Factors affecting wind power generation.
\\n\\n
Dr. Pletser’s experience includes 30 years of working with the European Space Agency as a Senior Physicist/Engineer and coordinating their parabolic flight campaigns, and he is the Guinness World Record holder for the most number of aircraft flown (12) in parabolas, personally logging more than 7,300 parabolas.
\\n\\nSeeing the 5,000th book published makes us at the same time proud, happy, humble, and grateful. This is a great opportunity to stop and celebrate what we have done so far, but is also an opportunity to engage even more, grow, and succeed. It wouldn't be possible to get here without the synergy of team members’ hard work and authors and editors who devote time and their expertise into Open Access book publishing with us.
\\n\\nOver these years, we have gone from pioneering the scientific Open Access book publishing field to being the world’s largest Open Access book publisher. Nonetheless, our vision has remained the same: to meet the challenges of making relevant knowledge available to the worldwide community under the Open Access model.
\\n\\nWe are excited about the present, and we look forward to sharing many more successes in the future.
\\n\\nThank you all for being part of the journey. 5,000 times thank you!
\\n\\nNow with 5,000 titles available Open Access, which one will you read next?
\\n\\nRead, share and download for free: https://www.intechopen.com/books
\\n\\n\\n\\n
\\n"}]',published:!0,mainMedia:null},components:[{type:"htmlEditorComponent",content:'
Preparation of Space Experiments edited by international leading expert Dr. Vladimir Pletser, Director of Space Training Operations at Blue Abyss is the 5,000th Open Access book published by IntechOpen and our milestone publication!
\n\n"This book presents some of the current trends in space microgravity research. The eleven chapters introduce various facets of space research in physical sciences, human physiology and technology developed using the microgravity environment not only to improve our fundamental understanding in these domains but also to adapt this new knowledge for application on earth." says the editor. Listen what else Dr. Pletser has to say...
\n\n\n\nDr. Pletser’s experience includes 30 years of working with the European Space Agency as a Senior Physicist/Engineer and coordinating their parabolic flight campaigns, and he is the Guinness World Record holder for the most number of aircraft flown (12) in parabolas, personally logging more than 7,300 parabolas.
\n\nSeeing the 5,000th book published makes us at the same time proud, happy, humble, and grateful. This is a great opportunity to stop and celebrate what we have done so far, but is also an opportunity to engage even more, grow, and succeed. It wouldn't be possible to get here without the synergy of team members’ hard work and authors and editors who devote time and their expertise into Open Access book publishing with us.
\n\nOver these years, we have gone from pioneering the scientific Open Access book publishing field to being the world’s largest Open Access book publisher. Nonetheless, our vision has remained the same: to meet the challenges of making relevant knowledge available to the worldwide community under the Open Access model.
\n\nWe are excited about the present, and we look forward to sharing many more successes in the future.
\n\nThank you all for being part of the journey. 5,000 times thank you!
\n\nNow with 5,000 titles available Open Access, which one will you read next?
\n\nRead, share and download for free: https://www.intechopen.com/books
\n\n\n\n
\n'}],latestNews:[{slug:"stanford-university-identifies-top-2-scientists-over-1-000-are-intechopen-authors-and-editors-20210122",title:"Stanford University Identifies Top 2% Scientists, Over 1,000 are IntechOpen Authors and Editors"},{slug:"intechopen-authors-included-in-the-highly-cited-researchers-list-for-2020-20210121",title:"IntechOpen Authors Included in the Highly Cited Researchers List for 2020"},{slug:"intechopen-maintains-position-as-the-world-s-largest-oa-book-publisher-20201218",title:"IntechOpen Maintains Position as the World’s Largest OA Book Publisher"},{slug:"all-intechopen-books-available-on-perlego-20201215",title:"All IntechOpen Books Available on Perlego"},{slug:"oiv-awards-recognizes-intechopen-s-editors-20201127",title:"OIV Awards Recognizes IntechOpen's Editors"},{slug:"intechopen-joins-crossref-s-initiative-for-open-abstracts-i4oa-to-boost-the-discovery-of-research-20201005",title:"IntechOpen joins Crossref's Initiative for Open Abstracts (I4OA) to Boost the Discovery of Research"},{slug:"intechopen-hits-milestone-5-000-open-access-books-published-20200908",title:"IntechOpen hits milestone: 5,000 Open Access books published!"},{slug:"intechopen-books-hosted-on-the-mathworks-book-program-20200819",title:"IntechOpen Books Hosted on the MathWorks Book Program"}]},book:{item:{type:"book",id:"6062",leadTitle:null,fullTitle:"Advances in Bioremediation and Phytoremediation",title:"Advances in Bioremediation and Phytoremediation",subtitle:null,reviewType:"peer-reviewed",abstract:"The pollution of soil and groundwater by harmful chemical compounds and heavy metals is becoming very serious in many countries. Although remediation is necessary as soon as possible, the performance of conventional bioremediation processes is not sufficient. This book deals with advances in bioremediation and phytoremediation processes by using excellent strains and a combination of processes. In the chapters of this book, the researchers have introduced the overall status of contamination; the characteristics of bioremediation using halobacteria, Candida yeast, and autochthonous bacteria; and phytoremediation using macrophytes. Moreover, other researchers introduced a process using biochar and electric currents, and this combination of processes and phytoremediation enhances the overall process.",isbn:"978-953-51-3958-4",printIsbn:"978-953-51-3957-7",pdfIsbn:"978-953-51-4023-8",doi:"10.5772/67970",price:119,priceEur:129,priceUsd:155,slug:"advances-in-bioremediation-and-phytoremediation",numberOfPages:200,isOpenForSubmission:!1,isInWos:1,hash:"7b537906414bbdbbe7a318c5702ef67e",bookSignature:"Naofumi Shiomi",publishedDate:"April 4th 2018",coverURL:"https://cdn.intechopen.com/books/images_new/6062.jpg",numberOfDownloads:9733,numberOfWosCitations:14,numberOfCrossrefCitations:17,numberOfDimensionsCitations:34,hasAltmetrics:0,numberOfTotalCitations:65,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"February 23rd 2017",dateEndSecondStepPublish:"March 16th 2017",dateEndThirdStepPublish:"September 22nd 2017",dateEndFourthStepPublish:"October 22nd 2017",dateEndFifthStepPublish:"December 22nd 2017",currentStepOfPublishingProcess:5,indexedIn:"1,2,3,4,5,6",editedByType:"Edited by",kuFlag:!1,editors:[{id:"163777",title:"Prof.",name:"Naofumi",middleName:null,surname:"Shiomi",slug:"naofumi-shiomi",fullName:"Naofumi Shiomi",profilePictureURL:"https://mts.intechopen.com/storage/users/163777/images/system/163777.jpeg",biography:"Dr. Naofumi Shiomi studied recombinant yeast and its utilization as a researcher at the Laboratory of Production Technology of Kanena Corporation for 15 years until 1998, and earned his PhD in Engineering from Kyoto University. He now works as a professor at the School of Human Sciences of Kobe College in Japan, where he teaches applied microbiology, biotechnology and life science in his \\Applied Life Science\\ laboratory. He has studied bioremediation for 26 years at Kobe College, and has published more than 40 papers and several book chapters on recombinant microorganisms and bioremediation. His recent research has also focused on the prevention of obesity and aging.",institutionString:"Kobe College",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"7",totalChapterViews:"0",totalEditedBooks:"6",institution:{name:"Kobe College",institutionURL:null,country:{name:"Japan"}}}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"126",title:"Ecology",slug:"environmental-sciences-ecology"}],chapters:[{id:"59373",title:"Introductory Chapter: Serious Pollution of Soil and Groundwater and the Necessity of Bioremediation",doi:"10.5772/intechopen.74403",slug:"introductory-chapter-serious-pollution-of-soil-and-groundwater-and-the-necessity-of-bioremediation",totalDownloads:831,totalCrossrefCites:0,totalDimensionsCites:0,signatures:"Naofumi Shiomi",downloadPdfUrl:"/chapter/pdf-download/59373",previewPdfUrl:"/chapter/pdf-preview/59373",authors:[{id:"163777",title:"Prof.",name:"Naofumi",surname:"Shiomi",slug:"naofumi-shiomi",fullName:"Naofumi Shiomi"}],corrections:null},{id:"58446",title:"The Pollution of Water by Trace Elements Research Trends",doi:"10.5772/intechopen.72776",slug:"the-pollution-of-water-by-trace-elements-research-trends",totalDownloads:1293,totalCrossrefCites:0,totalDimensionsCites:2,signatures:"Khaled Al-Akeel",downloadPdfUrl:"/chapter/pdf-download/58446",previewPdfUrl:"/chapter/pdf-preview/58446",authors:[{id:"212669",title:"Dr.",name:"Khaled",surname:"Alakeel",slug:"khaled-alakeel",fullName:"Khaled Alakeel"}],corrections:null},{id:"58349",title:"Biosorption of Heavy Metals by Candida albicans",doi:"10.5772/intechopen.72454",slug:"biosorption-of-heavy-metals-by-candida-albicans",totalDownloads:881,totalCrossrefCites:3,totalDimensionsCites:6,signatures:"Ismael Acosta Rodríguez, Juan Fernando Cárdenas-González, Víctor\nManuel Martínez Juárez, Adriana Rodríguez Pérez, María de\nGuadalupe Moctezuma Zarate and Nancy Cecilia Pacheco Castillo",downloadPdfUrl:"/chapter/pdf-download/58349",previewPdfUrl:"/chapter/pdf-preview/58349",authors:[{id:"26625",title:"Dr.",name:"Ismael",surname:"Acosta",slug:"ismael-acosta",fullName:"Ismael Acosta"},{id:"214409",title:"Dr.",name:"Juan Fernando",surname:"Cárdenas González",slug:"juan-fernando-cardenas-gonzalez",fullName:"Juan Fernando Cárdenas González"},{id:"214415",title:"Dr.",name:"Adriana Sarai",surname:"Rodríguez Pérez",slug:"adriana-sarai-rodriguez-perez",fullName:"Adriana Sarai Rodríguez Pérez"}],corrections:null},{id:"57078",title:"Recent Trend on Bioremediation of Polluted Salty Soils and Waters Using Haloarchaea",doi:"10.5772/intechopen.70802",slug:"recent-trend-on-bioremediation-of-polluted-salty-soils-and-waters-using-haloarchaea",totalDownloads:713,totalCrossrefCites:3,totalDimensionsCites:5,signatures:"Sonia Aracil-Gisbert, Javier Torregrosa-Crespo and Rosa María\nMartínez-Espinosa",downloadPdfUrl:"/chapter/pdf-download/57078",previewPdfUrl:"/chapter/pdf-preview/57078",authors:[{id:"165627",title:"Dr.",name:"Rosa María",surname:"Martínez-Espinosa",slug:"rosa-maria-martinez-espinosa",fullName:"Rosa María Martínez-Espinosa"},{id:"196514",title:"MSc.",name:"Javier",surname:"Torregrosa-Crespo",slug:"javier-torregrosa-crespo",fullName:"Javier Torregrosa-Crespo"},{id:"207042",title:"Mrs.",name:"Sonia",surname:"Aracil-Gisbert",slug:"sonia-aracil-gisbert",fullName:"Sonia Aracil-Gisbert"}],corrections:null},{id:"56643",title:"Laboratory-Scale Biodegradation of Fuel Oil No. 6 in Contaminated Soils by Autochthonous Bacteria",doi:"10.5772/intechopen.70350",slug:"laboratory-scale-biodegradation-of-fuel-oil-no-6-in-contaminated-soils-by-autochthonous-bacteria",totalDownloads:611,totalCrossrefCites:2,totalDimensionsCites:2,signatures:"Hilda Amelia Piñón-Castillo, Daniel Lardizabal Gutiérrez, Francisco\nJavier Zavala-Díaz de la Serna, Daniel Hernández-Castillo, Laila N.\nMuñoz-Castellanos, Blanca E. Rivera-Chavira and Guadalupe\nVirginia Nevárez-Moorillón",downloadPdfUrl:"/chapter/pdf-download/56643",previewPdfUrl:"/chapter/pdf-preview/56643",authors:[{id:"166633",title:"Dr.",name:"Guadalupe",surname:"Nevárez-Moorillón",slug:"guadalupe-nevarez-moorillon",fullName:"Guadalupe Nevárez-Moorillón"},{id:"175550",title:"Dr.",name:"Blanca E.",surname:"Rivera-Chavira",slug:"blanca-e.-rivera-chavira",fullName:"Blanca E. Rivera-Chavira"},{id:"207108",title:"Dr.",name:"Hilda Amelia",surname:"Piñon-Castillo",slug:"hilda-amelia-pinon-castillo",fullName:"Hilda Amelia Piñon-Castillo"},{id:"207109",title:"MSc.",name:"Daniel",surname:"Lardizabal-Gutiérrez",slug:"daniel-lardizabal-gutierrez",fullName:"Daniel Lardizabal-Gutiérrez"},{id:"207110",title:"Dr.",name:"Daniel",surname:"Hernández-Castillo",slug:"daniel-hernandez-castillo",fullName:"Daniel Hernández-Castillo"},{id:"207111",title:"Dr.",name:"Laila N.",surname:"Muñoz-Castellanos",slug:"laila-n.-munoz-castellanos",fullName:"Laila N. Muñoz-Castellanos"},{id:"211511",title:"Dr.",name:"Francisco Javier",surname:"Zavala-Díaz De La Serna",slug:"francisco-javier-zavala-diaz-de-la-serna",fullName:"Francisco Javier Zavala-Díaz De La Serna"}],corrections:null},{id:"58767",title:"Effectiveness of Sorghum Husk and Chicken Manure in Bioremediation of Crude Oil Contaminated Soil",doi:"10.5772/intechopen.71832",slug:"effectiveness-of-sorghum-husk-and-chicken-manure-in-bioremediation-of-crude-oil-contaminated-soil",totalDownloads:719,totalCrossrefCites:1,totalDimensionsCites:1,signatures:"Feyisayo V. Adams, Maryam F. Awode and Bolade O. Agboola",downloadPdfUrl:"/chapter/pdf-download/58767",previewPdfUrl:"/chapter/pdf-preview/58767",authors:[{id:"187708",title:"Dr.",name:"Bolade",surname:"Agboola",slug:"bolade-agboola",fullName:"Bolade Agboola"},{id:"221377",title:"Dr.",name:"Feyisayo",surname:"Adams",slug:"feyisayo-adams",fullName:"Feyisayo Adams"},{id:"222427",title:"Ms.",name:"Maryam F.",surname:"Awode",slug:"maryam-f.-awode",fullName:"Maryam F. Awode"}],corrections:null},{id:"56666",title:"Heavy Metal Removal with Phytoremediation",doi:"10.5772/intechopen.70330",slug:"heavy-metal-removal-with-phytoremediation",totalDownloads:1692,totalCrossrefCites:1,totalDimensionsCites:3,signatures:"Sevinç Adiloğlu",downloadPdfUrl:"/chapter/pdf-download/56666",previewPdfUrl:"/chapter/pdf-preview/56666",authors:[{id:"205818",title:"Associate Prof.",name:"Sevinç",surname:"Adiloğlu",slug:"sevinc-adiloglu",fullName:"Sevinç Adiloğlu"}],corrections:null},{id:"59817",title:"Potential and Constraints of Macrophyte Manipulation for Shallow Lake Management",doi:"10.5772/intechopen.74046",slug:"potential-and-constraints-of-macrophyte-manipulation-for-shallow-lake-management",totalDownloads:662,totalCrossrefCites:1,totalDimensionsCites:1,signatures:"Zeljka Rudic, Bojana Vujovic, Ljubinko Jovanovic, Dragan Kiković,\nIgor Kljujev, Mile Bozic and Vera Raicevic",downloadPdfUrl:"/chapter/pdf-download/59817",previewPdfUrl:"/chapter/pdf-preview/59817",authors:[{id:"141030",title:"Dr.",name:"Vera",surname:"Raicevic",slug:"vera-raicevic",fullName:"Vera Raicevic"},{id:"143894",title:"MSc.",name:"Mile",surname:"Bozic",slug:"mile-bozic",fullName:"Mile Bozic"},{id:"143896",title:"Dr.",name:"Zeljka",surname:"Rudic",slug:"zeljka-rudic",fullName:"Zeljka Rudic"},{id:"163271",title:"Prof.",name:"Ljubinko",surname:"Jovanovic",slug:"ljubinko-jovanovic",fullName:"Ljubinko Jovanovic"},{id:"239087",title:"Dr.",name:"Bojana",surname:"Vujovic",slug:"bojana-vujovic",fullName:"Bojana Vujovic"},{id:"239091",title:"Dr.",name:"Igor",surname:"Kljujev",slug:"igor-kljujev",fullName:"Igor Kljujev"},{id:"239093",title:"Prof.",name:"Dragan",surname:"Kikovic",slug:"dragan-kikovic",fullName:"Dragan Kikovic"}],corrections:null},{id:"56622",title:"Impact of Biochar on the Bioremediation and Phytoremediation of Heavy Metal(loid)s in Soil",doi:"10.5772/intechopen.70349",slug:"impact-of-biochar-on-the-bioremediation-and-phytoremediation-of-heavy-metal-loid-s-in-soil",totalDownloads:1413,totalCrossrefCites:4,totalDimensionsCites:9,signatures:"Wenjie Sun, Sha Zhang and Chunming Su",downloadPdfUrl:"/chapter/pdf-download/56622",previewPdfUrl:"/chapter/pdf-preview/56622",authors:[{id:"173666",title:"Dr.",name:"Chunming",surname:"Su",slug:"chunming-su",fullName:"Chunming Su"},{id:"205937",title:"Dr.",name:"Wenjie",surname:"Sun",slug:"wenjie-sun",fullName:"Wenjie Sun"},{id:"207000",title:"Mr.",name:"Sha",surname:"Zhang",slug:"sha-zhang",fullName:"Sha Zhang"}],corrections:null},{id:"58996",title:"Enhancement of Bioremediation and Phytoremediation Using Electrokinetics",doi:"10.5772/intechopen.73202",slug:"enhancement-of-bioremediation-and-phytoremediation-using-electrokinetics",totalDownloads:924,totalCrossrefCites:2,totalDimensionsCites:5,signatures:"Ikrema Hassan, Eltayeb Mohamedelhassan, Ernest K. Yanful and Ze-\nChun Yuan",downloadPdfUrl:"/chapter/pdf-download/58996",previewPdfUrl:"/chapter/pdf-preview/58996",authors:[{id:"219949",title:"Dr.",name:"Ikrema",surname:"Hassan",slug:"ikrema-hassan",fullName:"Ikrema Hassan"},{id:"232330",title:"Dr.",name:"Eltayeb",surname:"Mohamedelhassan",slug:"eltayeb-mohamedelhassan",fullName:"Eltayeb Mohamedelhassan"},{id:"232331",title:"Prof.",name:"Ernest",surname:"Yanful",slug:"ernest-yanful",fullName:"Ernest Yanful"},{id:"232332",title:"Dr.",name:"Ze-Chun",surname:"Yuan",slug:"ze-chun-yuan",fullName:"Ze-Chun Yuan"}],corrections:null}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"}},relatedBooks:[{type:"book",id:"4602",title:"Advances in Bioremediation of Wastewater and Polluted Soil",subtitle:null,isOpenForSubmission:!1,hash:"8b879725924ff3e5b59fb2f8cc12c562",slug:"advances-in-bioremediation-of-wastewater-and-polluted-soil",bookSignature:"Naofumi Shiomi",coverURL:"https://cdn.intechopen.com/books/images_new/4602.jpg",editedByType:"Edited by",editors:[{id:"163777",title:"Prof.",name:"Naofumi",surname:"Shiomi",slug:"naofumi-shiomi",fullName:"Naofumi Shiomi"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"5701",title:"Superfood and Functional Food",subtitle:"The Development of Superfoods and Their Roles as Medicine",isOpenForSubmission:!1,hash:"0c3c4e9924a0f6c2fe2df43d5dfc50fb",slug:"superfood-and-functional-food-the-development-of-superfoods-and-their-roles-as-medicine",bookSignature:"Naofumi Shiomi and Viduranga Waisundara",coverURL:"https://cdn.intechopen.com/books/images_new/5701.jpg",editedByType:"Edited by",editors:[{id:"163777",title:"Prof.",name:"Naofumi",surname:"Shiomi",slug:"naofumi-shiomi",fullName:"Naofumi Shiomi"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"5258",title:"Molecular Mechanisms of the Aging Process and Rejuvenation",subtitle:null,isOpenForSubmission:!1,hash:"fd825c8a444ab91728c15f350df7b5ea",slug:"molecular-mechanisms-of-the-aging-process-and-rejuvenation",bookSignature:"Naofumi Shiomi",coverURL:"https://cdn.intechopen.com/books/images_new/5258.jpg",editedByType:"Edited by",editors:[{id:"163777",title:"Prof.",name:"Naofumi",surname:"Shiomi",slug:"naofumi-shiomi",fullName:"Naofumi Shiomi"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"6538",title:"Current Topics on Superfoods",subtitle:null,isOpenForSubmission:!1,hash:"42525eaf5a539bc1e2318f4eb8dfea5a",slug:"current-topics-on-superfoods",bookSignature:"Naofumi Shiomi",coverURL:"https://cdn.intechopen.com/books/images_new/6538.jpg",editedByType:"Edited by",editors:[{id:"163777",title:"Prof.",name:"Naofumi",surname:"Shiomi",slug:"naofumi-shiomi",fullName:"Naofumi Shiomi"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"7594",title:"Current Topics in Biochemical Engineering",subtitle:null,isOpenForSubmission:!1,hash:"391609f1f0cb3bba32befeb3aa40ccf3",slug:"current-topics-in-biochemical-engineering",bookSignature:"Naofumi Shiomi",coverURL:"https://cdn.intechopen.com/books/images_new/7594.jpg",editedByType:"Edited by",editors:[{id:"163777",title:"Prof.",name:"Naofumi",surname:"Shiomi",slug:"naofumi-shiomi",fullName:"Naofumi Shiomi"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"6699",title:"Community and Global Ecology of Deserts",subtitle:null,isOpenForSubmission:!1,hash:"3f9477aa1d898626573100c92fa392e7",slug:"community-and-global-ecology-of-deserts",bookSignature:"Levente Hufnagel",coverURL:"https://cdn.intechopen.com/books/images_new/6699.jpg",editedByType:"Edited by",editors:[{id:"10864",title:"Dr.",name:"Levente",surname:"Hufnagel",slug:"levente-hufnagel",fullName:"Levente Hufnagel"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1591",title:"Infrared Spectroscopy",subtitle:"Materials Science, Engineering and Technology",isOpenForSubmission:!1,hash:"99b4b7b71a8caeb693ed762b40b017f4",slug:"infrared-spectroscopy-materials-science-engineering-and-technology",bookSignature:"Theophile Theophanides",coverURL:"https://cdn.intechopen.com/books/images_new/1591.jpg",editedByType:"Edited by",editors:[{id:"37194",title:"Dr.",name:"Theophanides",surname:"Theophile",slug:"theophanides-theophile",fullName:"Theophanides Theophile"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3092",title:"Anopheles mosquitoes",subtitle:"New insights into malaria vectors",isOpenForSubmission:!1,hash:"c9e622485316d5e296288bf24d2b0d64",slug:"anopheles-mosquitoes-new-insights-into-malaria-vectors",bookSignature:"Sylvie Manguin",coverURL:"https://cdn.intechopen.com/books/images_new/3092.jpg",editedByType:"Edited by",editors:[{id:"50017",title:"Prof.",name:"Sylvie",surname:"Manguin",slug:"sylvie-manguin",fullName:"Sylvie Manguin"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3161",title:"Frontiers in Guided Wave Optics and Optoelectronics",subtitle:null,isOpenForSubmission:!1,hash:"deb44e9c99f82bbce1083abea743146c",slug:"frontiers-in-guided-wave-optics-and-optoelectronics",bookSignature:"Bishnu Pal",coverURL:"https://cdn.intechopen.com/books/images_new/3161.jpg",editedByType:"Edited by",editors:[{id:"4782",title:"Prof.",name:"Bishnu",surname:"Pal",slug:"bishnu-pal",fullName:"Bishnu Pal"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"72",title:"Ionic Liquids",subtitle:"Theory, Properties, New Approaches",isOpenForSubmission:!1,hash:"d94ffa3cfa10505e3b1d676d46fcd3f5",slug:"ionic-liquids-theory-properties-new-approaches",bookSignature:"Alexander Kokorin",coverURL:"https://cdn.intechopen.com/books/images_new/72.jpg",editedByType:"Edited by",editors:[{id:"19816",title:"Prof.",name:"Alexander",surname:"Kokorin",slug:"alexander-kokorin",fullName:"Alexander Kokorin"}],equalEditorOne:null,equalEditorTwo:null,equalEditorThree:null,productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}}],ofsBooks:[]},correction:{item:{id:"65669",slug:"corrigendum-to-aedes-what-do-we-know-about-them-and-what-can-they-transmit",title:"Corrigendum to: Aedes: What Do We Know about Them and What Can They Transmit?",doi:null,correctionPDFUrl:"https://cdn.intechopen.com/pdfs/65669.pdf",downloadPdfUrl:"/chapter/pdf-download/65669",previewPdfUrl:"/chapter/pdf-preview/65669",totalDownloads:null,totalCrossrefCites:null,bibtexUrl:"/chapter/bibtex/65669",risUrl:"/chapter/ris/65669",chapter:{id:"63773",slug:"aedes-what-do-we-know-about-them-and-what-can-they-transmit-",signatures:"Biswadeep Das, Sayam Ghosal and Swabhiman Mohanty",dateSubmitted:"May 16th 2018",dateReviewed:"September 7th 2018",datePrePublished:"November 5th 2018",datePublished:null,book:{id:"8122",title:"Vectors and Vector-Borne Zoonotic Diseases",subtitle:null,fullTitle:"Vectors and Vector-Borne Zoonotic Diseases",slug:"vectors-and-vector-borne-zoonotic-diseases",publishedDate:"February 20th 2019",bookSignature:"Sara Savić",coverURL:"https://cdn.intechopen.com/books/images_new/8122.jpg",licenceType:"CC BY 3.0",editedByType:"Edited by",editors:[{id:"92185",title:"Dr.",name:"Sara",middleName:null,surname:"Savic",slug:"sara-savic",fullName:"Sara Savic"}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"}},authors:null}},chapter:{id:"63773",slug:"aedes-what-do-we-know-about-them-and-what-can-they-transmit-",signatures:"Biswadeep Das, Sayam Ghosal and Swabhiman Mohanty",dateSubmitted:"May 16th 2018",dateReviewed:"September 7th 2018",datePrePublished:"November 5th 2018",datePublished:null,book:{id:"8122",title:"Vectors and Vector-Borne Zoonotic Diseases",subtitle:null,fullTitle:"Vectors and Vector-Borne Zoonotic Diseases",slug:"vectors-and-vector-borne-zoonotic-diseases",publishedDate:"February 20th 2019",bookSignature:"Sara Savić",coverURL:"https://cdn.intechopen.com/books/images_new/8122.jpg",licenceType:"CC BY 3.0",editedByType:"Edited by",editors:[{id:"92185",title:"Dr.",name:"Sara",middleName:null,surname:"Savic",slug:"sara-savic",fullName:"Sara Savic"}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"}},authors:null},book:{id:"8122",title:"Vectors and Vector-Borne Zoonotic Diseases",subtitle:null,fullTitle:"Vectors and Vector-Borne Zoonotic Diseases",slug:"vectors-and-vector-borne-zoonotic-diseases",publishedDate:"February 20th 2019",bookSignature:"Sara Savić",coverURL:"https://cdn.intechopen.com/books/images_new/8122.jpg",licenceType:"CC BY 3.0",editedByType:"Edited by",editors:[{id:"92185",title:"Dr.",name:"Sara",middleName:null,surname:"Savic",slug:"sara-savic",fullName:"Sara Savic"}],productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"}}},ofsBook:{item:{type:"book",id:"9504",leadTitle:null,title:"Evidence-Based Approaches to Effectively Respond to Public Health Emergencies",subtitle:null,reviewType:"peer-reviewed",abstract:"
\r\n\tResponding to global public health emergencies require well-tested and effective approaches. During the current pandemic, healthcare systems worldwide were ill-prepared to respond to the rapid and far reaching impact of COVID-19. This should prompt researchers to re-examine policies, practices, methods and approaches that governments, health care and civic organizations may use to address health emergencies. With over 100 years of research on the implementation of innovative practices, system and organizational scientists are poised to help states, health care systems and other systems to develop, establish and employ evidence-based practices (EBPs) to effectively respond to public health emergencies.
\r\n\r\n\tThe primary aim of this book is to present theoretical and empirical knowledge on evidence-based policies, organizational practices, group and individual practices and approaches that may allow States and healthcare systems to effectively confront current (e.g., the COVID-19 pandemic), ongoing (e.g. HIV, opioid overdose) and upcoming epidemics affecting population health. The overall goal of this book is to advance knowledge on the development and dissemination of EBPs that contribute to a responsive, coordinated, reliable and effective public health system.
",isbn:"978-1-83969-144-7",printIsbn:"978-1-83969-143-0",pdfIsbn:"978-1-83969-145-4",doi:null,price:0,priceEur:0,priceUsd:0,slug:null,numberOfPages:0,isOpenForSubmission:!1,hash:"355f26e9a65d22c4de7311a424d1e3eb",bookSignature:"Dr. Erick Guerrero",publishedDate:null,coverURL:"https://cdn.intechopen.com/books/images_new/9504.jpg",keywords:"Implementation, Dynamic Systems, Public Health, Emergencies, Coordination, Collaboration, Networks, Teams, Organizational Learning, Implementation, Public Health Crises, Pay for Performance",numberOfDownloads:null,numberOfWosCitations:0,numberOfCrossrefCitations:null,numberOfDimensionsCitations:null,numberOfTotalCitations:null,isAvailableForWebshopOrdering:!0,dateEndFirstStepPublish:"October 19th 2020",dateEndSecondStepPublish:"November 27th 2020",dateEndThirdStepPublish:"January 26th 2021",dateEndFourthStepPublish:"April 16th 2021",dateEndFifthStepPublish:"June 15th 2021",remainingDaysToSecondStep:"3 months",secondStepPassed:!0,currentStepOfPublishingProcess:4,editedByType:null,kuFlag:!1,biosketch:"Dr. Erick Guerrero is an internationally recognized researcher in healthcare access and redesign and Co-Principal Investigator in several public health research projects in the United States, Latin American, and Europe. He is also leading culturally responsive consortiums to respond to other public health crises including institutional racism and COVID-19.",coeditorOneBiosketch:null,coeditorTwoBiosketch:null,coeditorThreeBiosketch:null,coeditorFourBiosketch:null,coeditorFiveBiosketch:null,editors:[{id:"294761",title:"Dr.",name:"Erick",middleName:null,surname:"Guerrero",slug:"erick-guerrero",fullName:"Erick Guerrero",profilePictureURL:"https://mts.intechopen.com/storage/users/294761/images/system/294761.jpg",biography:"Erick Guerrero completed his doctoral degree at the University of Chicago in 2009. In 2016, Dr. Guerrero received tenure as Associate Professor at the University of Southern California. Since 2018, he has been serving as the Founder and Director at the I-LEAD Institute, a research and consulting firm in Silicon Beach. Dr Guerrero has a background in clinical psychology and organizational behavior. As a clinician, he has provided counseling to individuals and families for the past 23 years. As an organizational researcher, Dr Guerrero has published more than 60 peer-reviewed manuscripts and 2 books on implementation of evidence-based practices in health and human service organizations. Dr Guerrero currently co-leads three large studies on disparities and implementation research to respond to the opioid epidemic funded by the U.S. National Institute of Health. He is also leading culturally responsive consortiums to respond to other public health crises including institutional racism and COVID-19.",institutionString:"I-Lead Institute",position:null,outsideEditionCount:0,totalCites:0,totalAuthoredChapters:"3",totalChapterViews:"0",totalEditedBooks:"1",institution:null}],coeditorOne:null,coeditorTwo:null,coeditorThree:null,coeditorFour:null,coeditorFive:null,topics:[{id:"16",title:"Medicine",slug:"medicine"}],chapters:null,productType:{id:"1",title:"Edited Volume",chapterContentType:"chapter",authoredCaption:"Edited by"},personalPublishingAssistant:{id:"259492",firstName:"Sara",lastName:"Gojević-Zrnić",middleName:null,title:"Mrs.",imageUrl:"https://mts.intechopen.com/storage/users/259492/images/7469_n.png",email:"sara.p@intechopen.com",biography:"As an Author Service Manager my responsibilities include monitoring and facilitating all publishing activities for authors and editors. From chapter submission and review, to approval and revision, copyediting and design, until final publication, I work closely with authors and editors to ensure a simple and easy publishing process. I maintain constant and effective communication with authors, editors and reviewers, which allows for a level of personal support that enables contributors to fully commit and concentrate on the chapters they are writing, editing, or reviewing. I assist authors in the preparation of their full chapter submissions and track important deadlines and ensure they are met. I help to coordinate internal processes such as linguistic review, and monitor the technical aspects of the process. As an ASM I am also involved in the acquisition of editors. Whether that be identifying an exceptional author and proposing an editorship collaboration, or contacting researchers who would like the opportunity to work with IntechOpen, I establish and help manage author and editor acquisition and contact."}},relatedBooks:[{type:"book",id:"8335",title:"Effective Prevention and Treatment of Substance Use Disorders for Racial and Ethnic Minorities",subtitle:null,isOpenForSubmission:!1,hash:"ca6c7d5d975b1fa9ce320b1162b0dad6",slug:"effective-prevention-and-treatment-of-substance-use-disorders-for-racial-and-ethnic-minorities",bookSignature:"Erick Guerrero and Tenie Khachikian",coverURL:"https://cdn.intechopen.com/books/images_new/8335.jpg",editedByType:"Edited by",editors:[{id:"294761",title:"Dr.",name:"Erick",surname:"Guerrero",slug:"erick-guerrero",fullName:"Erick Guerrero"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"6550",title:"Cohort Studies in Health Sciences",subtitle:null,isOpenForSubmission:!1,hash:"01df5aba4fff1a84b37a2fdafa809660",slug:"cohort-studies-in-health-sciences",bookSignature:"R. Mauricio Barría",coverURL:"https://cdn.intechopen.com/books/images_new/6550.jpg",editedByType:"Edited by",editors:[{id:"88861",title:"Dr.",name:"R. Mauricio",surname:"Barría",slug:"r.-mauricio-barria",fullName:"R. Mauricio Barría"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1591",title:"Infrared Spectroscopy",subtitle:"Materials Science, Engineering and Technology",isOpenForSubmission:!1,hash:"99b4b7b71a8caeb693ed762b40b017f4",slug:"infrared-spectroscopy-materials-science-engineering-and-technology",bookSignature:"Theophile Theophanides",coverURL:"https://cdn.intechopen.com/books/images_new/1591.jpg",editedByType:"Edited by",editors:[{id:"37194",title:"Dr.",name:"Theophanides",surname:"Theophile",slug:"theophanides-theophile",fullName:"Theophanides Theophile"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3092",title:"Anopheles mosquitoes",subtitle:"New insights into malaria vectors",isOpenForSubmission:!1,hash:"c9e622485316d5e296288bf24d2b0d64",slug:"anopheles-mosquitoes-new-insights-into-malaria-vectors",bookSignature:"Sylvie Manguin",coverURL:"https://cdn.intechopen.com/books/images_new/3092.jpg",editedByType:"Edited by",editors:[{id:"50017",title:"Prof.",name:"Sylvie",surname:"Manguin",slug:"sylvie-manguin",fullName:"Sylvie Manguin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"3161",title:"Frontiers in Guided Wave Optics and Optoelectronics",subtitle:null,isOpenForSubmission:!1,hash:"deb44e9c99f82bbce1083abea743146c",slug:"frontiers-in-guided-wave-optics-and-optoelectronics",bookSignature:"Bishnu Pal",coverURL:"https://cdn.intechopen.com/books/images_new/3161.jpg",editedByType:"Edited by",editors:[{id:"4782",title:"Prof.",name:"Bishnu",surname:"Pal",slug:"bishnu-pal",fullName:"Bishnu Pal"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"72",title:"Ionic Liquids",subtitle:"Theory, Properties, New Approaches",isOpenForSubmission:!1,hash:"d94ffa3cfa10505e3b1d676d46fcd3f5",slug:"ionic-liquids-theory-properties-new-approaches",bookSignature:"Alexander Kokorin",coverURL:"https://cdn.intechopen.com/books/images_new/72.jpg",editedByType:"Edited by",editors:[{id:"19816",title:"Prof.",name:"Alexander",surname:"Kokorin",slug:"alexander-kokorin",fullName:"Alexander Kokorin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"1373",title:"Ionic Liquids",subtitle:"Applications and Perspectives",isOpenForSubmission:!1,hash:"5e9ae5ae9167cde4b344e499a792c41c",slug:"ionic-liquids-applications-and-perspectives",bookSignature:"Alexander Kokorin",coverURL:"https://cdn.intechopen.com/books/images_new/1373.jpg",editedByType:"Edited by",editors:[{id:"19816",title:"Prof.",name:"Alexander",surname:"Kokorin",slug:"alexander-kokorin",fullName:"Alexander Kokorin"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"57",title:"Physics and Applications of Graphene",subtitle:"Experiments",isOpenForSubmission:!1,hash:"0e6622a71cf4f02f45bfdd5691e1189a",slug:"physics-and-applications-of-graphene-experiments",bookSignature:"Sergey Mikhailov",coverURL:"https://cdn.intechopen.com/books/images_new/57.jpg",editedByType:"Edited by",editors:[{id:"16042",title:"Dr.",name:"Sergey",surname:"Mikhailov",slug:"sergey-mikhailov",fullName:"Sergey Mikhailov"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"371",title:"Abiotic Stress in Plants",subtitle:"Mechanisms and Adaptations",isOpenForSubmission:!1,hash:"588466f487e307619849d72389178a74",slug:"abiotic-stress-in-plants-mechanisms-and-adaptations",bookSignature:"Arun Shanker and B. Venkateswarlu",coverURL:"https://cdn.intechopen.com/books/images_new/371.jpg",editedByType:"Edited by",editors:[{id:"58592",title:"Dr.",name:"Arun",surname:"Shanker",slug:"arun-shanker",fullName:"Arun Shanker"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}},{type:"book",id:"878",title:"Phytochemicals",subtitle:"A Global Perspective of Their Role in Nutrition and Health",isOpenForSubmission:!1,hash:"ec77671f63975ef2d16192897deb6835",slug:"phytochemicals-a-global-perspective-of-their-role-in-nutrition-and-health",bookSignature:"Venketeshwer Rao",coverURL:"https://cdn.intechopen.com/books/images_new/878.jpg",editedByType:"Edited by",editors:[{id:"82663",title:"Dr.",name:"Venketeshwer",surname:"Rao",slug:"venketeshwer-rao",fullName:"Venketeshwer Rao"}],productType:{id:"1",chapterContentType:"chapter",authoredCaption:"Edited by"}}]},chapter:{item:{type:"chapter",id:"74076",title:"Wind Power Forecasting",doi:"10.5772/intechopen.94550",slug:"wind-power-forecasting",body:'Electricity sector especially in supply industry over the last various years across the world has underwent through numerous structural and systematic changes due to two main reasons: orientation of industry towards privatizations (reforms) and movement of electricity generation towards clean and pollution free renewable energy sources [1]. In this changing environment forecasting electricity becomes one of the most important exercises in managing the power systems. Forecasting plays a significant role in operation planning, scheduling and real time balancing of power system. Mainly, there are three forecasting issues in present day power systems namely electricity load, price and the renewable energy sources. Among the recently emerged renewable sources of energy (solar energy), the wind power industry has witnessed tremendous growth and has taken a leading role [2, 3].
Besides this, the electricity based on renewable energy sources perceived as an alternate source of energy and their penetration within the power system is rising at a very fast rate [4]. Among new sources of renewable energy, the wind energy has seen tremendous growth over recent years; in various countries, it is a true alternative to fossil fuels. Furthermore, wind power generation capacity varies constantly, stochastic, intermittent in nature and associated with generation of other ramp events. In spite of that, it is freely available & pollution free source of energy; so, it has gained an extensive interest and one of the most established renewable energy alternatives to the conventional energy resources. On approaching towards the end of 2016, 486.8 GW would be worldwide installed wind nameplate capacity due to growth rate of 12.5%. As per estimate, wind power towards the end of 2021 will approach to 817 GW with growth rate of 10.4%. These wind capacity installations are mainly utilized in electric power systems based on large grid and their interconnections [5, 6]. Now-a-days another fast growing eco-friendly electrical generation technologies are solar, geothermal and tidal energy.
The uncertainty associated with wind power originates from uncertainties in its derivatives such as: wind speed & direction forecasts. In coordination with fast deployment of wind farms establishes a demand for efficient forecasting methods related to wind power production. The high is forecast reliability, low will be reserve maintenance cost of the system, which will result technical and commercial implications for proper management and working of power systems. Wind power forecasting (WPF) depicts how much wind power is to be expected at particular instant of time in the days to come. WPF is one of the most critical aspects in wind power integration and operation [6, 7, 8]. As per time horizons, the WPF has been done on the basis of long, medium and short term.
The availability of wind power is largely influenced by the prevailing weather conditions, seasonal variations and time spam variation and therefore, it is characterized by strong fluctuations, uncertainty and intermittency. These characteristics of wind power create a great attention towards it. Consequently, power generation from wind cannot be matched easily to the electricity demand like power generated with conventional plants. The penetration (share of wind power to meet demand) level of wind power introduces new challenges for the power system, some of them include:
Integration with Grid: The management of intermittence of wind generation is the key issue related to its integration with grid. The transmission utility is only responsible for the balancing of demand and supply at grid level. Therefore, it is necessary to schedule the supply in advance in order to meet the load profile. The load is corresponding to the total demand of electricity consumption over a definite area. The load forecast is usually given by the load forecasting models. The Mean Absolute Percentage Error (MAPE) of load is in the order of 0.87–1.34% [9] for the day ahead or week ahead predictions. Still continuous effort has been made by various researchers and practitioners for improving the performance of load forecasting models and techniques. i.e. it is reached in advance stage of research.
Integration with Electricity Markets: Generally, the electricity market is build by two mechanisms. The first one is spot energy market or so called Day Ahead market, where the bulk energy necessary to cover the load profile for the next coming day is traded on the generation cost. An auction process followed by bidding permits the settlement of electricity price and generation for the various bidding hours. The second mechanism is ancillary service market or so called intraday market, where differences between planned production and actual load are traded (due to the power plant failure or due to intermittence of wind power generation). The ancillary service market is very important for a stable operation of the power grid and span across various time frames. Therefore, it is additionally important for consumers as well as suppliers to know the future electricity price, so that they can make strategies. Like load forecasting the electricity price is in its advance stage of research and error rate (MAPE) reported is 3.96–4.92% [10].
Therefore, the accurate forecasts of wind power generation is an essential factor for a successful integration of large amounts of wind power into the electricity supply system, aiming at precise information on timing and magnitude of power generation from these variable sources.
Among requirements of wind power forecasting over three different forecasting horizons, there are different framework for the forecasting which includes single step ahead, multiple lead hours ahead and probabilistic forecasting. Typically multiple step and probabilistic forecasting is more complicated because in multiple, the error is multiples at every lead hour prediction; whereas, in probabilistic several statistical factors contribute additional complexity and additional complicacy. Moreover, it also affects the profits of a utility directly.
The predicted values can be provided to end-users either in a deterministic or in probabilistic format, with the former, a specific value for energy production at a particular time step (15-minutes or one hour) is forecasted; whereas, in later, range of possible output is forecasted on the behalf of deterministic forecasted values using probability theory.
Single Step Ahead Forecasting.
It is the estimation of any quantity today for the next coming day with utmost possible precision and reliability. We have at our disposal the past values of this quantity, the data of one or several time series along with other several factors on which these time series are produced.
With
By the Eq. (1), e, is the prediction error or noise present between present forecasting value and n previous observations. WP is the wind power, T is the target, for multiple step the target matrix is increased with respect to each step in advance as given below in Eq. (3, 4).
Multi Step Ahead Forecasting.
The multiple steps ahead or multiple lead hour prediction is forecasting a pattern of values for given time series. It is an approach that works step-by-step by using current prediction for deterministic next stage prediction. In case of multi-step ahead prediction various anomalies like error accumulation and complexity of data prevails when prediction period is long. It all occurs due to propagation of bias and variances form previous prediction of future prediction. Because of this large forecasting horizon & error present in forecasting this method is suffered from the low performance & higher inaccuracy that is because of use of approximated values rather than actual values. The main reason for this higher inaccuracy is that the error is multiplied in every step-ahead prediction. So, the selection of input parameter function to fit the time series can be a challenging task for the power system researchers.
The probabilistic forecast systems are designed to estimate the uncertainty of a forecast and used to produce the application of probabilistic forecasting. The verification is an essential part of probabilistic forecast systems. The correct and accurate use of probability forecasts means that, given a large sample, on average and event will occur at the same frequency as the forecast probability [11].
As far as literature is concerned, number of forecasting methods have been designed and analyzed over last few decades. Based on information in research papers, author has examined various developments in the field of wind power generation & its derivatives prediction such as speed or direction. The major emphasis is led on facilitation of a number of issues concerned with techniques involved in WPF, focuses on complexity reduction in forecasting issues with higher accuracy in forecasting for different time span. This research mainly focuses on motivating power system researchers to design highly efficient and accurate models whether online/offline considering various issues related to wind power which in twin result in reliable operation of power system models by utilizing energy resources economically. On carrying out comparative study and analysis of accuracy in forecasting models, hybrid models outperformed all other models.
The generation of wind power is highly influenced by nature and seasons. So, it has been a tedious task to design a sound prediction model by taking in account above two factors. But, AI and machine learning have come with an advantage for developing new models due to their higher efficiency and accuracy. After a deep insight of various research papers authors have observed that the NN is the most prevailing approach for wind power and its derivatives estimation. It has also been observed that, hybrid models have been found to be more accurate model and for getting more accuracy, the training data should be updated regularly with small time span. Although for real time operation of power system, researchers have to move towards online models. There are three main steps involved in WPF (i) Input Selection, (ii) Data Pre-processing, & (iii) Forecasting models (tool) used.
The higher uncertainty in wind nature is result of uncertainties in its derivatives that affect systems of reliability. If forecast reliability is higher than operational cost of wind power system is lowered, in turn benefitting wind farm owners as they will have more substantial saving as well as have better efficiency of the system [12]. Apart from all this, wind power prediction is still a tedious task because wind flow is an unpredictable natural phenomenon and wind speed time series possesses various characteristics like: high volatility, high complexity, non linearity and non-stationary due to prevent physical conditions of place [13, 14]. After an extensive study of various research papers more than 46 exogenous variables have been observed as given in Table 1Table 1.
The input variables selection is main task because the accurate prediction by a forecasting model is highly influenced by proper input variables and their past results in the field of wind speed & power prediction and estimation. Furthermore, the selection of input variables for a prediction model mainly depends on exogenous and without exogenous variables. The various input selection techniques are as discussed.
These are very common model in which wind is a function of exogenous variables and forecasting tool input is the output of NWP models. These physical models forecasting process depends on entire input corresponding to wind power derivatives and are deterministic one. Their implementation process is very complex to perform, take high computation time to carry out forecasting process and depends on physical variables concerned with wind farm location. The equation which is used to convert wind speed into power is as follows as: Wp = 0.5.ρ.A.v3. Here, ρ denotes the air density; v denotes the wind velocity through an intercepting area A of wind turbine. Actually, this equation follows the different physical variables corresponding to wind turbine. The purpose of NWP models is to predict the wind speed of surrounding area of wind mill.
In statistical models, wind remains a function that works using past captured values. These models are trained by providing data patterns that are measured statistically. They are based on historical data patterns generated by wind power and hence, they are not based on computation of any form of mathematical expression. These models outperform other short term forecasting horizon over prediction accuracy and these models are easy to implement & validate. They employed the statistics like: Cross Correlation (CC), Auto Correlation Function (ACF) and Partial Auto Correlation Function (PACF) for input selection on the basis of standard deviation, variance, mean and slope of input curve etc. The Figure 1 shows ACF and PACF of hourly Wind Power time series based on these two parameters input time lag parameterization of both time series and Artificial Intelligence (AI) take place. The higher is the value of ACF more is correlation between two consecutive series. However, the selection of input variables is one of the most important part of NN based forecasting model on with the accuracy of the model depends and that also determines the input architecture of the model. During the training of NN model, there may be problem of overtraining or over fitting that leads to poor accuracy of model. Therefore, it is necessary to know the relation that exists between present time wind power series along with their past time lag series. The input time lag is given below in Table 2. The wind forecast problem aims to find an estimate WP(t + k) of the wind vector WP(t + n) based on the previous n measurements WP(t), WP(t-1),. .., WP(t-n).
ACF & PACF for hourly wind power series.
Class | Input variable | Input data |
---|---|---|
1. Atmospheric Characteristics | (1) Temperature (2) Pressure, (3) Humidity (4) Rainfall, (5) Cloud formation, (6) Cloud cover, (7) Turbulance, (8) Radiations Effect, (9) Density | |
2. Topographic Characteristics | (10) Turbine position, (11) Turbine size, (12) Hub height, (13) Tower height, (14) Elevation, (15) Degree in Latitude | |
3. Wind Power Characteristics | (16) Wind speed, (17) Wind direction, (18) Radiation transmission, (19) Sine & Cosine of wind direction, (20) Air density, (21) Local wind profile | f(wind Speed); (d-m,t), m = 1,2,3,4,7,8, 168, 365 |
4. Behavior Indices | (22) Hydrological cycle, (23) cloud-radiation interaction, (24) spatial behavior, (25) Temporal behavior, (26) Spatial resolution | f(wind power; (d-m,t-n), m = 1,2,3,4,7,8, 168, 365 and n = 0,1,2,3,4 |
5. Other Stochastic Uncertainty | (27) Ocean-land interactions, (28) Regime switching, (29) Exchanges of momentum, (30) Load distribution among parallel turbines, (3) 1Thunders, (32) Storms, (33) Risk index, (34) Guest wind speed | f(wind direction; (d-m,t-n), m = 1,2,3, 168, 365 and n = 0,1,2,3,4 |
6. Geographical Conditions | (35) Orography, (36) Surface roughness, (37) Obstacles, (38) Geographical height, (39) Mean sea level pressure, (40) Air temperature, (41) Soil wetness, (42) Atmosphere covering, (43) Snow covering, (44) Moisture with land surface, (45) Complex terrain, (46) Terrain roughness |
Factors affecting wind power generation.
S. No. | Time lag series | No. of time lag |
---|---|---|
1. | WP (t-1) | 1 |
2. | WP (t-1), WP (t-2) | 2 |
3. | WP (t-1), WP (t-2), WP (t-3) | 3 |
4. | WP (t-1), WP (t-2), WP (t-3), WP (t-4) | 4 |
5. | WP (t-1), WP (t-2), WP (t-3), WP (t-4), WP (t-5) | 5 |
6. | WP (t-1), WP (t-2), WP (t-3), WP (t-4), WP (t-5), WP (t-6) | 6 |
7. | A1 | Approximate Series |
8. | D1, D2, D3, D4, D5, D6 | Detailed Series |
Inputs used.
It is the combination of NWP and statistical tools for input data selection. In this, on the bases of statistical analysis, the NWP variables are pre-processed to time lag for the prediction of next step.
The input data and wind data pattern is accumulated in raw form and does not possesses highly efficient forecasting capability with accurate precision. Raw data is unpredictable, irregular, seasonal and more complex due to changing weather. While prediction computation, over-fitting or over-training of NN is the main issue in time series variation leading to foot fall in accuracy of forecasted values. Data pre-processing means data cleaning data transformation and data reduction input data and converting it into useful information as per dimensions. Data must be classified based on seasonal and weather variable variation. Kalman filter is an appropriate solution to various problems such as: complexity in data, over-fitting and outliers of input data generated during learning process [15, 16]. As Unscented Kalman Filter (UKF) achieves higher efficiency in handling random fluctuations, so it is an economical and adequate choice for non-linear estimation of wind speed [17].
In presented work, in order to investigate the performance of different forecasting models, real wind generation data of Ontario Electricity Market (OEM) from 2011 to 2014 [18] has been considered. For obtaining more accuracy and over-training avoidance in learning process to achieve greater accuracy, large set of data values have not been considered, as generation of wind power is dependent function on numerous parameters such as: changing season, temperature and weather conditions. As time moves wind capacity (defined as actual energy produced in comparison to energy actually dissipated by turbines under favorable conditions) can fluctuate. The main concern of Wavelet Transform (WT) is to collect the meaningful information with removal of noise & irregularities from the original signal. From the available literature on forecasting and experimental analysis, it has been observed that Daubechies wavelet at different levels performs an appropriate smoothness of the signal with respect to wave-length, which results in an appropriate behavior of input data pattern for wind power prediction tool.
The WT implementation is done to decompose wind power series broadly into constitutive series set. This set of constitutive series help in reduction of input data and outperforms original wind series in behavior leading to prediction accuracy improvement. The WT divides wind series signal into two distinguishing signals having low and high frequency, then the decomposed signals are provided to the separate NN model for training. There are four filters (decomposition low pass & high pass filter, reconstruction low & high pass filter) used in Discrete Wavelet Transform (DWT) for scaling the input data pattern into approximate (A) and detailed (D) signals as given in Table 2 [19, 20, 21, 22, 23, 24]. Empirical Model Decomposition (EMD) has also been used to decompose the wind power series into high and low frequency signals [25]. The NN models train themselves better with the pre-processed data, as a result of this better prediction performance.
For the past two decades, models based on machine learning have captured attention & become more sophisticated and reliable contenders in spite of traditional statistical models in forecasting. These are non parametric & non-linear models also known as data driven or black box models having usage of historical data patterns to learn the stochastic dependency between past and future. These NN’s models always leave behind other traditional statistical models such as: linear regression and Box-Jenkins approaches. The NNs can be successfully used for modeling and forecasting non-linear time series [26].
The conventional statistical models (persistence, Moving Average & Gray Models) are identical to the direct random time-series model. Based on a number of historical data, pattern identification, parameter estimation, model checking are utilized to make a mathematical model for the prediction problem.
Traditional Models
Naïve Predictor: In order to get a significant evaluation of WPF a naïve model should be used. This is one of the old and simple ways to forecast wind power & speed also called persistence model. It is based on the simple assumption that wind power at present time t will be same in a future time (t + x) [27].
Simple Moving Average: The moving average predicts the wind power based on simply the average of past values of wind power. It has also been used as a benchmark for assessing the accuracy criteria of prediction model.
Gray Model (1,1) Predictor: GM (n, m) model is based on the Gray theory as demonstrated by Professor Deng in 1982. GM (n, m) denotes a Gray model where n is the order differential equation and m is the no. of variables. It predicts the future values of time series based on the recent data fluctuations. There are various types of Gray Models as designed by various researchers but because of computational efficiency of GM (1, 1) is generally used.
Linear or Time Series (TS) Models
According to the methods which have been proposed by Jenkins, these models can be further divided as follows: autoregressive model (AR), moving average model (MA), autoregressive moving average model (ARMA), auto regressive integrated moving average model (ARIMA) [28]. Generalized Autoregressive Conditional Heteroskedasticity (GARCH) has been used for interval forecasting to simulate the fluctuating characteristics of the residual series in Mictrogrid China. Fractional-ARIMA method has been proposed to overcome the disadvantage of ARIMA method, which has been characterized by a slow decay in its ACF [29]. The stochastic and seasonality pattern of wind power has been tackled by designing a combined Autoregressive Fractionally Integrated Moving Average (ARFIMA) and GARCH model [30]; whereas, for above said problem ref. [31] demonstrated ARMA with Vector Auto-regression and ref. [32] designed different ARMA models for wind speed and direction tuples prediction (above said problem).
The FFNN architecture, which is also called as Multi Layer Perceptron (MLP), along with back propagation (BP) as the learning algorithm is the most popular choice among researchers. The neural network (NN) and machine learning algorithms structures used by most of the researchers after 2000 in the leading journals are: Feed Forward Neural Network (FFNN), Recurrent Neural Network (RNN), Radial Basis Function Neural Network (RBFNN), Support Vector Machine (SVM), Support Vector Regression (SVR), Adaptive Neuro Fuzzy Inference System (ANFIS), Extreme Learning Machine (ELM), Adaptive Wavelet Neural Network (AWNN), General Regression Neural Network (GRNN), and Linear Neural Network with Time Delay (LNNTD).
In this, wind forecasting has been done by the three different models: (i) Benchmark, (ii) NN and (iii) WT based model. In the first category, only Naïve Predictor has been considered. This is the standard benchmark for wind forecasting applications, in which the previous values of input wind power series have been used for the next lead hour as forecasted values. In the second category, different ANN based models have been taken into consideration with different structure of network and learning algorithms. The NN along with gradient-based optimization techniques is most popular choice among all researchers and associated with the short comings of local minima and sensitivity to initial value persists as a result of poor accuracy. So, as to resolve above said problems, global evolutionary algorithms (EA) such as Genetic Algorithms (GA) [1, 23], Particle Swarm Optimization (PSO) [19, 33, 34] have been utilized. The main advantages of EA lie in its global convergence, inherent parallel search nature, and great robustness. These algorithms generate a high quality solution within a short computation time.
For proper input selection, there is need of complete experimental analysis on the basis of error rate. The input structures of WT based models are different from that of the non WT based models. In the WT based models, the input is the combination of Wind Power series and WT based approximated and detailed wind power series. Therefore, the number of input nodes is more as compared to non WT models. The structure of WT based FFNN for wind power prediction has been shown in Figure 2 & detailed prediction steps are:
Hourly curve for load, price & wind power from Ontario electricity market.
Step 1: From the raw data of wind power, a time series as input is selected on the behalf of ACF.
Step 2: Supply the created input signal to WT for performing multilevel decomposition on wind power signal by utilizing Daubechies (db10) wavelet.
Step 3: Now extract the multi level approximation A6 and 1, 2, 3,4,5,6 level detailed coefficients D1 to D6 of input wind power series signal.
Step 5: The approximated and detailed wind power series along with six original time lags has been used as an input variables.
Step 6: A three layer FFNN, as shown in Figure 3, has been selected having thirteen input nodes equal to the number of input variables, twelve hidden neurons with tangential sigmoid transfer function, and one output neuron with pure linear activation function, with each series. The network is trained using Levenberg–Marquardt (LM) training algorithms with architecture [12–11–1]. The momentum constant and learning rate have been kept equal to 0.06 and 0.001, respectively.
WT based FFNN for wind power forecasting.
Step 7: For the prediction, one year wind data has been trained and tested for next one month, similar process is continuously repeated up-to next 24 months with one month moving window. The maximum epochs were set equal to 10,000 with the performance goal of 0.001.
Step 8: The output values found by the network has been assessed on the accuracy criterion with actual wind power data series.
The aim of forecast evaluation is to assess, the general quality of a forecast by comparing the forecasted system states to actual observed states. The forecast evaluation provides a forecaster with:
The ability of better improvement and understanding of forecast. The evaluation of forecast exposes all those sub-spaces whose forecasting error is more out of model state space. So, a forecaster can take advantage of analyzing sub-spaces & utilize it for improving forecasting model.
Justifying the cost associated with resources used in forecasting model. The forecast performance assessment in accuracy terms gives a measure that can be directly linked to the utility or forecast user. Then coast and utility are compared with each other.
The ability of performing model selection so that maximum certainty of results can be obtained with the comparison of others.
In most of the forecasting models accuracy is the criterion for selecting a particular method for the forecasting. For a consumer accuracy of forecasting is most important. The various methods for accuracy calculation given below:
The Error
Where, WPt, is actual observation at time t, Ft, is forecast for time t
The Mean Absolute Error (MAE)
The Root Mean Square Error (RMSE)
Percentage Error (PE)
The Mean Absolute Percentage Error (MAPE)
The prediction performance of forecasting carried out by the different models used in this research is justified on the basis of forecasting accuracy indices. The methodology described above has been applied to predict the wind power of OEM for two years from November 2012 to October 2014 on MAPE & MAE accuracy criteria. The software used for training and testing of NN is MATLAB version R2011b. The extensive use of WT for data pre-processing makes the results more significant and effective. From the results Table 3, it is clear that the results achieved with the help of WT based models have been found to be better up to 40–60% as compare to non WT based models. The 24 hours actual and forecasted wind power curves with error curve have been shown in Figure 4.
Model | Naïve | FFNN | ERNN | GANN | PSONN | GAPSONN | GRNN | LNNTD | WT + FFNN |
---|---|---|---|---|---|---|---|---|---|
MAPE | 15.016 | 13.83 | 13.885 | 14.015 | 13.91 | 13.915 | 14.48 | 13.825 | 5.948 |
MAE | 65.073 | 58.415 | 58.145 | 58.413 | 58.4675 | 58.29209 | 62.285 | 58.0475 | 23.225 |
Overall prediction comparisons for all models used.
One day ahead actual & forecasted wind power curve during winter season.
The uncertainty of forecasts is mainly due to the noise of training data, the misspecification of NN model for regression and input data selection.
NN Model Uncertainty: Uncertainty in NN forecasting arises due to misspecification in input parameters and structure of model which occurs due to local minima in the training process, random generation of input weights and so on. In case of global minima, misspecifications lead to non-eligible uncertainties in results related to prediction. The other factor behind model uncertainty is that during training finite samples never guarantee consistent generalization in performance of NN for future days. Basically, in WPF, it has become impossible to gather accurate information for reducing uncertainties while predicting and hence collectively called as model uncertainty. Due to model uncertainty, uncertainty in output should be handled carefully for accurate estimation in NN.
Data Uncertainty: Not only model uncertainty but also data noise adds to prediction uncertainty. If the data is stochastic in nature, then modeling is deterministically is really difficult. Both model misspecification and data noise are the major sources of uncertainties that affect the forecasting results.
In this, probabilistic forecasting of wind power has been performed in coordination with single step ahead wind power point forecasts. The major emphasis of probabilistic forecasting is to take into account the uncertainty associated with the wind power with probabilistic forecasting attributes such as: sharpness, reliability, resolution and discrimination. It consists of a set of prediction intervals which works in coordination with the best forecasts of single step ahead of wind power for the next coming hour; the interval forecasting has been incorporated. With a pre-assumed probabilistic value, the basic aim of interval forecasting is to find out the range of prediction interval in which next hour wind power output lies. This framework has been consequently used for evaluating and analyzing the skill of the models for one lead hour point forecast. Thus, the overall results have been proving the reliability of results and show how the resolution may improve the forecasts skill.
The probabilistic forecasting has a wide range of statistical parameters on which the probabilistic outcomes of wind power lies. The prediction intervals (PI) stands for a wide range of possible probabilistic values within which the observed wind power values lies with a certain predefined probability. The basic idea behind the prediction intervals is to estimate the uncertainty associated with observed wind power
For a given sample size α has been a significant level which has been used to take into account the CI of the certain prediction intervals. The probabilistic stochastic interval (PSI) can be obtained by:
In the Eq. (12), the lower bound and upper bound can be expressed as:
In (13) and (14)
For the WT based model, the upper bound curve and lower bound curves obtained at 95% of the confidence and the actual measured wind power curve in 24 hours has been shown in Figure 5.
PI with nominal confidence 95% in 24 hours look ahead.
The uncertainty, complexity and seasonal aspects associated with the wind contribute high level of uncertainties in wind power generation. Because weather conditions and wind speeds vary very much in different seasons. Therefore, for a perfect efficient forecasting model it is necessary to take care of input variables and their proper selection in time series. Actually, the improper input cause improper training of NN model as a result of that poor accuracy of forecasts. In this chapter, in order to take care of models forecast performance, probabilistic parameters have been taken into consideration.
In order to evaluate the performance on probabilistic forecasting, on the basis of single step reliable Prediction Intervals (PI’s) need to be derived. In this, instead of exact values of forecast a range of forecasting interval need to be considered. If the predicted values lie in that range then, the performance of model is good otherwise model is poor one. Furthermore, power system operations require useful efficient forecast values with high level of reference confidence. Therefore, to fulfill the need of power system, more practical data based model should be required with high-confidence-level PI’s.
Voltammetry is an electrochemical technique for current-voltage curves, from which electrode reactions at electrode-solution interfaces can be interpreted. Since current-voltage curves, called voltammograms, include sensitive properties of solution compositions and electrode materials, their analysis provides not only chemical structures and reaction mechanisms on a scientific basis but also electrochemical manufacture on an industrial basis. The voltammograms vary largely with measurement time except for steady-state measurements, and so it is important to pay attention to time variables. Voltage is a controlling variable in conventional voltammetry, and the current is a measured one detected as a function of applied voltage at a given time.
\nThe equipment for voltammetry is composed of electrodes, solution, and electric instruments for voltage control. Electrodes and electric instruments are keys of voltammetry. Three kinds of electrodes are desired to be prepared: a working electrode, a counter one, and a reference one. The three will be addressed below.
\nLet us consider a simple experiment in which two electrodes are inserted into a salt-included aqueous solution. When a constant current is applied to the two electrodes, reaction 2H+ + 2e− → H2 may occur at one electrode, and reaction 2OH− → H2O2 + 2e− occurs at the other. The current is the time variation of the electric charge, and hence it is a kind of reaction rate at the electrode. Since the applied current is a sum of the two reaction rates, one being in the positive direction and the other being in the negative, it cannot be attributed to either reaction rate. A technique of attributing the reactions is to use an electrode with such large area that an uninteresting reaction rate may not become a rate-determining step. This electrode is called a counter electrode. The current density at the counter electrode does not specifically represent any reaction rate. In contrast, the current density at the electrode with a small area stands for the interesting reaction rate. This electrode is called a working electrode. It is the potential difference, i.e., voltage, at the working electrode and in the solution that brings about the electrode reaction. However, the potential in the solution cannot be controlled with the working electrode or the counter one. The control can be made by mounting another electrode, called a reference electrode, which keeps the voltage between an electrode and a solution to be constant. However, the constant value cannot be measured because of the difference in phases. A conventionally employed reference electrode is silver-silver chloride (Ag-AgCl) in high concentrated KCl aqueous solution.
\nAn electric instrument of operating the three electrodes is a potentiostat. It has three electric terminals: one being a voltage follower for the reference electrode without current, the second being a current feeder at the counter electrode, and the third being at the working electrode through which the current is converted to a voltage for monitoring. A controlled voltage is applied between the working electrode and the reference one. These functionalities can readily be attained with combinations of operational amplifiers. A drawback of usage of operational amplifiers is a delay of responses, which restricts current responses to the order of milliseconds or 10 kHz frequency.
\nVoltammetry includes various types—linear sweep, cyclic, square wave, stripping, alternating current (AC), pulse, steady-state microelectrode, and hydrodynamic voltammetry—depending on a mode of the potential control. The most frequently used technique is cyclic voltammetry (CV) on a time scale of seconds. In contrast, currently used voltammetry at time as short as milliseconds is AC voltammetry. We describe here the theory and tips for practical use of mainly the two types of voltammetry.
\nThe theory of voltammetry is to obtain expressions for voltammograms on a given time scale or for those at a given voltage. First of all, it is necessary to specify rate-determining steps of voltammograms. There are three types of rate-determining steps under the conventional conditions: diffusion of redox species in solution near an electrode, adsorption on an electrode, and charging processes at the double layer (DL). Electric field-driven mass transport, called electric migration, belongs to rare experimental conditions, and hence it is excluded in this review. When a redox species in solution is consumed or generated at an electrode, it is supplied to or departed from the electrode by diffusion unless solution is stirred. When it is accumulated on the electrode, the change in the accumulated charge by the redox reaction provides the current. Whenever electrode voltage is varied with the time, the charging or discharging of the DL capacitor causes current. Therefore, the three steps are frequently involved in electrochemical measurements.
\nA mass transport problem on voltammetry is briefly described here. The redox species is assumed to be transported by one-directional (x) diffusion owing to heterogeneous electrode reactions. Then, the flux is given by f = −D(∂c/∂x), where c and D are the concentration and the diffusion coefficient of the redox species, respectively. Redox species in solution causes some kinds of chemical reaction through chemical reaction rates, h(c, t). Then the reaction rate is the sum of the diffusional flux and the chemical reaction rate, ∂c/∂t = −∂f/∂x − h(c, t). Here the equation for h = 0 is called an equation of continuum. Eliminating f with the above equation on the assumption of a constant value of D yields ∂c/∂t = D(∂2c/∂x2) − h(c, t). This is an equation for diffusion-chemical kinetics. The expression at h = 0 is the diffusion equation. A boundary condition with electrochemical significance is the control of c at the electrode surface with a given electrode potential. If the redox reaction occurs in equilibrium with the one-electron transfer at the electrode, the Nernst equation for the concentrations of the oxidized species, co, and the reduced one, cr, holds.
\nwhere Eo is the formal potential. If there is no adsorption, the zero-flux condition in the absence of accumulation is valid:
\nThe other conditions are concentrations in the bulk (x → ∝) and the initial conditions.
\nIf the mass transport is controlled only by x-directional diffusion, cr and co are given by the diffusion equations, ∂c/∂t = D(∂2c/∂t2) for c = cr or co. An electrochemically significant quantity is not concentration in any x and t, but a relation between the surface concentrations and the current (the flux at x = 0). On the assumption of Do = Dr = D, of the initial and boundary conditions, (cr)t = 0 = c*, (co)t = 0 = 0, and (cr)x = ∞ = c*, (co)x = ∞ = 0, a solution of the initial-boundary problem is given by [1].
\nwhere j is the current density. The common value of the diffusion coefficients yields co + cr = c* for any x and t. Inserting this relation and Eq. (3) into the Nernst equation, (co)x = 0 = c*/[1 + exp[−F(E − Eo)/RT]], we obtain the integral equation for j as a function of t or E.
\nWhen the voltage is linearly swept with the time at a given voltage scan rate, v, from the initial potential Ein, Eq. (3) through the combination with the Nernst equation becomes
\nThe above Abel’s integral equation can be solved by Laplace transformation. When the time variation is altered to the voltage variation through E = Ein + vt, the current density is expressed as
\nwhere ζ = (E − Eo)F/RT and ζi = (Ein − Eo)F/RT. Evaluation of the integral has to resort to numerical computation. Current at any voltage should be proportional to v1/2, as can be seen in Eq. (5). The voltammogram for v > 0 rises up from Eo, takes a peak, and then deceases gradually with the voltage. The decrease in the current is obviously ascribed to relaxation by diffusion. The peak current density is expressed by
\nat Ep = Eo + 0.029 V at 25°C, where 0.446 comes from the numerical calculation of the integral of Eq. (5).
\nPractical voltage-scan voltammetry is not simply linear sweep but cyclic voltammetry (CV), at which applied voltage is reversed at a given voltage in the opposite direction. The theoretical evaluation of the voltammogram should be at first represented in the integral form with the time variation and then express the time as the voltage. One of the features of the diffusion-controlled cyclic voltammograms is the difference between the anodic peak potential and the cathodic one, ΔEp (in Figure 1), of which value is 59 mV at 25°C.
\nVoltammograms calculated from Eq. (5) for v = (a) 180, (b) 80 and (c) 20 mV s−1.
AC voltammetry can be performed when the time variation of voltage is given by E = Edc + V0eiωt, where ω is the frequency of applied AC voltage, i is the imaginary unit, V0 is its voltage amplitude, and Edc is the DC voltage. A conventional value of V0 is 10 mV. When this voltage form is inserted into Eq. (3) together with the Nernst equation, the AC component of the current density is represented by [2].
\nA voltammogram (j vs. Edc) at a given frequency takes a bell shape, which is expressed by sech2{(Edc − Eo)/RT}. The functional form of sech2 is shown in Figure 2. The peak current appears at Edc = Eo.
\nVoltammogram calculated from Eq. (10).
The AC-impedance technique often deals with the real impedance, Z1, = 1/2Y1 and the imaginary one, Z2 = −1/2Y1, where Y1 is the real admittance given by
\nHere Y2 is the imaginary admittance, equal to Y1. Since Z1 = −Z2, the Nyquist plot, i.e., −Z2 vs. Z1, is a line with the slope of unity. The term 1 + i in Eq. (7) has come from (Dω)1/2, originating from (Diω)1/2. Therefore, it can be attributed to diffusion. In other words, diffusion produces the capacitive component as a delay.
\nWhen the redox species with reaction R = O + e− is adsorbed on the electrode and has no influence from the redox species in the solution, the sum of the surface concentrations of R and O is a constant, Γ*. Then the surface concentration of the oxidized species, Γo, is given by the Nernst equation:
\nThe time derivative of the redox charge corresponds to the current density, j = d(FΓo)/dt. Application of the condition of voltage sweep, E = Ein + vt, to Eq. (9) yields.
\nThe voltammogram takes a bell shape (Figure 2), of which peak is at E = Eo, similar to the AC voltammogram. The current at any voltage is proportional to v. Since the negative-going scan of the voltage provides negative current values, the cyclic voltammogram should be symmetric with respect to the I = 0 axis. The peak current is expressed as jp = F2Γ*v/4RT. The width of the wave at jp/2 is 90 mV at 25°C.
\nSince a phase has its own free energy, contact of two phases provides a step-like gap of the free energy, of which gradient brings about infinite magnitude of force. In order to relax the infinity, local free energy varies from one phase to the other as smoothly as possible at the interface. The large variation of the energy is compensated with spontaneously generated space variations of voltage, i.e., the electric field, which works as an electric capacitor. The capacitance at solution-electrode interface causes orientation of dipoles and nonuniform distribution of ionic concentration, of which layer is called an electric double layer (DL).
\nWhen the time variation of the voltage is applied to the DL capacitance, Cd, the definitions of the capacitance (q = CdV) and the current lead
\nwhere Cd generally depends on the time. This dependence is significant for understanding experimentally observed capacitive currents.
\nThe DL capacitance has exhibited the frequency dispersion expressed by Cd = (Cd) 1Hz f −λ, called the constant phase element [3, 4, 5] or power law [6, 7], where λ is close to 0.1. Inserting this expression and V = V0eiωt into Eq. (11) yields
\nThis is a simple sum of the real part of the current and the imaginary one, indicating that the equivalent circuit should be a parallel combination of a capacitive component and a resistive one, both depending on frequency. Since the ratio, −Z2/Z1, for Eq. (12) is 1/λ, the Nyquist plots have slopes less than 10 rather than infinity.
\nIf the capacitive charge is independent of the time, the capacitive current should be I = d(CV)/dt = C(E − Eo)/v. Therefore, it takes a horizontal positive (v > 0) and a negative line (v < 0), as shown in Figure 3 (dashed lines). When the time dependence of C, i.e., Cd = (Cd)0t−λ, is applied to Eq. (11), for the forward and the backward scans, respectively, we have
\nCapacitive voltammograms by CV at v= 0.5 V s−1 for (dashed lines) the ideal capacitance and for Eq. (13) (solid curves) at λ = 0.2.
The variation of CV computed from Eq. (13) (Figure 3, solid curves) is similar to our conventionally observed capacitive waves.
\nVoltammograms can identify an objective species by comparing a peak potential with a table of redox potentials and furthermore determine its concentration from the peak current. Their results are, however, sometimes inconsistent with data by methods other than electrochemical techniques if one falls in some pitfalls of analytical methods of electrochemistry. For example, a peak potential is influenced by a reference electrode and solution resistance relevant to methods. Peak currents are varied complicatedly with mass transport modes as well as associated chemical reactions. Since the theory on voltammetry covers only some restricted experimental conditions, it can rarely interpret the experimental data successfully. This review is devoted to some voltammetric tips which can lead experimenters to reasonable interpretation.
\nIt is rare to observe a reversible voltammogram in which both oxidation and reduction waves appear in a symmetric form with respect to the potential axis at a similar peak potential, as in Figure 1. Frequently observed voltammograms are irreversible, i.e., either a cathodic or an anodic wave appears; a value of a cathodic peak current is quite different from the anodic one in magnitude; a cathodic peak potential is far from the anodic one. These complications are ascribed to chemical reactions and/or phase transformation after the charge-transfer reaction. A typical example is deposition of metal ions on an electrode. The complications can be interpreted by altering scan rates and reverse potentials.
\nA wave at a backward scan is mostly attributed to electrode reactions generated by experimenters rather than to species latently present in the solution. That is, it is artificial. It is caused either by the reaction of the wave at the forward scan or the reaction of the rising-up current just before the reverse potential. A source of the backward wave can be found by changing the reverse potentials.
\nSome voltammograms have more than two peaks at one-directional scan. The appearance of the two can be interpreted as a two-step sequential charge-transfer reaction. However, multiple waves appear also by combinations of chemical reactions and adsorption. The peak current and the charge for this case are quite different from the predicted ones, as will be described in Section 3.2. Change in scan rates may be helpful for interpreting the multiple waves.
\nIt is possible to predict theoretically a controlling step of voltammograms from their shape (a bell type corresponding to an adsorption wave or a draw-out type corresponding to a diffusion wave). However, the shape strongly depends on chemical complications, adsorption, and surface treatment of the electrodes. When redox species in solution is partially adsorbed on an electrode, the electrode process is far from a prediction because of very high concentration in the adsorbed state. A draw-out-shaped wave can be observed even for the adsorbed control. It is important to estimate which state the reacting species takes on the electrode. Potentials representing of voltammetric features do not express a controlling step in reality although the theory does. One should pay attention to the current. The peak current controlled by diffusion with one-electron transfer is given by Ip = 0.27 cAv1/2 μA (c, bulk concentration mM; A, electrode area mm2; v, potential sweep rate mV s−1). The microelectrode behavior sometimes comes in view at v < 10 mV s−1, A < 0.1 mm2, so the measured current is larger than the estimated value. On the other hand, the peak current controlled by adsorption is given by Ip = 1.6 Av nA when one redox molecule is adsorbed at 1 nm2 on the electrode. The voltammogram by adsorption often differs from the ideal bell shape due to adsorbed molecular interaction and DL capacity. Division of the area of the peak by the scan rate yields the amount of adsorbed electricity. Comparison of this with the anticipated amount of adsorption may be helpful for understanding the electrode process.
\nThe peak potential difference ΔEp between the oxidation wave and the reduction wave (Figure 1) has been used for a prediction of the reaction mechanism. For example, ΔEp = 60 mM suggests the diffusion-controlled current accompanied by one-electron exchange, whereas ΔEp = 30 mM infers a simultaneous reaction with two electrons. Then what would happen for 120 mV which is sometimes found? A half-electron reaction might not be accepted. Potential shift over 60 mV occurs by chemical complications. In contrast, the voltammogram by adsorbed species shows theoretically a bell shape with the width, E1/2 = 90 mV, at the half height of the peak (Figure 2). This value is based on the assumption of the absence of interaction among adsorbed species. However, adsorption necessarily yields such high concentrations as strong interaction.
\nIt is necessary to pay attention to the validity of analyzing ΔEp and E1/2. The peak potential is the first derivative of a voltammogram. Since ΔEp is a difference between the two peaks, it is actually the second-order derivative of the curves in the view of accuracy. In other words, the accuracy of ΔEp is lower than that of peak current. Furthermore, peak potentials as well as E1/2 readily vary with scan rates owing to chemical reactions and solution resistance. One should use the peak current for data analysis instead of the potentials.
\nVoltammograms of a number of redox species have been reported to be diffusion controlled from a relationship between Ip and v1/2. The redox species exhibiting diffusion-controlled current is, however, limited to ferrocenyl derivatives under conventional conditions. Voltammograms even for [Fe(CN)6]3−/4− and [Ru(NH3)6]3+ are deviated from the diffusion control for a long-time measurement. Why have many researchers assigned voltammograms to be the diffusion-controlled step? The proportionality of Ip to v1/2 in Eq. (6) has been confused with the linearity, Ip = av1/2 + b (b ≠ 0). The plot for the adsorption control (Ip = kv) also shows approximately a linear relation for Ip vs. v1/2 plot in a narrow domain of v, as shown in Figure 4B. The opposite is true (Figure 4A). Therefore, it is the intercept that determines a controlling step of either the diffusion or adsorption. Some may say that the intercept can be ascribed to a capacitive current. If so, the peak current should be represented by Ip = av1/2 + bv, which exhibits neither linear relation with v1/2 nor v.
\nPlots of Ip of (A) K3Fe(CN)6 and (B) polyaniline-coated electrode against v1/2 and v. Both plots show approximately linear relations.
There is a simple method of determining a controlling step either by diffusion or adsorption. Current responding to diffusion-controlled potential at a disk electrode in diameter less than 0.1 mm would become under the steady state after a few seconds [8]. Adsorption-limited current should become zero soon after the potential application. Many redox species, however, show gradual decrease in the current because reaction products generate an adsorbed layer which blocks further electrode reactions.
\nIt is well known that currents vary not only with applied voltage but also with the time. It is not popular, however, to discuss quantitatively time dependence of CV voltammograms. Enhancing v generally increases the current and causes the peak potential to shift in the direction of the scan. A reason for the former can be interpreted as generation of large current at a shorter time (see Eqs. (6) and (10)), whereas the latter is ascribed to a delay of reaction responses as well as a voltage loss of the reaction by solution resistance. Then the voltage effective to the reaction is lower than the intended voltage, and so the observed current may be smaller than the predicted one. Although Ip is related strongly with Ep, the relationship has rarely been examined quantitatively.
\nA technique of analyzing the potential shift is to plot Ip against Ep, [9] as shown in Figure 5. If the plots on the oxidation side (Ip > 0) and the reduction side (Ip < 0) fall each on a straight line, the slope may represent conductivity. If values of both slopes are equal, the slope possibly stands for the conductivity of the solution or membrane regardless of the electrode reaction. The potential extrapolated to the zero current on each straight line should be close to the formal potential. Since this plot is simple technically, the analytical result is more reliable than at least discussion of time dependence of Ep.
\nPlots of Ip vs. Ep by CV of the first (circles) and the second (triangles) peak of tetracyanoquinodimethane (TCNQ), and ferrocene (squares) in 0.2 M (CH3)4NPF6 included acetonitrile solution when scan rates were varied, where triangles were displayed by 0.4 V shift.
Most researchers have quoted the Randles-Sevcik equation, jp = 0.446 (nF)3/2c*(Dv/RT)1/2, for the diffusion-controlled peak current without hesitation, where n is the electron transfer number of the reaction. According to Faraday’s law, the electrolytic quantity is proportional to nc*. Why is the peak current proportional to n3/2 instead of n? Let us consider voltammetry of metal nanoparticles (about 25 nm in diameter) composed of 106 metal atoms dispersed in solution. Faraday’s law predicts that the current is 106 times as high as the current by the one metal atom. However, Randles-Sevcik equation predicts the current further (106)1/2 = 1000 times as large, just by the effect of the potential scan. The order 3/2 is specific to CV. The order of n for AC current and pulse voltammetry is 2 [10]. On the other hand, the diffusion-controlled steady-state currents at a microelectrode and a rotating disk electrode are proportional to n. Comparing the differences in the order by methods, we can predict that the time variation of the voltage increases the power of n.
\nLet a potential width from a current-rising potential to Ep be denoted by ΔE. When an n-electron transfer reaction occurs through the Nernst equation at which F in Eq. (1) is replaced by nF, the concentration-potential curve takes the slope n times larger than that at n = 1 (see co/cr ≅ nF(E − Eo)/RT near E = Eo in Eq. (1)). Then we have (ΔE)n = (ΔE)n = 1/n. The period of elapsing for (ΔE)n becomes shorter by 1/n, as if v might be larger by n times. Then v in Eq. (6) should be replaced by (nv)1/2. Combining this result with the flux j/nF, the current becomes n3/2 times larger than that at n = 1. Therefore, the factor n3/2 results from the Nernst equation. This can be understood quantitatively by replacing F in Eq. (3) by nF. There are quite a few reactions for n ≥ 2 both for Nernst equation and in the bulk as stable species. The term n3/2 is valid only for a concomitant charge-transfer reaction, i.e., simultaneous occurrence n-electron transfer rather than a step-by-step transfer. Apparent two-electron transfer reactions in the bulk, for example, Cu, Fe, Zn, and Pb, cause other reactions immediately after the one-electron transfer.
\nAn electrochemical response is observed as a sum of the half reactions at the two electrodes. In order to extract the reaction at the working electrode, a conventional technique is to increase the area of the counter electrode so that the reaction at the counter electrode can be ignored. If the counter electrode area is increased by 20 times the area of the working electrode, the observed current represents the reaction of the working electrode with an error of 5%. Let us consider the experiment in which nanoparticles of metal are coated on a working electrode for obtaining capacitive currents or catalyst currents. Then, the actual area of the working electrode can be regarded as the area of the metal particles measured by the molecular level. Then, the area will be several thousand times the geometric area so that the observed current may represent the reaction at the counter electrode. This kind of research has frequently been found in work on supercapacitors. On the other hand, if the electrode reaction is diffusion controlled, the current is determined by the projected area of the diffusion layer. Then the current is not affected by the huge surface area of nanoparticles.
\nIt is important to examine whether or not a reaction is controlled by at a counter electrode. A simple method is to coat nanoparticles also on the counter electrode. Then the current in the solution may become so high that the potential of the working electrode cannot be controlled. It is better to use a two-electrode system. Products at the counter electrode are possible sources of contaminants through redox cycling.
\nThe Ag-AgCl electrode is most frequently used as a reference electrode in aqueous solution because of the stable voltage at interfaces of Ag-AgCl and AgCl-KCl through fast charge-transfer steps, regardless of the magnitude of current density. The “fast step” means the absence of delay of the reaction or being in a quasi-equilibrium. The stability without delay is supported with high concentration of KCl.
\nWhen an Ag-AgCl electrode is inserted to a voltammetric solution, KCl necessarily diffuses into the solution, associated with oxygen from the reference electrode. Thus, the reference electrode is a source of contamination by salt, dichlorosilver and oxygen. It is interesting to examine how much amount a solution is contaminated by a reference electrode [9]. Time variation of ionic conductivity in the pure water was monitored immediately after a commercially available Ag-AgCl electrode was inserted into the solution. Figure 6 shows rapid increase in the conductivity as if a solid of KCl was added to the solution. Oxygen included in the concentrated KCl may contaminate a test solution. Even the Ag-AgxO electrode, which was formed by oxidizing silver wire, increased also the conductivity, probably because the surface is in the form of silver hydroxide. As a result, no reference electrode can be used for studying salt-free electrode reactions. If neutral redox species such as ferrocene is included in a solution, the potential reference can be taken from redox potential of ferrocene.
\nTime-variation of conductivity of water into which (circles) Ag|AgCl, (triangles) Ag|AgxO, and (squares) AgCl-coated Ag wire were inserted. Conductivity measurement was under N2 environment.
When a constant voltage is applied to the ideal capacitance C, the responding current decays in the form of exp(−t/RC), where R is a resistance in series connected with C. It has been believed that a double-layer capacitance in electrochemical system behaves as an ideal capacitor, where R is regarded as solution resistance. However, any exponential variation cannot reproduce transient currents obtained at the platinum wire electrode in KCl aqueous solution, as shown in Figure 7. The current decays more slowly than by exp(−t/RC), because it is approximately proportional to 1/t. The property of non-ideal capacitance is the result of the constant phase element of the DL capacitance, as described in Section 2.3. The dependence of 1/t can be obtained approximately by the time derivative of q = V0C0t−λ for the voltage step V0.
\nChronoamperometric curves when 0.2 V vs. Ag|AgCl was applied to a Pt wire in 0.5 M KCl aqueous solution. Solid curves are fitted ones by exp(-t/RC) for three values of RC.
The slow decay is related with a loss of the performance of pulse voltammetry, in which diffusion-controlled currents can readily be excluded from capacitive currents. The advantage of pulse voltammetry is based on the assumption of the exponential decay of the capacitive current. Since the diffusion current with 1/t1/2 dependence is close to the 1/t dependence, it cannot readily be separated from the capacitive current in reality. A key of using pulse voltammetry is to take a pulse time to be so long as a textbook recommends.
\nHigh-performance potentiostats are equipped with a circuit for compensation of resistance by a positive feedback. Unfortunately, the circuit is merely useful because voltammograms depend on intensity of compensation resistances of the DL capacitance. It should work well if the DL capacitance is ideal.
\nAC techniques have an advantage of examining time dependence at a given potential, whereas CV has a feature of finding current-voltage curves at a given time. The former shows the dynamic range from 1 Hz to 10 kHz, while the latter does conventionally from 0.01 to 1 Hz. This wide dynamic range of the AC technique is powerful for examining dynamics of electrode reactions. Analytical results by the former are often inconsistent with those by the latter, because of the difference in the time domain. The other scientific advantage of the AC technique is to get two types of independent data set, frequency variations of real components and imaginary ones by the use of a lock-in amplification. The independence allows us to operate mathematically the two data, leading to the data analysis at a level one step higher than CV. An industrial advantage is the rapid measurement, which can be applied to quality control for a number of samples. The analysis of AC impedance necessarily needs equivalent circuits of which components do not have any direction relation with electrochemical variables.
\nData of the electrochemical AC impedance are represented by Nyquist (Cole-Cole) plots, that is, plots of the imaginary component (Z2) of the impedance against the real one (Z1), as shown in Figure 8. The simplest equivalent circuit for electrochemical systems is the DL capacitance Cd in series with the solution resistance RS. The Nyquist plot for this series circuit is theoretically parallel to the vertical axis (Figure 8A-a), but experiments show a slope of 5 or more (Figure 8A-b). This behavior, called constant phase element (CPE) and the power law, has been verified for combinations of various materials and solvents [6, 7, 11, 12]. The equivalent circuit for Eq. (12) is a parallel combination of capacitance and resistance (Figure 8B). Even without an electrode reaction, current always includes a real component.
\n(A) Nyquist plots for a RC-series circuit with ideal capacitor (a) and DL capacitor (b). (B) Equivalent circuit with the power-law of Cd. (C) Randles circuit.
The equivalent circuit with the Randles type is a parallel combination of the ideal DL capacitor Cd with the ideal resistance Rct representing the Butler-Volmer-type charge-transfer resistance. Practically, the Warburg impedance (the inverse of Eq. (8)) due to diffusion of redox species is incorporated in a series into Rct (Figure 8C). Rct cannot be separated from the DL resistance because of the frequency dispersion. Since even the existence of Rct is in question (Section 3.12), it is difficult to determine and interpret Rct. The usage of a software that can analyze any Nyquist plots will provide values of R and C. Even if analyzed values are in high accuracy, researches should give them electrochemical significance.
\nResidual current varies with treatments of electrodes such as polishing of electrode surfaces and voltage applications to an extremely high domain. It can often be suppressed to yield reproducible data when the electrode is replaced by simple platinum wire or carbon rod having the same geometric area. Simple wire electrodes are quite useful especially for measurements of DL capacitance and adsorption. One of the reasons for setting off large residual current is that the insulator of confining the active area is not in close contact with the electrode, so that the solution penetrated into the gap will give rise to capacitive current and floating electrode reactions. Since the coefficient of thermal expansion of the electrode is different from that of the insulator, the residual current tends to get large with the elapse from the fabrication of the electrode. This prediction is based on experience, and there are few quantitative studies on residual currents.
\nUnexpected gap has been a technical problem at dropping mercury electrodes. If solution penetrates the inner wall of the glass capillary containing mercury, observed currents become irreproducible. Water repellency of the capillary tip has been known to improve the irreproducibility in order to reduce the penetration. A similar technique has been used for voltammetry at oil-water interfaces and ionic liquid-water interfaces at present.
\nVoltammograms are said to vary with electrode reaction rates, and the rate constants have been determined from time dependence of voltammograms. The fast reaction of which rate is not rate determining has historically been called “reversible.” In contrast, such a slow reaction that a peak potential varies linearly with log v is called “irreversible.” A reaction between them is called “quasi-reversible.” The distinction among the three has been well known since the theoretical report on the quasi-reversible reaction by Matsuda [1]. This theory is devoted to solving the diffusion equations with boundary conditions of the Butler-Volmer (BV) equation under the potential sweep. As the standard rate constant ks in the BV equation becomes small, the peak shifts in the direction of the potential sweep from the diffusion-controlled peak. Steady-state current-potential curves in a microelectrode [13] and a rotating disk electrode also shift the potential in a similar way. According to the calculated CV voltammograms in Figure 9, we can present some characteristics: (i) if the oxidation wave shifts to the positive potential, the negative potential shift should also be found in the reduction wave. (ii) Both the amounts of the shift should have a linear relationship to log v. (iii) The shift should be found in iterative measurements. (iv) The peak current should be proportional to v1/2.
\nCV voltammograms (solid curves) at a normally sized electrode and steady-state voltammograms (dashed curves) at a microelectrodes in 12 μm in diameter, calculated theoretically for v = 0.5 V s−1, D = 0.73 × 10−5 cm2 s−1, ks = (a) 0.1, (b) 0.01, (c) 0.001, (d) 0.0001 cm s−1. The potential shift of CV is equivalent to the wave-shift at a microelectrode through the relation, v = 0.4RTD/αFa2 (a: radius).
The authors attempted to find a redox species with the above four behaviors. Some redox species can satisfy one of the four requirements, but do not meet the others. Most reaction rate constants have been determined from the potential shift in a narrow time domain. They are probably caused by follow-up chemical reactions, adsorption, or DL capacitance. For example, CV peak potentials of TCNQ and benzoquinone were shifted at high scan rates, whereas their steady-state voltammograms were independent of diameters of microdisk electrodes even on the nanometer scale [14]. The shift at high scan rates should be due to the frequency dispersion of the DL capacitance, especially the parallel resistance in the DL (Figure 8B). Values of the heterogeneous rate constants and transfer coefficients reported so far have depended not only on the electrochemical techniques but also research groups. Furthermore, they have not been applied or extended to next developing work. These facts inspire us to examine the assumptions and validity of the BV formula.
\nLet us revisit the assumptions of the BV equation when an overvoltage, i.e., the difference of the applied potential from the standard electrode potential, causes the electrode reaction. The rate of the oxidation in the BV equation is assumed to have the activation energy of α times the overvoltage, while that of the reduction does that of (1 − α) times. This assumption seems reasonable for the balance of both the oxidation and the reduction. However, the following two points should be considered. (i) Once a charge or an electron is transferred within the redox species, the molecular structure changes more slowly than the charge transfer itself occurs. The structure change causes solvation as well as motion of external ions to keep electric neutrality. These processes should be slower than the structure change. If the overvoltage can control the reaction rate, it should act on to the slowest step, which is not the genuine charge-transfer process. (ii) Since a reaction rate belongs to the probability theory, the reaction rate (dc/dt) at t is determined with the state at t rather than a state in the future. In other words, the rate of the reduction should have no relation with the oxidation state which belongs to the future state. The BV theory assumes that the α times activation energy for the oxidation is related closely with 1-α times one for the reduction. This assumption is equivalent to predicting a state at t + Δt from state at t + 2Δt, like riding on a time machine. This question should be solved from a viewpoint of statistical physics.
\nDevelopment of scanning microscopes such as STM and AFM has allowed us to obtain the molecularly and atomically regulated surface images, which have been used for interpreting electrochemical data. Then the electrochemical data are expected to be discussed on a molecular scale. However, there is an essential problem of applying photographs of regularly arranged atoms on an electrode to electrochemical data, because the former and the latter include, respectively, microscopically local information and macroscopically averaged one. A STM image showing molecular patterns is information of only a part of electrode, at next parts of which no atomic images are often observed but noisy images are found. Electrochemical data should be composed of information both at a part of the electrode showing the molecular patters and at other parts showing noisy, vague images. Noisy photographs are always discarded for interpreting electrochemical data although the surfaces with noisy images also contribute electrochemical data.
\nAn ideal experiment would be made by taking STM images over all the electrodes that provide electrochemical data and by obtaining an averaged image. However, it is not only impossible to take huge amounts of images, but the averaged image might be also noisy. It may be helpful to describe only a possibility of reflecting the STM-imaged atomic structure on the electrochemical data.
\nVoltammograms by adsorbed redox species, called surface waves, are frequently different from a bell shape (Figure 2). Really observed features are the following: (i) the voltammogram does not suddenly decay after the peak, exhibiting a tail-like diffusional wave; (ii) the peak current and the amount of the electricity are proportional to the power less than the unity of v; (iii) the oxidation peak potential is different from the reduction one; (iv) the background current cannot be determined unequivocally; and (v) voltammograms depend on the starting potential. Why are experimental surface waves different from a symmetric, bell shape in Figure 2?
\nA loss of the symmetry with respect to the vertical line passing through a peak can be ascribed to the difference in interactions at the oxidized potential domain and at the reduced one. Since redox species takes extremely high concentration in the adsorbed layer, interaction is highly influenced on voltammetric form. When the left-right asymmetry is ascribed to thermodynamic interaction, it has been interpreted not only with Frumkin’s interaction [15] but also Bragg-Williams-like model for the nearest neighboring interactive redox species [16]. On the other hand, most surface waves are asymmetric with respect to the voltage axis even at extremely slow scan rates. This asymmetry cannot be explained in terms of thermodynamics of intermolecular interaction, but should resort to kinetics or a delay of electrode reactions. There seems to be no delay in the electrode reaction of the monomolecular adsorption layer, different from diffusion species. The delay resembles the phenomenon of constant phase element (CPE) or frequency power law of DL capacitance, in that the redox interaction may occur two-dimensionally so that the most stable state can be attained. This behavior belongs to a cooperative phenomenon [17]. A technique of overcoming these complications is to discuss the amount of charge by evaluating the area of the voltammogram. It also includes ambiguity of eliminating background current and assuming the independence of the redox charge from the DL charge.
\nThe simplest theories for voltammetry are limited to the rate-determining steps of diffusion of redox species and reactions of adsorbed species without interaction. Variation of scan rates as well as a reverse potential is helpful for predicting redox species and reaction mechanisms. Furthermore, the following viewpoints are useful for interpreting mechanisms:
comparison of values of experimental peak currents with theoretical ones, instead of discussing ΔEp and E1/2;
examining the proportionality of Ip vs. v or vs. v1/2, i.e., zero or non-zero values of the intercept of the linearity;
a reference electrode and a counter electrode being a source of contamination in solution;
attention to very slow relaxation of DL capacitive currents;
inclusion of ambiguity in the equivalent circuit with the Randles type.
If your research is financed through any of the below-mentioned funders, please consult their Open Access policies or grant ‘terms and conditions’ to explore ways to cover your publication costs (also accessible by clicking on the link in their title).
\n\nIMPORTANT: You must be a member or grantee of the listed funders in order to apply for their Open Access publication funds. Do not attempt to contact the funders if this is not the case.
",metaTitle:"List of Funders by Country",metaDescription:"If your research is financed through any of the below-mentioned funders, please consult their Open Access policies or grant ‘terms and conditions’ to explore ways to cover your publication costs (also accessible by clicking on the link in their title).",metaKeywords:null,canonicalURL:"/page/open-access-funding-funders-list",contentRaw:'[{"type":"htmlEditorComponent","content":"Book Chapters and Monographs
\\n\\nMonographs Only
\\n\\nBook Chapters and Monographs
\\n\\n\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\\n\\nMonographs Only
\\n\\nLITHUANIA
\\n\\nBook Chapters and Monographs
\\n\\n\\n\\nBook Chapters and Monographs
\\n\\n\\n\\nBook Chapters and Monographs
\\n\\n\\n\\nSWITZERLAND
\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\\n\\n\\n\\nBook Chapters and Monographs
\\n\\nBook Chapters and Monographs
\n\nMonographs Only
\n\nBook Chapters and Monographs
\n\n\n\nBook Chapters and Monographs
\n\n\n\nBook Chapters and Monographs
\n\nBook Chapters and Monographs
\n\nBook Chapters and Monographs
\n\nBook Chapters and Monographs
\n\n\n\nBook Chapters and Monographs
\n\nBook Chapters and Monographs
\n\n\n\nMonographs Only
\n\n\n\nLITHUANIA
\n\nBook Chapters and Monographs
\n\n\n\nBook Chapters and Monographs
\n\n\n\nBook Chapters and Monographs
\n\n\n\nSWITZERLAND
\n\nBook Chapters and Monographs
\n\n\n\nBook Chapters and Monographs
\n\n\n\nBook Chapters and Monographs
\n\n