Results of the linear bivariate models.
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Barely three months into the new year and we are happy to announce a monumental milestone reached - 150 million downloads.
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Some of the major developments in Turkey’s economy during the past decades has been the liberalization of capital markets and implementation of floating exchange rate regime. These developments with the rapid growth of Turkey’s economy has attracted international investors and thus increased Turkey’s integration into the global economy. Turkey, as emerging market, became attractive to foreign investors for portfolio diversification but shocks in exchange rate markets create volatility in the stock market. It can react positively or negatively to fluctuations in foreign exchange markets. Thus, exporters can benefit from the local currency depreciation due to higher export competitiveness, while importers will pay higher prices for imported goods, thus determining a company’s cash flow and market value. Causality refers to exchange rates that vary from stock markets. On the other hand, if a country’s exports depend mainly on foreign inputs, the resulting relationship between equity and exchange rates may be insignificant. Since Turkey is a net importer of goods and services, potentially, the depreciation of Turkish lira will cause the value of shares to fall.
\nThere are two main theories suggesting a relation between exchange rates and stock prices. The first is the flow-oriented exchange rate models [1] that focus on the current account or trade balance and predicts that changes in exchange rates will affects the country’s real economic variables and therefore stock prices by affecting international competition and trade balance. According to this approach, there is a positive relationship between the two and the causality from exchange rate to stock prices. Fluctuations in exchange rates makes the domestic companies more competitive in case of the depreciation of the national currency, thus increase their exports. Because, these fluctuations affect the costs and profits of many companies due to borrowing in foreign currencies to finance their operations. This affects the stock prices of firms [1].
\nSecond approach is the stock-oriented approach which predicts that movements on stock prices affect exchange rates and thus a causality from stock prices to exchange rates via capital account [2]. As capital is part of the stock, it can influence the exchange rate through the demand of money. According to this, a rising stock prices will attract capital inflows to a country and this will lead to a decline in exchange rates by increasing demand for local currency [3].
\nIt has become a generally accepted notion that these two variables are the way to go for emerging economies to enable economic growth and development. The role of exchange rate is much more important for small open economies in particular emerging markets. In this chapter we seek to shed some light on the analysis of the symmetric and asymmetric effects of exchanges rates on the stock prices in Turkey at industry level using a linear and nonlinear framework. This study is of great interest for a country that has import-oriented economy and completed its financial liberalization in the early 1990s. Because the empirical studies trying to prove the relationship between the exchange rates and the stock prices have mixed results regarding the two main views mentioned above.
\n\nFigure 1 shows the dynamics of Turkey’s three major stock market indices. The 2008 crisis is seen as the most important point of decline in the trend. Since Borsa Istanbul is generally a foreign-invested market, the performance of the Turkish stock markets is negatively affected by foreign investors via the global financial crises. During this period, the risk premium was raised for Turkey. In parallel, CDS values increased. A similar effect occurred after 2018. The Turkish economy has shown that it is not fragile and has exceeded stress tests. Thus, after 2008, the index displayed a strong rise. The depreciation of the exchange rates at the end of the period led to a downward trend in three major stock market indices.
\nStock market dynamics in Turkey (logs in TRY).
On the other hand, Figure 2 shows the developments in the exchange rate market in Turkey. The exchange rates displayed a stable outlook in the first half of the period, but an upward trend in the second half of the period. Recently, the depreciation of the exchange rate accelerated. Thus, it seems to have a negative impact on stock market performance especially when the index gets cheaper in Turkish Lira terms, so the trend is expected to turn up.
\nTurkish lira to Euro&Dollar Currency Basket.
Therefore to see whether the relationship between exchange rates and three major stock market indices is symmetric or asymmetric in Turkey, we employed four different methods: linear bivariate ARDL model is applied to investigate linear relationship between stock prices and the exchange rates; linear multivariate ARDL model employed to show that changes in some additional variables such as interest rates and industrial production have symmetric or asymmetric effects on stock prices; as exchange rates has different impact on different sectors of the economy, multivariate ARDL models employed to analyze the relationship between them. Moreover, the relationship should not be based on the linear but also on nonlinear dimension. Thus finally, nonlinear bivariate and multivariate ARDL models applied to analyze the non-linear relationship between stock prices and the exchange rates in Turkey.
\nThis study is of great interest for a country that has import-oriented economy, has completed its financial liberalization in the early 1990s, and become an attractive destination for foreign investors. The rationale for assessing the role of symmetric and asymmetric effects of exchanges rate on stock prices in Turkey is based on the perception, as expressed by [1, 2], that the stock prices can react positively or negatively to fluctuations in exchange rates. Determining the factors that cause movements in stock prices is very important and is of great interest to policy makers and investors. The role of exchange rate on stock prices is much more important for small open economies in particular emerging markets. There is no sufficient research evidence showing the links between foreign exchange rate and Turkish stock market. We believe that this study will fill the gap in the literature in this area.
\nThe rest of the chapter is organized as follows: Section 2 review the related literature; Section 3 describes data and methods applied; Section 4 presents empirical findings and discusses the implications of the analysis; and, finally, Section 5 concludes the paper and provides policy implications.
\nThe relationship between stock prices and exchange rates has been extensively studied by many researches. Some find positive association between the two [4, 5] others discover negative relations [6, 7] and even no relationship at all [8].
\nStudies on the relationship between exchange rate and stock prices in the literature can be summarized in different categories according to their empirical results. Firstly, there are some studies that find significant positive relationship between the two. For instance, the relationship between stock prices and exchange rates on financial, manufacturing, and services indices and fifteen sub-indices in Turkey investigated using Johansen cointegration test and the results show evidence that there is a long-run relationship among these indices and exchange rates. The results suggest that exchange rate exposure on financial and manufacturing industries have positive forex beta for the dollar exchange rate, but in terms of service industries there is negative forex beta [9]. A similar exercise undertook to investigate the effects of changes in foreign exchange on the stock returns on company level using panel data analysis. The results show evidence that changes in real exchange rate has positive and significant impact on stock returns in the manufacturing and trade sectors between the years 2006–2014 [10].
\nSecondly, there are some studies that find negative relationship between the two [6, 11]. For example, Akıncı and Küçükçayşı analyses the relationships between stock markets and exchange rates in 12 countries and finds that the exchange rate has negative effect on the stock market index [6]. Belen and Karamelikli investigates the causality between the exchange rates and stock returns in Turkey and finds no evidence supporting any causal relationship between the dollar exchange rate and the BIST-30 Index [11]. Tsai examine the relationship between stock price index and exchange rate in six Asian countries, namely Singapore, Thailand, Malaysia, the Philippines, South Korea, and Taiwan. Their results show that all countries in the study have negative the relationship between stock prices and exchange rates, which is in line with the portfolio balance effect [12]. Recently, the relationships between real exchange rate returns and real stock price returns in Malaysia, the Philippines, Singapore, Korea, Japan, the United Kingdom and Germany examined using dynamic conditional correlation (DCC) and multivariate generalized autoregressive conditional heteroskedasticity (MGARCH) models. The results show that there is a negative relationship between real exchange rate return and real stock price return in Malaysia, Singapore, Korea and the UK [13].
\nThirdly, there are some studies that find two-way causality between the exchange rate and stock prices [14]. For instance, Zeren and Koç examines the relationship between exchange rates and stock market indices in Turkey, Japan and England. They use using the time varying causality test and find two-way causality between the exchange rate and stock prices for during the global crises period. However, some empirical studies find one-way causality between the exchange rate and stock prices [14]. Coskun et al. investigate the link between stock index and macroeconomic variables (USD exchange rate, exports and imports, industrial production index, and gold price using monthly data for Turkey. Using Granger causality, they find one-way causality from exchange rate to BIST, and using impulse response function their results suggest positive response of BIST to exchange rate shock [4]. Aydemir and Demirhan analyses the causality between exchange rates and stock prices for national 100, services, financials, industrials, and technology indices. The results suggest that there is positive bi-directional causal relationship from technology indices to exchange rate, but in terms of national 100, services, financials and industrials indices to exchange rate the paper does provide negative causality [15]. On the other hand, Kendirli and Çankaya (2016) analyze the causal relationship between the USD and Istanbul Stock Exchange National 30 Index from 2009:01 to 2014:12 monthly data and find no causal relationship between USD and BIST-30 index returns [8].
\nFourthly, there are some studies that investigates short and long-run relationship between the two [16]. Recently, the relationship between the stock prices and exchange rates, specifically BIST 100 and 23 sectors indexes investigated using ARDL model. The results suggest that the long run relationship exist only between exchange rate and textile, wholesale and retail, and technology indices [17]. The short and long-term relations between exchange rate and financial sector index, industrial sector index, service sector index and technology sector index investigated in Turkey [18]. The results suggest that exchange rate has no long term relationship with stock prices and the sectors. However, in short term relationship, the results show that exchange rate has bidirectional causality with stock prices, technology and service sectors while a unidirectional causality with financial sector index. Akel and Gazel (2014) investigate the long-run and short-run equilibrium relationships between real effective industrial index in Turkey. Based on ARDL cointegration analysis, they find that there is a positive relationship between industrial index and Dollar Index and Euro/TL exchange rate, but there is no evidence on the relationship between real effective exchange rate and industrial index. Based on VECM model, they find that industrial index is positively related to the REER while it is negatively related to the Dollar Index and Euro/TL exchange rate [19].
\nThis study investigates symmetric and asymmetric effects of exchange rates on three major stock market indices in Turkey using four different models. Firstly, linear and nonlinear bivariate ARDL models are estimated where the exchange rates are the only determinant of stock prices. The linear models are used to capture the symmetric effects of exchange rate changes while the nonlinear models are applied to capture asymmetric effects of exchange rate changes on stock prices.
\nFollowing Pesaran et al. [20] and Shin et al. [21] we apply the following the bivariate model to account for cointegration between exchanges rate and stock prices in Turkey.
\nwhere \n
By now, we basically assume that exchange rate changes have symmetric effects on stock prices, but it might be possible that the effects could be asymmetric. In order to assess whether exchange rate changes have asymmetric effects on stock prices, we decompose the exchange rates into its positive and negative partial sums. For example, there might be differences between increases and decreases of the short-run interest rates. The partial sum of positive values is computed by replacing negative values with zeros as \n
The \n
Thus, the error correction form of the Eq. (3) takes the following form with POS and NEG variables.
\nSecondly, linear and nonlinear multivariate ARDL models are estimated where industrial production index (IP), volatility index (VIX) and interest rates (IR) are used as a determinants of stock prices in Turkey. In order to account the effect of these variables on stock prices we employ a linear multivariate model of Moore & Wang [22] and Bahmani-Oskooee & Saha [23] as follows:
\nwhere \n
As the interest rates are significant determinants of stock prices [25, 26], we use the short term (overnight) interest rates as a broad measure of financing costs. However, the effects of on stock prices are ambiguous [27, 28]. And finally, considering the international effects and theoretical predictions [29, 30], the volatility index is included in the model.
\nFrom Eq. (5), the coefficients estimate we get are the only long run effects. In order to infer the short-run effects, the Eq. (5) need to be rewrite in an error correction modeling format proposed by Pesaran et al. [20]. Therefore, we follow Pesaran et al.’s [20] bound testing approach and consider the following error-correction forms of multivariate model respectively:
\nThe Eq. (6) give short-run as well as long-run estimates in one step, where \n
Once the cointegration established, the long-run effects of exchange rates, industrial productions, interest rates and volatility index on stock prices are captured by the estimates of \n
The nonlinear multivariate ARDL models are constructed to assess the asymmetric effects of exchange rate changes on stock prices as follows:
\nWhere the exchange rate is replaced by new generated POS and NEG variables. Thus the nonlinearity comes from the two new variables where POS refers appreciation of home currency and NEG refers depreciation of the home currency.
\nIn this chapter both linear and nonlinear ARDL models are estimated for bivariate and multivariate models by using monthly data over the period of 2003 M1 to 2018 M12 for three major stock market indices in Turkey. The results of short and long-run estimates of both linear and nonlinear for the bivariate and multivariate models are reported in Tables 1 and 2. Each of the tables consist of three panels: Panel A reports the short run estimates, Panel B reports the long-run estimates and the diagnostic statistics are then reported in Panel C. To ensure one of the requirements of Pesaran et al.’s [20] method that the variables could be I(0) or I [1] but not I [2], we use the traditional Augmented Dickey-Fuller (ADF) tests on levels as well as the first differenced variables. The lag order of the ADF test statistics is determined by the Akaike Information Criterion (AIC) and the results show that there are no I [2] variables.
\nIn the bivariate models, the exchange rates are considered as the determinant of stock markets. Table 1 gives the result of the linear bivariate modes. Looking at the linear model from Panel A, the short run coefficients associated with exchange rates are significant for all stock markets. The results show that all stock market indices are effected negatively by exchange rates changes as expected in the economic theory. The panel B shows that there is a positive long-run relationship between exchange rates and all markets.
\nPanel C reports the diagnostics statistics. The results of F test are slightly above the upper bound critical value of 3.35 in all stock indices. The error-correction model denoted by ECM test which shows negative and significant coefficients for all markets. Moreover, the LM test is also applied and the results show insignificant for all markets suggesting that there is no autocorrelation in the optimum model. Ramsey’s RESET statistics are also reported to judge misspecification. For instance, if the test statistics of RESET test is more than the critical value of 3.84, it indicates a misspecification problem in the model at some significance level. Given its critical value, the RESET statistic is insignificant for all stock market indices, suggesting that the model is correctly specified in the sector. The CUSUM and CUSUM square tests are also reported to establish stability of the short run and the long run estimates. The test results show that the estimated parameters for all stock market indices are stable. As can be seen, estimates are stable at least by one of the tests. Based on the above results, we can conclude that the exchange rate has short-run effects on three major stock market indices (BIST All, BIST100 and BIST30) in Turkey.
\nHowever, we would also like to see whether the short-run effects change if non-linear adjustment process used. Then the answer will be based on the results of non-linear ARDL models reported in Table 2. The results show that the currency appreciation (ΔPOS) has significant negative short-run effects on all markets, while depreciation (ΔNEG) has no effect as it is insignificant. This results suggests that exchange rate changes in Turkey have asymmetric effect on stock indices in Turkey.
\nWhen we look at the long-run effects in Panel B, the currency appreciation has positive impact on all stock indices, but the effects are statistically insignificant. The currency depreciation also has no effect on any indices in Turkey. In order to see whether the long-run assessment is valid, we report F test and ECMt-1 test results. In order to further validate the short-run and long-run asymmetric effects, the equality of short-run and long-run coefficient estimates is also tested applying Wald test. As for the long-run asymmetry we test whether λ2 = λ3. According to the Wald test statistic, the asymmetry effects between exchange rates and stock prices are supported for all markets in the short-run.
\n\nTables 3 reports the results of short and long-run estimates of linear multivariate models for BIST All Shares, BIST 100 and BIST 30 stock prices. Panel A captures the symmetric effects of exchange rates on stock prices as well as other macroeconomics explanatory variables. The results show that all markets namely, BIST All, BIST100 and BIST30, are negatively affected by exchange rate changes. These markets on the other hand have a positive and statistically significant relationship with industrial production index implying that economic activity in Turkey has a significantly positive impact on the stock markets in the short run.
\nHowever, all markets have affected negatively by an increase in interest rates which implies that high interest rates lead to decrease in the investment level in the country and hence decrease economic activity. Likewise, volatility index (VIX) have a negative relationship with all stock market indices which implies that an increase in uncertainty lead to decrease the profitability of firm and thus lead to decrease stock prices in the short run.
\nVariables | \nBIST All | \nBIST 100 | \nBIST 30 | \n
---|---|---|---|
\n | \n | ||
\n\n | \n−0.46(−7.01) *** | \n−0.45(6.94)* ** | \n−0.45(−6.97) *** | \n
\n\n | \n−1.21 (−5.20) *** | \n−1.25(5.37)* ** | \n−1.28(−5.46) *** | \n
\n\n | \n−0.62 (−2.52) * | \n−0.62(2.53)** | \n−0.6 (−2.4) * | \n
\n | \n0.46(2.93) ** | \n0 .47(2.95)*** | \n0.51(3.03) ** | \n
\n | \n | ||
\n\n | \n1.86 (3.45) *** | \n1.82(3.43)*** | \n1.76(3.46) *** | \n
\n | \n | ||
Adjusted \n | \n0.327 | \n0.33 | \n0.33 | \n
\n\n | \n4.35 | \n4.47 | \n4.72 | \n
\n\n | \n−0.05 (−2.84) ** | \n−0.04(2.87)*** | \n−0.05(−2.95) ** | \n
\n\n | \n3.91 (0.14) | \n3.97(0.14) | \n3.68(0.16) | \n
\n\n | \n0.69 (0.56) | \n0.62(0.60) | \n0.55(0.65) | \n
CS (\n | \nStable | \nStable | \nStable | \n
Results of the linear bivariate models.
Notes: Numbers inside the parentheses are t-ratios. Superscript *** represents the significance at 1% level, ** at the 5% level and * at the 10% level. The ∆ denotes the first difference of the variables.
Variables | \nBIST All | \nBIST 100 | \nBIST 30 | \n
---|---|---|---|
\n | \n | ||
\n\n | \n−0.45 (−6.76)*** | \n−0.442(6.70)*** | \n−0.44(−6.69)*** | \n
\n\n | \n−1.58(−5.13)*** | \n−1.62(5.27)* ** | \n−1.66(−5.33)** | \n
\n\n | \n−0.92(−2.85)** | \n−0.92(2.84)* ** | \n−0.88(−2.68)** | \n
\n\n | \n0.02 (0.20) | \n0.0219(0.25) | \n0.02(0.23) | \n
Constant | \n0.88** (3.05)** | \n0.88(3.09)*** | \n0.94(3.18)** | \n
\n | \n | ||
\n\n | \n0.81 (1.20) | \n0.81(1.20) | \n0.78(1.19) | \n
\n\n | \n0.22 (0.19) | \n0.266(0.23) | \n0.24 (0.21) | \n
\n | \n | ||
Adjusted \n | \n0.335 | \n0.34 | \n0.34 | \n
\n\n | \n4.67* | \n4.76* | \n5,01** | \n
\n\n | \n−0.08(−2.68) ** | \n−0.082(2.71)*** | \n−0.09(−2.81) *** | \n
\n\n | \n3.64 (0.16) | \n3.51(0.17) | \n3.31(0.19) | \n
\n\n | \n1.11 (0.35) | \n1.05(0.37) | \n0.99(0.40) | \n
CS (\n | \nStable | \nStable | \nStable | \n
Wald (short run) | \n37.99*** | \n39.34*** | \n38,28*** | \n
Wald (long run) | \n0.79 | \n0.71 | \n0.76 | \n
Results of the non-linear bivariate models.
Notes: Numbers inside the parentheses are t-ratios. Superscript *** represents the significance at 1% level, ** at the 5% level and * at the 10% level. The ∆ denotes the first difference of the variables.
Variables | \nBIST All | \nBIST 100 | \nBIST 30 | \n
---|---|---|---|
\n | \n | ||
\n\n | \n−0.23(3.98)*** | \n−0.19(3.43)*** | \n−0.20(.50)*** | \n
\n\n | \n−0.84(4.23)*** | \n−1.00(5.07)*** | \n−1.01(5.03)*** | \n
\n\n | \n−0.45(2.26)** | \n\n | \n |
\n\n | \n−0.60(3.88)*** | \n−0.56(3.64)*** | \n−0.57(3.56)*** | \n
\n\n | \n1.36(4.10)*** | \n1.41(8.24)*** | \n1.36(7.84)*** | \n
\n\n | \n−0.15(2.06)** | \n−0.14(3.82)*** | \n−0.14(3.72)*** | \n
Constant | \n0.69(2.06)** | \n0.71(2.10)** | \n0.87(2.56)** | \n
\n | \n | ||
\n\n | \n0.22(1.09) | \n0.13(0.65) | \n0.15(0.75) | \n
\n\n | \n−2.98(4.61)*** | \n−2.88(4.33)*** | \n−2.95(4.35)*** | \n
\n\n | \n1.75(4.06)*** | \n1.74(3.93)*** | \n1.60(3.50)*** | \n
\n\n | \n−0.17(1.96)* | \n−0.21(2.25)** | \n−0.21(2.22)** | \n
\n | \n | ||
Adjusted \n | \n0.59 | \n0.58 | \n0.57 | \n
\n\n | \n4.61** | \n429** | \n4.22** | \n
\n\n | \n−0.20(3.76)*** | \n−0.19(3.63)*** | \n−0.19(3.62)*** | \n
\n\n | \n2.29(0.31) | \n4.28(0.11) | \n2.69(0.26) | \n
\n\n | \n2.48(0.06) | \n2.43(0.07)* | \n1.54(0.20) | \n
CS (\n | \nUnstable | \nStable | \nStable | \n
Results of the linear multivariate models.
Notes: Numbers inside the parentheses are t-ratios. Superscript *** represents the significance at 1% level, ** at the 5% level and * at the 10% level. The ∆ denotes the first difference of the variables.
When we look at the long run coefficient presented in Panel B, the industrial production index carries significant and positive relationship with all markets while interest rates and volatility index carries negative and significant relationship with stock prices in Turkey. Focusing on the exchange rate on stock prices, we found that in the long run the exchange rate changes affect stock prices positively. Thus the short run relationship between stock prices and exchange rate is not sustained in the long run. When cointegration established among variables then the long run relationship will be relevant. And thus we carry diagnostic statistics reported under Panel C. The F statistic is slightly above the upper bound critical value of 3.35 in all stock prices. The F statistic is statistically significant for all markets which establishes cointegration among variables. We also carry ECM test which is another indication of cointegration and the lagged error term (\n
We also test the asymmetric effects of exchange rate changes on stock prices using the nonlinear multivariate models (see Table 4). Thus we decompose the exchange rates changes into its positive (\n
Variables | \nBIST All | \nBIST 100 | \nBIST 30 | \n
---|---|---|---|
\n | \n | ||
\n\n | \n−0.22(3.83)*** | \n−0.19(3.39)*** | \n−0.20(3.45)*** | \n
\n\n | \n−1.07(4.11)*** | \n−1.21(4.61)*** | \n−1.23(4.57)*** | \n
\n\n | \n−0.58(2.04)** | \n\n | \n |
\n\n | \n−0.06(0.45) | \n−0.19(1.41) | \n−0.16(1.24) | \n
\n\n | \n−0.45(2.29)** | \n−0.33(1.73)* | \n−0.35(1.74)* | \n
\n\n | \n1.38(7.98)*** | \n1.37(7.83)*** | \n1.32(7.39)*** | \n
\n\n | \n−0.16(4.27)*** | \n−0.17(4.37)*** | \n−0.17(4.25)*** | \n
Constant | \n0.86(1.64)* | \n1.21(2.38)** | \n1.35(2.57)** | \n
\n | \n | ||
\n\n | \n−0.017(0.06) | \n−0.26(1.06) | \n−0.22(0.85) | \n
\n\n | \n−0.029(0.46) | \n−0.84(1.46) | \n−0.77(1.27) | \n
\n\n | \n−2.00(2.43)** | \n−1.48(1.89)* | \n−1.60(1.94)** | \n
\n\n | \n1.65(3.07)*** | \n1.31(2.33)** | \n1.19(2.00)** | \n
\n\n | \n−0.19(1.62)* | \n−0.31(2.58)** | \n−0.30(2.42)** | \n
\n | \n | ||
Adjusted \n | \n0.59 | \n0.58 | \n0.57 | \n
\n\n | \n4.18** | \n4.17** | \n4.08** | \n
\n\n | \n−0.22(4.16)*** | \n−0.22(4.11)*** | \n−0.21(4.05)*** | \n
\n\n | \n2.51(0.28) | \n4.56(0.11) | \n2.97(0.22) | \n
\n\n | \n1.4(0.22) | \n1.48(0.21) | \n0.77(0.50) | \n
CS (\n | \nStable | \nStable | \nStable | \n
Wald (short-run) | \n13.35*** | \n10.06*** | \n10.44*** | \n
Wald (long-run) | \n0.49 | \n2.50 | \n2.06 | \n
The results of the non-linear multivariate models.
Notes: Numbers inside the parentheses are t-ratios. Superscript *** represents the significance at 1% level, ** at the 5% level and * at the 10% level. The ∆ denotes the first difference of the variables.
The aim of this chapter is multiresolution analysis with the application of advanced economic techniques using four different ARDL models to shed some light on the analysis of the symmetric and asymmetric impact of exchange rates on three major stock market indices in Turkey using monthly data from 2003M1 to 2018M12. This chapter also attempts to differentiate the short-run and long-run relationship between exchange rates and market indices. The motivating question is whether the relationship between the two is symmetric or asymmetric in Turkey? To answer the question, we employed four different methods: linear bivariate ARDL model is applied to investigate linear relationship between stock markets and the exchange rates; linear multivariate ARDL model employed to show that changes in some additional variables such as interest rates and industrial production have symmetric or asymmetric effects on stock markets; as exchange rate has different impact on different sectors of the economy, multivariate ARDL models employed to analyze the relationship between them. Moreover, the relationship should not be based on the linear but also on non-linear dimension. Thus finally, non-linear bivariate and multivariate ARDL models applied to analyze the non-linear relationship between stock market indices and the exchange rates in Turkey.
\nThis study is of great interest for a country that has import-oriented economy, has completed its financial liberalization in the early 1990s, and become an attractive destination for foreign investors. The rationale for assessing the role of symmetric and asymmetric effects of exchanges rate on stock markets in Turkey is based on the perception, as expressed by (Dornbusch and Fischer 1980 and Frankel 1992), that the stock markets can react positively or negatively to fluctuations in exchange rates. Determining the factors that cause movements in stock markets is very important and is of great interest to policy makers and investors. The role of exchange rates on stock markets is much more important for small open economies in particular emerging markets. There is no sufficient research evidence showing the links between foreign exchange rate and Turkish stock market. We believe that this study will fill the gap in the literature in this area.
\nThe findings show that exchange rates have asymmetric effects on all three major stock market indices both in the short and long-run. When we look at the long-run, the currency appreciation has positive and significant effect on stock market indices but currency depreciation does not have an effect. This finding is in line with the understanding that Turkish sectors heavily depends on the import of raw and intermediate goods. The results also show that the economic activity has positive and significant effects on three major stock market indices implying that it is the main determinant in the long-run. Moreover, interest rates and volatility index were negative and significant in all markets. Thus, it has important implications for policy makers to provide stable prices and diverse investors.
\nhttps://orcid.org/0000-0003-4565-9581.
\nPOMs is one of the most outstanding materials in modern chemistry, as the metal-oxide clusters with abundant structures and interesting properties [1, 2, 3, 4, 5, 6], which render them to potential applications in electrochemistry [7, 8], photochemistry [9, 10], catalytic fields [11, 12], and so on (Figure 1). Chalkley reported the photoredox conversion of H3[PW12O40] into a reduced POM by photoirradiation with UV light in the presence of 2-propanol as a reducing reagent in 1952 [13]. Hill et al. started systematic investigation of photoredox catalysis using POMs in the 1980s [14]. Accordingly, POMs photocatalysis has been applied to a wide range of reactions, including H2 evolution, O2 evolution, CO2 reduction, metal reduction, and the degradation of organic pollutants and dyes [15, 16, 17, 18, 19, 20].
The potential application field of arsenomolybdates.
POMs are subdivided into isopolyoxometalates, which feature addenda metal and oxygen atoms, and heteropolyoxometalates, where a central heteroatom provides added structural stabilization and enables reactivity tuning [21]. In recent years, the research of POMs is mainly focused on heteropolyoxometalates. The arsenomolybdates are essential member of the heteropolymolybdates family [22], because of the redox properties of Mo and As atoms. The discoveries of many excellent articles on arsenomolybdates for ferromagnetic, antitumor activity, electrocatalysis properties, and lithium-ion battery performance have been reported in the last years [23, 24, 25, 26]. However, there is no stress and discuss on the progress of arsenomolybdates for degradation of organic dyes. Arsenomolybdates possess high-efficient proton delivery, fast multi-electron transfer, strong solid acidity and excellent reversible redox activity [27], which may result to prominent photocatalytic activities. In particular, the integration of metal-organic frameworks (MOFs) into arsenomolybdates for photocatalysis has attracted widespread attention over the past decade, since MOFs combine porous structural and ultrahigh internal surface areas.
Based on these results, we provide a summary of recent works in the synthesis, structure, the photocatalytic activity, reaction kinetics and mechanism mechanisms of arsenomolybdates, which aim at finding the direction followed with the opportunities and challenges for the arsenomolybdates photocatalysis to accelerate the step to realize its practical application in degradation of organic dyes.
Arsenomolybdates crystals reported were almost synthesized via self-assembly processes using hydrothermal method (Figure 2). Many factors in the synthetic process should be considered, such as reaction time and temperature, concentration of staring materials, compactness, pH values, and so on. The some experiments indicate that the temperatures are in the range of 110–180°C for srsenomolybdates synthesized, when the pH value of the mixture is adjusted to approximately 3–6.8, [HxAs2Mo6O26](6 − x)− (abbreviated {As2Mo6}), [(MO6)(As3O3)2Mo6O18]4− (abbreviated {As6Mo6}) and [AsIIIAsVMo9O34]6− (abbreviated {As2Mo9}) types were easy to formed, when the pH value is within the range of 2.5–5.5 and 2–4, [AsMo12O40]3− (abbreviated {AsMo12}) and [As2Mo18O62]6− (abbreviated {As2Mo18}) types were successfully synthesized. At the same time, the choice of transition metal, organic ligand, and molybdenic source have also affect for arsenomolybdates crystals. Therefore, further exploration of synthetic conditions is necessary, which can provide more experimental data for arsenomolybdates.
The synthesis chart of arsenomolybdates crystal.
Up to now, various structures of arsenomolybdates were reported and discussed in detail. The following types are classical arsenomolybdates clusters: (i) {As2Mo6} type, Pope’s group reported the first {As2Mo6} cluster [28], in which the Mo6O6 ring is constructed from six MoO6 octahedra connected via an edge-sharing mode, the opposing faces have two capped AsO4 tetrahedra. Then Zubieta’s group and Ma’s group reported [MoxOyRAsO3]n− (RAsO3 = organoarsenic acid) and [Mo6O18(O3AsPh)2]4−(Ph = PhAsO3H2) clusters [29, 30]. (ii) {As6Mo6} type, which is derived from the A-type Anderson anion [(MO6)Mo6O18]10−, the central {MO6} octahedron is coordinated with six {MoO6} octahedra hexagonally arranged by sharing their edges in a plane. The cyclic As3O6 trimers are capped on opposite faces of Anderson-type anion plane. Each As3O6 group consists of three AsO3 pyramids linked in a triangular arrangement by sharing corners and bonded to the central MO6 octahedron and two MoO6 octahedra via μ3-oxo groups. Wang and co-workers reported the compound (C5H5NH)2(H3O)2[(CuO6)Mo6O18(As3O3)2] [31], Zhao groups synthesized the compound [Cu(arg)2]2[(CuO6)Mo6O18(As3O3)2]·4H2O [32]. (iii) {AsMo12} type, has a AsO4 tetrahedron at the center and 12 surrounding MoO6 octahedra, such as [NBu4]6[Fe(C5H5)2][HAsMo12O40]2 [33]. {As2Mo9}) type, is derived from the trivacant Keggin moiety, which is capped by a triangular pyramidal {AsO3} group, e.g., [Cu(en)2H2O]2{[Cu(en)2][Cu(en)2AsIIIAsVMo9O34]}2·4H2O and [Cu(en)2 (H2O)]4[Cu(en)2(H2O)2]{[Cu(phen)(en)][AsIIIAsVMoVI9O34]2} [34, 35]. (iv) {As2Mo18} type, as a classical Wells–Dawson cluster, can be described as two [AsMo9O34]9− units derived from an Keggin anion by the removal of a set of three corner-sharing MoO6 octahedra, e.g., [Himi]6[As2Mo18O62]·11H2O [36].
In comparison with the classical arsenomolybdates, many nonclassical arsenomolybdates have also been prepared in the past of years, such as Ag12.4Na1.6Mo18As4O71 [37], (NH4)11[AgAs2Mo15O54]3·6H2O·2CH3CN [38], [AsIII2FeIII5MMo22O85 (H2O)]n− (M = Fe3+, n = 14; M = Ni2+ and Mn2+, n = 15) [39], {Cu(2,2′-bpy)}2{H2As2Mo2O14} [40], [{Cu(imi)2}3As3Mo3O15]·H2O [41], and so on. The novel arsenomolybdate structure is gaining more and more attention.
In recent years, POMs have attracted a lot of attention as photocatalysts for the decomposition of wastewater [42]. Organic dyes, such as methylene blue (MB), rhodamine B (RhB), azon phloxine (AP), and so on, is a typical organic pollutant in waste water. In this work, the photocatalytic activities of arsenomolybdates are investigated via the photodecomposition of organic dyes under UV light irradiation (Figure 3). The photocatalytic reactions were conducted using a common process [27]: arsenomolybdates and organic dyes solution were mixed and dispersed by ultrasonic. The suspension was stirred until reached the surface-adsorption equilibrium. Then, a high pressure Hg lamp was used as light source to irradiate the mixture, which was till stirred for keeping the mixture in suspension. At regular intervals, the sample was withdrawn from the vessel and arsenomolybdates was removed by several centrifugations, and the clear liquid was analyzed by using UV–Vis spectrophotometer.
The structure of dyes and photodecomposed product.
The common arsenomolybdates photocatalysis are shown in Figure 4. The photocatalytic activities of arsenomolybdates are review via the photodecomposition of MB under UV light irradiation (Figure 5). Su groups reported six compounds with [HxAs2Mo6O26](6 − x)− clusters and copper-organic complexes. Six {As2Mo6} compounds were irradiated for 135 min under, the photocatalytic decomposition rates are 94.5%, 93.0%, 92.1%, 92.2%, 93.6%, and 96.5%, respectively [43]. Then the {Co(btb)(H2O)2}2{H2As2Mo6O26}·2H2O exhibited better photocatalytic activity in the degradation of MB at the same process, the photocatalytic decomposition rate is 94.27% [44]. Su groups synthesized two {As2Mo6} compounds with [HxAs2Mo6O26](6 − x)− clusters and free organic ligands, photocatalytic activities of they are detected, the conversion rate of MB is 91.8% and 92.2% when adding two {As2Mo6} compounds as the catalyst 160 min later, respectively [45].
The common arsenomolybdates photocatalysis polyoxoanion.
The arsenomolybdates photocatalytic decomposition rates of MB under UV irradiation.
The above data show that the photocatalytic activity of the compound composed of [HxAs2Mo6O26](6 − x)− clusters and metal-organic complexes is higher than supramolecular assemblies based on isomers [HxAs2Mo6O26](6 − x)− clusters in the degradation of MB under UV irradiation, which maybe that the polyoxoanions can connect with transition metals in diverse modes, which enhanced the contact area between catalysts and substrates availing charge-transfer.
The three {As6Mo6} compounds, ((phen)(H2O)4]2 [(CoO6)(As3O3)2Mo6O18]·2H2O,{[Co(phen)2(H2O)]2[(CoO6)(As3O3)2Mo6O18]}·4H2O and {[Zn(biim)2(H2O)]2[(ZnO6)(As3O3)2Mo6O18]}·4H2O), as catalysts under UV light irradiation after 180 min [46], the photocatalytic decomposition rates of MB are about 92.64, 93.40, and 94.13%.
Yu groups prepared three Keggin arsenomolybdates, the photocatalytic decomposition rates of MB are 94.2% for (Hbimb)(H2bimb)[AsMo8VIVV4Co2O40], 96.1% for (Hbimb)2(H2bimb)0.5 [AsMo8VIVV4Cu2O40]·1.5H2O, 99.8% for [CuI (imi)2][{CuI(imi)2}4{AsMo6V Mo6VIO40(VIV2O2)}] after 90 min irradiation, respectively [47].
Four biarsenate(III) capped Keggin arsenomolybdates with tetravanadium(IV) substituted were prepared, which exhibit excellent degradation activity for MB under UV light. The absorption peaks of MB reduced obviously after 120 min in the presence of four Keggin arsenomolybdates, the degradation rates for MB are 92.9%, 95.8%, 96.6%, and 97.7%, respectively [48].
The photocatalytic decomposition rate of MB is about 96% for [{Cu(btp)2}3{As2Mo18O62}] after 40 min [26], and the photocatalytic decomposition rates were 96.32% and 95.57% for [Cu(pyr)2]6[As2Mo18O62] and [Ag(pyr)2]6[As2Mo18O62] after irradiation for 45 min [25]. Yu reported that (H2bimyb)3(As2Mo18O62) exhibits high-efficient degradation ability for MB under UV light. After UV light irradiation of (H2bimyb)3(As2Mo18O62) for 70 min, the photocatalytic decomposition rate is 95.82% [49].
It is reported that the conversion rate of MB is 94.6% when adding compound [Cu(imi)2]5Na[(AsO4)Mo9O27(AsO3)]·5H2O as the photocatalyst after 105 min [50]. {Cu(2,2′-bpy)}2{H2As2Mo2O14} as photocatalyst was investigated via the photodecomposition of MB under UV light irradiation and the same conditions. The photocatalytic decomposition rate of MB that is 96.7% after 180 min [40].
The photocatalytic activities of arsenomolybdates as photocatalysts are review via the photodecomposition of RhB under UV light irradiation. The photocatalytic decomposition rates of RhB are about 96.34 and 95.7% for {Co(btb)(H2O)2}2{H2As2Mo6O26}·2H2O and [{Cu(abi){H4AsIIIAsVMo9O34}](abi)4[Cu(abi)2]·H2O as photocatalysts under UV light irradiation after 135 and 140 min, respectively [27, 44]. [{Cu(btp)2}3{As2Mo18O62}] as photocatalyst was investigated decomposition rate of RhB after 40 min is about 96% [26]. The photocatalytic decomposition rates of RhB are 94.42 and 95.07% for [M(pyr)2]6[As2Mo18O62] (M = Cu,Ag) under UV light irradiation after 45 min [25].
The photocatalytic decomposition rates of RhB are 95.9% for (Hbimb)(H2bimb)[AsMo8VIVV4Co2O40], 94.3% for (Hbimb)2(H2bimb)0.5[AsMo8VIVV4Cu2O40]·1.5H2O, 95.8% for [CuI (imi)2][{CuI(imi)2}4{AsMo6VMo6VIO40(VIV2O2)}] after 108 min irradiation, respectively [47].
AP, as one of the azo dyes, is relatively difficult to degrade, and so it was used as target molecules to evaluate the photocatalytic activity of arsenomolybdates under UV irradiation. The photocatalytic activity of {pyr}{Hbib}2{AsIII2(OH)2AsV2Mo18O62} was evaluated for the degradation of AP under UV irradiation [51], the degradation rate is 91.02% after UV light irradiation 90 min. In addition, the photocatalytic activity of noncapped 0D analog (H2bimyb)3(As2Mo18O62) was also studied under the same condition. Compared with {pyr}{Hbib}2 {AsIII2(OH)2AsV2Mo18O62}, only 32.76% of AP was degraded by (H2bimyb)3(As2Mo18O62) after 90 min [49], which indicates that the photocatalytic degradation effect of the bi-arsenic capped Dawson compound on AP is much better than that of noncapped analog. The 3D Dawson organic-inorganic hybrid arsenomolybdate, {Ag(diz)2}3[{Ag(diz)2}3(As2Mo18O62)]· H2O exhibits merit photocatalytic properties for degradation of refractory dyes AP under UV light [52], the photocatalytic decomposition rate is 93.24% after 80 min.
The photocatalytic activities of (imi)2[{CuI(imi)2}2{Na(imi)2} {AsIIIAs2VMo18O62}]·2H2O and {CuI0.5(trz)}6[{CuI0.5(trz)}6(As2Mo18O62)] were evaluated for degradation of AP under UV irradiation. The photocatalytic decomposition rates are 89.06 and 96.38% after 80 min [53]. The photocatalytic decomposition rates are 92.49% of AP for [Cu(pyr)2]6[As2Mo18O62] and 92.25% of AP for [Ag(pyr)2]6[As2Mo18O62] after irradiation 135 min [25].
On the basis of the aforementioned points, {As2Mo18} type arsenomolybdates with 3D networks possess the highest photocatalytic activities for photodecomposition of MB, RhB and AP under UV light irradiation. The following factors are maybe considered: First, quantity of Mo and O atoms in unit cell is a factor, which can increases the amount of charge-transfer from HOMO of O to LUMO of Mo, generating more electron-hole pairs. Second, the enhanced photocatalytic activity may have arisen from the 3D architecture, more extended 3D frameworks favor the migration of excited holes/electrons to the surfaces of {As2Mo18} type to initiate the photocatalytic degradation reaction with organic dyes.
Experimental and theoretical studies of arsenomolybdates photocatalysis have revealed that it typically proceeds based on the following mechanism [41, 42, 48, 52]: Irradiated of arsenomolybdates by UV light with energy equal to or greater than the Eg value of itself, which induces intramolecular charge-transfer from the HOMO of O to the LUMO of Mo, leading to the formation of photoexcited states, subsequently photogenerated electron–hole pairs were generated. The O2 captures electron to form •O2ˉ and the hole reacts with H2O or OH− ions to form •OH. The •O2ˉ and •OH radical decompose organic dyes’ molecules into the final product, the detail of photocatalytic reaction is shown in Eqs. (1)–(4).
Some research data show that the samples were washed and dried after the arsenomolybdates as photocatalysis several cycles, and the infrared or X-ray diffraction test were carried out, the infrared spectra or X-ray diffraction data of arsenomolybdates demonstrate that there are almost unchanged before and after photocatalytic reaction [44, 45, 46, 47, 48], which indicate that arsenomolybdates photocatalysis have excellent structural stability.
In this chapter, the arsenomolybdates are presented, and the attention is mainly focus on photocatalytic degradation of organic dyes. Various strategies are summarized and discussed based on the knowledge of synthesis, structure and photocatalytic properties for arsenomolybdates, which reflects the major directions of recent research in this field. There are vast research opportunities as new arsenomolybdates architectures are discovered in future; the great effort to promote the development of arsenomolybdates is needed to reduce the gap with commercial applications.
This work was supported by the Project of Introducing Talent of Guangdong University of Petrochemical Technology (2019rc052).
The authors declare no competing financial interest.
L-arginine
ethylenediamine
imidazole
2,2′-bipyridine
1,4-bis(1,2,4-triazol-1-y1)butane)
1,10′-phenanthroline
biimidazole
1,4-Bis(imidazol-l-yl)butane
1,3-bis(1,2,4-triazol-1-yl)propane
pyrazole
1, 4-bis(1-imidazoly)benzene
1,4-Bis(imidazol-l-ylmethyl) benze
2-aminobenzimidazole
1,4-bis(1-imidazolyl)benzene
1,2-diazole
1,2,3-triazole
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