Open access peer-reviewed chapter

The Coupled Magnetic Field Effects on the Microstructure Evolution and Magnetic Properties of As-Deposited and Post- Annealed Nano-Scaled Co-Based Films — Part II

By Donggang Li, Qiang Wang, Agnieszka Franczak, Alexandra Levesque and Jean-Paul Chopart

Submitted: April 28th 2015Reviewed: August 26th 2015Published: December 2nd 2015

DOI: 10.5772/61349

Downloaded: 1276

Abstract

Superimposed external magnetic fields during electrodeposition process offers the possibility to tailor the microstructure and properties of the obtained films in a very efficient, contactless, and easily controllable way, which is caused by so-called magnetohydrodynamic (MHD) effect. On the other hand, the non-equilibrium state of as-electrodeposited nanocrystalline films provides a strong thermodynamic potential for microstructural transformation. This means that the beneficial effect of magneto-electrodeposition on a nanocrystalline film can be completely consumed by thermal exposure at a relatively low temperature. Magnetic field annealing has been confirmed to be useful for tailoring the microstructure of as-deposited nanocrystalline films for their widespread uses.

Keywords

  • coupled magnetic field effects
  • microstructure evolution
  • nano-scaled Co-based films

1. Evolution of morphology in electrodeposited nanocrystalline Co–Ni alloy films by in situ high magnetic field application

1.1. Introduction

It is well known that the magnetic properties of deposits (such as GMR effect, coercivity fields, moment per atom, etc.) are strongly related to the morphology, i.e., grain shape, grain size, and layer roughness. For instance, the lower the roughness of Co–Cu multi-layers, the higher the GMR effect is visible. On the opposite, an increase in roughness of the magnetic layer leads to an increase of its coercivity fields Hc [1]. The morphology of electrodeposits is especially sensitive to mass transport and chemical reactions, which can be controlled by a magnetic field due to the Lorentz force induced by the interaction of magnetic field and current (magnetohydrodynamic effect, MHD). Therefore, superimposing a magnetic field during electrodeposition is an interesting interdisciplinary zone, with promising opportunities for producing or tailoring novel nanocrystalline materials with better magnetic properties. For instance, as a non-contact method, magnetic field can be used for optimization of electrodeposited CoNi alloys that can be used in wireless micro-robots for biomedical applications [2].

Recently, weak magnetic field (lower than 1 T) effects on the electrodeposition process and the morphology of ferromagnetic deposits have been reported by different groups [3]. Krause et al. [4] reported that Co deposit shape changed into double-sized hexagonal crystallites, if a 1 T magnetic field was applied parallel to the surface of substrate. Ispas et al. [5] found that smaller grains and lower roughness for NiFe electrodeposits have been obtained with superimposition of a magnetic field up to 0.7 T. A similar observation of reducing the grain size and roughness in NiCu alloy with an application of a parallel-to-electrode magnetic field has been made by Tabakovic et al [6]. On the contrary, atomic force microscopy in Ref. [7] showed that a magnetic field induced an increase in the surface roughness of the Ni-layer electrodeposits. Many other experimental results highlight that the influence of magnetic field on the morphology of electrodeposits is varied between different reports, and not fully understood. Thanks to the development of superconducting technology, similar studies for electrochemical reaction with an in situ high magnetic field (HMF) application [8] can be conducted to undertake other experimental investigations in order to understand the magnetically induced effects and obtain new materials due to better control of ion transport in bath and crystallization process, and in turn better control of the magnetic properties of deposits by the application of magnetic fields. In this work, we focus on the effects of HMF on the morphology of the nanocrystalline CoNi film. A clear dependence of grain shape, grain size, and layer roughness on magnetic flux density was characterized by field-emission scanning electronic microscopy (FE-SEM) and atomic force microscopy (AFM).

1.2. Experimental

All electrodeposition experiments were performed in a three-electrode cell without agitation. ITO (1000 A) glass of 1 cm diameter was used as the working electrode, the counter electrode was a quadrate Pt plate of 1×2cm, and Hg/Hg2SO4/K2SO4(sat.) was used as reference electrode. The aqueous electrolyte contained 0.3 M CoSO4.7H2O + 0.7 M NiSO4.6H2O + 0.4 M H3BO3 + 0.015 M saccharin. The pH was adjusted to 4.7 by adding 1 M NaOH solution. Galvanostatical deposition, using a current density of 10 mA /cm2 was performed at 50℃ for 1 min. A water-cooled superconducting magnet (CNRS, Grenoble, France) supplied a magnetic flux density up to 12 T, which was superimposed to the electrochemical cell during the electrodeposition process in the parallel direction to the vertical electrode surface. Surface morphology and chemical composition of the deposited films were investigated by FE-SEM appended with an energy-dispersive X-ray spectroscope (EDX, SUPRA 35, Japan) at three points of the CoNi films. The topography and the roughness were investigated with AFM (NTEGRA AURA, NT-MDT, Russia). Each sample was measured in areas of 5μm×5μmat three different positions on the film.

1.3. Results and discussion

Typical FE-SEM morphologies of CoNi films electrodeposited with different magnetic intensities up to 12T are shown in Figure 1. The figure demonstrates drastic morphological variations with the magnetic flux density (B). The short-clavated shape of the grains is similar in two cases: electrodeposition without magnetic field and with a weak magnetic field of 1 T (Figure 1. a–b). When the applied magnetic field was increasing from 3 to 12 T, nanosheets-like structures in a three-dimensional network without obvious grain boundary are clearly observed in CoNi deposits. The morphologies of these deposits are very similar to those reported in Bai. et al.’s work [9], although these authors found this kind of nanowires structure in Fe-Co deposits. The dependence of the mean diameter of these nanosheets on the magnetic flux density shows a tendency to firstly increase and then decrease. In the case of electrodeposition under superimposition of 12 T magnetic field (Figure 1 f), the mean size of the silk-like nanosheets in the film reaches a minimum with some agglomerate distributing in it, which can also be observed in Figure 1a. In addition, there is an evolution of grain shape from short-clavate in case of 0—1 T to nanosheets at 3–12 T.

Figure 1.

FE-SEM images showing the morphology of CoNi films electrodeposited with high magnetic fields of (a) 0 T, (b) 1 T, (c) 3 T, (d) 6 T, (e) 9 T, (f) 12 T.

Table 1 displays the magnetic field effect on CoNi film composition during the electrodeposition. It can be seen that cobalt contents in the film augmented from 70% to around 79% with the increase of B from 0 to 9 T, but decreased when the magnetic fields increased from 9 to 12 T. The dependence of Co/Ni ratio on B exhibits a similar trend as the evolution of morphology. To discuss the field-dependent behavior of the composition and morphology, it has to be considered that the magneto-electrochemical process is both Co (Ni) deposition and hydrogen-ion reduction at the meantime. As generally known, magnetohydrodynamic effect in a magnetic field oriented parallel to the electrode surface yields significant convection, which diminishes the diffusion layer thickness in the vicinity of electrode, and therefore increases the current efficiency. However, at high magnetic flux densities the Co deposition is diminished, since the hydrogen-ion reduction dominates the total reduction process resulting in the decrease of the current efficiencies of Co. This retarded effect is in agreement with the results obtained in the experiments of Uhlemann et al. [8] under similar conditions.

Applied magnetic fieldCo (at %) in the filmCo/Ni composition ratio
0 T
1 T
3 T
6 T
9 T
12 T
70.4 ± 0.6
76.6 ± 0.4
76.5 ± 0.6
77.4 ± 0.3
78.8 ± 0.5
76.3 ± 0.4
2.38
3.27
3.26
3.43
3.72
3.22

Table 1.

Compositions of the deposited CoNi films as a function of the magnetic flux density.[16]

Figure 2.

AFM images of top-view of CoNi films electrodeposited under high magnetic fields of (a) 0 T, (b) 1 T, (c) 3 T, (d) 6 T, (e) 9 T, (f) 12 T.

In order to quantitatively analyze the effects of HMF on grain size and roughness of the electrodeposited film, AFM top view (5×5μm2) images of the surface topography of nanocrystalline films are shown in Figure 2. The shape and size of the grains are different in these typical samples deposited with imposed magnetic fields, being small and uniform in the case of (0–1 T); larger and irregular with accumulative cluster in the case of (3–9 T); smallest shape and more uniform in the case of 12 T. This difference indicates that the application of HMF modified the film nucleation and growth processes on the surface of cathode. It should be mentioned that the disappearance of "nanosheets" in the AFM image comparing with its existence in the SEM image is probably related to the difference in surface analysis between AFM (3D overview with the tip scanning in perpendicular to the surface) and SEM (2D morphological structure in the direction parallel to the surface).

The average values of surface roughness and lateral feature size, which can be used to characterize the grain size, were calculated using standard Nova software of AFM as shown in Figure 3. AFM investigations show that the curves of the feature size and roughness exhibit non-monotonic increase up to 9 T. In contrast, feature size and roughness decreased dramatically with further magnetic field increase up to 12 T, eventually becoming smaller than in the case without magnetic field. It must be pointed out that the mean grain size obtained here based on the AFM images agrees well with the calculated result by using Scherrer’s formula according to the X-ray diffraction.

Figure 3.

The dependence of roughness and grain size of CoNi films on the magnetic flux density.

The main focus of this short communication is high magnetic field effects on the electrodeposition of CoNi alloy. As regards deposition rate, the effect is observed in the mass transport limited regime [10], where the magnetic field influences the diffusion of the ions toward the cathode, but not the redox reaction. The results can be discussed by the overlapping effects of two types of force under a HMF in the direction parallel to the surface of cathode. One is the Lorentz force given by FL=q(E+v×B)(where, qis the electrical charge of an ion, Eis the electrical field vector, vis the velocity of ions in electrolyte), which is responsible for a macro-MHD to decrease the thickness of the diffusion layer near the electrode, and in turn to improve the current efficiency of deposition. Whereas, at high fields the other paramagnetic force has to be taken into account, given by Fm=χmB2c/2μ0(where, χmis the molar susceptibility of the ions, cis the molar concentration, μ0is the permeability of free space), which causes paramagnetic ions to move in the direction of concentration gradient. In other words, the mass transport from electrolyte to the surface of cathode is modified by the paramagnetic force, which is in a perpendicular direction to the magnetic field. Firstly, the force acts near the edge of the electrode due to the concentration gradient in the applied magnetic field. Secondly, it acts on the whole electrode surface most likely combining with the gravitational effect and the secondary effect of the Lorentz force on the concentration profile. According to the estimation of Coey et al. [11], the value of paramagnetic force acting in aqueous electrolytes is of order 104(N/m3) with a field of 1 T. Therefore, a dramatic increase of Fmin a 12 T magnetic field up to about 106(N/m3), which has a magnitude comparable to that of the Lorentz force, changes the mass transport regime, and then the deposit morphology.

Obviously, the combined effects of these forces, depending on the magnetic field amplitude, cannot be discriminated in a simple way. Adsorption phenomena of ionic species and hydrogen evolution have to be regarded as very important reactions that govern the deposition process. The magnetic convection can dramatically modify these two reactions, changing the local pH and therefore texture and morphology of the deposits [12].

The present work paves the way for optimized electroplated alloys, which have been far found the most utility in micro/nano electro mechanical systems (MEMS/NEMS). These MEMS devices such as microactuators, mocrorobots, sensors, require excellent magnetic properties for actuated wirelessly by application of external magnetic fields. From the morphological viewpoint, the magnetic properties depend not only on the chemical position but also strongly on the grain size and roughness [13]. Therefore, the in situ application of high magnetic field during the electrodeposition is exceptionally well suited for tailoring the magnetic properties of Co-based magnetic alloy for MEMS applications, by non-contact controlling compositions, grain shape, grain size and roughness.

1.4. Conclusion

The influence of a parallel (with respect to the surface of the working electrode) high magnetic field on the morphology of electrodeposited CoNi film has been investigated. The FE-SEM figures demonstrated that magnetic field induced drastic morphological variations from short-clavated grain shape to silk-like nanowires. Applied magnetic fields led to an increase of the Co/Ni atomic ratio in the deposits. AFM characterization showed that the grain size and the surface roughness firstly increased with increasing magnetic flux density (0–9 T) and then decreased (9–12 T). The non-monotonic dependence of morphology on magnetic flux density could be explained by the overlapping of cumulative effects of Lorentz force on the current efficiency and of paramagnetic force on the mass transport during the electrodeposition process that induces no obvious modifications on ionic adsorption, hydrogen evolution, and local pH.

Note: The main part, figures, and tables in this Section 1 have been published in Ref., as Li D, Levesque A, Franczak A, Wang Q, et al. Talanta 2013;110(15):66–70.

2. Growth and magnetic properties of the Co–Cu/Cu films electrodeposited under high magnetic field

2.1. Introduction

During the past few years, a great interest was focused on the Co–Cu alloys, mainly because of their applications in magnetic sensing devices. It has been shown that due to the modifiable magnetic characteristics of deposited Co–Cu films, it is possible to obtain some desired properties of this system suitable for sensor applications [14]. Moreover, the Co–Cu alloys are ideal candidates to study the giant magnetoresistance phenomenon (GMR), which can be applied for magnetic recording and in micro-switching devices [15]. The heterogeneous Co–Cu films were usually prepared by physical vapor deposition techniques [16], while the electrodeposition one has been demonstrated useful to prepare films consisting of a metastable solid solution [17-18]. However, the composition and properties of the films are highly dependent on the deposition parameters, irrespective of the production methods.

In electrodeposition, the growth mechanism, morphology, microstructural and magnetic properties of the films depend on electrolyte pH [19], deposition potential or current density [20], intensity of agitation [21], to-be-deposited type of substrate [22], etc.. The morphology of electrodeposited metals is determined by the interplay of various atomistic phenomena occurring in electrocrystallization, in particular, the transport of ions toward the electrode and the dynamics of surface processes [23]. The establishment of a correlation between these phenomena and the formation of morphology is important in order to control film microstructure by monitoring the deposition parameters. It has been recently shown that a superimposition of an external magnetic field during electrodeposition process offers the possibility for tailoring microstructure and properties of the obtained films, what is caused by so-called magnetohydrodynamic (MHD) effect [24]. This effect is mainly considered to influence the ion transport and diffusion process in the electrolyte. Simultaneously, the growth processes of electrodeposited films are affected and changes in the microstructure of deposited films under magnetic electrodeposition conditions are observed [25].

Electrolytic growth of metals differs from other methods, providing the possibility of depositing films with structures different from those formed from the vapor phase. The electrochemical deposition is frequently characterized as a non-equilibrium material processing. Using the non-equilibrium conditions for metallurgic, inorganic, and organic crystal growths, the dendritic patterns can be observed [26]. Dendrite growth is one of the natural phenomena and fundamental of processing materials. During these growths, hierarchical structures consisting of main stems and many side branches are formed. Metallic dendrites are an important class of materials, and they are attractive due to their high surface-area-to-volume ratios and their high degrees of connectivity. These properties are useful for a number of applications, including catalysis [27].

Up to the date, many of the works considering dendritic structure of deposited films get dealed with their formation influenced by the electrodeposition parameters (pH, metallic ion concentration, electrolyte temperature) rather than the influence of a high magnetic field. It is expected that dendrite growth may change its behaviour when depositing under magnetic field conditions and a superimposed B-field may present a new effect on the material performance. It is also believed that it is important to study the bahavior of Co–Cu films electrodeposited under superimposed magnetic field for production of potential sensor applications that properties can be controlled by the deposition parameters. Thus, in this study the compositional, morphological, structural, and magnetic properties are investigated as a function of applied external high magnetic field. It is observed that the changes in the film properties might have come from the variation of Co:Cu ratio in the films produced under magnetic conditions.

2.2. Experimental method

The electrochemical experiments were performed in a conventional three-electrode cell. The working electrode (WE) was a glass substrate of a square size of 10 × 10 mm and 1.1 mm height, covered with ITO (In2O3:SnO2) coating (electric contact layer) and embedded into a cylindrical holder. The counter electrode was made of a platinum plate and the reference electrode was a saturated mercury sulphate electrode (SSE). Electrodeposition process has been carried out in a cylindrical double-wall cell under the conditions listed in Table 2. The electrochemical cell was plunged into the gap of Drusch EAM 20G electromagnet that delivers a uniform horizontal magnetic field parallel or perpendicular to the electrode surface.

DepositChemical agentConcentration mol/LSolution pHSolution temperature,
οC
Current density,
mA/cm2
Depositon time,
sec
Magnetic field,
T
Cu
seed layer
CuSO4.6H2O
H3BO3
0.03
0.4
450–2050
Co–Cu
film
CoSO4.7H2O
CuSO4.6H2O
H3BO3
0.4
0.03
0.4
450–2060≤12

Table 2.

Processing conditions of electrodeposition of the Co–Cu/Cu films.

The electrodeposition process included two steps that were related to: firstly – deposition of Cu seed-layer directly onto ITO/glass substrate in order to improve deposit adherence, secondly – deposition of Co–Cu proper layer. The Cu seed-layer deposition was undertaken without an applied magnetic field, while the Co–Cu layers deposition was performed under the superimposition of magnetic field with the strength up to 12 T in parallel-to-electrode surface orientation. The electrolyte pH was adjusted to proper level by addition of sulfuric acid. All of the electrochemical investigations were carried out using the chronopotentiometry method, where a constant current density was applied. The potential of the working electrode was controlled by means of a potentiostat-galvanostat VersaSTAT 4. Bruker D8 Advance has been employed to obtain X-ray diffraction patterns using standard θ–2θ geometry. Morphology of the obtained coatings has been investigated by scanning electron microscopy HITACHI SU-70 and the chemical composition has been determined by WD-XRF. The hysteresis loops have been measured by means of a vector VSM at room temperature and the magnetic field has been applied in the film in-plane configuration.

2.3. Results and discussion

2.3.1. Film growth

Figure 4 represents the X-ray diffraction patterns of electrodeposited Co–Cu/Cu films with and without a superimposed high magnetic field. The diffractograms indicate the polycrystalline nature of deposited films.

Figure 4.

X-ray diffraction patterns of electrodeposited Co–Cu/Cu films with and without a superimposed magnetic field.

Though the hexagonal centered-packed structure is the most stable phase of bulk cobalt up to 420οC, experimental data reveal the coexistence of both fcc and hcp phases of Co in all Co–Cu/Cu samples. Both phases are closed-packed structures that differ only in the stacking sequence of atomic planes in the cubic (111) direction. Low activation energy for formation of stacking faults could easily lead to formation of both phases in the samples. These phase transition phenomena are also observed in electrodeposited Co–Ni powders of dendritic structure reported in [28]. The lattice parameters (ao) extracted for Co–Cu/Cu films are formed to be very close (3.61–3.55 Å) to each other and are between fcc copper (3.614 Å) and fcc cobalt (3.544 Å). This confirms the formation of Co–Cu solid solution phase. Therefore, the presence of hcp Co may suggest that the Co atoms exist within the CoCu solid solution matrix, as reported in [29-30]. A superimposed high magnetic field does not bring about any phase compositional changes in the deposited films. The X-ray diffraction patterns corresponding to the other Co–Cu/Cu samples deposited under magnetic field conditions were similar. However, the SEM investigations shown in Figure 5 reveal some interesting morphological changes under superimposed high magnetic field.

Figure 5.

SEM images of electrodeposited Co–Cu/Cu films under magnetic field conditions of: (a) –0 T, (b) –6 T, (c) –9 T, (d) –12 T.

The micrographs indicate that the electrodeposited Co–Cu/Cu alloy films are composed of two layers. This feature is especially well observed in the Co–Cu/Cu film deposited without an applied magnetic field (Figure 5a). The bottom layer is a compact thin film, while the surface layer consists of submicron-scale granular-like crystallites that adhere to the bottom layer. A superimposed high magnetic field during electrodeposition (Figure 5b–d) induces the growth of crystallites from both top and bottom layers, respectively. The granular-like nucleus observed at 0 T deposition begins to grow perpendicularly to the substrate surface and the branch-like structure is observed. The particles of a compact bottom layer grow as well, but not as fast as that of the top one. Under the magnetic field of 12 T (Figure 5d), a whole substrate surface is covered by well-defined and well-developed branched crystallites. Furthermore, a closer view of the Co–Cu/Cu film morphology obtained during electrodeposition under 12 T magnetic field (Figure 6) confirms the XRD observations revealing the presence of both fcc Cu and embedded into it hcp atoms of Co. As it can be seen, the Co–Cu/Cu film consisted of the parallel growth of branched features of fcc Cu and hexagonal-shaped crystallites of Co.

Figure 6.

SEM image of the Co–Cu/Cu film electrodeposited at 12 T magnetic field, indicating the privilege growth of fcc Cu crystallistes and embedded into it some hcp atoms of Co.

Thus, the experimental results show that the surface morphology is strongly dependent on a superimposed magnetic field, more exactly on the concentration of each ions affected by an external magnetic field. With the increase of magnetic flux density, the amount of the Cu atoms in the film increased, while that of the Co atoms decreased. (Figure 7).

Figure 7.

Chemical composition of electrodeposited Co–Cu/Cu films under non-magnetic and magnetic conditions.

In the non-magnetic electrodeposition, the Co–Cu/Cu films are composed of almost equal amount of each element, 49 wt% of Co and 51 wt% of Cu. Under high magnetic field conditions, the content of Co decreases down to 1 wt% at 12 T magnetic field with simultaneous increase of Cu content up to 99 wt%. Thus, the surface morphology is strongly influenced by the Cu to Co ratio and changes from the individual particles to submicron-scale branched form, as indicated by SEM images. Therefore, the dendritic-like growth of electrodeposited Co–Cu films containing relatively high amount of Cu may be attributed to short-range crystalline order and diffusive growth of Cu as reported in Refs. [31]. It can be assumed then that a strong growth of (111) plane under magnetic conditions of electrodeposition is assigned to the diffusive growth of fcc Cu structure.

The observed effects of a superimposed magnetic field are due to the magnetohydro-dynamic (MHD) effect caused by a higher convection in the electrolyte, as a result of the Lorentz force [32]: FL=J×B, which is a product of the current density flowing perpendicularly to the magnetic field. From the experimental results, it can be found that the dendrite-like forms were disordered and spacing between them became larger due to the application of the B-field, what is especially well observed during deposition at 6, 9, and 12 T magnetic field (Figure 5b–d). These phenomena clearly indicated the existence of rather intense convection during dendritic-like form growth, which has been also reported in [33]. This convection not only increases the transport of Cu and Co ions toward electrode surface but also the rate of hydrogen evolution (HER) is increased as well, affecting the deposit growth. The presence of hydrogen bubbles may be clearly seen in Figure 2d, where the presence of black holes in the bottom layer can be visible. The action of HER is recognized as a hydrogen gas bubble stirring that charges the hydrodynamic conditions as well as mass transfer in the vicinity of electrode. Hydrodynamic conditions play an important role in determining the final morphology of electrodeposits. This is mainly because as the transport of cations becomes diffusion-limited, the concentration of ions at the cathode becomes zero, leading to instability and triggering the formation of dendrite-like branched forms. Thus, as the first step the Co–Cu layer is formed with a deposition at the fewer surface steps acting as nuclei. A flow of the metal ions to the growing dendritic-like forms is localized and leads to the coalescence of hydrogen bubbles. The high local current densities concentrated around the bubbles due to their non-conductivity causes faster growth of finer crystallites. The microscopic current distribution is changed due to the adsorption of hydrogen bubbles enhanced by a magnetic field. As a final result, the current density distribution and coalescence of hydrogen bubbles create well-defined branched-like structures of different length scales. It is also assumed that dendrite crystals have a higher surface free energy compared to the equilibrium shape of the crystal and are, therefore, thermodynamically unstable compared to the latter. The origin of the dendrite therefore results from the kinetics of crystal growth under the condition where coupling between the surface phenomena (charge-transfer reactions or crystal-growth process) and the bulk transport in fluid phase occur in the system [34]. Moreover, the effect of a superimposed external high magnetic field on the morphology of electrodeposited Co–Cu/Cu alloy films seems to be a very interesting method, regarding on the possibility of electrodeposition of multilayer films, just by applying external B-field during the process.

2.3.2. Magnetic properties

Figure 8 indicates the hysteresis loops of Co–Cu/Cu alloy films electrodeposited with and without a superimposed magnetic field, measured in-the-film-plane at room temperature. It can be clearly seen that it is harder to magnetise the Co–Cu/Cu film grown under superimposed magnetic field. The Co–Cu/Cu films electrodeposited under 0 and 1 T are saturated more easily when compared to the film deposited under 3 T magnetic field, which has more inclined magnetization curve. This may indicate a more disordered arrangement of the Co atoms and, therefore, less degree of ferromagnetic order in the samples deposited under 3 T magnetic field. Furthermore, the coercive field increases for the Co–Cu/Cu samples electrodeposited under magnetic field from 110 Oe at 0 T, up to 200 Oe for the film deposited at 3 T, respectively. This value is in agreement with those usually found in Co–Cu based granular alloys with Co-rich clusters larger than 10 nm [35] and with the Co–Cu alloy containing 15 wt% of Co reported by Gomez et al. [36]. The observed magnetic behavior may be attributed then to the change of Cu:Co ratio in the Co–Cu/Cu film that is caused by the magnetic electrodeposition conditions.

Figure 8.

Magnetic behavior of the Co–Cu/Co films electrodeposited with and without a superimposed magnetic field.

When the electrodeposition process is carried out without an applied magnetic field, the chemical composition of Co–Cu/Cu film is almost equal for each Co and Cu element. A superimposed magnetic field enhances the deposition rate of copper ions, suppressing that of cobalt. Thus, the Co–Cu/Cu films consist mainly of copper crystallites (88 wt%) with low incorporation of cobalt nucleus (12 wt%), which has been already shown in the X-ray diffraction patterns (Figure 4) and confirmed by SEM analysis (Figure 5). Moreover, the compositional investigations (Figure 6) have shown that in the Co–Cu/Cu samples electrodeposited under magnetic field higher than 3 T, a drastical decrease of ferromagnetic Co atoms in the films (1 wt% at 12 T) was observed. Thus, the Co–Cu/Cu films electrodeposited at 6, 9, and 12 T magnetic field were characterized as non-magnetic materials. The presented results are in agreement with the compositional dependence of saturation magnetization and coercive field given by Karaagac et al. [37]. The authors presented the EDX results, which have shown that both magnetization and coercivity are strongly affected by increasing amount of non-magnetic Cu component in the film. This in turn resulted in the increased density of dendritic-like structure of deposited films. Furthermore, the observed magnetic properties of Co–Cu/Cu alloy films are in range of which they may be controlled by electrodeposition parameters, such as superimposed magnetic field, and can be potentially used in sensor technology.

2.4. Conclusion

The influence of high magnetic fields on the growth of electrodeposited Co–Cu/Cu alloy films was studied. Furthermore, the magnetic properties of electrodeposited films in dependence on their microstructure have been determined. The Co–Cu/Cu films were of polycrystalline nature that has been preserved under magnetic electrodeposition conditions. The alloy films deposited without an applied magnetic field possessed a morphology consisting of two layers: compact bottom and top one, of granular-like structure. A superimposed external magnetic field induced the growth of both layers and as a consequence, a well-developed branched structure was formed. This was associated with the increase of Cu content in the films, which rose up drastically under magnetic field conditions. Therefore, a possible explanation for the dendritic-like growth in the surface morphology of electrodpeosited Co–Cu/Cu films may be the diffusive growth of Cu and hydrogen evolution that is favored when external magnetic field is superimposed during the process. The magnetic measurement revealed that magnetic behavior of the deposited films is controlled by the film composition, mainly by the amount of non-magnetic Cu component, which varies under magnetic field conditions. Thus, the morphological and structural changes observed under magnetic electrodeposition conditions increase the surface/volume ratio in the film and enhance their shape anisotropy.

3. Microstructure evolution and magnetic properties of CoFe2O4 thin films prepared by one-step magneto-electrodeposition

3.1. Introduction

Due to their excellent electrochemical performance, higher magnetic anisotropy, and moderate saturation magnetization, iron-cobalt oxides with spinel structures have attracted considerable interests as promising candidates for modern innovative applications, such as gas sensors[38], catalysts for various reactions[39], anodes for lithium ion batteries[40], magneto-optic recording media[41]. Up to now, a variety of methods of synthesizing CoxFe3-xO4 thin films have been developed including sputtering, physical vapor deposition, chemical vapor deposition, pulsed laser deposition, and electrochemical deposition [4245]. Most of these techniques involve a two-step process, first the CoFe alloy precursors formation, and then followed by oxidation at high temperature [46]. However, the high-temperature annealing can cause unwanted reactions between the substrate and the deposited film, which affect the grain size, morphology, chemical stability, and the magnetic property [47]. It is widely accepted that the practical application of CoxFe3-xO4 thin films will depend on the capability of precisely controlling the composition, particle size, and structure during the preparation process. Magneto-electrodeposition could be an alternative method to obtain CoxFe3-xO4 thin films by single-step at low temperature, with precisely controlling the ratio of Co:Fe, morphology, and microstructure, furthermore to tailor the chemical and physical properties of the films. Recently, magnetic fields are widely used to control the mass transfer processes in electrochemical cells, since under magnetic fields a Lorenz force arises, and the magnetohydrodynamics (MHD) convection governs the hydrodynamic boundary layers. Krause et al. [4] found that in electrodeposition under a 1 T magnetic field, Co deposit shape changed into double-sized hexagonal crystallites. The previous study of us also shown that magnetic fields induced drastic morphological variations in the electrodeposited CoNi films from short-clavated grain shape to silk-like nanowires, and the applied magnetic fields led to an increase of the Co:Ni ratio in the deposits. In addition, because of the higher instantaneous current density in comparison to direct current plating, pulse electrodeposition has been found to be an effective means of perturbing the adsorption/desorption processes and hence offers an opportunity of controlling the microstructure of the electrodeposits. This work presents one-step pulse-electrodeposition of Cobalt-Ferrite thin film on the Ti substrate under 1 T magnetic fields. The aim of this work is to study the evolution of composition, surface morphology, and microstructure of cobalt ferrite thin films under the condition of magneto-pulse-electrodeposition.

3.2. Experimental

All electrodeposition experiments were performed in a conventional three-electrode cell without agitation. Polished titanium of 1 cm diameter was used as the working electrode, the counter electrode was a quadrate Pt plate of 1×1cm, and Ag/AgCl/KNO3(sat.) was used as a reference electrode. The electrolyte was composed of 100 mM Co2+, 50 mM Fe3+, 150 mM triethanolamine (TEA), and 2 M NaOH. Pulse-electrodeposition using a potentiostat-galvanostat VersaSTAT 4 was performed at 80℃. The electrochemical cell was plunged into the gap of Drusch EAM 20G electromagnet that delivers a uniform horizontal magnetic field up to 1 T parallel to the electrode surface. To deposit good-quality films, various parameters such as deposition potential, magnetic flux density, deposition time, and duty cycle etc. were optimized as shown in Table 3.

Pulse-potential
V1Ag/AgCl
Deposition time, t1Pulse-potential
V2Ag/AgCl
Deposition time, t2CyclesMagnetic field
–1.17 V ~ –1.19 V1 s–0.95 V4 s3001 T

Table 3.

Processing conditions of electrodeposition of the cobalt ferrite films. [51]

The surface morphology and chemical composition of the deposited films were investigated by scanning electronic microscopy (SEM) appended with an energy-dispersive X-ray spectroscope (EDX, SUPRA 35) at three different positions on the films. The topography were investigated with atomic force microscopy (AFM). For the characterization of the microstructure of the films, X-Ray diffraction (XRD, Bruker D8 Advance) measurements were performed using standard θ-2θ geometry with Cu Kαradiation.

3.3. Results and discussion

Since in case of without magnetic field, the electrodeposited films obtained under the experimental condition in this work were not adherent and covered the substrates bad, all the electrodeposition were optimized by performing in a 1 T magnetic field. Typical SEM and AFM morphologies of cobalt ferrite films pulse-electrodeposited with potential ranged from –1.17 to –1.19 V Ag/AgCl are shown in Figure 9.

Figure 9.

The SEM images of CoxFe3-xO4 thin films deposited at (a) –1.17 V Ag/AgCl; (b) –1.18 V Ag/AgCl;(c) –1.19 V Ag/AgCl potentials assisted by 1 T magnetic field; and the typical AFM image of its at (d) –1.18 V Ag/AgCl.[51]

The figure demonstrates drastic morphological variations with the pulse-potential during the electrodeposition process. The spherical grain linked together to form a coralliform morphology as shown in Figure 9a. While in case of the potential up to –1.18 V Ag/AgCl, the top of the branches in coral seemed to split into many irregular small grains. With the increase of the applied potential to –1.19 V Ag/AgCl, the grains of this coralliform deposit are very similar to the structure of sea anemones, that is, every spherical grain consisted of many crystal whiskers in it. Since the difference in surface analysis between AFM (3D overview in perpendicular to the surface) and SEM (2D morphological structure in parallel to the surface), the AFM image could not answer the morphology evolution of the films, but shown the films are composed of fairly large number of round nanometer-sized grains. The average values of lateral feature size, which can be used to characterize the grain size, were calculated according to AFM images in the following section.

Corresponding to the evolution of the morphology, we use the EDX to measure the change of composition in the deposited films with different pulse-potentials. The results in Table 4 have shown that the Co:Fe ratio depended on the deposition potential. The Co concentrations in the films were lower at less negative potentials and higher at more negative potentials. With the deposition potential that went to more negative values, more Co2+ were reduced at the electrode surface, resulting in an increase of the Co:Fe ratio in the film. These phenomena may be attributed to the MHD effect in a magnetic field, which yields significant convection, and in turn increases the current efficiency. However, due to the different kinetic reaction rate between Fe3+ and Co2+ substitution, the deviation between the Co and Fe concentration at the electrode surface was larger when the growth rate of the film was faster at more negative potentials caused by the MHD effect [48]. The deviation resulted in the Co:Fe ratio in the CoxFe3-xO4 thin films a non-linear variation with the deposition potential. In case of –1.18 VAg/AgCl, the x value was 0.97, which indicates that the film obtained under this condition was composed of almost CoFe2O4. This can be verified in the X-ray diffraction pattern.

Pulse-potentialCo (at%)Fe (at%)O (at%)x
–1.17 V Ag/AgCl
–1.18 V Ag/AgCl
–1.19 V Ag/AgCl
8.6
14.2
12.1
31.1
29.9
30.5
60.3
55.9
57.4
0.65
0.97
0.85

Table 4.

The dependence of the composition of CoxFe3-xO4 (0<x<1) films on the deposition potentials, the x value in CoxFe3-xO4 was calculated based on the Co:Fe ratio in the films.[51]

The X-ray scan of the CoxFe3-xO4 films pulse-electrodeposited on titanium were shown in Figure 10. Despite of the high peaks (marked with black dots) for the substrate (Ti), the films exhibited the diffraction peaks corresponding to both the transition metal oxides (Fe2O3) and the spinel cobalt ferrite (CoFe2O4). At less negative potential, the film was mostly composed of Fe2O3; while at more negative potentials, the film was mostly composed of CoFe2O4. Especially at –1.18 VAg/AgCl, the said planes as (111),(220),(311),(400),(511) corresponded to the CoFe2O4. The peaks shown in Figure 10 agree well with the Co:Fe ratio measured by EDX. For example, the x value in CoxFe3-xO4 films was near unit at –1.18 VAg/AgCl, which implied that by adjusting the potential assisted by magnetic field, we could prepare spinel cobalt ferrite without other oxidations by one-step magneto-electrodeposition method.

Figure 10.

The X-ray diffraction pattern of cobalt ferrite films deposited at different potentials.[51]

Since the morphology and microstructure of the films were dramatically depended on the potential during the electrodeposition, the grain size should also be affected by the MHD effect caused by the interaction between the pulse-current with the magnetic field. We have calculated the crystallites size by use of Scherrer’s equation and AFM measurement (Table 5). The particle size R0 was estimated from AFM analysis by the following equation [49]: R0=(A0πN0)12, in which A0 represents the AFM total image area and N0 is the grain number. According to these two calculated methods, the obtained films consisted of different nuclei sizes due to the changing amplitude of pulse-potential. It should be mentioned that the calculated mean grain size by using Scherrer’s formula according to the X-ray diffraction share the same trend as that measured based on the AFM images. With the potential moving to more negative, the MHD effects increase to bring more Co2+(Fe3+) to the surface of the electrode, which results in the fast nucleation and is responsible for the small grain size at –1.18 VAg/AgCl. However, in case of –1.19 VAg/AgCl, the Co (Fe) deposition becomes diminished, since the hydrogen-ion reduction dominates the total reduction process resulting in the decrease of the current efficiencies of Co (Fe). This may be a reason for the formation of bigger grain by growth at more higher pulse-potential.

Potential (VAg/AgCl)Sherrer (nm)AFM (nm)
–1.17
–1.18
–1.19
33
25
50
47 ± 2
38 ± 2
61 ± 2

Table 5.

Comparison of crystallites size of electrodeposited CoxFe3-xO4 films obtained by calculations based on Scherrer equation and AFM.[51]

From the morphological viewpoint, the properties of the electro-deposited films depend not only on the chemical position but also strongly on the morphology, grain size, and microstructure [50]. Therefore, the in situ application of magnetic field during the pulse-electrodeposition is exceptionally well suited for tailoring the properties of cobalt ferrite, by non-contact controlling Co:Fe ratio, grain shape, grain size, and phase composition. The present work paves the way for optimized electroplated cobalt ferrite thin films by adjusting the potential during one-step magneto-electrodeposition.

3.4. Conclusion

The influence of the interaction between the pulse-potential and a magnetic field with a flux density up to 1 T on the morphology and microstructure of electrodeposited CoxFe3-xO4 film has been investigated. The SEM figures demonstrated that MHD effects induced drastic morphological variations from coral-like to sea-anemone-like. More negative potential led to an increase of the Co:Fe atomic ratio in the deposits. The XRD pattern further verified that at –1.18 VAg/AgCl, we could obtain CoFe2O4 film with ultra-fine grains in it by one-step magneto-electrodeposition. The non-monotonic dependence of morphology, composition, and microstructure on pulse-potential may be attributed to the overlap effects of MHD on the current efficiency and on the hydrogen-ion reduction during the deposition process.

Note: The main part, figures, and tables in this Section 3 have been published on the 9th International Pamir Conference on Fundamental and Applied MHD, Riga, Latvia, June 16–20, 2014, Ref. [51].

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 51425401, 51101032), the Fundamental Research Funds for the Central Universities (Grant Nos. N130402002, N140902001), Agence Nationale de la Recherche France (Programme COMAGNET, Grant No. 2010-INTB-903-01). The authors would like to thank Dr. A. Levesque for her contributions about the SEM, XRD analysis, and useful discussion. The authors are also indebted to Dr. Piort Zabinski from the AGH University of Poland for his support of AFM in this work.

© 2015 The Author(s). Licensee IntechOpen. This chapter is distributed under the terms of the Creative Commons Attribution 3.0 License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Donggang Li, Qiang Wang, Agnieszka Franczak, Alexandra Levesque and Jean-Paul Chopart (December 2nd 2015). The Coupled Magnetic Field Effects on the Microstructure Evolution and Magnetic Properties of As-Deposited and Post- Annealed Nano-Scaled Co-Based Films — Part II, Electroplating of Nanostructures, Mahmood Aliofkhazraei, IntechOpen, DOI: 10.5772/61349. Available from:

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