Open access peer-reviewed chapter

Nanofluid with Colloidal Magnetic Fe3O4 Nanoparticles and Its Applications in Electrical Engineering

By Lucian Pîslaru-Dănescu, Gabriela Telipan, Floriana D. Stoian, Sorin Holotescu and Oana Maria Marinică

Submitted: March 30th 2016Reviewed: September 5th 2016Published: March 15th 2017

DOI: 10.5772/65556

Downloaded: 1017

Abstract

In this study, we propose a new type of a cooling agent based on magnetic nanofluid for the purpose of replacing the classical cooling fluids in electrical power transformers. The magnetite (Fe3O4) nanoparticles were synthesized by the co-precipitation method from an aqueous medium of salts FeCl3x6H2O and FeSO4x7H2O in the molar ratio Fe3+/Fe2+ = 2:1, by alkalization with 10% aqueous solution of NaOH at 80°C, for 1 h. The size of the magnetite nanoparticles, as measured by X-ray diffraction method, was 14 nm and by scanning electron microscopy (SEM), they are between 10 and 30 nm. Magnetite powder was placed in oleic acid as a surfactant to prevent agglomeration of nanoparticles. The resulting mixture was dispersed in transformer oil UTR 40, with the role of carrier liquid. The magnetic, rheological, thermal and electrical characteristic properties of the obtained Fe3O4 transformer oil-based nanofluid were determined. A mathematical model and numerical simulation results are very useful for investigating the heat transfer performances of the magnetic nanofluid. Based on this study, it was tested the cooling performance of this magnetic nanofluid for two types of electrical power transformers as compared to classical methods. We also presented a microactuator based on the same magnetic nanofluid.

Keywords

  • colloidal magnetic Fe3O4 nanoparticles
  • X-ray diffraction
  • SEM
  • electrical transformer
  • magnetic nanofluid coolant
  • heat transfer
  • magnetic properties
  • microactuator
  • mass transfer
  • pulse width modulation
  • mathematical model
  • numerical simulation

1. Introduction

Magnetic nanofluids, known also as ferrofluids or magnetic liquids, are stable colloidal suspensions of superparamagnetic nanoparticles such as γ-Fe2O3, α-Fe2O3, Fe3O4, CoFe2O4, Mn1−xZnxFe2O4, in a carrier liquid (an organic solvent or water) [15]. In order to prevent the aggregation of magnetic nanoparticles and to attain a stable magnetic nanofluid, the nanoparticles are coated with a surfactant during the preparation process [1, 48]. The characterization of magnetic nanoparticles and of the obtained magnetic nanofluid is carried out by various techniques in order to determine their structural, magnetic, rheological and magneto-rheological properties [111]. The development of the synthesis methods leads to the possibility of tailoring the magnetic nanofluids and consequently, their physical properties, such that it fulfills the requirements of a certain application [1, 5, 1224].

Besides the well-known application of ferrofluids in sealing and lubrication, recent developments envisaged their potential in fields like actuation [22, 23], medicine [1, 16], biotechnology [14, 24], as cooling fluids [2529] or as liquid core in power transformers [30, 31]. The applications in medicine and biotechnology require from the magnetic nanofluid to be biocompatible. Therefore, water-based magnetic nanofluids are the candidates for magnetic hyperthermia for cancer treatment and targeted drug delivery, as well magnetic separation for purification of cells, proteins or else. The applications envisaged in electrical engineering require from the proposed magnetic nanofluid to also have good thermal and insulating properties. These conditions can be fulfilled by the transformer oil-based magnetic nanofluids.

This chapter is addressing the application of a Fe3O4 magnetic nanofluid based on transformer oil, as cooling and insulating fluid of a power transformer. Thus, the preparation procedure and the characterization of structural, magnetic, rheological, thermal and electrical properties are presented. The mathematical model applied to the problem is introduced, and the numerical results for two power transformers are discussed. The use of this Fe3O4 magnetic nanofluid in a micro-actuation application is also presented.

2. The synthesis and complex characterization of nanofluid with colloidal magnetic Fe3O4 nanoparticles

2.1. Nanofluid synthesis

The materials used for the synthesis of nanofluid with colloidal magnetic Fe3O4 nanoparticles we can mention: hexahydrated ferric chloride (FeCl3x6H2O) of 99% purity obtained from Merck Germany; ferrous sulfate sheptahydrate (FeSO4x7H2O) of 98% purity purchased from Chimopar, Romania; sodium hydroxide (NaOH) of 99% purity and oleic acid (C18H34O2) of 99% purity provided by Riedel de Haen. Other chemicals were of analytic grade. The reagents were used without further purification. All solutions were prepared with deionized water.

The transformer oil-based ferrofluid with Fe3O4 nanoparticles was synthesized by chemical co-precipitation method [23], using FeCl3×6H2O and FeSO4×7H2O with a molar ratio of Fe2+/Fe3+ = 1:2, dissolved in 300 ml of water and treated with NaOH 10%. The mixture was stirred at 80°C for 1 h. The resulting black color precipitate of Fe3O4 was washed with deionized water and magnetically decanted until a pH of 7 was reached. Then, 10 ml of HCl 0.1 N was added to the Fe3O4 precipitate for peptization. The mixture was washed and decanted again until pH 7, dried at 90°C and treated with acetone for water removal. A small part of the obtained powder was analyzed [X-ray diffraction, scanning electron microscopy (SEM) and elemental analysis EDX] for structural properties. The remaining part of the powder was treated with 2 ml of oleic acid as surfactant, and with 5 ml of toluene and heated at 90°C for toluene removal. Finally, the mixture was dispersed in 50 ml of UTR 40 transformer oil, under strong stirring for 20 h in order to obtain the magnetic nanofluid. Figure 1 schematically presents the transformer oil-based magnetic nanofluid of Fe3O4 synthesis.

Figure 1.

Transformer oil-based magnetic nanofluid of Fe3O4 synthesis.

2.2. Nanofluid characterization

2.2.1. Powder characterization of Fe3O4 nanoparticles

The Fe3O4 powder was structurally characterized by X-ray diffraction using a diffractometer D8 ADVANCE type X Bruker-AXS in conditions: Cu-Kα radiation (γ = 1.5406 Å), 40 KV/40 mA, filter kβ of Ni, in the 2θ range of 25–70°, using a step of 0.04° and measuring time on point of 1 s.

The XRD pattern of the powder is presented in Figure 2 and shows the peaks corresponding to the Fe3O4 highlighted by “hkl” Miller indices (220), (311), (400), (422), (511) and (440), [2, 4], which denote a spinel structure with lattice parameter a = 0.83778 nm, in accord with the literature data (JCPDS file no. 19-629). According to the (311) peak, the medium size of the crystallites determined by Scherrer formula (1) is 14 nm.

Figure 2.

The Fe3O4 XRD pattern of the Fe3O4 nanoparticles.

D=0.9λBcosθ,E1

where D is the crystallites medium size, γ is the wavelength of this X-ray (γ = 0.154059 nm), Bis the full width at half maximum (FWHM) and θ is the half diffraction angle of crystal orientation peak.

The morphology of the sample was studied by SEM using a Carl Zeiss SMT FESEM-FIB Auriger type scanner. The elemental analysis (energy-dispersive X-ray spectroscopy EDX) was performed with an energy dispersive probe of Inca Energy 250 type Oxford Instruments LTD England coupled to SEM.

The topology of the Fe3O4 powder analyzed by scanning electron microscopy evidenced two types of surface: smooth surface and rough surface (fracture). A crystalline structure of the material was found for the first type of surface, which is composed of crystallites having average sizes between 10 and 30 nm (Figure 3) in good agreement with the diffraction analysis. For the second type of surface, a structure of acicular type agglomerates was found (Figure 4).

Figure 3.

The SEM image for the first structure.

Figure 4.

The SEM image for the second structure.

The elemental analysis confirms the presence of Fe3O4 (Figure 5) and shows that the resulting black powder contains 70.14%Fe, 24.96% O, 4.16% C and 0.74% Cl (Table 1). The presence of the Fe3O4 is exhibited by elemental Fe-peaks of about 6.45 and 0.75 keV. The high percentage of oxygen is related to its existence in the iron oxide.

ElementWeight (%)Atomic (%)
C K4.1610.89
O K24.9649.01
Cl K0.740.66
Fe K70.1439.45
Totals100.00100.00

Table 1.

Analysis data for Fe3O4 nanoparticles, energy dispersive.

Figure 5.

The elemental analysis for Fe3O4 powder: (a) the SEM image and (b) the elemental energy dispersive X-ray analysis.

The SEM image (Figure 5a) and the elemental energy dispersive X-ray analysis (Figure 5b) confirms the data determined by X-ray diffraction. The content of C and Cl represents the little impurities.

2.2.2. Characteristic properties of the nanofluid with colloidal magnetic Fe3O4 nanoparticles used as a cooling fluid for power transformers

2.2.2.1. Magnetic properties

The full magnetization curve and the hysteresis loop of the transformer oil-based magnetic nanofluid (MNF/UTR 40), with a solid volume fraction of the dispersed magnetite particles of 1.67%, were measured at room temperature (25°C), using a vibrating sample magnetometer—VSM 880—ADE Technologies USA, in the magnetic field range of 0–950 kA/m.

The magnetization M measured at the maximum value of the applied magnetic field, approx. 900 kA/m, is considered to be the nominal magnetization of the investigated sample. Also, the absence of hysteresis loop area indicates a specific behavior of soft magnetic material (Figure 6) with the magnetic characteristics shown in Table 2.

SampleM(Gs)M(kA/m)Mr(kA/m)Hc(kA/m)ρ24oC(g/cm3)ϕFe3O4(%)
MNF/UTR 40503.980.961.67

Table 2.

Physical properties of MNF/UTR 40 sample.

Figure 6.

Hysteresis loop and full magnetization curve of the transformer oil-based magnetic fluid sample shows specific behavior of soft magnetic materials: (a) hysteresis loop for UTR 40-based MNF sample and (b) full magnetization curve for UTR 40-based MNF sample.

In Table 2, Mrrepresents the remnant magnetization and Hcis the coercive magnetic field; ρ24oCis the density of the magnetic fluid at 24°C and ϕFe3O4is the solid volume fraction of the dispersed magnetite.

According to Shliomis [32], the magnetic behavior of a diluted magnetic nanofluid (ϕFe3O4<5)under the action of an external magnetic field is well described by the single-particle model, which states that the energy of dipolar interactions is lower than the thermal energy. In this case, the equilibrium static magnetization is a superposition of Langevin functions,

M=ϕmMd(cothξ1ξ)=ϕmMdL(ξ),E2

with

ξ=πμ0MdDm3H6kBT,E3

representing the Langevin parameter. Herein Md=480kA/mis the monodomenial magnetization of magnetite, μ0=4π×107H/mis the magnetic permeability of vacuum, Dmis the magnetic diameter of the dispersed magnetite particles, His the applied magnetic field, kB=1.38×1023J/Kis the Boltzmann constant and Tis the absolute temperature.

In low magnetic fields (<1mT), with ξ0, the Langevin function becomes L(ξ)ξ3, that is a linear variation in sample magnetization with the applied field. Knowing that the initial magnetic susceptibility is χiL=M/H, one can obtain:

χiL=πμ0ϕmMd2Dm318kBTE4

On the other hand, in the region of intense magnetic fields (ξ>>1), the Langevin function is given by L(ξ)11ξ, and static magnetization of the magnetic nanofluid is approximated by the following relationship [33],

MϕmMd(16kBTπμ0MdDm3H),E5

where ϕm=Ms/Mdis the magnetic volume fraction, with Msrepresenting the saturation magnetization of the magnetic nanofluid sample. The above relationship shows that the magnetization reaches saturation for very high values of the magnetic field (H).

In fact, in real ferrofluids, the dimensional polydispersity of the magnetic particles is a characteristic that cannot be neglected and, in the absence of inter-particle interactions, an accurate expression of magnetization is obtained [34],

M=Ms0L(ξ)f(x)dx,E6

where f(x)is the log-normal distribution function (Figure 7)

Figure 7.

(a) TEM image of mono-layer covered magnetite nanoparticles with oleic acid and stably dispersed in hexane; (b) dimensional distribution of the magnetic particles physical diameters is well approximated by the log-normal distribution function.

f(x)=1xS2πexp(-ln2xD02S2),E7

with xis the magnetic diameter of the magnetite particles; f(x)dxrepresenting the probability that the magnetic diameter of the magnetic particles to be in the range of (x;x+dx); D0is the dimensional distribution parameter, defined by the relationship ln(D0)=ln(x); Sis also a dimensional distribution parameter, representing the deviation of ln(x)value from ln(D0)[35].

Another important aspect regarding the magnetization evaluation that should be considered is the dependence of the dispersed nanoparticles magnetic moments with their magnetic diameters [36, 37]. Here, Ms(x)=nm(x)and the ferrofluid magnetization become

M=n0m(x)L(ξ)f(x)dx,E8

with nrepresenting the density of the dispersed magnetite particles in magnetic fluid and mis the dipolar magnetic moment.

The linear dependence of the initial magnetic susceptibility versus magnetic particle concentration in low fields, rel. (4), and the asymptotic variation in magnetization in intense magnetic fields, rel. (5), form the basic instruments of magnetogranulometric analysis, in order to determine the mean magnetic diameter of the dispersed magnetic particles,

Dm=D0exp(S22),E9

and standard deviation

σ=Dm2Dm2,E34
σ=D0exp(S22)[expS21]1/2,E10

where the dimensional distribution parameters are evaluated first,

S=13ln3χiLH0Ms,E11
D03=6kBTπμ0MdH0Ms3χiLH0,E12

and

n=μ0MsH0kBT,E13

The expression of the dimensional distribution parameters was obtained from rel. (8), considering the above presented limit cases and evaluating the initial magnetic susceptibility and saturation magnetization, respectively.

In the linear region of small magnetic fields (H<1kA/m)from static magnetization curve, measured for the MNF/UTR 40 sample, the initial magnetic susceptibility has been evaluated. Msand H0magnetic field were determined in the quasi-saturation region (H>700kA/m), where the contribution to the ferrofluid magnetization is given by the magnetic particle interactions with the applied magnetic field, inter-particle interactions being neglected. As a result, in the saturation region can be considered that the magnetic nanofluid magnetization varies linearly with 1/Haccording to Langevin’s law, even for concentrated samples. In Figure 8, which represents the final part (quasi-saturation) of the magnetization curve in M=f(1/H)representation, Msis obtained as the intersection with the ordinate axis. Also, the ratio of the magnetization curve slope and the corresponding absolute value of Msis the value of H0field, where R2represents the measure of accuracy of the fit in linear regression (Table 3).

SampleχiL(-)R2(χiL)(-)Ms(kA/m)Ms(Gs)H0(kA/m)R2(Ms)(-)
MNF/UTR 400.110.994674.2453.2334.720.98580

Table 3.

Initial magnetic susceptibility and saturation magnetization of the transformer oil-based magnetic fluid sample.

Figure 8.

Obtaining Msand H0 field in the quasi-saturation region of the magnetization curve, in M=f(1/H) representation, where the ferrofluid magnetization varies linearly with 1/H, according to Langevin’s law.

Magnetogranulometric analysis of the MNF/UTR 40 sample has revealed a mean magnetic diameter of the magnetite particles of Dm=6.46nmand a standard deviation of σ=2.18nm. The log-normal distribution parameters (rel. (11)–(13)), evaluated directly from the magnetization curve, were obtained through non-linear regression, using rel. (8). Considering the thickness of non-magnetic layer at the surface of magnetic nanoparticles of δm=0.83nm[33],

Dp=Dm+2δm,E14

a value of 8.12 nm was determined for the mean physical diameter. Furthermore, a thickness of 1.9 nm of the oleic acid monolayer cover of magnetite particles δs[38] leads to a hydrodynamic diameter of the particles of Dh=11.92nm,

Dh=Dp+2δsE15

Main results obtained through magnetogranulometric analysis of the MNF/UTR 40 sample are summarized in Table 4.

SampleD0(nm)S(-)n(×1022 partic./m3)Dm(nm)σ(nm)Dp(nm)Dh(nm)
MNF/UTR 406.120.334.506.462.188.1211.92

Table 4.

Main properties of MNF/UTR 40 sample obtained through magnetogranulometric analysis, including the log-normal distribution parameters values.

2.2.2.2. Rheological properties

Rheological investigations, carried out with an Anton Paar Physica MCR 300 rheometer using a double-gap concentric cylinder geometry, consisted of measuring the dynamic viscosity curves of the samples in the absence of the magnetic field. The shear rate, γ˙, varied from 1 s−1 to 1000 s−1, at different values of working temperature t=(20;40;60;80)oC. The viscosity curves (Figure 9) measured for both the transformer oil-based magnetic nanofluid (MNF/UTR 40) and the carrier liquid-transformer oil (UTR 40) showed that adding a small volume fraction of magnetic particles in the carrier (φFe3O41.67%)leads to a very mild increase in the dynamic viscosity and the Newtonian behavior of the samples is preserved throughout the investigated temperature range.

Figure 9.

Viscosity curves showed that the Newtonian behavior of the carrier (UTR 40) (a) is preserved throughout the temperature range, also for the magnetic nanofluid (MNF/UTR 40), (b) that contains a small amount of the dispersed magnetic particles, indicating an efficient steric stabilization.

This behavior indicates the absence of the magnetic particle interactions, that is, a very good stability of the sample, mainly due to the efficient steric stabilization. An Arrhenius-type relationship describes the sample viscosity behavior with temperature,

η=ηrefexp[-EaR(1T1Tref)],E16

where Tref=20oCis considered the reference temperature; ηref(Pas)is the dynamic viscosity corresponding to the reference absolute temperature; Εa(Jmol-1)means the activation energy and R=8.31447Jmol1K1is the ideal gas constant.

Considering a shear rate of 100 s−1, rel. (16) was used to fit the dependence η=η(T), with activation energy as fit parameter (Figure 10).

Figure 10.

Arrhenius type dependence of the samples dynamic viscosity with temperature: (a) carrier liquid UTR 40 and (b) transformer oil-based magnetic nanofluid MNF/UTR 40.

In Table 5, it can be observed that the value of the viscous flow activation energy does not change after dispersing a small amount of surfacted magnetite particles in the carrier liquid. It can be concluded that the adding of small volume fractions of surfacted magnetite particles in a carrier liquid(ϕFe3O4<5), as transformer oil, has no significant influence on the rheological properties of the samples.

SampleφFe3O4(%)Εa(Jmol-1)
MNF/UTR 401.6728.27 × 103
UTR 4028.38 × 103

Table 5.

Viscous flow activation energy of the carrier liquid (UTR 40) and the magnetic nanofluid (MNF/UTR 40).

2.2.2.3. Thermal properties

The addition of metallic nanoparticles (magnetic or non-magnetic) or non-metallic (e.g., diamond nanoparticles) in transformer oils in order to improve their cooling performances is a solution that was demonstrated by several patents and associated research works (e.g. [3945]). This paragraph analyzes the thermal properties of the magnetic nanofluid, which was tested for use as cooling and insulating medium in power transformers.

Determination of the effective thermal properties that characterize the cooling fluids in our study as well as their modeling using analytical formulae is representing a main problem of the topic in discussion. Irrespective of the considered approach, either theoretical or experimental, a representative element of the studied medium has to be chosen. It has to be underlined that the determination of the properties of heterogeneous materials has to be made by complying with the request of representativeness of the studied volume, that is, the considered volume of the heterogeneous material must be sufficiently large in order to be statistically representative irrespective of the type of the carried out experiment [46, 47].

The main properties that are influencing the thermal behaviour of a material are the heat capacity, thermal conductivity, density, thermal expansion coefficient and thermal diffusivity (a property that depends on the first three). Various experimental studies determined that the effective properties of nanofluids (magnetic or non-magnetic) are dependent on the following characteristics of their components [25, 4850]: the thermo-physical properties of the carrier fluid, nanoparticles and surfactant; nanoparticles volume fraction, size distribution, mean diameter and shape; temperature; magnetic field (in the case of magnetic nanoparticles).

A review of the reference literature regarding the main properties of the transformer oil-based fluids and their dependence with the temperature outlined the followings: specific heat is increasing as linear function with temperature; thermal conductivity is decreasing as a quasi-linear function with temperature especially for transformer oils; dynamic viscosity is decreasing with the increasing temperature; the dielectric constant has relatively low values and decreases with the increasing temperature [5153].

2.2.2.3.1. Thermal conductivity

The thermal conductivity of magnetic nanofluids can be described as a function of several parameters, among the most important are the thermal conductivities of the carrier liquid and magnetic nanoparticles and their dependence on temperature and pressure, the volume fraction, the shape and the size distribution of the nanoparticles. The interfacial thermal resistance between the nanoparticles and the surrounding liquid is also considered. It has been proved numerically and experimentally that an applied magnetic field can affect the thermal conductivity of a magnetic nanofluid due to the consequent ordering of magnetic dipoles of the nanoparticles along the field lines [25, 54].

There are many Maxwell-type models developed for the thermal conductivity of mixtures (also named effective thermal conductivity—ETC), either solid matrix—solid filler or liquid carrier and dispersed nanoparticles that are based on the Maxwell model, which is recommended for low volume fraction of the filler/nanoparticles and considers that the nanoparticles are identical, spherical and non-interacting. The Holotescu-Stoian model, developed initially for the solid matrix—solid filler mixture and presented in Refs. [55, 56], introduced for the first time the filler particle size distribution in the Maxwell model. The expression for the effective thermal conductivity of the Holotescu-Stoian model, rel. (17), in the case of a magnetic nanofluid is [57],

ke=kfkp+2kf+2ϕe(kpkf)kp+2kfϕe(kpkf),E17

where keis the effective thermal conductivity of the magnetic nanofluid, kpis the thermal conductivity of the magnetic nanoparticles, kfis the thermal conductivity of the carrier fluid, ϕeis the equivalent volume fraction, defined by

ϕe=ϕFe3O4(Dm+δ)32(Dm+δ)23,E18

with ϕFe3O4is the solid nanoparticles volume fraction (magnetite in this case),Dmis the magnetic diameter, δ=2δmis the double thickness of the non-magnetic layer, and

u=0uf(x)dxE19

with ubeing a magnetic diameter dependent function and f(x)is the log-normal distribution function.

The relationship between physical (geometrical) diameter Dp, magnetic diameter Dmand δis given by

Dp=Dm+δ.E20

This model, confirmed by the experimental data [57], was applied to determine the thermal conductivity of the analyzed magnetic nanofluid sample. The results (at room temperature) are given in Table 6, and we observe that the addition of magnetite nanoparticles alone is increasing the thermal conductivity of the magnetic nanofluid. The transformer oil thermal conductivity is decreasing with the increasing temperature, thus the cooling performance can be diminished at normal operating conditions in power transformers (and other electrical equipments). We can conclude that the addition of the magnetite nanoparticles can counteract this disadvantage. Moreover, during the operation of a power transformer, for instance, the magnetic field is acting on the magnetic nanofluid, influencing its physical properties, and generating the magneto-convection that can enhance the heat transfer, as shown in the next section.

Property/sampleUTRNPMNF_UTRΔX/XUTR
ke(W/m K)0.1271.390.135+6.29%
cp(J/kg K)1910.10.8921867.8−2.2%
β(1/K)7.15 × 10−41.2 × 10−46.44 × 10−4−9.94%

Table 6.

Thermal expansion coefficients.

2.2.2.3.2. Specific heat

The specific heat of the magnetic nanofluid, at constant pressure, was determined using the following mixture formula [58]

ρMNF(T)cp,MNF(T)=(1ϕ)ρUTR(T)cp,UTR(T)+ϕmρNP(T)cp,NP(T),E21

where the transformer oil specific heat was determined by using

cp,UTR(T)=5.025T+1789.50E22

and the specific heat of the magnetite by using [59],

cp,NP(T)=0.6334+0.871103T,E23

where T (K) is the absolute temperature of the solid and ρis the mass density of the material.

The numerical results obtained for the magnetic nanofluid specific heat indicate a slightly decrease compared to that of the carrier liquid. In what it concerns the effect of an applied magnetic field on the specific heat capacity of a magnetic nanofluid, for a certain range of temperature, the reference literature indicates the influence of the nanoparticles volume fraction and nanofluid composition (carrier liquid and nanoparticles). Also, the magnitude and the applied field orientation relative to the gravitational field (as the experiments were conducted in gravitational field) should be considered. Korolev et al. [60] analyzed the influence of an applied magnetic field (oriented perpendicularly on gravity) on a transformer oil-based magnetic nanofluid with magnetite nanoparticles, having a solid volume fraction of 7.4%, in the temperature range from 15 to 80°C. The experiment showed that, for a certain temperature, the specific heat capacity has a maximum in the investigated range of the applied magnetic field, which, according to the authors, indicates the presence of a magneto-caloric effect.

2.2.2.3.3. Thermal expansion coefficient

Similarly, to determine the thermal expansion coefficient of the magnetic nanofluid, a corresponding mixing formula was used [61],

βMNF=βUTR[11+(1ϕFe3O4)ρUTRϕFe3O4ρNPβNPβUTR+11+ϕFe3O41ϕFe3O4ρNPρUTR],E24

where βMNF[1/K] is the thermal expansion coefficient of MNF, βUTRis the thermal expansion coefficient of the transformer oil [62], βNPis the thermal expansion coefficient of the magnetite nanoparticles [63], ρUTR=0.867g/cm3(at 20°C) and ρMNF=0.96g/cm3(at 24°C) are the measured densities of the transformer oil and the magnetic nanofluid, respectively.

The results of the calculations, summarized in Table 6, give the thermal properties at room temperature. We observe that the analyzed thermal properties have a diverging behavior. While the thermal expansion coefficient and specific heat are decreasing, the thermal conductivity is increasing. The last column is indicating the relative variation compared to the corresponding property of the carrier liquid (transformer oil).

2.2.2.3.4. Evaluation of the heat transfer potential of the magnetic nanofluid

To determine the potential performance of the magnetic nanofluid for heat transfer, we considered the figure-of-merit (FOM), as defined for natural convection [64],

FOMNC=[βρ2cpk1n1/η]n,E25

where n=0.25for laminar flow and n=0.33for turbulent flow.

The results obtained for the FOM of the carrier liquid and the magnetic nanofluid, using the properties determined above, are presented in Table 7. The comparison of the relative increase of FOM indicates that the addition of nanoparticles is advantageous for both laminar and turbulent flow.

Property/sampleUTRMNF_UTRΔX/XUTR
FOM, n=0.2518.6119.57+5.15%
FOM, n=0.3391.8596.25+4.8%

Table 7.

FOM results, obtained for the carrier liquid and for the magnetic nanofluid.

2.2.2.4. Electric permittivity

As underlined above, the use of a magnetic nanofluid in electrical engineering applications imposes restrictions regarding its insulating properties. Transformer oils are known to be electrical insulators so they are an appropriate carrier liquid for a magnetic nanofluid used in such applications. If the magnetic nanoparticles volume fraction is kept in certain limits, the magnetic nanofluid preserves its insulating properties within the required limits, too [49, 50].

We estimated the effective electric permittivity of the magnetic nanofluid εMNF, using the Maxwell-Garnett equation for mixtures:

εMNF=εUTR+3ϕFe3O4εUTRεNPεUTRεNP+2εUTRϕFe3O4(εNPεUTR),E26

with εUTRis the electric permittivity of the transformer oil and εNPis the electric permittivity of the magnetite nanoparticles, ϕFe3O4being the volume fraction of the magnetite nanoparticles.

The results are presented in Table 8, along with the relative difference between the values corresponding to the transformer oil and magnetic nanofluid, ε0being the free space permittivity, approximate equal to 8.85 × 10−12 F/m.

Property/sampleUTRNPMNF_UTRΔε/ εUTR
ε(F/m)2.2 × ε081 × ε02.26 × ε02.85%

Table 8.

Effective electric permittivity of the Fe3O4 transformer oil-based magnetic nanofluid.

We observed that for the current volume fraction of magnetic nanoparticles, the insulating properties of the magnetic nanofluid remain very close to those of the carrier liquid (UTR 40). In what concerns the effect of working temperatures in the power transformer, experimental studies showed that electrical permittivity decreases with increasing temperature in the case of transformer oils [51].

3. Heat transfer and electromagnetic field by numerical simulation for the electrical transformer cooled by a specific nanofluid

A colloidal Fe3O4 specific nanofluid dispersed in oil transformer UTR 40, named MNF/UTR 40, is utilized in a number of technologically relevant applications where external magnetic fields are used to adjust their flow. A mathematical model and numerical simulation results are useful for investigating the heat transfer properties of the magnetic nanofluid. Based on this study, it was built and tested the experimental model: low power, medium voltage, single-phased transformer type TMOf-24-5” (Figure 18) and low power, medium voltage, single-phased transformer type TMOf2-36kV-40 kVA (Figure 19). First of all, it was used for the transformer the transformer oil UTR 40 as cooling and insulating liquid. After that, this oil was drained and the experimental model was filled with magnetic nanofluid based on transformer oil MNF/UTR 40. The MNF/UTR 40 specific nanofluid has been shown to provide both thermal and dielectric benefits to transformers, and can be utilized to improve cooling by enhancing fluid circulation within transformer windings, to increase transformer capacity to withstand lightning impulses, while also minimizing the effect of moisture on typical insulating fluids. Magnetic nanofluid flow may be influenced by external magnetic fields, and the retention force of a magnetic nanofluid can be adjusted by changing either the magnetization of the fluid or the magnetic field in the region. Opposite to usual magnetic fluids, the magnetizable nanofluids destined to heat transfer should have a low concentration of magnetic nanoparticles in order to make them competitive with the non-magnetic fluids.

Figure 11.

The 2D simplified model and the FEM mesh made of triangular elements: (a) computational domain and (b) detailed view—windings, iron core, case.

Figure 12.

Magnetic field, temperature and flow fields for mono-phased transformer of low power and medium voltage, type TMOf-24-5, (a) Heat transfer and thermal flow—upper part, (b) detail—temperature, buoyancy flow, (c) heat transfer and thermal flow—bottom part and (d) magnetic field.

Figure 13.

Magnetic field and body forces when the coolant is a magnetic nanofluid, MNF/UTR 40: (a) detail (top)—magnetic body forces, (b) detail (top)—buoyancy forces, (c) detail (bottom)—magnetic body forces, (d) detail (bottom)—buoyancy forces.

Figure 14.

2D, axial model - magnetic flux density field, temperature distribution, and flow field for the horizontal design TMOf-24-5 type transformer: (a) the coolant is regular UTR 40 transformer oil and (b) the coolant is a magnetic nanofluid, MNF/UTR 40.

Figure 15.

2D, axial model - magnetic flux density field, temperature distribution, and flow field for the vertical design TMOf 2-36kV-40kVA type transformer: (a) the coolant is regular UTR 40 transformer oil and (b) the coolant is a magnetic nanofluid, MNF/UTR 40.

Figure 16.

The aggregate active parts, core and windings [44].

Figure 17.

Magnetic cores and the core rolling device [44].

3.1. Mathematical model

Several simplifying assumptions aimed and keeping the physical system within approachable software and hardware limits are requested and 2D models are best candidates, providing numerical simulation relevant results, of satisfactory accuracy. Following this path, we consider a 2D, Cartesian cross-sectional model, as shown in Figure 11.

The heat transfer and transport processes under the influence of the magnetic field for two prototypes electric transformer: low power mono-phased transformer (24 kVA), at medium voltage (20/√3//0,4/√3kV), TMOf-24-5 and low power mono-phased transformer (40 kVA), at medium voltage (30/√3//0,4/√3kV), prototype TMOf 2-36kV-40 kVA, are described by the following set of coupled partial differential equations [44]:

  • electromagnetic field—quasi-steady, harmonic diffusion,

    (jωσω2ε0εr)A+×(μ01μr1×A)σu×(×A)=Je,E27

  • momentum balance (Navier-Stokes),

    ρ[ut+(u)u]=p+μ0(M)Hfmg+μf2u+fT,E28

  • mass conservation (incompressible flow),

    u=0,E29

  • heat transfer (energy equation),

    ρcp[Tt+(u)T]=k2T+EJϕe.E30

Here: uis the velocity; pis the pressure; Tis the absolute temperature; Ais the magnetic vector field; Mis the magnetization (in the magnetic nanofluid); His the magnetic field strength; Eis the electric field strength; Jϕeis the angular component of the (external) current density (in the coil); fTis the buoyancy body force term; fmgis the magnetic body force term; σis the electrical conductivity; kis the thermal conductivity; μ0is the magnetic permeability of vacuum (μair=μrairμ0μ0;μrair1); μfis the kinematic viscosity; ρis the mass density; cpis the specific heat. Heat transfer occurs by conduction in the solid regions of the system and by convection and diffusion in the fluid region. The temperature variation in the fluid region is responsible for a gravitational flow (Boussinesq approximation), whose structure depends on the cell geometric aspect ratio and thermal conditions. All subdomains have linear physical properties, except for the magnetic nanofluid (based on transformer oil), whose magnetization characteristic is nonlinear.

The magnetic field magnetizes the magnetic nanofluid, and the corresponding body force term adds to the gravitational, thermal flow of the magnetic nanofluid coolant. The flow structure is the result of the two competing forces: thermal force and magnetic force. In this study, we deal with a super-paramagnetic magnetic nanofluid where the influence of the coercive magnetic field intensity, Hcor the remnant induction, Bris discarded. The constitutive law for the magnetic field of the magnetic fluid is then

B=μ0(H+M).E31

The magnetic field produced by the electrical current in the coil magnetizes the fluid and is responsible for the magnetic body forces that influence the thermally induced flow. The magnetization of the magnetic fluid is approximated here by the analytic formula

Mx,y=aarctan(bHx,y),E32

with a=104A/mand b=3×105m/Aare empiric constants. The magnetic body forces are then obtained out of the magnetic energy, by taking its derivatives with respect to the coordinates

fmg=μ0(M)H.E33

The strategy that we used in the numerical simulation consists of solving for the magnetic field first, and then using the active power thus obtained as heat source in the heat transfer and flow parts of the problem. The obtained solutions are steady state [65] for heat transfer and flow and quasi-steady (harmonic) for the electromagnetic field.

The main dimensions (windings, iron core, case sizes) are those of the single-phased transformer considered in our study. The amperturns of the windings correspond to the nominal working point, when the iron core exhibits lower levels of magnetization—the amperturns are compensated.

3.2. Simulation results for mono-phased transformer of low power and medium voltage type TMOf-24-5 compared to the mono-phased transformer of low power and medium voltage type TMOf2-36kV-40 kVA

Numerical simulation of the mono-phased transformer of low power and medium voltage type TMOf-24-5 evidenced that the convective heat transfer in the channels between the windings and between the windings and core (3–5 mm) is less important in the overall process, therefore it was discarded, and only conduction heat transfer was accounted for in these areas. Figure 12 shows simulation results for a non-magnetic, regular cooling fluid—the temperature field (surface color map, Figure 12ad), the thermal flow (streamlines and velocity vectors, Figure 12ac), magnetic flux density (Figure 12d, surface color map, iso-lines of magnetic vector field). Apparently, the thermal flow exhibits two minor recirculation areas—in the upper and lower part of the windings, by the top and bottom covers—trapped within a larger recirculation cell that develops by the lateral wall. For the heat transfer part of the problem, we assumed a convection (Robin) type boundary condition (the ambient temperature was assumed to be Tamb=300K, with a heat transfer coefficient of h=2W/m2K, that is, moderate natural convection.

The iron core, although less magnetized in this particular regime (compensated primary and secondary amperturns), plays a crucial role in the heat transfer problem.

When a colloidal Fe3O4 specific nanofluid MNF/UTR 40 is utilized as a coolant, magnetic body forces add to the thermal, gravitational body forces. Figure 13 displays the magnetic field and forces (magnetic and thermal). Apparently, the magnetic forces contribute differently to the overall convection flow: in the upper part of the cell they add to the buoyancy forces, whereas in the lower part they are opposite. However not unexpected, Eq. rel. (33), another important finding is the effect that the en-parts of the windings and the iron core have: these are regions of high gradient magnetic field strength, and it is here that the body magnetization forces are significant. The orientation of the magnetic forces versus the thermal forces is an important factor in providing an optimal design. We observe that the thermal gravitationally driven forces and the magnetic forces act concurrently in this plane, their combined effect being greater at the left and right end regions. Similarly, the heat transfer direction is from the hotter regions (core and windings) to the case, but with enhanced convection and increased heat removal efficiency. Comparing the two cooling options, that is, specific nanofluid MNF/UTR 40 (Figure 14b) versus regular coolant UTR 40 (Figure 14a) apparently the MNF/UTR 40 may do better in cooling the transformer. This essentially means a lower hot spot temperature by approximately 10° in this model and a more uniform temperature distribution. These results suggest that the vertical design of the low-power mono-phased transformer (40 kVA), at medium voltage (30/√3//0,4/√3kV) prototype TMOf 2-36kV-40kVA (Figure 15) may be advisable [66, 67]. This prototype TMOf 2-36kV-40kVA realized in compliance with the constructive solutions with characteristics specific for the aimed purpose presents the following advantages: reduced weight and dimensions in comparison with the current power transformers that have the same rated voltage and rated power, following the intensification of the cooling effect in the presence of the specific nanofluid MNF/UTR 40 (Figure 15b). The number of convection zones is greater when the coolant is magnetic nanofluid MNF/UTR 40 (Figure 15b) as compared to the regular coolant, that is, the UTR 40 transformer oil (Figure 15a). Also, because of the execution form of the magnetic circuit and of the metallic construction (tank-bottom-lid), the construction of the power transformer in the aggregate is realized with a smaller consumption of the main materials: copper, magnetic steel sheet and the specific nanofluid MNF/UTR 40 are included.

4. Designing the electrical transformer cooled by nanofluid with colloidal magnetic Fe3O4 nanoparticles dispersed in UTR 40 transformer oil

The low-power mono-phased transformer (40 kVA), at medium voltage (30/√3//0,4/√3kV), prototype vertical design TMOf 2-36kV-40kVA type transformer has the active part (Figures 16 and 17), magnetic iron core with the high voltage (HV) and low voltage (LV) windings fixed in a finned metallic tank constituted from two parts air-proof assembled through a soldering that is soft and capable of elastic deformation for the taking-over of the variation with temperature of the cooling liquid volume (Figure 19). The magnetic circuit is coating type, constituted of two identical cores of rectangular shape (flat-core), back to back disposal (Figure 17). The aggregate active parts (Figure 16) are the magnetic core with the high voltage and low voltage windings, fixed on a metallic lid with their axes in a vertical position, the most convenient situation for the heat transfer enhancement by the nanoparticles in the presence of the electromagnetic field. With a view to performing comparative tests related to the use of magnetic nanofluid MNF/UTR 40 as cooling and insulating fluid transformers and regular UTR 40 transformer oil cooling, the mono-phased transformer of low power and medium voltage, the horizontal design TMOf-24-5 type transformer (Figure 18) and mono-phased transformer of low power and medium voltage the vertical design TMOf 2-36kV-40kVA type transformer (Figure 19) has been achieved [44]. The numerical simulation results show that the direction of the magnetizing force in comparison with the gravitational thermal force is an important element in assuring of an optimal heat transfer. Both numerical simulations as well as laboratory measurements [6567] confirm the following aspects: about the usage of a magnetic nanofluid MNF/UTR 40 as cooling and insulating fluid for transformers, this provides for magnetization body forces that add to the thermal, gravitational forces. In the vertical layout of the transformer, these forces act concurrently with the thermal flow, and the overall effect is the enhancement of the heat transferred from the aggregate active parts (core and windings) to the ambient.

Figure 18.

Mono-phased transformer of low power and medium voltage, the horizontal design TMOf-24-5 type transformer.

Figure 19.

Mono-phased transformer of low power and medium voltage, the vertical design TMOf 2-36kV-40kVA type transformer [44].

In both cases, first of all, the regular UTR 40 transformer oil as cooling and insulating fluid was used for the transformers. After that, this oil was drained and the transformers were filled with magnetic nanofluid MNF/UTR 40 as cooling and insulating fluid.

Figures 20 and 21 show the temperature on the surface of the ribbed tank when magnetic nanofluid MNF/UTR 40 is used for the vertical design TMOf 2-36kV-40kVA type transformer after 1 h of operation. Monitoring of the temperature was achieved with the thermographic camera, FLUKE Ti 20. The temperature does not exceed the value of 54°C. Magnetic nanofluid MNF/UTR 40 provides also the increase of the transformer’s capacity to sustain over-voltages and withstand better to degradation in time due to humidity, as compared to the regular UTR 40 transformer oil coolant. Thus, transformers with reduced dimensions and higher efficiency with loading capacity and extended life duration may be designed.

Figure 20.

Temperature distribution by thermographic imaging-the tank- for mono-phased transformer of low power and medium voltage, type TMOf2-36kV-40 kVA, after 1 h of operation.

Figure 21.

3D characteristic of the temperature depending on the X and Y coordinates, associated with the thermographic image in Figure 20.

5. Nanofluid with colloidal magnetic Fe3O4 nanoparticles used in microactuation process

Based on the afore described magnetic nanofluid, we can make a microactuator whose operation complies with the principle of Pulse Width Modulation (PWM) [23, 68]. The output PWM rectangular pulse form for a pulse duty factor of 14% is presented in Figure 22. The PWM generator discharges on the microactuator magnetic nanofluid impedances, two windings L1 and L2 (Figure 23). The electromagnetic force developed by the microactuator and implicitly the movement of the magnetic nanofluid depends mainly on the windings excitation voltage pulse duty factor Ku %. Passing an electric current by the microactuator windings results a magnetic field. The net effect of this magnetic field is a mass transfer of the magnetic nanofluid. Also, the maximum amplitude of the excitation voltage is constant, Umax = 15 V. The RMS value of the current that goes through the coils of the actuator, for a fixed frequency of the PWM voltage, depends mainly on the pulse duty factor. Two windings, L1 and L2, are excited with a rectangular waveform, counter phase, in compliance with Figure 22.

Figure 22.

The output PWM rectangular pulse form, for a pulse duty factor of 14%.

Figure 23.

The microactuator with magnetic nanofluid during testing [68].

Acknowledgments

The authors express special thanks to Prof. Alexandru Mihail Morega, corresponding Member of the Romanian Academy, for valuable results concerning the numerical simulations. The research was performed with the support of UEFISCDI, PNCDI II Programme—Joint Applied Research Projects, Romania, Contract 63/2014, Environment energy harvesting hybrid system by photovoltaic and piezoelectric conversion, DC/DC transformation with MEMS integration and adaptive storage. Also, the numerical simulations were conducted in the Laboratory for Multiphysics Modeling, at UPB, with the support of the PNCDI-II “Parteneriate” Contract 21-043/2008.

© 2017 The Author(s). Licensee IntechOpen. This chapter is distributed under the terms of the Creative Commons Attribution 3.0 License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Lucian Pîslaru-Dănescu, Gabriela Telipan, Floriana D. Stoian, Sorin Holotescu and Oana Maria Marinică (March 15th 2017). Nanofluid with Colloidal Magnetic Fe3O4 Nanoparticles and Its Applications in Electrical Engineering, Nanofluid Heat and Mass Transfer in Engineering Problems, Mohsen Sheikholeslami Kandelousi, IntechOpen, DOI: 10.5772/65556. Available from:

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