The values of the passive components for the second‐order Bessel band‐pass filter.
This study presents an apparatus for the measurement of the electrical volume resistivity of concrete structures in civil and industrial constructions in 2.5 accuracy class, which operates at 500 Hz, for measuring the in situ resistivity of concrete in the range of 5–100 Ωm that is immune to errors due to the polarization phenomena at the interface probe/concrete sample. Also, a quench protection active system (QPS), which works in tandem with a superconducting coil structures (SCSs), in order to prevent the damaging effects when the coil structures pass from the superconducting state into normal conduction state (quench), is presented. An SCS made of YBCO tape high‐temperature superconductor (HTS) type, with a critical temperature of 92 K, has been experimented. In order to minimize the heat transfer influx by convection, the SCSs are confined to a cryostat, which is vacuumed at about 0.001 mbar. The working temperature of the HTS coil structures is about 77 K, ensured by liquid nitrogen as cryogenic agent. Finally, the measurement of the electrical resistance of the sensing element (SE) as part of the resistive‐type gas sensor is shown. The SE is placed on a Wheatstone bridge. The electrical resistance of the SE is variable by an amount ΔR, on when all the resistances of a Wheatstone bridge are nominally equal.
- electrical resistivity
- reinforced concrete structures
- coil structures of superconducting
- quench protection
- sensing element
- gas sensors
1. Measurement of the electrical resistivity of concrete structures
Measurement of the electrical volume resistivity of concrete structures in civil and industrial constructions shows a particular importance in order to establish the status thereof. In practice, often, it counts the problem of investigating the degradation of reinforced concrete that was not provided with electrodes for monitoring. The degradation of reinforced concrete structures is a complex process concerted and synergy action due to several requests for the nature of the physical (mechanical stress, shock and vibration, weather air/diurnal temperature variations, especially around the freezing temperature of water, etc.), chemical (salinity of the soil and/or of the phreatic water is in contact with the concrete, the content of aggressive atmospheric pollutants, etc.) and microbiological (load microbiological alteration of the exploitation environment). Measurement of the electrical volume resistivity of concrete structures can be achieved by using a quadrupole consisting of the power electrodes, E1, E2, by means of which I [A], the current and the measurement electrodes, E3, E4, to measure a potential difference, ∆V [V], are injected (Figures 1 and 2). An apparent resistivity  ρapp [Ωm] is obtained
Here, k is a sample‐specific geometrical factor and I [A] is the injected current. In this case, the RMS value of the injected current is 1 mA. Based on the technical solutions protected by patent application , we prototyped an apparatus for measuring the in situ resistivity of concrete structures.
Measurement apparatus of the in situ electrical resistivity of concrete structures is conceived modularly having as components the following electronic modules, as shown in Figures 1 and 2: constant current generator module positions 1, 2 and 3, signal conditioning module position 4, band‐pass filter position 5, rectifier module position 6, measurement and display module positions 7–9, and window comparator module positions 10–12 [2–6]. The errors due to electrochemical polarization phenomena are eliminated by powering the current electrodes E1, E2 with a constant of 1‐mA intensity sinusoidal current , of 500 ± 5 Hz. The constant current generator module is made by cascading the standard generator sine function sub‐module and of constant voltage/current converter sub‐module of 1 mA RMS. Accompanying the current flow through the concrete sample, a voltage drop of approx. ΔU proportional to the resistivity of concrete, ρ, is recorded at the central contacts of the concrete sample, E3 and E4.
The measuring probe is of special construction, so as to ensure the parallelism of the electrodes E1–E4, Figures 1 and 2 and equal distance between them. The concept of the measuring probe allows easy manoeuvrability in the field, regardless of the orientation of the measuring plane (horizontal, vertical walls and beam‐reinforced concrete) and simultaneously uniform pressing of the electrodes and even on surfaces with dislevelments up to 15 mm. In order to ensure as good as possible constant electric contact between electrodes E1–E4 and the measured concrete structures surface, they are provided with sponge patches capped by cotton cloth discs (protective bags attached to the electrodes by snap rings). To eliminate the errors due to both AC and DC stray currents, low and high frequency, the signal ΔU at E3, E4 electrodes is passed through a ‘band‐pass’ filter of 500 ± 10 Hz  (with minimum 40‐dB attenuation for ±150 Hz).
One of the important electronic modules is the active fourth‐order band‐pass filter. The band‐pass filter is made by cascading a second‐order active band‐pass Bessel filter with a second‐order active band‐pass Butterworth filter. Both filters are realized with the use of the Texas Instruments integrated active filters UAF42 . Bessel and Butterworth second‐order band‐pass filter design was made by using software program FilterPro™ developed by Texas Instruments Company dedicated to developing applications for the integrated circuit UAF42 Texas Instruments—active filter.
With notations required by Texas Instruments, the values of the passive components are obtained from Table 1 for the second‐order Bessel band‐pass filter and from Table 2 for second‐order Butterworth band‐pass filter, by running the software program FilterPro™.
|f0 [Hz]||R2A [kΩ]||RF1 [kΩ]||RF2 [kΩ]||C1A||C2A||RQ [kΩ]|
|f0 [Hz]||R2A [kΩ]||RF1 [kΩ]||RF2 [kΩ]||C1A||C2A||RQ [kΩ]|
It can be noted, Figures 3 and 4, that the integrated active filter circuit UAF42  contains an operational amplifier unused for filtering function. This is used to achieve signal conditioning, the amplification after filtration, respectively.
Input voltage of the signal conditioning electronic block is sinusoidal, having amplitude peak to peak in the range of 10–20 mV, recorded at the central contacts of the concrete sample, E3 and E4, Figure 2. This voltage is amplified to the level of 500–1000 mV peak to peak, by using the fourth operational amplifier available into the integrated circuit UAF 42 Texas Instruments—active filter, Figure 3, used in the inverting connection. In this case, the gain, as the ratio of the output voltage at this operational amplifier (i.e. from input of the second‐order Bessel filter) and the input voltage at the inverting connection of the operational amplifier, Figure 3, can be written as
Input voltage from the second‐order active filter Butterworth is sinusoidal, having maximum amplitude peak to peak of 1000 mV. The filter is active, so that the maximum output voltage amplitude is the same, 1000 mV peak to peak. This voltage is amplified to the level of 5000 mV peak to peak by using the fourth operational amplifier available into the integrated circuit UAF 42 Texas Instruments—active filter, Figure 4, used in the inverting connection. In this case, the gain, as the ratio of the output voltage at this operational amplifier and the input voltage at the inverting connection of the operational amplifier, Figure 4, can be written as
Experimentation of the second‐order band‐pass active filter Bessel was performed as follows:
at the input of the second‐order band‐pass active filter Bessel, Figure 3, a sinusoidal voltage with a peak‐to‐peak amplitude of 1000 mV and a frequency range of f = 50–1000 Hz, from the arbitrary function generator FLUKE 281, was applied;
the output of band‐pass filter Bessel is connected to the LeCroy 324 digital oscilloscope channel 1, in order to measure the amplitude of the output voltage;
by using the entire spectrum of the frequencies, in the range of f = 50–1000 Hz, for the sine wave voltage applied to the input, the characteristic of the second‐order band‐pass active filter Bessel, Figure 5, can be drawn.
Experimentation of the second‐order band‐pass active filter Butterworth was performed as follows:
at the input of the second‐order band‐pass active filter Butterworth, Figure 4, a sinusoidal voltage with a peak‐to‐peak amplitude of 1000 mV and a frequency range of f = 50–1000 Hz, from the arbitrary function generator FLUKE 281, was applied;
the output of band‐pass filter Butterworth is connected to the LeCroy 324 digital oscilloscope channel 2, in order to measure the amplitude of the output voltage;
by using the entire spectrum of the frequencies, in the range of f = 50–1000 Hz, for the sine wave voltage applied to the input, the characteristic of the second‐order band‐pass active filter Butterworth, Figure 6, can be drawn.
The fourth‐order filter, obtained by cascading the two second‐order filters, Bessel and Butterworth, was tested in the same conditions. The characteristic of the fourth‐order band‐pass active filter is shown in Figure 7.
In order to eliminate the measurement error due to the polarization phenomena between the reinforced concrete surface (conductor environment of type II) and the electrodes E1, E2 (conductor environment of type I), the apparatus includes the current generator module, made by cascading the standard generator sine function sub‐module of 500 ± 5 Hz and of constant voltage/current converter sub‐module of 1 mA RMS.
In order to eliminate the measurement error due to the potential leakage currents both in DC and in AC, of low and high frequency, and of the interference signals, respectively, with frequencies below 350 Hz and above 1 kHz, the apparatus includes the fourth‐order band‐pass active filter made by cascading the two second‐order band‐pass active filter modules Bessel and Butterworth filters. As I pointed out, the apparatus for the measurement of the electrical volume resistivity of concrete structures in civil and industrial constructions provides the measurements of resistivity in the range of 5–100 Ωm, the 2.5 accuracy class. By using a window comparator electronic module, Figure 1, the apparatus allows the optical viewing of the values less than 5 Ωm and over 100 Ωm, through two leads. The apparatus shows the good functional stability, observed during experiments for a wide range of types of concrete structures. Also, the calibration can be done easily by using a potentiometer P1, Figure 4.
As concrete structures degrade (through decrease of the alkalinity, carbonation, increase in chloride content, etc.), the resistivity decreases substantially . Today at important buildings, from design phase is provided embedding electrodes that allowing both measuring/monitoring of the concrete resistivity and determination of the potential of corrosion of the reinforcement [9–11].
Experiments were performed in two stages.
Stage 1. Calibration
Standard concrete sample (SCS) for which precisely the electrical resistivity is known, determined by the classical method , is measured in order to calibrate the apparatus:
(A1) it is checked using a ‘TRUE RMS AC + DC’ multimeter set on the mA scale and having probes connected to E1 and E2 electrodes, respectively, that RMS value of the injected current is to 1 mA;
(B1) the sponge and protective bag for probes (up to saturation) are soaked with a solution of 3–5% NaCl concentration;
(C1) the electrodes E1–E4 are applied on the SCS sample surface;
(D1) the measurement apparatus of the in situ electrical resistivity of concrete structures is calibrated, through adjusting the amplification of the instrumentation amplifier, by rotating the calibration potentiometer on the front panel, Figures 1 and 2, until the apparatus indicates the known resistivity value of the SCS sample.
Stage 2. Measuring the electrical resistivity of concrete structures
(A2) before performing a new measurement, the sponge and the protective bag are soaked again (to saturation) with a solution of 3–5% NaCl concentration;
(B2) the electrodes E1–E4 are applied on the concrete structure surface;
(C2) the measured value of the electrical resistivity of concrete structures is read on the digital display of 3 1/2 digits.
2. Protection to quench hazard in high‐temperature superconducting coil structures
2.1. The case of a single HTS superconducting coil
The superconducting coil structures can get out of the superconducting state (can normalize), for various reasons, such as the following:
if temperature exceeds the critical temperature;
if the injected current growth slope is too steep, after entering the superconducting coil structures in the superconducting state and stabilizing to the temperature regime at a value of 77 K (liquid nitrogen temperature);
if the injected current through the superconducting coil structures exceeds the critical current;
if the superconducting coil structures are subjected to mechanical vibrations .
Therefore, the superconducting coil structures always work in tandem with a protection system, called quench protection, in order to prevent the damaging effects of their exit from the superconducting state, for the reasons previously described.
This study refers to the quench protection active system (QPS), which works in tandem with a superconducting coil structure. In our case, the superconducting coil structures are made from a tape of material based on YBCO, having a critical temperature of 92 K. Since cooling is made with liquid nitrogen, the working temperature of the superconducting coil structures is in the temperature range of 77 K. The superconducting coil structures are arranged in a cryostat within which a high vacuum of about 0.001 mbar is achieved, in order to minimize the heat transfer to the outside by removing the convective heat transfer. Also, the superconducting coil structures are immersed in liquid nitrogen. Table 3 presents the electrical resistance of the superconducting coil structures versus the cryostat temperature.
|Temperature in the cryostat T [K]||The measured resistance of the superconducting coil R [Ω]*|
At the critical temperature, the resistance of the coil temperature ensemble is 0.52 Ω (superconducting coil resistance to which the connecting wire resistance and the junction resistance are added). All the connecting wires are made of superconducting material YBCO, HTS type that has a thermal conductivity of ∼1 W/mK. The connecting wires are introduced in a sheath of nonmagnetic stainless steel pipe and the terminals are made by copper. Bonding the HTS strip of copper terminals is carried out with a mixture of indium and 5% Ag (to minimize the junction resistance).
Figure 10 presents the variation of the voltage measured on the superconducting coil structures after entering into the superconducting state, depending on the injected current. The current is injected through the superconducting coil structures, with a slope of 1 A/s  by the programmable power supply type AMI 03300PS‐430‐601. Critical current value is determined from the curve U = f (I), Figure 10, by coming down with a tangent at exponential area of the curve. The value of the critical current was determined using this procedure and it is 120 A. The intersection with current axis, Figure 10, will give the exact value of critical current of the superconducting coil structures at 77 K. For a current greater than or equal to the critical current, the voltage measured on the superconducting coil structures has a sudden increase. The superconducting coil structures get out of the superconducting state, and the quench protection must act accordingly in order to prevent the damaging effects.
The quench protection system (QPS) is made of two ultrafast switches made with high‐power IGBT's transistors (Isolate Gate Bipolar Transistor). The key parameters of the active protection system are as follows:
The maximum quench detection time is tQ = 800 ns;
The actual reaction time is in the interval tR = 2.78–3.5 μs;
The energy is discharged in the range of 1–10 kJ.
A quench active protection system, Figure 11, for HTS coil structures must solve the following problems:
The detection of the QUENCH.
Decoupling the HTS coil structures from the programmable power supply.
The coupling of the HTS‐type superconducting coil structures on a discharge resistance RD. In this case, the magnetic energy stored in the coil inductivity L, WM = Li2/2, is dissipated through Joule effect, WJ = Ri2, by the discharge resistance RD and the dynamic resistance of the semiconductor device that compose the command power electronic switch.
To comply with its aim, the quench protection active system, Figures 11 and 27, must comprise the following parts: ultrafast electronic switches, T1 and T2 (K1 and K2, respectively), an electronic circuit for quench detection and a discharge resistance, RD.
The design of the quench protection system (QPS) is modular, and it comprises the electronic modules presented next.
Quench detection and signal processing electronic module. This module, named 1. on the Figure 11, contains the following parts:
An operational amplifier electronic block with galvanic isolation;
A precision, differential amplifier electronic block with the common mode rejection factor CMRR = 100 dB;
An amplifier electronic block with the gain A = 10 and CMRR = 100 dB;
An electronic block, which performs the module mathematical function;
An optical interface electronic block, double opto‐coupler, with TTL signals recovery;
A logic sequence programming electronic block.
The power electronic module. This module, named 2. on the Figure 11, comprises the following electronic blocks:
Two drivers electronic blocks IGBT T1/IGBT T2 (Block 1 Driver IGBT T1 and Block 2 Driver IGBT T2);
An electronic block of ultrafast switches made with the power transistors IGBT T1/IGBT T2;
A discharge resistance block, RD.
Electronic module of voltage stabilized power supplies. This module, named 3. on the Figure 11, comprises the following blocks:
The ±12 VDC differential power supply for powering the analogical electronic circuits and the power supply +5 VDC for powering the digital electronic circuits;
The ±15 and ±12 VDC differential voltage power supply for powering the operational amplifier electronic circuit with optical isolation for the quench signal processing;
The 2x20 VDC power supply with galvanic isolation for powering the drivers that command the two IGBT power transistors, T1 and T2.
The discharge resistance RD, Figures 11 and 12, was made from 99.9% pure Cu wire, solenoid shape, having four turns with section Φ = 2 mm, with the wire diameter of D = 50 mm, and the value of the DC resistance of RD = 0.128 Ω. The DC measurement was performed with the Agilent 34461A multimeter.
One of the important electronic modules is the amplifier block with galvanic isolation. Design of the amplifier block with galvanic isolation, Figure 13, is made with the integrated circuit IC1 type ISO 124, Burr Brown manufacturing by Texas Instruments. It is noticed that the useful signal is acquired through a divider, made with four potentiometers P1–P4, respectively. In this way, the dividing factor is adjustable allowing the useful signal threshold setting for which the voltage of the amplifier input is interpreted as quench voltage. Also, it can be seen the separation way of the power supply, Figure 13. A differential stabilized power supply of DC voltage of ±15 VDC, which is powering the first part of the amplifier block with galvanic isolation type ISO 124, which acquires the useful signal and a differential stabilized power supply of DC voltage of ± 12 VDC, which is completely galvanic isolation from first is powering the part of the output amplifier.
The power electronic module of the active electronic protection system QPS contains two electronic ultrafast switches made with the power transistors IGBT T1/IGBT T2 type Fuji 2MBI600NT—060, Figures 14 and 15, two drivers electronic blocks IGBT T1/IGBT T2, type VLA 517—01R—FUJI  Figures 16 and 17, and a discharge resistance RD, Figures 11 and 12, with the role of picking the energy stored in a superconducting coil that is composed of two identical sections, serially connected, when at least one of the coils is normalized.
The first ultrafast switch made with the power transistors IGBT T1, Figures 11 and 18, allows the supply of the superconducting coil from the voltage power supply, in normal operation, as well as voltage power supply decoupling when the coil is normalized. The second switch made with the power transistors IGBT T2, Figures 11 and 18, enables the coupling of the superconducting coil on the discharge resistance RD, when at least one of the coils L1 and L2 serially connected is normalized (leaves the superconducting state).
Five possible cases of conduction are distinguished for ultrafast switches made with IGBT power transistors T1/T2, according to the conduction state of the two identical sections of superconducting coil L1 and L2 as follows:
Coil inductance L = L1 + L2 is in the superconducting state, in which case IGBT power transistor T1 is in a state of conduction (ON) and IGBT power transistor T2 is found in the locked state (OFF), Figure 19;
Inductance coil L1 was normalized and both IGBT power transistors T1 and T2 are in a state of conduction (ON) for a period of tM1 = 300 ns, Figure 20;
Inductance coil L1 was normalized and IGBT power transistor T1 is in the locked state (OFF) and IGBT power transistor T2 is found in a state of conduction (ON), Figure 21;
Inductance coil L2 was normalized and both IGBT power transistors T1 and T2 are in a state of conduction (ON) for a period of tM1 = 300 ns, Figure 22;
Inductance coil L2 was normalized and IGBT power transistor T1 is in the locked state (OFF) and IGBT power transistor T2 is found in a state of conduction (ON), Figure 23.
The logic sequence programming electronic block, Figure 11, performs the following functions:
Should the coils L1 and L2 work in their superconducting state, in which case the IGBT power transistor T1 will be in the conducting state (saturated), and the IGBT power transistor T2 is in the locked state. In this case, through the superconducting coil L = L1 + L2, Figure 11 flows the current I1 = 80A.
When the quench phenomenon appears, when at least one of the coils L1 or L2 is normalized, VCOMMAND transits from ‘0’ logic to ‘1’ logic. VCOMMAND triggers the voltage UM1 over a period tM1 and both the IGBT transistors T1 and T2 are conducting, for a period of tM1 = 300 ns. In the following sequence, Figures 24–26, the IGBT power transistor T1 will be in the locked state, and the IGBT power transistor T2 will be in the conducting state. Note that the UQ1 is the command voltage applied onto IGBT T1 and the UQ2 is the command voltage applied onto IGBT T2. In this way, the superconducting coil L = L1 + L2 will be in parallel with the discharge resistance RD. The magnetic energy accumulated in the superconducting coil L = L1 + L2 is dissipated through the protection resistor, discharge resistance RD. The energy is discharged in the range of 1–10 kJ.
From Figures 25 and/or 26, the maximum quench detection time of the QPS as tQ = 800 ns can be determined by assessing transition from logic zero to logic one (positive logic) of the signal UQ2 or by assessing transition from logic one to logic zero (positive logic) of the signal UQ1, respectively. The reaction time of the QPS, tR,will take into account and by the actual transition from logic zero to logic one (positive logic), ‘ton’, for both the command driver's and the IGBT's transistors, respectively. Thus, the transition from logic zero to logic one and transition from logic one to logic zero, respectively, for the driver command type VLA 517—01R—FUJI , ton‐driver = toff‐driver = tDRIVER = 1.5 μs.
Also, the transition from logic one to logic zero for high‐power IGBT transistor type Fuji 2MBI600NT – 060 toff‐IGBT is determined based on the dispersion of such semiconductor device fabrication: (toff‐IGBT)MIN = 0.48 μs and (toff‐IGBT)MAX = 1.20 μs. The reaction time tR can be calculated as follows:
The minimum reaction time is
tRMIN = tQ + tDRIVER + (toff– IGBT)MIN = 0.8 µs + 1.5 μs + 0.48 μs = 2.78 μs.
The maximum reaction time is
tRMAX = tQ + tDRIVER + (toff – IGBT)MAX = 0.8 µs + 1.5 μs + 1.2 μs = 3.5 μs.
The actual detection time lies in the interval tR = 2.78–3.5 μs.
Advantages of the QPS , which provides the HTS coil structures protection to quench, are as follows:
Makes a quench detection under quench detection time t0 = 800 ns;
Makes a decoupling of the power supply, which supplies the superconducting coil through an electronic ultrafast switch, capable of commuting under 1 µs;
Makes the crossing of the superconducting coil in parallel on a discharge resistance, RD, after the decoupling from the voltage power supply, through an electronic ultrafast switch capable of commuting under 1 µs.
2.2. The case of a variable number of HTS superconducting coils, which may form dipolar, cuadripolare, sextupolare or octupolare structures
Active protection for multipolar set of superconducting coils, whose block diagram is given in Figure 27, operates in the following way:
Constructively, a multiple number of 2, the superconducting coils 2–8 multipolar BS1, …, BS8 superconducting coils forming the multipole assembly are connected in series. A multiple number of 2, from 2 to 8 electronic amplifiers with galvanic isolation blocks, equal to the number of superconducting coil assembly previously established, BIG1, BIG2, …, BIG8, having the role of individually conditioning the useful signal originated from each superconducting coil in part, are disposed in parallel with each superconducting coil in part, Figure 27. The two ultrafast electronic switches, Figure 27, K1 and K2, respectively, perform connecting and disconnecting the power source voltage and discharge resistance RD, respectively .
The first ultrafast electronic switch, K1, allows for powering the superconducting multipolar coils BS1, …, BS8 from the power supply voltage, in normal operation, when all the superconducting coils are in a superconducting state. Also, the first ultrafast electronic switch, K1, allows power supply decoupling when at least one of the multipolar superconducting coils assemblies BS1, …, BS8 was normalized.
The second ultrafast electronic switch, K2, allows coupling of the superconducting coils multipolar BS1, …, BS8 on a discharge resistance, RD, in the case when at least one of the multipolar superconducting coils assemblies BS1, …, BS8 was normalized. Also, the second ultrafast electronic switch K2 allows multipolar superconducting coil BS1, …, BS8 decoupling from discharge resistance, RD, in normal operation, when all the superconducting coils are in a superconducting state.
One of the important electronic modules is the precision analogue summing circuit, Figures 27 and 28. The precision analogue summing circuit is achieved using three analogue‐integrated circuits type AMP 03, instrumentation operational amplifier from Analog Devices . Each of these operational amplifiers is used in specific connection of summing . At the exit VOUT, Figure 28, we obtain the sum of all four signals that are applied to the inputs IN1, IN2, IN3 and IN4.
The performance of an active electronic protection system (QPS), in both cases A and B, can be evaluated by the visualization and recording of dissipated energy on the discharge resistance RD, Figures 11 and 27, by using the system shown in Figure 29. When a high‐temperature superconductor (HTS) coil structure that is in a superconductive state is shifting into normal conduction state (quench), the evolution of voltage drop on the superconducting coil structures will be that around the critical current, Figure 10 and Table 4.
|I [A]||U [mV]|
The QPS will detect a quench situation. By multiplying the instantaneous current i(t) that passes through the discharge resistance RD with the instantaneous voltage u(t) from the discharge resistance RD, the instantaneous power is obtained, Figure 29. The dissipated energy on the discharge resistance RD is obtained by integrating the instantaneous power.
The YBCO tape high‐temperature superconductor, with a critical temperature of 92 K, is used in the construction of superconducting coils tested. The superconducting coil structures are immersed to a cryostat filled with liquid nitrogen as cryogenic agent to decrease the working temperature of the HTS coil structures at about 77 K. Heat transfer by convection is minimized by creating a vacuum at a level of 0.001 mbar.
The experimental results confirm that the quench protection works as expected for the working conditions of the YBCO tape HTS coil structures. Figure 30 shows the QPS of the superconducting coil during the experiments.
3. Measurement of the electrical resistance of the sensing element as part of the resistive type gas sensors
Rare‐earth oxides have been extensively explored for several advanced applications, such as in electronics, optics and heterogeneous catalysis, thanks to their peculiar properties arising from the availability of the 4f shell . Ceria, either in its pure form or doped with cations Ca2+, Mg2+, Sc2+, Y3+, Zr4+, potentially has a wide range of applications like gas sensors , oxygen pumps and amperometric oxygen monitors and is adopted in three‐way catalysts for reducing the emission of the toxic pollutants (CO, NOx and hydrocarbons, etc.) from automobile, owing to its high oxygen storage capacity, associated with its rich oxygen vacancies and low redox potential between Ce3+ and Ce4+. CeO2 doped with rare‐earth ions exhibits high oxide ion conductivity at a relatively low temperature (about 600°C) and thus has been applied in solid oxide fuel cells [21, 22]. In case of rare‐earth‐doped CeO2, the Y2O3 (YDC) system has been studied due its relatively high electrical conductivity and the relative abundance of the yttrium element. The measured electrical conductivity value is 3.0 × 10−3 S/cm at 500°C and 6.0 × 10−2 S/cm at 700°C. If the sensing element is resistance, as components of the gas sensor can range from less than 100 ΩΩto several hundred of kΩ, depending on the sensing element design and the physical environment in which to be measured, you can use two main methods, as follows: measuring resistance indirectly, using a constant current source or measuring resistance using the Wheatstone bridge for which a single element varies.
3.1. Measuring resistance of the sensing element indirectly, by using a constant current source
If the power dissipation through the resistive sensing element is small, a technique for measuring resistance can be used, as shown in Figure 31. This technique consists of measuring the voltage output when a constant current is injected through the resistive sensing element, using an accurate means of measuring the voltage and an accurate current source, respectively. Thereby, any change in the current will be interpreted as a resistance change.
3.2. Measuring resistance of the sensing element by using the Wheatstone bridge for which a single element varies
A Wheatstone bridge measures resistance indirectly by comparison with a similar resistance, Figure 32(a). In this case, all the resistances are nominally equal, but one of them (the sensing element) is variable by an amount ΔR. As the equation indicates, Figure 32(b), the relationship between the bridge output and ΔR is not linear. By using an instrumentation operational amplifier, (in‐amps) as a Wheatstone bridge amplifier, is performed a better gain accuracy. Usually, this gain accuracy is set with a single resistor, RG and does not unbalance the bridge .
Excellent common mode rejection can be achieved with modern in‐amps. The excitation voltage VB is typically 10 VCC stabilized.