and additionally resist severe deformation at relevant operating pressures.
- osmotic power
- pressure retarded osmosis
- structure parameter
- pressure dependence
Pressure retarded osmosis (PRO) is one feasible technology that can be used to exploit the mixing energy from salt gradients which is commonly referred to as salinity gradient power or osmotic power [1, 2]. In PRO the transport of water through the membrane is caused by the difference in osmotic pressure across the membrane skin, and the net volume increase on the high saline side due to mass transport against a pressure gradient can be utilised to run a turbine. It should be mentioned that indirect alternatives to exploit the osmotic power, such as osmotic energy recovery in desalination of sea water, have gained increasing attention recently [3, 4, 5].
The mass transport of salt and water in PRO can be characterised by three parameters, the water permeability,
Resent research has showed that various transport models [14, 15, 16, 17] fail to accurately model PRO performance as a function of pressure increase. Kim and Elimelech  have related the deviation between observed and modelled performance to adverse effects between the membrane support and the feed channel spacer. Both membrane deformation and obstruction of water permeation were proposed mechanisms to explain the reduced membrane performance at increasing pressures. In case of membrane obstruction,
The interaction between the membrane and the feed spacer is found to reduce the PRO performance of flat sheet membranes. Hollow fibres are self-supporting structures, meaning that the use of spacers is avoided. Any pressure dependency of the PRO performance of hollow fibre membranes must therefore be related to other mechanisms than interactions between membrane and spacer. Chou
The objective of this paper is to present a hypothesis for the interaction between the membrane and spacer which partly builds on the hypothesis of Kim and Elimelech . Based on characterisation experiments we have demonstrated good correlation between measured and modelled membrane performances by applying a pressure dependent structure parameter. Further, the implications of membrane and spacer interactions in PRO will be discussed and related to the need for optimisation of the characteristic parameters of PRO membranes.
2.1. PRO modelling
A simplified flow diagram indicating main components in a PRO process such as pre-treatment stage, membrane modules, and pressure exchanger, is given in Figure 1. In PRO, water will be transported against a pressure gradient due to the difference in osmotic pressure between the draw solution and the feed solution. The net volume increase on the high saline side, which are operated at elevated pressure, can
Since the volume of salt transported through the membrane is negligible compared to the volume of water, the volume flux can be replaced by the water flux,
Different model frameworks describing the transport of salt and water through osmotic membranes have been developed by several authors [15, 20, 21, 22, 23, 24]. This paper is based on the stagnant boundary layer model presented by Thorsen and Holt , and the basic equations are given below.
Figure 2 shows the cross section of an osmotic membrane in a cross-flow cell, indicating the concentration profile of salt at a given position in the cell, from the fresh water side, through the membrane and to the sea water side.
The transport of water and salt (
The coupled transport of salt in the support membrane and the boundary layers can be expressed by the mass balance
where the porosity,
The equation relates the concentration difference of salt over the membrane skin to the bulk concentrations of salt, and furthermore to the characteristic membrane parameters, as well as the boundary layer thickness on each side,
which is valid when the salt water faces the skin side of the membrane,
2.2. Pressure dependency of the structure parameter
The left sketch in Figure 3 illustrates the cross section of a PRO membrane at zero trans-membrane pressure. The support membrane rests on the top of the filaments of the feed spacer. The contact area between the membrane and the spacer will in such case be low, and the presence of the spacer material has little or no impact on the mass transfer. An eventual impact will be included in the structure parameter determined by modelling of isobaric experiments.
When pressure is applied on the skin side in a PRO experiment the pressure will exert a force on the membrane, such that feed spacer will be squeezed into the support membrane. This situation is illustrated in Figure 3 (right sketch). As a result, the membrane may be deformed, and the contact area between the membrane and the feed spacer might increase. Furthermore, the properties of the support structure, such as porosity and interconnections between pores, might be affected. The net effect of these phenomena can be modelled as an increased structure parameter.
A simple equation has been developed in order to illustrate the pressure dependency on the structure parameter and the implicit effect on the water flux:
All results presented in this work were obtained from measurements performed with two small cross-flow units as illustrated in Figure 5. Two membrane cells with different effective membrane area of 6.1 and 9.5 cm2, respectively, were applied. The channel width was 1.1 cm and the depth of the draw channel was 0.07 cm for both cells. The depths of the feed channels for the two different cells were 0.1 and 0.05 cm, respectively. The draw channels were filled with a 0.07 cm thick diamond spacer, whereas different types of spacers were used in the feed channels.
Both feed and draw solution were pumped through the cross-flow cell using dual-piston pumps with displacement volumes of approximately 10 ml/stroke. The fluids were fed into the pumps from reservoirs placed on balances, and subsequently recycled back to the reservoirs. The cross-flow cells and up-stream tubing were immersed in temperature controlled water baths to maintain the temperature at 20°C during the experiments. The pressures,
3.2. Membranes and feed water spacers
The membranes used in this study include one CTA membrane and two TFC membranes (TFC1 and TFC2) from Hydration Technology Inc. and one TFC membrane (TFC3) from Nitto Denko. It should be noted that TFC1 and TFC2 are the first and second generation of the same membrane.
A relatively coarse tricot spacer with 0.5 mm thickness has been used as feed water spacer in our standard test protocols. In addition, some experiments were performed with a finer tricot spacer with 0.25 mm thickness. Photos of both types of spacers are shown in Figure 4.
3.3. Test protocol
The salt water solutions were made by dissolving NaCl (p.a.) in degassed (vacuum) and purified water. Degassed and purified water was also used as feed solution in the PRO experiments, and for all pre-treatment and rinsing steps.
If prescribed by the manufacturer, the membranes were pre-treated by immersion in a fluid of composition specified by the membrane manufacturer (often 50 vol. % methanol) for a prescribed time (typically 30 to 300 seconds). Subsequently, the samples were immersed in purified water for minimum 60 minutes prior to assembly in one of the membrane cells. The membranes that were not pre-conditioned were immersed in purified water prior to assembly in one of the membrane cells, in some cases combined with vacuum degassing of the sample.
After assembly, a hydraulic water permeability test was performed. The water flux was measured for minimum four pressure steps, ranging from 1 to 10 bar. Each pressure step lasted for minimum 1 hour. Subsequently, two independent osmotic flow experiments were performed at isobaric conditions. The first experiment was performed in FO mode,
3.4. Experimental conditions
For the osmotic experiments, the flow velocities (based on open channel) were 1.08 and 0.76 cm/s for the draw channel and the feed channel, respectively, unless stated otherwise. These flow velocities are in the same order as expected flow velocities in a full-scale membrane module for sea water/fresh water PRO. For the hydraulic water permeability experiments, purified water was supplied to both sides of the membrane.
During the osmotic experiments both sides of the membrane were conditioned at ambient pressure by bypassing the back-pressure valve shown in Figure 5. During the hydraulic water permeability experiments, and some of the PRO experiments, the back-pressure valve was used to regulate the applied pressure on the draw side. However, most PRO experiments were performed using a closed draw solution loop instead of the back-pressure valve. The closed draw solution loop was continuously pressurised by the volume increase in the draw solution loop.
4. Data analyses and modelling
4.1. Flux and permeability calculations
The water flux was determined based on mass changes in the feed reservoirs. The reported water fluxes were estimated based on the initial phase in each experiment,
4.2. Determination of A, B and S from isobaric osmotic flow experiments
4.3. Modelling of PRO experiments
In order to assess the specific power production as function of applied pressure each experiment was divided into pressure steps. The water and salt fluxes, and the salt concentrations on both sides of the membrane, were calculated by mass balances for each pressure step, using the membrane parameters determined for the applied membrane, according to Section 4.2.
4.4. Determination of pressure dependency of the structure parameter
In order to assess the pressure dependency of the structure parameter,
5. Results and discussion
5.1. Modelling of PRO experiments with constant S
Figure 7 shows the water flux and specific power as function of trans-membrane pressure for two CTA membranes with imbedded reinforcement. The membranes originated from two different production batches. Symbols correspond to experimental data, whereas lines correspond to modelled values which are based on the characteristic membrane parameters determined from the osmotic flow experiments.
It can be observed from Figure 7 that the measured water fluxes, and thus the specific power, were not very high, which is typical for asymmetric membranes. Furthermore, a significant deviation between measured and modelled performance was observed at increasing trans-membrane pressure.
5.2. Modelling of PRO experiments with pressure dependent S
Figure 8 shows the same experiments as presented in Figure 7 with the distinction that the modelled values were obtained by using a pressure dependent structure parameter. The pressure dependent structure parameter obtained for the two CTA membranes is plotted as function of trans-membrane pressure in Figure 9.
It can be observed that the structure parameter increases significantly with increasing pressure for both membrane samples. Further, the observed variation in the structure parameter with trans-membrane pressure resembles the proposed behaviour given by Eq. (10).
Figure 10 shows the water flux and specific power as function of trans-membrane pressure for two parallel runs with a TFC membrane with imbedded reinforcement, denoted as TFC1. The modelled values were obtained by using a pressure dependent structure parameter. Note that the difference in salt concentration across the membrane skin at maximum specific power was 26.4 and 28.2 g/l for Experiment 1 and Experiment 2, respectively, which explains the observed difference in performance for the two experiments.
Figure 11 shows the pressure dependency of the structure parameter for the two experiments performed with TFC1. Generally, it was observed that the structure parameter of the TFC1 membrane was less affected by pressure than the CTA membrane.
5.3. Impact of flow velocity on the pressure dependency of S
Table 1 summarises a series of PRO experiments, each performed with different cross-flow velocities and using the membrane denoted TFC2. Experiments 5 and 9 were both performed at standard conditions. The maximum specific power,
All experiments were modelled according to the procedure described in Section 4.4, and the respective pressure dependent structure parameters are shown in Figure 12.
From the reported specific power data in Table 1 it was observed that the TFC2 membrane (second generation) performed significantly better than the TFC1 membrane (first generation). Further, the results from Experiment 5 and Experiment 9 performed at identical conditions are very similar and indicate good reproducibility.
Comparing the pressure dependency of the structure parameter for the two different TFC membranes in Figure 12 and Figure 11, it was observed that the structure parameter of the TFC2 membrane was less influenced by increasing trans-membrane pressure. Further, the increase in structure parameter with increasing trans-membrane pressure was observed to have relatively identical slopes for all experiments performed with the TFC2 membrane. Additionally, the structure parameter was observed to decrease at increasing flow velocities.
Figure 13 illustrates the membrane and the feed channel in a cross-flow cell. Since the support membrane is a porous structure some water might be anticipated to flow in the longitudinal direction inside the support membrane as illustrated by the red arrows. The flow velocity inside the support membrane and the penetration depth for the longitudinal flow inside the support will depend on the cross-flow rate, as well as both the flow resistance in the spacer material and in the support membrane, respectively.
For low cross-flow rates and for feed spacers with low pressure drop, the pressure gradient in the feed channel will be small, and little or no water will flow in the longitudinal direction inside the support membrane. At higher cross-flow rates, the pressure gradient in the membrane support will increase, and a significant flow of water inside the support membrane may occur. This will reduce the magnitude of the structure parameter since the effective diffusion length will be reduced when the support structure become more saturated.
Even if high cross-flow velocities may improve mass transfer through the membrane by the effects discussed above, such measure will require increased pumping energy and additionally result in lower utilisation of the feed solution. It should be noted that large pressure losses are unacceptable in sea water/fresh water PRO, and sufficiently low pressure losses are important factors to be considered during development and design of membrane modules for application in PRO plants.
5.4. Impact of spacer selection on the pressure dependency of S
Table 2 summarises results from PRO experiments performed with the TFC3 membrane that was produced without fabric reinforcement.
|12||4.6||27.1||19.0||2·0.25 mm||HH 15-TH48|
|13||4.9||28.1||21.5||2·0.25 mm||HH 15-TH48|
|14||4.3||28.3||20.0||0.50 mm||HH 15-TH48|
|15||4.6||28.1||21.7||2·0.25 mm||HH 15-TH48||Spacer inv.|
Two different feed spacers having different thickness and structure were tested. Both spacers were of the tricot type. The feed spacer of 0.25 mm thickness had a much finer structure with smaller distance between the filaments (
The modelled structure parameter in the experiments performed with the 0.5 mm thick spacer was observed to increase more rapidly with increasing pressure compared to the experiments performed with the less coarse spacer of 0.25 mm thickness. Comparing the two experiments performed with the 0.5 mm spacer it was observed that the introduction of the extra non-woven fabric reduced the observed pressure dependency of the structure parameter. This indicates that improving the support for the membrane does influence the compaction of the membrane structure and the resulting increase in the structure parameter at elevated pressures.
The positive impact on the pressure dependency of the structure parameter by including the extra non-woven fabric was also observed for the experiments performed with the 0.25 mm feed spacer. The structure parameter of the fabric was estimated to 0.13 mm by performing independent salt diffusion experiments. The additional transport resistance exerted by the non-woven fabric can be recognised in the modelled structure parameter as the reinforcement layer ideally should add 0.13 mm to the isobaric structure parameter. This increment was not observed in Experiment 12; however, the deviation is within the expected uncertainty found in the pressure dependent structure parameters.
In Experiment 15, the feed spacer was inverted such that the “flat” side was facing the membrane, resulting in a slightly higher structure parameter compared to the experiments performed with normal orientation of the spacer.
These results show that the extent of support for the membrane is crucial for the PRO performance. It was observed that the coarser spacer resulted in both a faster and a larger increase in the structure parameter at increasing pressure, compared to the more fine-structured spacer providing more support to the membrane. Similar behaviour has been observed in multiple experiments performed with different types of PRO membranes, and agrees well with recent literature . The effect of introducing the extra reinforcement was observed to be larger for the coarser spacer.
5.5. Proposed measures to improve PRO performance at elevated pressures
In order to promote a high specific power in sea water/fresh water PRO, the structure parameter must be low, preferably less than 0.5 mm. The isobaric structure parameters measured for many existing membranes are well below this value. However, when pressurised, an excessive increase in the structure parameter have been observed for many potentially good PRO membranes. An improved strength of the support membrane which is more resistant to compression will therefore be required.
The results in Figure 14 suggest that one approach to reduce the pressure dependency of the structure parameter might be to apply fine textured feed spacers. However, this will result in increased pressure drop in the feed channel, which might drastically reduce the net produced power in a PRO plant. Even the relatively coarse 0.5 mm feed spacer used in the present work will result in an unacceptable pressure loss. Thus, it should be investigated if it is possible to cast the support membrane directly on a feed spacer, possibly a fine textured tricot type. Supposing that this is viable, two membrane sheets may be separated by
5.6. Uncertainty in experiments and modelling
The calculation of pressure dependent structure parameters in this paper were based on the assumption that the water and salt permeability were independent of the applied pressure, which may appear to be somewhat contradictory to part of the literature [18, 19]. Nevertheless, our assumption is based on several arguments. (1) In the presented work, the PRO experiments were performed with a tricot type feed spacer that has been found to result in the lowest variation in the modelled membrane parameters due to variations in trans-membrane pressures , and (2) initial water permeability tests using pressures up to 10 bar were performed prior to all PRO experiments. Thus, any membrane deformation that could be expected to influence the skin properties of the membrane as a result of pressurisation should have occurred during the water permeability tests. And (3) the obtained water permeability that were calculated at several pressure steps for each membrane were found to be independent of trans-membrane pressure.
At the end of each PRO experiment the amount of salt on the feed side was determined and compared with the amount of salt calculated by using the transport model. If an excess of salt was determined this was attributed to a hydraulic leakage, and subsequently a leakage volume was calculated by assuming zero salt rejection for the leakage. A leakage permeability,
The pressure dependency of the structure parameter in PRO has been investigated for flat sheet membranes, and a transport model including procedures for determination of the pressure dependency of the structure parameter have been presented.
The results from laboratory experiments show that the structure parameter increases significantly with increasing trans-membrane pressure. This was the case both for the CTA membrane and the three TFC membranes that were tested, however, the impact of pressure on the structure parameter was found to be larger for the CTA membrane. Furthermore, the increase in the structure parameter was observed to depend on the type of feed spacer. Using a finely textured spacer of the tricot type reduced the impact of pressure on the structure parameter in comparison to a coarser spacer material. Applying a non-woven backing material between the membrane and the fresh water spacer was also observed to reduce the impact of pressure on the structure parameter. These results show that developing membranes with sufficiently low structure parameter for pressures relevant for PRO will rely on the membrane’s ability to resist deformation during compression. The type of feed spacer is another factor which is crucial to avoid deformation and the resulting increase in the structure parameter at elevated pressures.
The results also showed that increased flow velocities in the feed channel and the draw channel, respectively, will improve the mass transfer of water through the membrane. This might be partly ascribed to reduced concentration polarisation on the membrane surfaces. It is also suggested that high pressure gradients in the feed channel may result in convective flow in parts of the support membrane, improving the mass transfer conditions further. However, large frictional losses in the flow channels, will drastically reduce the net produced power in a sea water/fresh water PRO plant, and must be avoided. This will limit the choice of feed spacers that can be used for PRO.
|A||water permeability (m/s/Pa)|
|Aleak||hydraulic leakage permeability (m/s/Pa)|
|B||salt permeability (m/s)|
|cf||bulk concentration at the fresh water side (g/l)|
|cfm||surface concentration at the fresh water side (g/l)|
|cp||concentration at the interface between the skin and the porous support (g/l)|
|cs||bulk concentration at the salt water side (g/l)|
|csm||surface concentration at the salt water side (g/l)|
|Δcskin||concentration difference across the membrane skin (= csm − cp) (g/l)|
|D||diffusion coefficient (m2/s)|
|ds||salt water film thickness (m)|
|df||freshwater film thickness (m)|
|F||constant in Eq. (10)|
|i||corrected van’t Hoff coefficient (−)|
|JV||volume flux (m/s)|
|Jw||water flux (m/s)|
|Js||salt flux (mol/m2/s)|
|P||specific power (W/m2)|
|Pmax||maximum specific power (W/m2)|
|posm||practical osmotic pressure (bar)|
|Δp||trans-membrane pressure (bar)|
|Δpmax||maximum trans-membrane pressure (bar)|
|Δpref||reference pressure in Eq. (10) (bar)|
|Qwater,in||volumetric flow of water entering a module (−)|
|Qwater,out||volumetric flow of water exiting a module (−)|
|R||universal gas constant (J/K/mol)|
|S||structure parameter (m)|
|S0||isobaric structure parameter (m)|
|T||absolute temperature (K)|
|udraw||empty channel velocity at draw side (cm/s)|
|ufeed||empty channel velocity at feed side (cm/s)|
|x||direction perpendicular to the membrane surface (m)|
|Δxmem||membrane thickness (m)|
|Δπskin||osmotic pressure difference across the membrane skin (bar)|